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SrTiO3 Displacive Transition Revisited via Coherent X-Ray Diffraction

S. Ravy, D. Le Bolloc’h, R. Currat, A. Fluerasu, C. Mocuta, and B. Dkhil
Phys. Rev. Lett. 98, 105501 – Published 5 March 2007

Abstract

We present a coherent x-ray diffraction study of the antiferrodistortive displacive transition of SrTiO3, a prototypical example of a phase transition for which the critical fluctuations exhibit two length scales and two time scales. From the microbeam x-ray coherent diffraction patterns, we show that the broad (short-length scale) and the narrow (long-length scale) components can be spatially disentangled, due to 100μm-scale spatial variations of the latter. Moreover, both components exhibit a speckle pattern, which is static on a 10mn time scale. This gives evidence that the narrow component corresponds to static ordered domains. We interpret the speckles in the broad component as due to a very slow dynamical process, corresponding to the well-known central peak seen in inelastic neutron scattering.

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  • Received 10 November 2006

DOI:https://doi.org/10.1103/PhysRevLett.98.105501

©2007 American Physical Society

Authors & Affiliations

S. Ravy1, D. Le Bolloc’h2, R. Currat3, A. Fluerasu4, C. Mocuta4, and B. Dkhil5

  • 1Synchrotron SOLEIL, L’Orme des merisiers, Saint-Aubin BP 48, 91192 Gif-sur-Yvette cedex, France
  • 2Laboratoire de physique des solides, Université Paris-sud, CNRS, UMR 8502, F-91405 Orsay Cedex, France
  • 3Institut Laue-Langevin, 6, rue Jules Horowitz, Boîte postale 156, 38042 Grenoble Cedex 9, France
  • 4European Synchrotron Radiation Facility, 6 rue Jules Horowitz, Boîte postale 220, 38043 Grenoble Cedex, France
  • 5Laboratoire Structures, Propriétés et Modélisation des Solides, Ecole Centrale Paris, CNRS, UMR 8580, Grande Voie des Vignes, F-92295 Chatenay-Malabry Cedex, France

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Vol. 98, Iss. 10 — 9 March 2007

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Images

  • Figure 1
    Figure 1
    (a) Temperature dependence of the peak intensity (●) of the Qs superstructure reflection (20μm×20μm entrance slits). The solid line is a fit to a power law. Right-hand scale, HWHM of the BC (▴) and the NC (■). The lines are guides for the eye. (b) θ scan across Qs at 104 K (200μm×200μm entrance slits). Intensity scale is logarithmic. The dashed line is a sum of a L (solid line) and L1.7 line shape (see text).Reuse & Permissions
  • Figure 2
    Figure 2
    Integrated intensity around the Qs reciprocal position as a function of the vertical translation of the sample. Intensity scale is logarithmic. The two 2D maps obtained at the positions indicated by arrows are displayed in Fig. 3a, 3c.Reuse & Permissions
  • Figure 3
    Figure 3
    (a), (c) 2D patterns obtained at the Qs superstructure peak intensity position for two different z positions of the beam, corresponding to the arrows in Fig. 2. The same logarithmic color scale is used for both images. Saturated values are shown in white. (b), (d) display the vertical profiles indicated by white arrows in (a), (c). In (b) the (dotted) solid lines are fits to a (L2) L line shape. In (d) the dotted line is a sum of a L2 and a L line shape (solid line) for the NC and the BC, respectively. The (blue) arrow points the BC maximum. The inset in (d) is a zoom of (c) around the NC, in linear color scale.Reuse & Permissions
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