2-Methyl-4-chlorophenoxyacetic acid (MCPA) is a highly mobile herbicide that is frequently detect... more 2-Methyl-4-chlorophenoxyacetic acid (MCPA) is a highly mobile herbicide that is frequently detected in global potable water sources. One potential mitigation strategy is the sorption on biochar to limit harm to unidentified targets. However, irreversible sorption could restrict bioefficacy thereby compromising its usefulness as a vital crop herbicide. This research evaluated the effect of pyrolysis temperatures (350, 500 and 800°C) on three feedstocks; poultry manure, rice hulls and wood pellets, particularly to examine effects on the magnitude and reversibility of MCPA sorption. Sorption increased with pyrolysis temperature from 350 to 800°C. Sorption and desorption coefficients were strongly corelated with each other (R2 = 0.99; P < .05). Poultry manure and rice hulls pyrolyzed at 800°C exhibited irreversible sorption while for wood pellets at 800°C desorption was concentration dependent. At higher concentrations some desorption was observed (36% at 50 ppm) but was reduced at l...
Mechanized sugarcane harvest is replacing the historic practice of field burning, due to environm... more Mechanized sugarcane harvest is replacing the historic practice of field burning, due to environmental concerns of the particulate and emissions during burning. However, the impact of these practices on soil greenhouse gas (GHG) production potential is not fully known. Thus, the present work quantified the potential production, in 1 g of soil, of greenhouse gases (GHG) in three systems of sugarcane management. The systems were: area with a history of burning sugarcane before harvest (B) and another with two systems of management of “green sugarcane” in two periods of implantation - 5 (G-5) and 10 years (G-10). A laboratory incubation experiment was used to assess the production potentials of carbon dioxide (CO2), nitrous oxide (N2O) and methane (CH4) in 1g of soil samples by the different sugarcane management systems. The results of this study demonstrate that the sugarcane management systems had an impact on the potential production of CO2 in the soil. In addition, when the results...
2-Methyl-4-chlorophenoxyacetic acid (MCPA) is a highly mobile herbicide that is frequently detect... more 2-Methyl-4-chlorophenoxyacetic acid (MCPA) is a highly mobile herbicide that is frequently detected in global potable water sources. One potential mitigation strategy is the sorption on biochar to limit harm to unidentified targets. However, irreversible sorption could restrict bioefficacy thereby compromising its usefulness as a vital crop herbicide. This research evaluated the effect of pyrolysis temperatures (350, 500 and 800°C) on three feedstocks; poultry manure, rice hulls and wood pellets, particularly to examine effects on the magnitude and reversibility of MCPA sorption. Sorption increased with pyrolysis temperature from 350 to 800°C. Sorption and desorption coefficients were strongly corelated with each other (R2 = 0.99; P < .05). Poultry manure and rice hulls pyrolyzed at 800°C exhibited irreversible sorption while for wood pellets at 800°C desorption was concentration dependent. At higher concentrations some desorption was observed (36% at 50 ppm) but was reduced at l...
Mechanized sugarcane harvest is replacing the historic practice of field burning, due to environm... more Mechanized sugarcane harvest is replacing the historic practice of field burning, due to environmental concerns of the particulate and emissions during burning. However, the impact of these practices on soil greenhouse gas (GHG) production potential is not fully known. Thus, the present work quantified the potential production, in 1 g of soil, of greenhouse gases (GHG) in three systems of sugarcane management. The systems were: area with a history of burning sugarcane before harvest (B) and another with two systems of management of “green sugarcane” in two periods of implantation - 5 (G-5) and 10 years (G-10). A laboratory incubation experiment was used to assess the production potentials of carbon dioxide (CO2), nitrous oxide (N2O) and methane (CH4) in 1g of soil samples by the different sugarcane management systems. The results of this study demonstrate that the sugarcane management systems had an impact on the potential production of CO2 in the soil. In addition, when the results...
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Papers by Kurt Spokas