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Thermodynamic Properties of Alloys of the Binary Al-Sm, Sm-Sn and Ternary Al-Sm-Sn Systems

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Abstract

Mixing enthalpies of the liquid binary Al-Sm (0 < xSm < 0.15; 0.37 < xSm < 1), Sm-Sn (0 < xSn < 0.13; 0.56 < xSn < 1) alloys and ternary Al-Sm-Sn alloys (along the three concentration sections: (Sm0.87Sn0.13)1−xAlx (0 < x<0.32); (Sm0.44Sn0.56)1−xAlx (0 < x<0.12); (Al0.85Sm0.15)1−xSnx (0 < x<0.032)) were determined by an isoperibolic calorimetry technique at 1410-1670 K. Thermodynamic properties of liquid Al(Sn)-Sm alloys were described in the whole concentration range using the model of ideal associated solution. Thermodynamic activities of components of the Al(Sn)-Sm melts demonstrate large negative deviation from the ideal behavior, and the mixing enthalpies are characterized by significant exothermic effects. The minimum value of the mixing enthalpy of the Al-Sm melts is −47.1 ± 0.5 kJ/mol at xSm = 0.35 (T = 1500 K, undercooled melt), Sm-Sn is −67.7 ± 0.5 kJ/mol at xSn = 0.48 (T = 1450 K, undercooled melt). The obtained results were compared with the data from survey of the binary Al(Sn)-Sm systems and with the values calculated by the different models from the data for the binary boundary subsystems of the ternary Al-Sm-Sn system.

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Authors and Affiliations

  1. Frantsevich Institute for Problems of Material Science, National Academy of Science of Ukraine, Krzhyzhanovsky Str., 3, Kyiv, 03680, Ukraine

    M. O. Shevchenko, V. V. Berezutski, M. I. Ivanov, V. G. Kudin & V. S. Sudavtsova

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  1. M. O. Shevchenko
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Shevchenko, M.O., Berezutski, V.V., Ivanov, M.I. et al. Thermodynamic Properties of Alloys of the Binary Al-Sm, Sm-Sn and Ternary Al-Sm-Sn Systems. J. Phase Equilib. Diffus. 36, 39–52 (2015). https://doi.org/10.1007/s11669-014-0353-3

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