Bioenergy production from waste is one of the emerging and viable routes from renewable resources... more Bioenergy production from waste is one of the emerging and viable routes from renewable resources (in addition to wind and solar energy). Many developing countries can benefit from this as they are trying to solve the large amounts of unattended garbage in landfills. This waste comes in either liquid (wastewater and oil) or solid (food and agricultural residues) form. Waste has negative impacts on the environment and, consequently, any form of life that exists therein. One way of solving this waste issue is through its usage as a resource for producing valuable products, such as biofuels, thus, creating a circular economy, which is in line with the United Nations (UN) Sustainable Development Goals (SDGs) 5, 7, 8, 9, and 13. Biofuel in the form of biogas can be produced from feedstocks, such as industrial wastewater and municipal effluent, as well as organic solid waste in a process called anaerobic digestion. The feedstock can be used as an individual substrate for anaerobic digesti...
Biochar - Productive Technologies, Properties and Application [Working Title]
Biochar, or carbon obtained from biomass, is a particularly rich source of carbon created by ther... more Biochar, or carbon obtained from biomass, is a particularly rich source of carbon created by thermal burning of biomass. There is a rise of interest in using biochar made from waste biomass in a variety of disciplines to address the most pressing environmental challenges. This chapter will provide an overview on the methods employed for the production of biochar. Biochar has been considered by a number of analysts as a means of improving their ability to remediate pollutants. Process factors with regards to biochar properties are mostly responsible for determining biomass production which is discussed in this present chapter. Several characterization techniques which have been employed in previous studies have received increasing recognition. These includes the use of the Fourier transform infrared spectroscopy and the Scanning electron microscope which duly presented in this chapter. This chapter also discusses the knowledge gaps and future perspectives in adopting biochar to remed...
A thesis submitted to the Faculty of Science and Agriculture in fulfillment of the requirements f... more A thesis submitted to the Faculty of Science and Agriculture in fulfillment of the requirements for the Degree of Master Of Science (Chemistry) in the Department of Chemistry at the University of Zululand, 2018
For over a decade, ionic liquids (ILs) have attracted enormous attention from scientists across t... more For over a decade, ionic liquids (ILs) have attracted enormous attention from scientists across the globe. The history of these compounds traces back to 1914 where the inception of the first IL with a melting point of 12°C was made. Years later, a progression of the remarkable related compounds have been discovered. Out of many analogous compounds realized from time to time, the imidazolium class of ionic liquid is the most studied because of their air and moisture stability. The physicochemical properties of ILs differ significantly depending on the anionic/cationic species and alkyl chain length. ILs have found application in many scientific fields the most recent being good solvents and stabilizing agents in the nanomaterial synthesis. Studies have showed that ILs not only stabilize as synthesized nanomaterials but also provide environmentally green routes towards nanomaterials engineering.
We report a green route for the synthesis of PbS nanoparticles in an imidazolium based ionic liqu... more We report a green route for the synthesis of PbS nanoparticles in an imidazolium based ionic liquid (IL) (1-ethyl-3-methylimidazolium methanesulfonate) using single source and dual source precursor methods. Lead ethyl xanthogenate complex was used as single source molecular precursor for the synthesis of PbS nanoparticles, whereas in dual source approach organic sulfur (1-dodecanethiol) and inorganic sulfur (sodium sulfide) sources were used to observe the suitability of different sulfur sources on formation of PbS nanoparticles. The results showed that the temperature has an effect on the as prepared nanoparticles for both routes. X-ray diffraction (XRD) studies confirmed formation of cubic phase of PbS from both routes. Electron microscopy techniques showed that the nanoparticle morphologies differed significantly depending on the synthetic factors such as temperature, nature of precursors and ranged from spherical to cubic shapes.
Bioenergy production from waste is one of the emerging and viable routes from renewable resources... more Bioenergy production from waste is one of the emerging and viable routes from renewable resources (in addition to wind and solar energy). Many developing countries can benefit from this as they are trying to solve the large amounts of unattended garbage in landfills. This waste comes in either liquid (wastewater and oil) or solid (food and agricultural residues) form. Waste has negative impacts on the environment and, consequently, any form of life that exists therein. One way of solving this waste issue is through its usage as a resource for producing valuable products, such as biofuels, thus, creating a circular economy, which is in line with the United Nations (UN) Sustainable Development Goals (SDGs) 5, 7, 8, 9, and 13. Biofuel in the form of biogas can be produced from feedstocks, such as industrial wastewater and municipal effluent, as well as organic solid waste in a process called anaerobic digestion. The feedstock can be used as an individual substrate for anaerobic digesti...
Biochar - Productive Technologies, Properties and Application [Working Title]
Biochar, or carbon obtained from biomass, is a particularly rich source of carbon created by ther... more Biochar, or carbon obtained from biomass, is a particularly rich source of carbon created by thermal burning of biomass. There is a rise of interest in using biochar made from waste biomass in a variety of disciplines to address the most pressing environmental challenges. This chapter will provide an overview on the methods employed for the production of biochar. Biochar has been considered by a number of analysts as a means of improving their ability to remediate pollutants. Process factors with regards to biochar properties are mostly responsible for determining biomass production which is discussed in this present chapter. Several characterization techniques which have been employed in previous studies have received increasing recognition. These includes the use of the Fourier transform infrared spectroscopy and the Scanning electron microscope which duly presented in this chapter. This chapter also discusses the knowledge gaps and future perspectives in adopting biochar to remed...
A thesis submitted to the Faculty of Science and Agriculture in fulfillment of the requirements f... more A thesis submitted to the Faculty of Science and Agriculture in fulfillment of the requirements for the Degree of Master Of Science (Chemistry) in the Department of Chemistry at the University of Zululand, 2018
For over a decade, ionic liquids (ILs) have attracted enormous attention from scientists across t... more For over a decade, ionic liquids (ILs) have attracted enormous attention from scientists across the globe. The history of these compounds traces back to 1914 where the inception of the first IL with a melting point of 12°C was made. Years later, a progression of the remarkable related compounds have been discovered. Out of many analogous compounds realized from time to time, the imidazolium class of ionic liquid is the most studied because of their air and moisture stability. The physicochemical properties of ILs differ significantly depending on the anionic/cationic species and alkyl chain length. ILs have found application in many scientific fields the most recent being good solvents and stabilizing agents in the nanomaterial synthesis. Studies have showed that ILs not only stabilize as synthesized nanomaterials but also provide environmentally green routes towards nanomaterials engineering.
We report a green route for the synthesis of PbS nanoparticles in an imidazolium based ionic liqu... more We report a green route for the synthesis of PbS nanoparticles in an imidazolium based ionic liquid (IL) (1-ethyl-3-methylimidazolium methanesulfonate) using single source and dual source precursor methods. Lead ethyl xanthogenate complex was used as single source molecular precursor for the synthesis of PbS nanoparticles, whereas in dual source approach organic sulfur (1-dodecanethiol) and inorganic sulfur (sodium sulfide) sources were used to observe the suitability of different sulfur sources on formation of PbS nanoparticles. The results showed that the temperature has an effect on the as prepared nanoparticles for both routes. X-ray diffraction (XRD) studies confirmed formation of cubic phase of PbS from both routes. Electron microscopy techniques showed that the nanoparticle morphologies differed significantly depending on the synthetic factors such as temperature, nature of precursors and ranged from spherical to cubic shapes.
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Papers by Zikhona Tshemese