Spin-Orbit Excitons in a Correlated Metal: Raman Scattering Study of

L Wang, H Liu, V Zimmermann, AK Yogi, M Isobe… - Physical Review Letters, 2024 - APS
L Wang, H Liu, V Zimmermann, AK Yogi, M Isobe, M Minola, M Hepting, G Khaliullin…
Physical Review Letters, 2024APS
Using Raman spectroscopy to study the correlated 4 d-electron metal Sr 2 RhO 4, we
observe pronounced excitations at 220 meV and 240 meV with A 1 g and B 1 g symmetries,
respectively. We identify them as transitions between the spin-orbit multiplets of the Rh ions,
in close analogy to the spin-orbit excitons in the Mott insulators Sr 2 IrO 4 and α-RuCl 3. This
observation provides direct evidence for the unquenched spin-orbit coupling in Sr 2 RhO 4.
A quantitative analysis of the data reveals that the tetragonal crystal field Δ in Sr 2 RhO 4 has …
Using Raman spectroscopy to study the correlated -electron metal , we observe pronounced excitations at 220 meV and 240 meV with and symmetries, respectively. We identify them as transitions between the spin-orbit multiplets of the Rh ions, in close analogy to the spin-orbit excitons in the Mott insulators and . This observation provides direct evidence for the unquenched spin-orbit coupling in . A quantitative analysis of the data reveals that the tetragonal crystal field in has a sign opposite to that in insulating , which enhances the planar orbital character of the effective wave function. This supports a metallic ground state, and suggests that -axis compression of may transform it into a quasi-two-dimensional antiferromagnetic insulator.
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