- Daughter of actors Marcello Mastroianni and Catherine Deneuve.
- Had a long-term relationship Benicio Del Toro.
- Speaks English fluently, having attended a bilingual Montessori school in Paris.
- Has a daughter, Anna Biolay, born in 2003.
- Member of jury at the Cannes Film Festival in 1998.
- Married author, composer and singer Benjamin Biolay in Paris. They only met several months earlier. (May 11, 2002)
- Half Italian on her father's side and French on her mother's side.
- Has supported Lionel Jospin's 2002 presidential campaign.
- Her older half-brother is her mother's son, the actor Christian Vadim.
- Granddaughter of French actor Maurice Dorléac and French actress Renée Simonot.
- Has a son, Milo Thoretton, with Pierre Thoretton (a French sculptor). (December 31, 1996)
- Has been close friend to Melvil Poupaud since their college years.
- To English-speaking audiences, her most visible role to date has been playing Kim Basinger's assistant in Ready to Wear (1994).
- Released the album "Home" together with her then-husband Benjamin Biolay, in 2004.
- Cousin of Federica Mastroianni and Delphine Cantelli.
- Ex-sister-in-law of Coralie Clément.
- Half-sister of Barbara Mastroianni.
- Born at 11:30 pm CET.
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