Efectos Termicos
Efectos Termicos
Efectos Termicos
CÓDIGO : 174443
SOLUCION
ECUACIÓN
T
C giP B T 20 C T 30 3 D τ−1
∫R
T0
∗dT = A T 0 ( τ −1 ) +
2
∗( τ 2
−1 ) +
3 ( )
∗( τ −1 ) + ∗
T0 τ
Calculando el τ
T 1153.15 K
τ= = =3.5685
T 0 323.15 K
J J
Q=∆ H=8.314 ∗11355.5893 K =94410.3694 ( RESPUESTA)
mol∗K mol
EJERCICIO N°02
¿Qué temperatura final alcanza 15moles de 1-buteno inicialmente a 260°C si se
les añade la cantidad de 2500KJ en un intercambiador de calor de flujo continuo a
una presión aproximada igual a la atmosférica?
DATOS
T
τ=
T0
T 533.15 K
τ= = =1.00
T 0 533.15 K
SOLUCIÓN
FÓRMULA
⟨C P ⟩ H B C 2 2 D
= A+ ∗T 0∗( τ +1 ) + ∗T 0∗( τ +τ +1 ) + 2
R 2 3 τ T0
Reemplazando en la fórmula
⟨C P ⟩ H 31.630∗10−3 −9.873∗10−6
=1.967+ ∗533.15∗( 1+1 ) + ∗533.152∗( 12+1+1 ) =16.0241
R 2 3
J J
⟨ C P ⟩ H =8.314 mol∗K ∗16.0241=133.2244 mol∗K
⟨ C P ⟩ H ( T −T 0 )
∆ H=
R
Q=2500000 J =n ∆ H
Q 2500000 J J
∆ H= = =166666.6667
n 15 mol mol
∆H
T= +T
⟨C P ⟩ H 0
J
166666.6667
mol
T= +533.15 K =¿
J
133.2244
mol∗K
T 1=1784.1721 K
T 1784.1721 K
τ= = =3.3465
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗24.0734=200.1462
R mol∗K mol∗K
J
166666.6667
mol
T 2= + 533.15 K =1366.1776 K
J
200.0734
mol∗K
T 1366.1776 K
τ= = =2.5625
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.53=187.3144
R mol∗K mol∗K
J
166666.6667
mol
T 3= + 533.15 K =1422.9196 K
J
187.3144
mol∗K
T 1422.9196 K
τ= = =2.6689
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.8069=189.6166
R mol∗K mol∗K
J
166666.6667
mol
T 4= +533.15 K=1412.1166 K
J
189.6166
mol∗K
T 1412.1166 K
τ= = =2.6486
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.7557=189.1909
R mol∗K mol∗K
J
166666.6667
mol
T 4= +533.15 K=1414.0944 K
J
189.1909
mol∗K
T 1414.0944 K
τ= = =2.6523
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.7651=189.2690
R mol∗K mol∗K
J
166666.6667
mol
T 5= + 533.15 K =1413.7309 K
J
189.2690
mol∗K
T 1413.7309 K
τ= = =2.6517
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.7635=189.2557
R mol∗K mol∗K
J
166666.6667
mol
T 6= +533.15 K=1 413.7928 K
J
189.2557
mol∗K
T 14 13.7928 K
τ= = =2.6518
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.7638=189.2582
R mol∗K mol∗K
J
166666.6667
mol
T 7= + 533.15 K =1413.7812 K
J
189.2582
mol∗K
T 1413.7812 K
τ= = =2.6518
T0 533.15 K
⟨C P ⟩ H J J
=8.314 ∗22.7638=189.2582
R mol∗K mol∗K
J
166666.6667
mol
T 8= + 533.15 K =1413.7812 K ( RESPUESTA )
J
189.2582
mol∗K