UNIFAC Etanol-Agua
UNIFAC Etanol-Agua
UNIFAC Etanol-Agua
Frecuencia
k Rk Qk vk1 vk2 q1=Gk1 q2=Gk2
1 CH3 (1) 0.9011 0.8480 1 0 0.848 0
2 CH2 (1) 0.6744 0.5400 1 0 0.54 0
3 OH (5) 1.0000 1.2000 1 0 1.2 0
4 H2O (7) 0.9200 1.4000 0 1 0 1.4
2.588 1.4 〖���〗 _�^𝑅=𝑞_� (1−
�_(�,�)/�_� 〗− (∑▒
Parámetros de interacción
k r1 r2 1 (1) 2 (1) 3 (5) 4 (7)
〖���〗 _�^�=1−�_�+
1 (1) 0.9011 0 0 0 986.5 1318 +��(�_�/�_� )]
2 (1) 0.6744 0 0 0 986.5 1318
3 (5) 1 0 156.4 156.4 0 353.5
4 (7) 0 0.92 300 300 -229.1 0
2.5755 0.92
P= 101.33
n 0 1 2 3 A
t(°C) 70 77.963547 77.963547 77.963547 Etanol (1) 16.8958
T(K) 343.15 351.11355 351.11355 351.11355 Agua (2) 16.3872
L1 1.0000 1.0000 1.0000 1.0000
L2 0.5410 0.5410 0.5410 0.5410 i xi
J1 1.0000 1.0000 1.0000 1.0000 1 1
J2 0.3572 0.3572 0.3572 0.3572 2 0
θ1 0.8480 0.8480 0.8480 0.8480
θ2 0.5400 0.5400 0.5400 0.5400 Para T=70°C
θ3 1.2000 1.2000 1.2000 1.2000 x1 Ganma 1
θ4 0.0000 0.0000 0.0000 0.0000 0 7.053
s11 2.1487 2.1487 2.1487 2.1487 0.1 3.400
s21 2.1487 2.1567 2.1567 2.1567 0.2 2.192
s31 1.2783 1.2836 1.2836 1.2836 0.3 1.661
s41 0.4581 0.4710 0.4710 0.4710 0.4 1.386
s12 0.5840 0.5957 0.5957 0.5957 0.5 1.228
s22 0.5840 0.5957 0.5957 0.5957 0.6 1.133
s32 2.7295 2.6885 2.6885 2.6885 0.7 1.072
s42 1.4000 1.4000 1.4000 1.4000 0.8 1.033
η1 2.1487 2.1487 2.1487 2.1487 0.9 1.010
η2 2.1487 2.1567 2.1567 2.1567 1 1.000
η3 1.2783 1.2836 1.2836 1.2836
η4 0.4581 0.4710 0.4710 0.4710
Ganma 1 1 1 1 1
Ganma 2 2.7879017 2.7967856 2.7967856 2.7967856
Psat1(KPa) 101.3300 101.3300 101.3300 101.3300
Psat2(KPa) 43.6743 43.6743 43.6743 43.6743
t (°C) 77.963547 77.963547 77.963547 77.963547
105.00
Para P=101.33 KPa
100.00
x1 T(x1) Ganma 1 P1(t) y1
0 100.00 6.6766 235.098 0.000
95.00
0.1 85.54 3.3731 137.144 0.457
TEMPERATURA (°c)
0.2 82.79 2.1934 123.083 0.533 90.00
0.3 81.46 1.6658 116.711 0.576
0.4 80.45 1.3903 112.097 0.615 85.00
0.5 79.60 1.2317 108.294 0.658
0.6 78.88 1.1347 105.170 0.707 80.00
0.7 78.30 1.073 102.749 0.762
0.8 77.91 1.0333 101.116 0.825 75.00
0.9 77.75 1.009 100.458 0.900 0 0
1 77.96 1 101.330 1.000
1
0.9
0.8
0.7
0.6
0.5
y1
0.4
0.3
0.2
0.1
0
0 0.1
〖���〗 _�^𝑅=𝑞_� (1− 〖���〗 _� )−[∑▒ 〖� _�
�_(�,�)/�_� 〗− (∑▒ 〖� _(�,�) �� �_(�,�)/�_� 〗 )]
KPa
B C
3795.17 230.918
3885.7 230.17
95.00
TEMPERATURA (°c)
90.00
85.00
80.00
75.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-y1
1
0.9
0.8
0.7
0.6
0.5
y1
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-x1
0.7 0.8 0.9 1