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A facile synthesis of UiO-66 systems and their hydrothermal stability

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Abstract

Zirconium-based UiO-66 type MOFs were synthesized using a standard reflux apparatus under a nitrogen atmosphere. This simple synthetic protocol was scaled up to 1 L scale, and can be readily scaled up to allow industrial production of high quality, homogeneous crystalline UiO-66 type MOF materials. The MOFs synthesized in this work exhibited excellent hydrothermal stability.

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Acknowledgements

Authors thank Mr. Yusuke Mukae for the calculation of solvent surface area of MOFs.

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Authors and Affiliations

  1. Toyota Central R&D Labs., Inc., Nagakute, Aichi, 480-1192, Japan

    Hirofumi Motegi, Kazuhisa Yano, Norihiko Setoyama, Yoriko Matsuoka, Tetsushi Ohmura & Arimitsu Usuki

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  1. Hirofumi Motegi
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  2. Kazuhisa Yano
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  3. Norihiko Setoyama
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  4. Yoriko Matsuoka
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  5. Tetsushi Ohmura
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  6. Arimitsu Usuki
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Corresponding author

Correspondence to Kazuhisa Yano.

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Motegi, H., Yano, K., Setoyama, N. et al. A facile synthesis of UiO-66 systems and their hydrothermal stability. J Porous Mater 24, 1327–1333 (2017). https://doi.org/10.1007/s10934-017-0374-5

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