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Plasmons and interband transitions of Ca11Sr3Cu24O41 investigated by electron energy-loss spectroscopy

Friedrich Roth, Christian Hess, Bernd Büchner, Udo Ammerahl, Alexandre Revcolevschi, and Martin Knupfer
Phys. Rev. B 82, 245110 – Published 9 December 2010

Abstract

Electron energy-loss spectroscopy studies have been performed in order to get a deeper insight into the electronic structure and elementary excitations of the two-leg ladder system Ca11Sr3Cu24O41. We find a strong anisotropy of the loss function for momentum transfers along the a and c crystallographic axes, and a remarkable linear plasmon dispersion for a momentum transfer parallel to the legs of the ladders. The investigated spectral features are attributed to localized and delocalized charge-transfer excitations and the charge-carrier plasmon. The charge-carrier plasmon position and dispersion in the long-wavelength limit agree well with expectations based upon the band structure of the two-leg ladder while the observed quasilinear plasmon dispersion might be related to the peculiar properties of underdoped cuprates in general.

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  • Received 15 October 2010

DOI:https://doi.org/10.1103/PhysRevB.82.245110

©2010 American Physical Society

Authors & Affiliations

Friedrich Roth1, Christian Hess1, Bernd Büchner1, Udo Ammerahl2, Alexandre Revcolevschi2, and Martin Knupfer1

  • 1IFW Dresden, P.O. Box 270116, D-01171 Dresden, Germany
  • 2Laboratoire de Physico-Chimie de l’État Solide, Université Paris-Sud, 91405 Orsay, France

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Issue

Vol. 82, Iss. 24 — 15 December 2010

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Images

  • Figure 1
    Figure 1
    (Color online) Schematic representation of the crystal structure of CaxSr14xCu24O41.Reuse & Permissions
  • Figure 2
    Figure 2
    (Color online) The momentum dependence of the EELS spectra of Ca11Sr3Cu24O41 for q parallel to the crystallographic a axis (q is increasing from top to bottom spectra). The upturn toward 0 eV is due to the quasielastic line.Reuse & Permissions
  • Figure 3
    Figure 3
    (Color online) The momentum dependence of the EELS spectra of Ca11Sr3Cu24O41 for q parallel to the crystallographic c axis (q is increasing from top to bottom spectra). The upturn toward 0 eV is due to the quasielastic line.Reuse & Permissions
  • Figure 4
    Figure 4
    Plasmon dispersion in Ca11Sr3Cu24O41 along the c direction. Within the error bars the plasmon scales linearly with momentum and the bandwidth amounts to 400meV in the considered momentum range. The gray curve represents the fit with a polynomial function [cf. Eq. (2)].Reuse & Permissions
  • Figure 5
    Figure 5
    (Color online) Angular dependence of the EELS response of Ca11Sr3Cu24O41 for q=0.15Å1 measured in the low-energy range between 0 and 10 eV. The upper spectrum (red line) corresponds to qa, and the lower spectra (purple line) represents qc.Reuse & Permissions
  • Figure 6
    Figure 6
    (Color online) Angular dependence of the EELS intensity for q=0.15Å1 measured at room temperature in the range between 0.4 and 2 eV. The horizontal dashed bars correspond to the two main crystallographic directions along or perpendicular to the c and a axis, respectivelyReuse & Permissions
  • Figure 7
    Figure 7
    (Color online) Left panel: the optical conductivity for Ca11Sr3Cu24O41 as derived by a Kramers-Kronig transformation of the EELS intensity (black circle) and the fit (red line). Right panel: the real part of the dielectric function subtracted by the Drude contribution which provides a value for the background dielectric constant of ϵ7.6.Reuse & Permissions
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