Abstract
Resonant inelastic x-ray scattering (RIXS) is an evolving tool for investigating the spin dynamics of strongly correlated materials, which complements inelastic neutron scattering. In isotropic spin- Heisenberg antiferromagnetic (HAFM) spin chains, both techniques have observed non-spin-conserving (NSC) excitations confined to the two-spinon phase space. However, a recent O -edge RIXS study of the one-dimensional HAFM observed spin-conserving (SC) four-spinon excitations outside the two-spinon phase space. Here, we demonstrate that analogous four-spinon excitations can also be accessed at the Cu edge in the related material . Through detailed modeling, we establish that these excitations appear in both the SC and NSC channels of the Cu edge, and are only captured by higher-order terms in the ultrashort core-hole lifetime expansion. Since these terms encode information about spin-spin correlations extending beyond nearest neighbors, our results offer different possibilities for studying nonlocal spin correlations in quantum magnets.
- Received 24 September 2021
- Revised 17 January 2022
- Accepted 3 August 2022
DOI:https://doi.org/10.1103/PhysRevB.106.L060406
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