An ancient and counterintuitive phenomenon know as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for speeding up relaxation is an important but challenging task in purely quantum system till now. Here, we report the first experiment, as far as we know,about the strong Mpemba effect in a single trapped ion system in which an exponentially expedited relaxation in time is observed by preparing an optimal initial state with no excitation of the slowest decaying mode. Also, we find that the condition of realizing such effect coincides with the Liouvillian exceptional point, featuring the coalescence of both the eigenvalues and the eigenmodes of the system. Our work provides an efficient strategy to exponentially accelerate relaxations of quantum system to their stationary state, and suggests a link unexplored yet between the Mpemba effect and the non-Hermitian physics. It could open up the door to engineer a wide range of dissipative quantum systems by utilizing the anomalous Mpemba effect, for applications in quantum simulation and quantum information processing.