... BC, Canada University of Sussex, Brighton, UK University of Florida, Gainesville, FL Universi... more ... BC, Canada University of Sussex, Brighton, UK University of Florida, Gainesville, FL University of ... LIST OF PARTICIPANTS KLEIDMAN, Peter B. KRAMER, Earl E. KREHER, Don L. LAMKEN ... Paul J. SEIDEL, Jaap J. SHULT, Ernie SIEMONS, Johannes SPENCE, Ted STINSON ...
The editors of this journal are pleased to offer electronic publication of accepted papers prior ... more The editors of this journal are pleased to offer electronic publication of accepted papers prior to print publication. These papers can be cited using the date of access and the unique DOI number. Any final changes in manuscripts will be made at the time of print publication and ...
The editors of this journal are pleased to offer electronic publication of accepted papers prior ... more The editors of this journal are pleased to offer electronic publication of accepted papers prior to print publication. These papers can be cited using the date of access and the unique DOI number. Any final changes in manuscripts will be made at the time of print publication and will be reflected in the final electronic version of the issue.
The editors of this journal are pleased to offer electronic publication of accepted papers prior ... more The editors of this journal are pleased to offer electronic publication of accepted papers prior to print publication. These papers can be cited using the date of access and the unique DOI number. Any final changes in manuscripts will be made at the time of print publication and ...
... 122-126 Budacia Elisabeta Andreea, Avram Emanuela Maria and Perju Alexandra REGIONAL CUSTOMS ... more ... 122-126 Budacia Elisabeta Andreea, Avram Emanuela Maria and Perju Alexandra REGIONAL CUSTOMS DIRECTORATES MANAGEMENT pp. ... 280-286 Hahn Rada Florina, Sabou Simona and Zima Liliana Adela PATRIARCHY IN THE SCHOOL: COVARIATES OF GENDER ...
... 97 Nikola arić, Irena Orović, Srdjan Stanković, Cornel Ioana; MONTENEGRO / FRANCE Space/Spat... more ... 97 Nikola arić, Irena Orović, Srdjan Stanković, Cornel Ioana; MONTENEGRO / FRANCE Space/Spatial-Frequency Based Image ... Liljana Gavrilovska, Vladimir Atanasovski, Valentin Rakovic, Ognen Ognenoski, Aleksandar Momiroski; MACEDONIA Providing Interoperability in ...
... Janssen Luiz Antonio Joia Ralf Klischewski Trond Knudsen Helmut Krcmar Herbert Kubicek Christ... more ... Janssen Luiz Antonio Joia Ralf Klischewski Trond Knudsen Helmut Krcmar Herbert Kubicek Christine Leitner Katarina Lindblad-Gidlund ... X Organization Additional Reviewers DimitrisApostolou, Greece Gaston Concha, Chile Ciprian Dobre, Romania Marleen Haase, Austria ...
... Spitkovsky (Williamsburg, VA, USA) Honorary and Advisory Editorial Board: Lewis A. Coburn (Bu... more ... Spitkovsky (Williamsburg, VA, USA) Honorary and Advisory Editorial Board: Lewis A. Coburn (Buffalo, NY, USA) Ciprian Foias (College ... Ireland Derek Kitson, Trinity College Dublin, Dublin, Ireland Rupert Levene, Trinity College Dublin, Dublin, Ireland Bojan Magajna, University ...
The reaction of RH (1) with Hg(OAc)(2), in EtOH, gave the acetate RHgOAc (2) [R = 2,6-[O(CH(2)CH(... more The reaction of RH (1) with Hg(OAc)(2), in EtOH, gave the acetate RHgOAc (2) [R = 2,6-[O(CH(2)CH(2))(2)NCH(2)](2)C(6)H(3)]. The corresponding RHgCl (3) was obtained from 2 and LiCl. The reaction of 3 with TeCl(4) (1:1 molar ratio), in anhydrous 1,4-dioxane, resulted in the transfer of the organic ligand from mercury to tellurium and the isolation of the unexpected ionic compounds [RTe](2)[Hg(2)Cl(6)] (4) and [RH(3)][HgCl(4)] (5). The molecular structures of 1-4 and 5·H(2)O were established by single-crystal X-ray diffraction. The acetate 2 and the chloride 3 are monomeric in solid state. In both mercury and tellurium organometallic compounds the organic group acts as an (N,C,N) "pincer" ligand. This coordination pattern provided stability for the rare [RTe](+) cation. Weak cation-anion interactions [Te···Cl 3.869(3) Å] are present between [RTe](+) and the dinuclear anion [Hg(2)Cl(6)](2-) in the crystal of 4. Theoretical calculations with DFT methods were performed for models of 3 and 4. The results show that in the cation of 4 the coordination of the nitrogen atoms play an important role for the stabilization of the structure found in the crystal whereas in 3 the coordination of the nitrogen atoms to the metal centre stabilizes to a less extent the structure found in solid state.
Hypervalent organoantimony(III) compounds of the type [2-(Me2NCH2)C6H4]PhSbCl (1), [2-(Me2NCH2)C6... more Hypervalent organoantimony(III) compounds of the type [2-(Me2NCH2)C6H4]PhSbCl (1), [2-(Me2NCH2)C6H4]MesSbBr (7) and [2-(Me2NCH2)C6H4]nAr(3-n)Sb [n = 1, Ar = Ph (4), Mes (9); n = 2, Ar = Ph (5), Mes (10)] were prepared via salt elimination reactions between [2-(Me2NCH2)C6H4]Li and MesMgBr and PhnSbCl(3-n), [2-(Me2NCH2)C6H4]SbBr2 or [2-(Me2NCH2)C6H4]nSbCl(3-n) (n = 1, 2), in appropriate molar ratios. Halogen exchange reactions with aqueous KBr or KI gave [2-(Me2NCH2)C6H4]ArSbX [Ar = Ph, X = Br (2), I (3); Ar = Mes, X = I (8)]. Metathesis reaction between 1 and MesMgBr affords [2-(Me2NCH2)C6H4]PhMesSb (6). Compounds 1-10 were investigated by means of NMR (1H, 13C) in solution and by mass spectrometry. The investigation of the molecular structures of 2-8 by single-crystal X-ray diffraction revealed that the nitrogen atoms of the pendant CH2NMe2 arms are strongly coordinated to the antimony atoms. All compounds exhibit chirality and crystallize as racemic mixtures.
... BC, Canada University of Sussex, Brighton, UK University of Florida, Gainesville, FL Universi... more ... BC, Canada University of Sussex, Brighton, UK University of Florida, Gainesville, FL University of ... LIST OF PARTICIPANTS KLEIDMAN, Peter B. KRAMER, Earl E. KREHER, Don L. LAMKEN ... Paul J. SEIDEL, Jaap J. SHULT, Ernie SIEMONS, Johannes SPENCE, Ted STINSON ...
The editors of this journal are pleased to offer electronic publication of accepted papers prior ... more The editors of this journal are pleased to offer electronic publication of accepted papers prior to print publication. These papers can be cited using the date of access and the unique DOI number. Any final changes in manuscripts will be made at the time of print publication and ...
The editors of this journal are pleased to offer electronic publication of accepted papers prior ... more The editors of this journal are pleased to offer electronic publication of accepted papers prior to print publication. These papers can be cited using the date of access and the unique DOI number. Any final changes in manuscripts will be made at the time of print publication and will be reflected in the final electronic version of the issue.
The editors of this journal are pleased to offer electronic publication of accepted papers prior ... more The editors of this journal are pleased to offer electronic publication of accepted papers prior to print publication. These papers can be cited using the date of access and the unique DOI number. Any final changes in manuscripts will be made at the time of print publication and ...
... 122-126 Budacia Elisabeta Andreea, Avram Emanuela Maria and Perju Alexandra REGIONAL CUSTOMS ... more ... 122-126 Budacia Elisabeta Andreea, Avram Emanuela Maria and Perju Alexandra REGIONAL CUSTOMS DIRECTORATES MANAGEMENT pp. ... 280-286 Hahn Rada Florina, Sabou Simona and Zima Liliana Adela PATRIARCHY IN THE SCHOOL: COVARIATES OF GENDER ...
... 97 Nikola arić, Irena Orović, Srdjan Stanković, Cornel Ioana; MONTENEGRO / FRANCE Space/Spat... more ... 97 Nikola arić, Irena Orović, Srdjan Stanković, Cornel Ioana; MONTENEGRO / FRANCE Space/Spatial-Frequency Based Image ... Liljana Gavrilovska, Vladimir Atanasovski, Valentin Rakovic, Ognen Ognenoski, Aleksandar Momiroski; MACEDONIA Providing Interoperability in ...
... Janssen Luiz Antonio Joia Ralf Klischewski Trond Knudsen Helmut Krcmar Herbert Kubicek Christ... more ... Janssen Luiz Antonio Joia Ralf Klischewski Trond Knudsen Helmut Krcmar Herbert Kubicek Christine Leitner Katarina Lindblad-Gidlund ... X Organization Additional Reviewers DimitrisApostolou, Greece Gaston Concha, Chile Ciprian Dobre, Romania Marleen Haase, Austria ...
... Spitkovsky (Williamsburg, VA, USA) Honorary and Advisory Editorial Board: Lewis A. Coburn (Bu... more ... Spitkovsky (Williamsburg, VA, USA) Honorary and Advisory Editorial Board: Lewis A. Coburn (Buffalo, NY, USA) Ciprian Foias (College ... Ireland Derek Kitson, Trinity College Dublin, Dublin, Ireland Rupert Levene, Trinity College Dublin, Dublin, Ireland Bojan Magajna, University ...
The reaction of RH (1) with Hg(OAc)(2), in EtOH, gave the acetate RHgOAc (2) [R = 2,6-[O(CH(2)CH(... more The reaction of RH (1) with Hg(OAc)(2), in EtOH, gave the acetate RHgOAc (2) [R = 2,6-[O(CH(2)CH(2))(2)NCH(2)](2)C(6)H(3)]. The corresponding RHgCl (3) was obtained from 2 and LiCl. The reaction of 3 with TeCl(4) (1:1 molar ratio), in anhydrous 1,4-dioxane, resulted in the transfer of the organic ligand from mercury to tellurium and the isolation of the unexpected ionic compounds [RTe](2)[Hg(2)Cl(6)] (4) and [RH(3)][HgCl(4)] (5). The molecular structures of 1-4 and 5·H(2)O were established by single-crystal X-ray diffraction. The acetate 2 and the chloride 3 are monomeric in solid state. In both mercury and tellurium organometallic compounds the organic group acts as an (N,C,N) "pincer" ligand. This coordination pattern provided stability for the rare [RTe](+) cation. Weak cation-anion interactions [Te···Cl 3.869(3) Å] are present between [RTe](+) and the dinuclear anion [Hg(2)Cl(6)](2-) in the crystal of 4. Theoretical calculations with DFT methods were performed for models of 3 and 4. The results show that in the cation of 4 the coordination of the nitrogen atoms play an important role for the stabilization of the structure found in the crystal whereas in 3 the coordination of the nitrogen atoms to the metal centre stabilizes to a less extent the structure found in solid state.
Hypervalent organoantimony(III) compounds of the type [2-(Me2NCH2)C6H4]PhSbCl (1), [2-(Me2NCH2)C6... more Hypervalent organoantimony(III) compounds of the type [2-(Me2NCH2)C6H4]PhSbCl (1), [2-(Me2NCH2)C6H4]MesSbBr (7) and [2-(Me2NCH2)C6H4]nAr(3-n)Sb [n = 1, Ar = Ph (4), Mes (9); n = 2, Ar = Ph (5), Mes (10)] were prepared via salt elimination reactions between [2-(Me2NCH2)C6H4]Li and MesMgBr and PhnSbCl(3-n), [2-(Me2NCH2)C6H4]SbBr2 or [2-(Me2NCH2)C6H4]nSbCl(3-n) (n = 1, 2), in appropriate molar ratios. Halogen exchange reactions with aqueous KBr or KI gave [2-(Me2NCH2)C6H4]ArSbX [Ar = Ph, X = Br (2), I (3); Ar = Mes, X = I (8)]. Metathesis reaction between 1 and MesMgBr affords [2-(Me2NCH2)C6H4]PhMesSb (6). Compounds 1-10 were investigated by means of NMR (1H, 13C) in solution and by mass spectrometry. The investigation of the molecular structures of 2-8 by single-crystal X-ray diffraction revealed that the nitrogen atoms of the pendant CH2NMe2 arms are strongly coordinated to the antimony atoms. All compounds exhibit chirality and crystallize as racemic mixtures.
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