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Exploring the synthesis of poly(azomethine-ester) through oxidative polycondensation of salicylaldehyde schiff bases

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Abstract

This work outlines the synthesis of Schiff base derivatives through the reaction of O-acyl salicylaldehyde with diverse amines, facilitated by ethanol as a solvent. The derivatives were structurally analyzed using 1H and 13C-NMR, FT-IR, and LC–MS techniques. The Schiff base derivative, bearing a phenol moiety, subsequently underwent oxidative polycondensation reaction in water, employing NaOCl as the mild and safe oxidant, presenting a sustainable alternative to conventional methods. The polymer was then subjected to investigations using 1H-NMR, FT-IR, DSC, TGA, SEM, and EDX spectroscopies, revealing exceptional thermal stability suitable for high-temperature applications. The results not only contribute to the development of poly(azomethine-ester) but also highlight the importance of adopting environmentally friendly methodologies in materials synthesis. The findings highlight the potential biological applications of the imine linkage and emphasize the use of green chemistry principles to promote sustainability in synthetic chemistry practices.

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Data Availability

The data that support the findings of this study are available from the corresponding author upon reasonablerequest.

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Acknowledgements

The author, Aashna Perwin expresses gratitude to the UGC for granting a fellowship and acknowledges the assistance received from IIT Delhi, MNIT-Jaipur, and CIF-JMI for conducting instrumental analysis on the samples.

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  1. Department of Chemistry, Jamia Millia Islamia, New Delhi, 110025, India

    Aashna Perwin & Nasreen Mazumdar

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Perwin, A., Mazumdar, N. Exploring the synthesis of poly(azomethine-ester) through oxidative polycondensation of salicylaldehyde schiff bases. J Polym Res 31, 214 (2024). https://doi.org/10.1007/s10965-024-04070-9

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