1. Introduction
Vanadium–titanium magnetite, as a strategic resource, is stored in China with reserves of 135 million tons, accounting for 37% of the world’s total [
1]. Extensive research has been conducted by predecessors, and processes for the efficient utilization of vanadium–titanium ore have been developed and perfected, providing a large quantity of high-quality vanadium–titanium products to the world annually. Compared to corresponding products without vanadium–titanium, the addition of vanadium–titanium can significantly improve the mechanical properties of the materials. For instance, the addition of an appropriate amount of vanadium to steel can enhance its wear resistance, strength, and hardness; titanium alloys, known for their high hardness and corrosion resistance, are widely used in fields such as aerospace and medicine [
2,
3]. These vanadium–titanium-containing products exhibit strong competitiveness compared to traditional products, so production units in the industry have more distinctive industrial characteristics. The expanded application of vanadium–titanium products will help promote the industrial development and upgrading of various countries. Among these resource utilization methods of vanadium–titanium magnetite, the blast furnace smelting process, in conjunction with the situation in China and many developing countries, enables the large-scale production of vanadium–titanium hot metal and slag, producing high value-added products while ensuring infrastructure construction.
Due to the titanium element being combined with carbon or nitrogen during the smelting process to form high-melting-point titanium carbide or carbonitride, the viscosity of the furnace slag is increased, making the separation of slag and iron difficult and reducing the desulfurization capacity, which significantly impacts the smooth operation of blast furnace smelting [
4,
5,
6,
7,
8]. Therefore, research on the blast furnace smelting of vanadium–titanium ore has been predominantly focused on vanadium–titanium slag over the past several decades. The effects of TiO
2 content on the melting and viscosity properties of vanadium–titanium slag have been investigated by Jing et al. [
9] and Pang et al. [
10]. The distribution behavior of Ti in slag and hot metal has been studied by Jiao et al. [
11], who found that a reduction in the operating temperature and carbon content in the hot metal can assist in decreasing the distribution of Ti into the hot metal. In order to improve the mobility of vanadium–titanium slag in blast furnace, Wang et al. [
12] and Lin et al. [
13] studied the effect of MgO and B
2O
3 content on vanadium–titanium slag and obtained their optimum ratio. The high-melting-point material in vanadium–titanium blast furnace slag is more sensitive to temperature, and compared with ordinary blast furnace slag, its existence plays a better role in protecting blast furnace lining. Typically, when the liquid slag and iron of a blast furnace pass through the cooling stave with low temperature in the furnace, the slag or molten iron can be solidified on the top to form a protective layer, thus reducing the erosion of the gas flow and the burden on the lining and enhancing the lifetime of the furnace lining [
14,
15]. With the increase in market demand for high-quality vanadium–titanium products, the smelting intensity of vanadium–titanium blast furnaces is increased to obtain more vanadium–titanium molten iron and vanadium–titanium slag. The smelting intensity of a blast furnace refers to the comprehensive dry coke amount or dry coke amount that can be burned in a day with an average effective volume per cubic meter of a blast furnace. It is an index of smelting speed. The improvement of blast furnace smelting intensity has an important influence on the change in multi-physical field in the furnace, which further tests the rationality of a blast furnace cooling system.
The blast furnace has been recognized as a large “black box” which complicates direct observations of the gas–solid flows within. Therefore, in the past, for a long time, the majority of researchers used experience to summarize the blast furnace smelting process. However, with the rapid advancement of computer technologies, the utilization of simulation and modeling to study substance flowing and multi-physics field changes within blast furnaces has become increasingly sophisticated. A two-dimensional full furnace model was established by Chu et al. [
16], which examined the effects of operational conditions on the internal state of the furnace. Numerical simulations of gas flow redistribution in the lump zone of a blast furnace shaft were conducted by Zhu et al. [
17]. To date, there have been few multi-physical field studies related to vanadium–titanium blast furnaces. This research focused on the temperature fields, velocity differences, and concentration fields in a vanadium–titanium blast furnace, revealing the internal working state of the furnace under various smelting intensities. This study is based on actual production data from a 1750 m
3 vanadium–titanium blast furnace, combined with experimentally measured parameters of softening and dripping and material balance calculations. A two-dimensional blast furnace model was developed using FLUENT to conduct numerical simulations of this furnace. This research provided a detailed description of the model’s formulation, solution methods, computational principles, and their application. The effects of high (1.40 t/(m
3·d)), medium (1.25 t/(m
3·d)), and low (0.80 t/(m
3·d)) smelting intensities on the internal state of the vanadium–titanium blast furnace were resolved, offering a theoretical basis for engineering applications. Low smelting intensity represents abnormal furnace conditions, while medium and high smelting intensities correspond to moderate and higher production efficiency, as well as the operational load of the blast furnace. The specific smelting intensity values were derived from a summary of historical data from the production site at Xichang Steel Vanadium of Pangang Group.
2. Model Development
A 2D model of the blast furnace was established based on the 2# blast furnace, which smelts vanadium–titanium magnetite, from Pangang Group Xichang Steel & Vanadium Co. Ltd. in China, as shown in
Figure 1. A two-dimensional structure grid is developed and is shown in
Figure 1b. The research object is the gas–solid reaction above the soft melt zone of vanadium–titanium blast furnace. Therefore, the two-phase flow is mainly considered in the mathematical model.
The model includes the flow, heat and mass transfer between gasses and solids, so the basic mathematical equations in the model include the conservation equations of mass, momentum, energy and chemical component transport, which can be described by Equation (1) under a steady state.
where i is the phase, the symbol “ϕ” represents the variable to be solved, and “Γ” and S denote the effective diffusion and source term for each variable, respectively. The term F characterizes the interactions between different phases, primarily including the gaseous phase (g) and solid phase (s). Based on a coordinate system (u and v), temperature (T), and mass fractions of chemical components (m), variables such as velocity components are calculated by solving conservation equations. The pressures of the gas and solid phases are computed through the continuity equation, which is derived by substituting the single variable “ϕ” into a unified formula, represented as Equation (1). The heat exchange between the gas and solid phases is incorporated into the source term S. In the mass conservation equations, the reaction rates of chemical components during phase changes are considered within the term F. The governing equations are shown in
Table 1 [
18].
Here, Rn refers to different reactions; MO, represents the molecular weight of O, kg/kmol; and represent the physical velocity of gasses and solids, respectively, m/s; and represent the specific enthalpy of gasses and solids, respectively, J/kg; and represent the equilibrium constant of gasses and solids, respectively; and represent the specific heat capacity of gasses and solids, respectively, J/kg/K; represents the stress tensor of gas, Pa; represents volume fraction of gas; P represents pressure, Pa; represents the density of the gas phase, kg/m3; represents gravitational acceleration, m/s2; represents volumetric heat flux, J/m3; and represents the specific enthalpy of reaction n, J/Kg.
The reactions included in the model are listed in
Table 2 [
19]. In the study of the internal processes of a furnace, the indirect chemical reactions occurring within are modeled using the unreacted core model. In this model, due to the presence of rate-limiting steps in the unreacted cores, only the reduction reactions of wüstite are considered.
In
Table 2, ε
ore is the ore volume fraction, %; F
ore is the volume fraction of ore in the solid phase, %; Φ
ore represents the average shape coefficient of the ore, 1. K
i.i and Deff
i.i represent the equilibrium constant and effective diffusion coefficient, respectively, which are taken from Takahashi et al.’s work [
20]. ki.i is the reduction rate constant which was taken from other work [
21,
22].
The standard k − ϵ turbulence model was employed to model the turbulent flow. The model constants used were turbulent viscosity coefficient (Cμ) = 0.09, TKE prandtl number = 1, TDR prandtl number = 1.3, energy prandtl number = 0.85, wall prandtl number = 0.85, and turbulent schmidt number = 0.7, with standard wall function.
The governing equations were discretized using the finite volume method (FVM), and the pressure–velocity coupling was solved using the SIMPLE algorithm.
The gas composition from the soft melting zone into the indirect reduction zone is calculated by the material balance, and the original condition of the material is listed in
Table 3. The calculation process refers to our previous research [
23]. The initial gas composition calculated by material balance is as follows: ① (smelting intensity 0.80 t/(m
3·d))40.19% CO, 1.39% H
2, 58.42% N
2; ② (smelting intensity 1.25 t/(m
3·d))42.96% CO, 4.64% H
2, 52.40% N
2; and ③ (smelting intensity 1.40 t/(m
3·d))44.03% CO, 5.72% H
2, 50.25% N
2.
At the inlet, a uniform velocity profile of gas was imposed, with velocities of 8.95 m/s, 9.00 m/s, and 9.05 m/s corresponding to low, medium, and high smelting intensities, respectively. The inlet temperatures of the gas under different smelting intensities were obtained from the softening–smelting experiment results (see
Section 3.1 for details). The no-slip boundary condition was applied on all solid walls, assuming zero velocity at the wall surface.
The temperature of the cohesive zone corresponding to different smelting intensities is obtained from the softening droplet experiment. The sample composition and experimental scheme are listed in
Table 4 and
Table 5, respectively. The experimental steps and instruments refer to our previous research [
24]. The results of the initial gas composition and softening temperature were then loaded in the simulation with a consideration of all the transfers and reactions. The conservation equations were solved numerically by the finite volume method with commercial software ANSYS FLUENT (release 2023 R1) [
25]. The simulation was considered to have converged when the residuals for each variable were less than 10
−5.
The assumptions for this model were as follows: (1) the powder phase was not considered; (2) other chemical reactions such as reduction of carbonate decomposition and reduction of non-ferrous compounds were ignored; (3) the initial gas temperature was 100 K higher than the temperature of the soft melting zone; and (4) the melting of solids was ignored.