- Reached fourth place in Miss Italy contest. (1996)
- She learned French in 4 months to play Jean Reno's sister in a French film.
- Murino was having a leg pain while filming the iconic horse riding scene in Casino Royale. Director Martin Campbell considered having a stunt performer to do it, but she refused a body double and performed the sequence herself.
- The day before Murino was scheduled to take an audition for the role in Casino Royale, she broke her rib in a horse riding accident. Yet she went ahead and gave the audition barely able to walk. She got a call back for next audition with the director Martin Campbell. This time being in a better health she ended up winning the role.
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