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Unidad 2

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n y(1/s) tau(pa) 29c ln(y) (xi) ln(tau) (yi) xiyi suma(xi*yi) x^2

1 4.5 51.8 1.5040774 3.94739015 5.9371803 525.592399 2.26224882


2 7.5 88.9 2.01490302 4.48751214 9.04190177 4.05983418
3 13 143 2.56494936 4.96284463 12.7294451 6.57896521
4 21 209.1 3.04452244 5.34281261 16.2663129 9.26911687
5 41 423.9 3.71357207 6.04949758 22.4652452 13.7906175
6 58 547.6 4.06044301 6.30554509 25.6033065 16.4871974
Sumatorias 16.9024673 31.0956022 92.0433918 52.44798

m 0.91975963
b 2.59156586 b-exp 13.3506605
x_bar 2.81707788
y_bar 5.18260037

y(1/s) tau Grafi. De model.


4.5 53.2477489 t=my^n
7.5 85.1821849
13 141.274207
21 219.59714
41 406.327516
58 559.0268
suma(xi)^2
285.6934 Y(1/s) vs. tau(pa)
600

f(x) = 9.38494462735708 x + 17.2471715055372


500 R² = 0.996062186384571

400

300

200

100

0
0 10 20 30 40 50 60 70

tau
600

500

400

300

200

100

0
0 10 20 30 40 50 60 70
60 70

0 70
Valores iniciales
num y(1/s) tau(pa) 29c ln(y) (xi) ln(tau) (yi) m n f(0)
1 4.5 51.8 1.5040774 3.94739015 7.23825326 1.11482424 0.08481392
2 7.5 88.9 2.01490302 4.48751214 -0.2618695
3 13 143 2.56494936 4.96284463 -0.123997
4 21 209.1 3.04452244 5.34281261 0.03067472
5 41 423.9 3.71357207 6.04949758 0.06986249
6 58 547.6 4.06044301 6.30554509 0.20051511
-2.4803E-07
y(1/s) tau(pa) 29c ln(y) (xi) ln(tau) (yi)
4.5 51.8 1.5040774 3.94739015
7.5 88.9 2.01490302 4.48751214
13 143 2.56494936 4.96284463 ln(tau)
Chart Title
(yi)
21 209.1 3.04452244 5.34281261 600
7
41 423.9 3.71357207 6.04949758
58 547.6 4.06044301 6.30554509 6
500 f(x) = 0.919759628062301 x + 2.59156586208219
R² = 0.998205159387477
5
400

4
300

3
200

2
100

1 0
0 10 20 30 40 5
0
1 1.5 2 tau(pa) 29c2.5 ln(y) (xi) 3 ln(tau) (yi)
3.5
ln(tau)
Chart Title
(yi)

759628062301 x + 2.59156586208219
05159387477

20 30 40 50 60 70

tau(pa) 29c2.5 ln(y) (xi) 3 ln(tau) (yi)


3.5 4 4.5
n y(1/s) tau 38.6c ln(y) (xi) ln(tau) (yi)
1 4.5 29.04 1.5040774 3.36867419
2 7.5 41.91 2.01490302 3.73552446
3 13 71.8 2.56494936 4.27388448
4 21 115.1 3.04452244 4.74580132
5 41 213.4 3.71357207 5.36316834
6 58 294.5 4.06044301 5.685279
7 97 483.1 4.57471098 6.18022367
Sumatorias 21.4771783 33.3525555

m 6.78829632
n 0.9287
n<1 pseudoplastico
ln(tau) (yi)
7

6 f(x) = 0.928726179276562 x + 1.91516253463925


R² = 0.99897342883776
5

0
1 1.5 2 2.5 3 3.5 4 4.5 5
Tasa de def. Esf. Cort,
0.01 4.2
Esf. Cort,
0.02 6.5
0.03 7 16

0.04 7.1 14 f(x) = 112.060606060606 x + 3.50666666666667


0.05 9.3 R² = 0.981795380095245
12
0.06 10.3
0.07 11.6 10

0.08 12.8 8
0.09 13.2
6
0.1 14.7
4

0
0 0.02 0.04 0.06 0.08 0.1 0.12
0.1 0.12
Estimacion de la viscosidad a partir de propiedades criticas

Determinar viscosidad para N2


a 50∘C y 854 atm

Ecuaciones
Mc=7.70M^(1/2) Pc^(2/3) Tc^(-1/6)

De Tablas Mc= 189.099558 mpoise


M= 28.013 g/mol 28.013
Pc=33.5 atm 33.5 Determinar Tr y Pr
Tc= 126.2 k 126.2 Tr= T/Tc Pr=P/Pc

Tr=(50+273.15)k/126.2k= 2.56061807
Pr=854atm/33.5atm= 25.4925373
1 poise= 1 g/cms
DATOS
CO2
𝜇 =2.6693×10^(−5) 𝑇^∗=𝜅𝑇
T (K) P (ATM) √𝑀𝑇/(𝜎^2 Ω_𝜇 ) /𝜖
300 1

M sigma e/k USANDO INTERPOLACIÓN


44.01 3.996 190 kT/e
omega
T* = kT/e omega OMEGA
1.57894737 1.08516384 0.15482702 0.04603578 1.28602664
Ω_𝜇=1.16145/𝑇^(∗0.14874) +0.52487/𝑒^(0.77320𝑇^∗ )
+2.16178/𝑒^(2.43787𝑇^∗ )

mu (poise) mu (poise)
0.00014936 0.00014923

diferencia % absoluta entre resultados


0.08788805
SANDO INTERPOLACIÓN
1.55 1.57894737 1.6
1.297 1.28715789 1.28
Calcula la viscocidad de la sig. mezcla de gases a 1 atmy 293 k, a partir de los datos
proporcionados sobre los compuestos puras a la misma presion y temperatura

mua
Esp.α F.Mol xα Peso M. μα Visc. Μ. μα
1 CO2 0.133 44.01 0.0001462 part 1
2 O2 0.039 32 0.0002031 0.35355339
3 N2 0.828 28.02 0.0001754

α β φαβ x x*φ Suma xa*mua


1 1 1 0.133 0.133
1 2 0.72966369 0.039 0.028456884 0.76327865 0.0000194446
1 3 0.72683788 0.828 0.601821765
2 1 1.39407673 0.133 0.185412205
2 2 1 0.039 0.039 1.05756715 0.0000079209
2 3 1.00622578 0.828 0.833154944
3 1 1.3696292 0.133 0.182160684
3 2 0.9924233 0.039 0.038704509 1.04886519 0.0001452312
3 3 1 0.828 0.828
. viscosidad me
part 1 part 2 part 3
0.35355339 0.70710678 4
0.35355339 0.648843 3.18073954
0.35355339 0.62370232 3.2961365

part 2 part 3 0.35355339 0.76092231 5.18192775


(1+(/))^(-1/2) ((1+((/)^0.5)*(/)^(1/4)))^2 0.35355339 0.70710678 4
0.35355339 0.68326012 4.16537746

dividir 0.35355339 0.78166196 4.95597406


0.35355339 0.73017506 3.84427947
2.54751E-05 0.35355339 0.70710678 4

ex
7.489737E-06 ej 4
ley de potencoa ec
ejer para viscocidad, viscodiades criticas
0.0001384651

0.0001714299

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