Comment on “Unconventional enhancement of ferromagnetic interactions in Cd-doped single crystals studied by ESR and Mössbauer spectroscopies”

PC Canfield, SL Bud'ko, A Palasyuk, TJ Slade - Physical Review B, 2021 - APS
Physical Review B, 2021APS
In the recent publication [Phys. Rev. B 102, 144420 (2020) PRBHB7 2469-9950
10.1103/PhysRevB. 102.144420], Cabrera-Baez et al., present a study of the effects of Cd
substitution for Zn in the ferromagnetic compound GdFe 2 Zn 20. As part of this paper they
claim that for GdFe 2 Zn 18.6 Cd 1.4 the effective moment of Gd is reduced by 25%, and the
saturated moment of Gd is reduced by over 40%. We regrew representative members of the
GdFe 2 Zn 20− x Cd x series and did not find any such reductions. In addition, we measured …
In the recent publication [Phys. Rev. B 102, 144420 (2020)PRBHB72469-995010.1103/PhysRevB.102.144420], Cabrera-Baez et al., present a study of the effects of Cd substitution for Zn in the ferromagnetic compound . As part of this paper they claim that for the effective moment of Gd is reduced by 25%, and the saturated moment of Gd is reduced by over 40%. We regrew representative members of the series and did not find any such reductions. In addition, we measured several crystals from the growth batch that was used by Cabrera-Baez et al. and did not see such reductions. Although there is a modest increase in with Cd substitution, there is no significant change in the Gd effective moment or the saturated moment associated with the low-temperature ferromagnetic state.
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