Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO3F.[1][2]
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| Other names
Bromine fluoride trioxide
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| BrFO3 | |
| Molar mass | 146.899 g·mol−1 |
| Appearance | colorless gas |
| Melting point | −9 °C (16 °F; 264 K) |
| reacts with water | |
| Related compounds | |
Related compounds
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Periodyl fluoride Perchloryl fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis
editSynthesis if perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid:[3]
- KBrO4 + 2SbF5 + 3HF → BrO3F + K[SbF6] + H[SbF6]•H2O
Physical properties
editPerbromyl fluoride forms a colorless gas that is stable in the absence of moisture.[4]
Chemical properties
editPerbromyl fluoride reacts with water:
- BrO3F + H2O → HBrO4 + HF
References
edit- ^ Johnson, Gerald K.; O'Hare, P. A. G.; Appelman, Evan H. (1972). "Perbromyl fluoride". 11 (4). NIST: 800–802. doi:10.1021/ic50110a028. Retrieved 5 June 2023.
{{cite journal}}: Cite journal requires|journal=(help) - ^ Appleman, Evan H.; Studier, Martin H. (July 1969). "Perbromyl fluoride". Journal of the American Chemical Society. 91 (16): 4561–4562. doi:10.1021/ja01044a049. ISSN 0002-7863. Retrieved 5 June 2023.
- ^ Steudel, Ralf (20 April 2011). Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding. Walter de Gruyter. p. 265. ISBN 978-3-11-083082-8. Retrieved 5 June 2023.
- ^ U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management. U.S. Government Printing Office. 1970. p. 10. Retrieved 5 June 2023.