Abstract
This study demonstrates the synthesis of TiO2 nanobelts using solution combustion derived TiO2 with enhanced photocatalytic activity for dye degradation and bacterial inactivation. Hydrothermal treatment of combustion synthesized TiO2 resulted in unique partially etched TiO2 nanobelts and Ag3PO4 was decorated using the co-precipitation method. The catalyst particles were characterized using X-ray diffraction analysis, BET surface area analysis, diffuse reflectance and electron microscopy. The photocatalytic properties of the composites of Ag3PO4 with pristine combustion synthesized TiO2 and commercial TiO2 under sunlight were compared. Therefore the studies conducted proved that the novel Ag3PO4/unique combustion synthesis derived TiO2 nanobelt composites exhibited extended light absorption, better charge transfer mechanism and higher generation of hydroxyl and hole radicals. These properties resulted in enhanced photodegradation of dyes and bacteria when compared to the commercial TiO2 nanocomposite. These findings have important implications in designing new photocatalysts for water purification.
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T. Schwartz, W. Kohnen, B. Jansen, U. Obst, Detection of antibiotic-resistant bacteria and their resistance genes in wastewater, surface water, and drinking water biofilms, FEMS Microbiol. Ecol., 2003, 43, 325–335.
D. D. Mara, S. Cairncross and W. H. Organization, Guidelines for the safe use of wastewater and excreta in agriculture and aquaculture: measures for public health protection/prepared by Duncan Mara & Sandy Cairncross, 1989.
M. D. Sobsey, Inactivation of health-related microorganisms in water by disinfection processes, Water Sci. Technol., 1989, 21, 179–195.
G. Korotcenkov, The role of morphology and crystallographic structure of metal oxides in response of conductometric-type gas sensors, Mater. Sci. Eng., R, 2008, 61, 1–39.
T. M. Shang, J. H. Sun, Q. F. Zhou, M. Y. Guan, Controlled synthesis of various morphologies of nanostructured zinc oxide: flower, nanoplate, and urchin, Cryst. Res. Technol., 2007, 42, 1002–1006.
K. M. Kim, K.-Y. Kang, S. Kim, Y.-G. Lee, Electrochemical properties of TiO2 nanotube-Li4Ti5O12 composite anodes for lithium-ion batteries, Curr. Appl. Phys., 2012, 12, 1199–1206.
X. Wu, W. Xing, L. Zhang, S. Zhuo, J. Zhou, G. Wang, S. Qiao, Nickel nanoparticles prepared by hydrazine hydrate reduction and their application in supercapacitor, Powder Technol., 2012, 224, 162–167.
A. Leelavathi, G. Madras, N. Ravishankar, Origin of enhanced photocatalytic activity and photoconduction in high aspect ratio ZnO nanorods, Phys. Chem. Chem. Phys., 2013, 15, 10795–10802.
V. Subramanian, E. Wolf, P. V. Kamat, Semiconductor-metal composite nanostructures. To what extent do metal nanoparticles improve the photocatalytic activity of TiO2 films?, J. Phys. Chem. B, 2001, 105, 11439–11446.
K. Nagaveni, M. Hegde, N. Ravishankar, G. Subbanna, G. Madras, Synthesis and structure of nanocrystalline TiO2 with lower band gap showing high photocatalytic activity, Langmuir, 2004, 20, 2900–2907.
K. Patil, M. Hegde, T. Rattan and S. Aruna, Chemistry of nanocrystalline oxide materials-Combustion synthesis, properties and applications, 2008.
Z. Zhang, C.-C. Wang, R. Zakaria, J. Y. Ying, Role of particle size in nanocrystalline TiO2-based photocatalysts, J. Phys. Chem. B, 1998, 102, 10871–10878.
K. Nagaveni, M. Hegde, G. Madras, Structure and Photocatalytic Activity of Ti1-xM xO2±d (M = W, V, Ce, Zr, Fe, and Cu) Synthesized by Solution Combustion Method, J. Phys. Chem. B, 2004, 108, 20204–20212.
W. Jiang, C. An, J. Liu, S. Wang, L. Zhao, W. Guo, J. Liu, Facile aqueous synthesis of ß-AgI nanoplates as efficient visible-light-responsive photocatalyst, Dalton Trans., 2014, 43, 300–305.
M. Ge, N. Zhu, Y. Zhao, J. Li, L. Liu, Sunlight-assisted degradation of dye pollutants in Ag3PO4 suspension, Ind. Eng. Chem. Res., 2012, 51, 5167–5173.
Y. Sang, L. Kuai, C. Chen, Z. Fang, B. Geng, Fabrication of a Visible-Light-Driven Plasmonic Photocatalyst of AgVO3@AgBr@Ag Nanobelt Heterostructures, ACS Appl. Mater. Interfaces, 2014, 6, 5061–5068.
J. S. Kim, E. Kuk, K. N. Yu, J.-H. Kim, S. J. Park, H. J. Lee, S. H. Kim, Y. K. Park, Y. H. Park, C.-Y. Hwang, Antimicrobial effects of silver nanoparticles, Nanomedicine, 2007, 3, 95–101.
Y. Liu, L. Fang, H. Lu, L. Liu, H. Wang, C. Hu, Highly efficient and stable Ag/Ag3PO4 plasmonic photocatalyst in visible light, Catal. Commun., 2012, 17, 200–204.
H. Zhao, L. Zhang, X. Gu, S. Li, B. Li, H. Wang, J. Yang, J. Liu, Fe2O3–AgBr nonwoven cloth with hierarchical nanostructures as efficient and easily recyclable macroscale photocatalysts, RSC Adv., 2015, 5, 10951–10959.
H. Yu, L. Xu, P. Wang, X. Wang, J. Yu, Enhanced photoinduced stability and photocatalytic activity of AgBr photocatalyst by surface modification of Fe(iii) cocatalyst, Appl. Catal., B, 2014, 144, 75–82.
X. Yang, J. Qin, Y. Jiang, K. Chen, X. Yan, D. Zhang, R. Li, H. Tang, Fabrication of P25/Ag3PO4/graphene oxide heterostructures for enhanced solar photocatalytic degradation of organic pollutants and bacteria, Appl. Catal., B, 2015, 166, 231–240.
J.-W. Xu, Z.-D. Gao, K. Han, Y. Liu, Y.-Y. Song, Synthesis of Magnetically Separable Ag3PO4/TiO2/Fe3O4 Heterostructure with Enhanced Photocatalytic Performance under Visible Light for Photoinactivation of Bacteria, ACS Appl. Mater. Interfaces, 2014, 6, 15122–15131.
X. Yang, H. Cui, Y. Li, J. Qin, R. Zhang, H. Tang, Fabrication of Ag3PO4-Graphene composites with highly efficient and stable visible light photocatalytic performance, ACS Catal., 2013, 3, 363–369.
H. Cui, X. Yang, Q. Gao, H. Liu, Y. Li, H. Tang, R. Zhang, J. Qin, X. Yan, Facile synthesis of graphene oxide-enwrapped Ag3PO4 composites with highly efficient visible light photocatalytic performance, Mater. Lett., 2013, 93, 28–31.
V. Bellat, R. Chassagnon, O. Heintz, L. Saviot, D. Vandroux, N. Millot, A multi-step mechanism and integrity of titanate nanoribbons, Dalton Trans., 2015, 44, 1150–1160.
N. Wu, J. Wang, D. N. Tafen, H. Wang, J.-G. Zheng, J. P. Lewis, X. Liu, S. S. Leonard, A. Manivannan, Shape-enhanced photocatalytic activity of single-crystalline anatase TiO2 (101) nanobelts, J. Am. Chem. Soc., 2010, 132, 6679–6685.
Z.-Y. Yuan, J.-F. Colomer, B.-L. Su, Titanium oxide nanoribbons, Chem. Phys. Lett., 2002, 363, 362–366.
Y. Wang, G. Du, H. Liu, D. Liu, S. Qin, N. Wang, C. Hu, X. Tao, J. Jiao, J. Wang, Nanostructured Sheets of Ti-O Nanobelts for Gas Sensing and Antibacterial Applications, Adv. Funct. Mater., 2008, 18, 1131–1137.
R. Hernandez-Delgadillo, D. Velasco-Arias, D. Diaz, K. Arevalo-Niño, M. Garza-Enriquez, M. A. De la Garza-Ramos, C. Cabral-Romero, Zerovalent bismuth nanoparticles inhibit Streptococcus mutans growth and formation of biofilm, Int. J. Nanomed., 2012, 7, 2109.
R. Hernandez-Delgadillo, D. Velasco-Arias, J. J. Martinez-Sanmiguel, D. Diaz, I. Zumeta-Dube, K. Arevalo-Niño, C. Cabral-Romero, Bismuth oxide aqueous colloidal nanoparticles inhibit Candida albicans growth and biofilm formation, Int. J. Nanomed., 2013, 8, 1645.
A. D. Mani, P. M. K. Reddy, M. Srinivaas, P. Ghosal, N. Xanthopoulos, C. Subrahmanyam, Facile synthesis of efficient visible active C-doped TiO2 nanomaterials with high surface area for the simultaneous removal of phenol and Cr (VI), Mater. Res. Bull., 2015, 61, 391–399.
F. M. Hossain, L. Sheppard, J. Nowotny, G. E. Murch, Optical properties of anatase and rutile titanium dioxide: Ab initio calculations for pure and anion-doped material, J. Phys. Chem. Solids, 2008, 69, 1820–1828.
S. B. Rawal, S. D. Sung, W. I. Lee, Novel Ag3PO4/TiO2 composites for efficient decomposition of gaseous 2-propanol under visible-light irradiation, Catal. Commun., 2012, 17, 131–135.
R. Liu, P. Hu, S. Chen, Photocatalytic activity of Ag3PO4 nanoparticle/TiO2 nanobelt heterostructures, Appl. Surf. Sci., 2012, 258, 9805–9809.
W. Zhou, G. Du, P. Hu, G. Li, D. Wang, H. Liu, J. Wang, R. I. Boughton, D. Liu, H. Jiang, Nanoheterostructures on TiO2 nanobelts achieved by acid hydrothermal method with enhanced photocatalytic and gas sensitive performance, J. Mater. Chem., 2011, 21, 7937–7945.
W. Teng, X. Li, Q. Zhao, J. Zhao, D. Zhang, In situ capture of active species and oxidation mechanism of RhB and MB dyes over sunlight-driven Ag/Ag3PO4 plasmonic nanocatalyst, Appl. Catal., B, 2012, 125, 538–545.
Y. Lei, L.-D. Zhang, G.-W. Meng, G.-H. Li, X. Zhang, C. Liang, W. Chen, S. Wang, Preparation and photoluminescence of highly ordered TiO2 nanowire arrays, Appl. Phys. Lett., 2001, 78, 1125–1127.
J. Liu, X. Fu, S. Chen, Y. Zhu, Electronic structure and optical properties of Ag3PO4 photocatalyst calculated by hybrid density functional method, Appl. Phys. Lett., 2011, 99, 191903.
X. Ma, B. Lu, D. Li, R. Shi, C. Pan, Y. Zhu, Origin of photocatalytic activation of silver orthophosphate from first-principles, J. Phys. Chem. C, 2011, 115, 4680–4687.
B. Xin, L. Jing, Z. Ren, B. Wang, H. Fu, Effects of simultaneously doped and deposited Ag on the photocatalytic activity and surface states of TiO2, J. Phys. Chem. C, 2005, 109, 2805–2809.
J. Kiwi, V. Nadtochenko, Evidence for the mechanism of photocatalytic degradation of the bacterial wall membrane at the TiO2 interface by ATR-FTIR and laser kinetic spectroscopy, Langmuir, 2005, 21, 4631–4641.
S. Sontakke, C. Mohan, J. Modak, G. Madras, Visible light photocatalytic inactivation of Escherichia coli with combustion synthesized TiO2, Chem. Eng. J., 2012, 189, 101–107.
G. Gogniat, S. Dukan, TiO2 photocatalysis causes DNA damage via Fenton reaction-generated hydroxyl radicals during the recovery period, Appl. Environ. Microbiol., 2007, 73, 7740–7743.
Q. Li, S. Mahendra, D. Y. Lyon, L. Brunet, M. V. Liga, D. Li, P. J. Alvarez, Antimicrobial nanomaterials for water disinfection and microbial control: potential applications and implications, Water Res., 2008, 42, 4591–4602.
G. A. Sotiriou, S. E. Pratsinis, Antibacterial activity of nanosilver ions and particles, Environ. Sci. Technol., 2010, 44, 5649–5654.
M. Rai, A. Yadav, A. Gade, Silver nanoparticles as a new generation of antimicrobials, Biotechnol. Adv., 2009, 27, 76–83.
A. Wu, C. Tian, W. Chang, Y. Hong, Q. Zhang, Y. Qu, H. Fu, Morphology-controlled synthesis of Ag3PO4 nano/microcrystals and their antibacterial properties, Mater. Res. Bull., 2013, 48, 3043–3048.
X. Yang, J. Qin, Y. Jiang, R. Li, Y. Li, H. Tang, Bifunctional TiO2/Ag3PO4/graphene composites with superior visible light photocatalytic performance and synergistic inactivation of bacteria, RSC Adv., 2014, 4, 18627–18636.
R. Sapkal, S. Shinde, T. Waghmode, S. Govindwar, K. Rajpure, C. Bhosale, Photo-corrosion inhibition and photoactivity enhancement with tailored zinc oxide thin films, J. Photochem. Photobiol., B, 2012, 110, 15–21.
S. Yan, Z. Li, Z. Zou, Photodegradation of rhodamine B and methyl orange over boron-doped g-C3N4 under visible light irradiation, Langmuir, 2010, 26, 3894–3901.
D. Wang, Y. Duan, Q. Luo, X. Li, J. An, L. Bao, L. Shi, Novel preparation method for a new visible light photocatalyst: mesoporous TiO2 supported Ag/AgBr, J. Mater. Chem., 2012, 22, 4847–4854.
W. Li, D. Li, S. Meng, W. Chen, X. Fu, Y. Shao, Novel Approach To Enhance Photosensitized Degradation of Rhodamine B under Visible Light Irradiation by the ZnxCd1-x S/TiO2 Nanocomposites, Environ. Sci. Technol., 2011, 45, 2987–2993.
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Eswar, N.K., Ramamurthy, P.C. & Madras, G. Enhanced sunlight photocatalytic activity of Ag3PO4 decorated novel combustion synthesis derived TiO2 nanobelts for dye and bacterial degradation. Photochem Photobiol Sci 14, 1227–1237 (2015). https://doi.org/10.1039/c5pp00092k
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DOI: https://doi.org/10.1039/c5pp00092k