We theoretically propose a mechanism to understand the violation of the Pauli-Clogston limit for the upper critical field ${\mathrm{H}}_{\mathrm{c}2}$ observed in the Ce bearing heavy Fermion material ${\mathrm{CeRh}}_2{\mathrm{As}}_2$ from the view point of spin singlet pairing. It is based on a duality concept, the dual simultaneous aspects of an electron: The itinerant part and localized part of quasiparticles (QPs) originated from the 4f electrons of the Ce atoms. While the itinerant QPs directly participate in forming the Cooper pairs, the localized QPs exert the internal field so as to oppose the applied field through the antiferromagnetic exchange interaction between them. This is inherent in the dense Kondo lattice system in general. We argue that this mechanism can be applied not only to the locally noncentrosymmetric material ${\mathrm{CeRh}}_2{\mathrm{As}}_2$, but also to globally inversion symmetry broken Ce-based materials such as ${\mathrm{CePt}}_3\mathrm{Si}$. Moreover, we point out that it also works for strongly Pauli-limit-violated spin triplet pairing systems, such as ${\mathrm{UTe}}_2$.

• Received 15 September 2022
• Revised 26 October 2022
• Accepted 9 November 2022

DOI:https://doi.org/10.1103/PhysRevB.106.184509