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Phase Separation Dynamics in a Concentration Gradient

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Published under licence by IOP Publishing Ltd
, , Citation A. M. Lacasta et al 1994 EPL 27 291 DOI 10.1209/0295-5075/27/4/007

0295-5075/27/4/291

Abstract

Phase separation dynamics with an initially nonuniform concentration are studied. Critical and off-critical behavior is observed simultaneously. A mechanism for an expanding phase-separated region is demonstrated and the time dependence of the concentration is determined. The final equilibrium state consists of a planar interface separating one phase from the other. The evolution to this state is characterized by an experimentally observable flux, j, crossing this interface. We find that j ∼ t−2/3 if patterns are formed in the bulk and j ∼ t−1/2 if the bulk remains homogeneous. The results are explained in terms of scaling arguments which are confirmed numerically.

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10.1209/0295-5075/27/4/007