Formation of the alkoxyalkyl complexes [M{CHMe(OMe)}(CO)2(?-C5H4R)](M = Mo, R = H; M = W, R = H or Me) and their transformations by loss of MeOH into ?3-propenoyl or vinyl complexes. Crystal structures of [Mo{CHMe(PPh3)}(CO)2(PPh3)(?-C5H5)]BF4, [Mo(?3-CH2CHC?O)(CO)(PPh3)(?-C5H5)] and [W(?-CH?CH2)...
Formation of the alkoxyalkyl complexes [M{CHMe(OMe)}(CO)2(?-C5H4R)](M = Mo, R = H; M = W, R = H or Me) and their transformations by loss of MeOH into ?3-propenoyl or vinyl complexes. Crystal structures of [Mo{CHMe(PPh3)}(CO)2(PPh3)(?-C5H5)]BF4, [Mo(?3-CH2CHC?O)(CO)(PPh3)(?-C5H5)] and [W(?-CH?CH2)...
Journal of the Chemical Society, Dalton Transactions, 1991
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