FeSe (en) 0.3-Separated FeSe layers with stripe-type crystal structure by intercalation of neutral spacer molecules

J Stahl, D Johrendt - arXiv preprint arXiv:1706.00314, 2017 - arxiv.org
J Stahl, D Johrendt
arXiv preprint arXiv:1706.00314, 2017arxiv.org
Solvothermal intercalation of ethylenediamine molecules into FeSe separates the layers by
1078 pm and creates a different stacking. FeSe (en) 0.3 is not superconducting although
each layer exhibits the stripe-type crystal structure and the Fermi surface topology of
superconducting FeSe. FeSe (en) 0.3 requires electron-doping for high-Tc similar to
monolayers of FeSe@ SrTiO3, whose much higher Tc may arise from the proximity of the
oxide surface.
Solvothermal intercalation of ethylenediamine molecules into FeSe separates the layers by 1078 pm and creates a different stacking. FeSe(en)0.3 is not superconducting although each layer exhibits the stripe-type crystal structure and the Fermi surface topology of superconducting FeSe. FeSe(en)0.3 requires electron-doping for high-Tc similar to monolayers of FeSe@SrTiO3, whose much higher Tc may arise from the proximity of the oxide surface.
arxiv.org