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Kinetics and mechanism of thermal decomposition of nitric acid in sulfuric acid solutions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The initial rates of thermal decomposition of HNO3 in aqueous and nonaqueous H2SO4 media were measured; their temperature dependences were determined for HNO3-H2SO4 systems.

  2. 2.

    The thermal decomposition of HNO3 in sulfuric acid solutions proceeds via the decomposition of N2O5.

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Authors and Affiliations

  1. Chernogolovka Branch, Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    A. I. Kazakov, Yu. I. Rubtsov, L. P. Andrienko & G. B. Manelis

Authors
  1. A. I. Kazakov
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  2. Yu. I. Rubtsov
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  3. L. P. Andrienko
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  4. G. B. Manelis
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2158–2161, October, 1987.

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Kazakov, A.I., Rubtsov, Y.I., Andrienko, L.P. et al. Kinetics and mechanism of thermal decomposition of nitric acid in sulfuric acid solutions. Russ Chem Bull 36, 1999–2002 (1987). https://doi.org/10.1007/BF00961972

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  • DOI: https://doi.org/10.1007/BF00961972

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