Thulium(II) fluorideis one of the fluoride salts of the lanthanide metal thulium, with the chemical compound of TmF2. It can react with zirconium tetrafluoride at 900 °C to form TmZrF6, which has a hexagonal structure.[1] In addition, low-temperature Mössbauer spectroscopy[2] and some theoretical studies[3] of thulium(II) fluoride have also been reported.
| Names | |
|---|---|
| Other names
Thulium difluoride
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| Identifiers | |
| Properties | |
| TmF2 | |
| Molar mass | 206.93 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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References
- ^ Ivanenko, O. P.; Kompanichenko, N. M.; Omel'chuk, A. O.; Rudkovs'ka, L. M.; Zinchenko, V. F. Reaction of zirconium tetrafluoride with nonstoichiometric lanthanide (samarium, europium, thulium, and ytterbium) fluorides. Ukrainskii Khimicheskii Zhurnal (Russian Edition), 2009. 75 (7-8): 83-88. ISSN: 0041-6045
- ^ Triplett, B. B.; Dixon, N. S.; Boolchand, P.; Hanna, S. S.; Bucher, E. Low temperature Moessbauer studies of thulium compounds. Journal de Physique, Colloque, 1974. 6: 653-657. ISSN: 0449-1947 .DOI: 10.1051/jphyscol:19746144
- ^ Michael Hülsen, Michael Dolg, Pascal Link, Uwe Ruschewitz (2011-06-25). "Improved valence basis sets for divalent lanthanide 4f-in-core pseudopotentials". Theoretical Chemistry Accounts. 129 (3–5): 367–379. doi:10.1007/s00214-010-0855-y. ISSN 1432-881X. Retrieved 2019-03-26.
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