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High-efficiency self-repairing anticorrosion coatings with controlled assembly microcapsules

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Abstract

Based on the principle of emulsion technology and self-assembly of materials, aromatic isocyanate derivatives easily reacted with polyols to form polyurethanes, and nonaromatic isocyanate derivatives were responsible for generating the capsule core of the self-healing microcapsules. In this paper, epoxy resin-based self-healing smart anticorrosion coatings with different types of microcapsules were prepared. The cores were IPDI/TMP–IPDI/DiPE–IPDI. The optimal conditions for the preparation of self-repairing microcapsules to achieve controlled assembly of a microcapsule material structure were determined. We set up a test model, incorporating thermal analysis, depression repair level calculation, salt spray corrosion tests, adhesion tests, and other indicators of application performance. The corrosion resistance was in the order: DiPE–IPDI > TMP–IPDI > IPDI > pure epoxy. The experimental results showed a self-healing efficiency of more than 80% for cores of DiPE–IPDI. Taking into account the overall properties, the best-quality coatings contained approximately 5% microcapsules of DiPE–IPDI.

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References

  1. White SR, Sottos NR, Geubelle PH, Moore JS, Kessler MR, Sriram SR, Brown EN, Viswanathan S (2001) Autonomic healing of polymer composites. Nature 409:794–797

    Article  Google Scholar 

  2. Evers CHJ, Luiken JA, Bolhuis PG, Kegel WK (2016) Self-assembly of microcapsules via colloidal bond hybridization and anisotropy. Nature 534:364–368

    Article  Google Scholar 

  3. Zhu DY, Rong ZM, Zhang MQ (2015) Self-healing polymeric materials based on microencapsulated healing agents: from design to preparation. Prog Polym Sci 49:175–220

    Article  Google Scholar 

  4. Wei HG, Wang YR, Guo J, Nancy ZS, Jiang DW, Zhang X, Yan XR, Zhu JH, Wang Q, Shao L, Lin HF, Wei SY, Guo ZH (2015) Advanced micro/nanocapsules for self-healing smart anticorrosion coatings. J Mater Chem A 3:469–480

    Article  Google Scholar 

  5. Koh E, Kim NK, Shin J, Kim YW (2014) Polyurethane microcapsules for self-healing paint coatings. RSC Adv 4:16214–16223

    Article  Google Scholar 

  6. Credico BD, Levi M, Turri S (2013) An efficient method for the output of new self-repairing materials through a reactive isocyanate encapsulation. Eur Polym J 49:2467–2476

    Article  Google Scholar 

  7. Schreiner C, Scharf F, Stenzel V, Rössler A (2017) Self-healing through microencapsulated agents for protective coatings. J Coat Technol Res 14:809–816

    Article  Google Scholar 

  8. Yi H, Yang Y, Gu X, Wang CY (2015) Multilayer composite microcapsules synthesized by Pickering emulsion templates and their application in self-healing coating. J Mater Chem A 3:13749–13757

    Article  Google Scholar 

  9. Yang Y, Wei Z, Wang C, Tong Z (2013) Versatile fabrication of nanocomposite microcapsules with controlled shell thickness and low permeability. ACS Appl Mater Interfaces 5:2495–2502

    Article  Google Scholar 

  10. Mauldin TC, Rule JD, SottosNR White SR, Moore JS (2007) Self-healing kinetics and the stereoisomers of dicyclopentadiene. J R Soc Interface 4:389–393

    Article  Google Scholar 

  11. Guadagno L, Raimondo M, Naddeo C, Longo P, Mariconda A, Binder WH (2014) Healing efficiency and dynamic mechanical properties of self-healing epoxy systems. Smart Mater Struct 23:045001–045011

    Article  Google Scholar 

  12. Wang HP, Hu SQ, Cai SJ, Yu F (2014) Preparation and properties of bisphenol A epoxy resin microcapsules coated with melamine–formaldehyde resin. Polym Bull 9:2407–2419

    Article  Google Scholar 

  13. Liu F, Zhang ZB, Xu LL, Tang MS (2012) Mechanical strength and resistance to ultraviolet radiation of repairing mortars Based on Epoxy Resin. Adv Mater Res 391–392:807–811

    Google Scholar 

  14. Haghayegh M, Mirabedini SM, Yeganeh H (2016) Microcapsules containing multi-functional reactive isocyanate-terminated polyurethane prepolymer as a healing agent. Part 1: synthesis and optimization of reaction conditions. J Mater Sci 51:1–13. https://doi.org/10.1007/s10853-015-9616-6

    Article  Google Scholar 

  15. Haghayegh M, Mirabedini SM, Yeganeh H (2016) Preparation of microcapsules containing multi-functional reactive isocyanate-terminated-polyurethane-prepolymer as healing agent, part II: corrosion performance and mechanical properties of a self-healing coating. RSC Adv 6:50874–50886

    Article  Google Scholar 

  16. Huang MX, Yang JL (2011) Facile microencapsulation of HDI for self-healing anticorrosion coatings. J Mater Chem 21:11123–11130

    Article  Google Scholar 

  17. Huang MX, Yang JL (2014) Salt spray and EIS studies on HDI microcapsule-based self-healing anticorrosive coatings. Prog Org Coat 77:168–175

    Article  Google Scholar 

  18. Ghosh B, Urban MW (2009) Self-repairing oxetane-substituted chitosan polyurethane networks. Science 323:1458–1460

    Article  Google Scholar 

  19. Wang ZH, Yang Y, Burtovyy R, Luzinov L, Urban MW (2014) UV-induced self-repairing polydimethylsiloxane-polyurethane (PDMS-PUR) and polyethylene glycol-polyurethane (PEG-PUR) Cu-catalyzed networks. J Mater Chem A 2:15527–15534

    Article  Google Scholar 

  20. Chen KL, Zhou SX, Wu LM (2015) Self-repairing nonfouling polyurethane coatings via 3D-grafting of PEG-b-PHEMA-b-PMPC copolymer. RSC Adv 5:104907–104914

    Article  Google Scholar 

  21. Koh E, Lee S, Shin J, Kim YW (2013) Renewable polyurethane microcapsules with isosorbide derivatives for self-healing anticorrosion coatings. Ind Eng Chem Res 52:15541–15548

    Article  Google Scholar 

  22. Aramaki K (2002) Self-healing mechanism of an organosiloxane polymer film containing sodium silicate and cerium(III) nitrate for corrosion of scratched zinc surface in 0.5 M NaCl. Corros Sci 44:1621–1632

    Article  Google Scholar 

  23. Fayyad EM, Almaadeed MA, Jones A, Abdullah AM (2014) Evaluation techniques for the corrosion resistance of self-healing coatings. Int J Electrochem Sci 9:4989–5011

    Google Scholar 

  24. Javierre E, Garcia SJ, Mol JMC, Vermolen FJ, Vuike C, Zwaag SV (2012) Tailoring the release of encapsulated corrosion inhibitors from damaged coatings: controlled release kinetics by overlapping diffusion fronts. Prog Org Coat 75:20–27

    Article  Google Scholar 

  25. Liu C, Ma CF, Xie QY, Zhang GZ (2017) Self-repairing silicone coating for marine anti-biofouling. J Mater Chem A 5:15855–15861

    Article  Google Scholar 

  26. Trask RS, Williams GJ, Bond IP (2006) Bioinspired self-healing of advanced composite structures using hollow glass fibres. J R Soc Interface 4:363–371

    Article  Google Scholar 

  27. White SR, Moore JS, Sottos NR, Krull BP, Santa Cruz WA, Gergely RCR (2014) Restoration of large damage volumes in polymers. Science 344:620–623

    Article  Google Scholar 

  28. Barthel MJ, Rudolph T, Teichler A, Paulus RM, Vitz J, Hoeppener S, Hager MD, Schacher FH, Schubert US (2013) Self-healing materials via reversible crosslinking of poly(ethylene oxide)–poly(furfuryl glycidyl ether) (PEO–PFGE) block copolymer films. Adv Func Mater 23:4921–4932

    Article  Google Scholar 

  29. Lai JC, Mei JF, Jia XY, Li CH, You XZ, Bao ZN (2016) A stiff and healable polymer based on dynamic-covalent boroxine bonds. Adv Mater 28:8277–8282

    Article  Google Scholar 

  30. Xing XM, Li LW, Wang T, Ding YW, Liu GM, Zhang GC (2014) A self-healing polymeric material: from gel to plastic. J. Mater Chem A 2:11049–11053

    Article  Google Scholar 

  31. Du Y, Qiu WZ, Wu ZL, Ren PF, Zhen Q, Xv ZQ (2016) Water-triggered self-healing coatings of hydrogen-bonded complexes for high binding affinity and antioxidative property. Adv Mater Interfaces 3:160–167

    Article  Google Scholar 

  32. Kowalski D, Ueda M, Ohtsuka T (2010) Self-healing ion-permselective conducting polymer coating. J Mater Chem 20:7630–7633

    Article  Google Scholar 

  33. Lomolder R, Plogmann F, Speiep P (1997) Selectivity of isophorone diisocyanate in the urethane reaction influence of temperature, catalysis, and reaction partners. J Coatings Technol 69:51–57

    Article  Google Scholar 

  34. Hatada K, Ute K, Oka KI, Pappas SP (1990) Unambiguous 13 C-NMR assignments for isocyanate carbons of isophorone diisocyanate and reactivity of isocyanate groups in Z- and E-stereoisomers. J Polym Sci Part A Polym Chem 28:3019–3027

    Article  Google Scholar 

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Authors and Affiliations

  1. Shenyang Research Institute of Chemical Industry Co., Ltd, Shenyang, 110021, China

    Fanhou Kong, Weichang Xu, Xuelong Zhang, Xin Wang, Yu Zhang & Jinglong Wu

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  1. Fanhou Kong
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  2. Weichang Xu
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  3. Xuelong Zhang
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  4. Xin Wang
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  5. Yu Zhang
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  6. Jinglong Wu
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Correspondence to Fanhou Kong.

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There is no conflict of interest for this manuscript. We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influence our work, there is no professional or other personal interest of any nature or kind in any product, service and/or company that could be construed as influencing the position presented in, or the review of, the manuscript entitled, “High Efficiency Self-repairing Anticorrosion Coatings with Controlled Assembly Microcapsules.”

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Kong, F., Xu, W., Zhang, X. et al. High-efficiency self-repairing anticorrosion coatings with controlled assembly microcapsules. J Mater Sci 53, 12850–12859 (2018). https://doi.org/10.1007/s10853-018-2596-6

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  • DOI: https://doi.org/10.1007/s10853-018-2596-6

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