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The amino acid sequence of bothropstoxin-II, an Asp-49 myotoxin from Bothrops jararacussu (Jararacucu) venom with low phospholipase A2 activity

J Protein Chem. 1998 May;17(4):381-6. doi: 10.1023/a:1022563401413.

Abstract

The complete amino acid sequence of bothropstoxin-II (BthTX-II), a myotoxin isolated from Bothrops jararacussu snake venom, is reported. The results show that BthTX-II is an Asp-49 phospholipase A2 (PLA2)-like protein composed of a single polypeptide chain of 120 amino acid residues (Mr = 13,976), containing one methionine and 14 half-cystines. Despite a high degree of homology with other PLA2's and the presence of the strategic residues known to compose the Ca2+-binding loop, namely Tyr-28, Gly-30, Gly-32, and especially Asp-49, besides His-48, Tyr-52, and Asp-99, all of them directly or indirectly involved in catalysis, BthTX-II revealed a very low PLA2 activity when assayed on egg yolk phosphatidylcholine. We attribute this low catalytic activity to the existence of extra mutations, e.g., Trp-5 for Phe-5, which points to the need of considering other strategic positions, since only Lys-49 PLA2's have been considered to be devoid of this enzymatic activity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Aspartic Acid / chemistry*
  • Bothrops
  • Chromatography, High Pressure Liquid
  • Crotalid Venoms / chemistry*
  • Crotalid Venoms / metabolism
  • Electrophoresis, Polyacrylamide Gel
  • Group II Phospholipases A2
  • Hydrolysis
  • Molecular Sequence Data
  • Phospholipases A / chemistry*
  • Phospholipases A / isolation & purification
  • Phospholipases A / metabolism*
  • Phospholipases A2
  • Reptilian Proteins
  • Serine Endopeptidases / metabolism

Substances

  • Crotalid Venoms
  • Reptilian Proteins
  • Aspartic Acid
  • Phospholipases A
  • Group II Phospholipases A2
  • Phospholipases A2
  • bothropstoxin II
  • Serine Endopeptidases
  • glutamyl endopeptidase