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Keywords = Transport coefficients in plasmas

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19 pages, 3564 KiB  
Article
Data-Based Kinematic Viscosity and Rayleigh–Taylor Mixing Attributes in High-Energy Density Plasmas
by Snezhana I. Abarzhi and Kurt C. Williams
Atoms 2024, 12(10), 47; https://doi.org/10.3390/atoms12100047 - 24 Sep 2024
Viewed by 192
Abstract
We explore properties of matter and characteristics of Rayleigh–Taylor mixing by analyzing data gathered in the state-of-the-art fine-resolution experiments in high-energy density plasmas. The eminent quality data represent fluctuations spectra of the X-ray imagery intensity versus spatial frequency. We find, by using the [...] Read more.
We explore properties of matter and characteristics of Rayleigh–Taylor mixing by analyzing data gathered in the state-of-the-art fine-resolution experiments in high-energy density plasmas. The eminent quality data represent fluctuations spectra of the X-ray imagery intensity versus spatial frequency. We find, by using the rigorous statistical method, that the fluctuations spectra are accurately captured by a compound function, being a product of a power law and an exponential and describing, respectively, self-similar and scale-dependent spectral parts. From the self-similar part, we find that Rayleigh–Taylor mixing has steep spectra and strong correlations. From the scale-dependent part, we derive the first data-based value of the kinematic viscosity in high-energy density plasmas. Our results explain the experiments, agree with the group theory and other experiments, and carve the path for better understanding Rayleigh–Taylor mixing in nature and technology. Full article
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16 pages, 3379 KiB  
Article
Preanalytic Integrity of Blood Samples in Uncrewed Aerial Vehicle (UAV) Medical Transport: A Comparative Study
by Noel Stierlin, Fabian Loertscher, Harald Renz, Lorenz Risch and Martin Risch
Drones 2024, 8(9), 517; https://doi.org/10.3390/drones8090517 - 23 Sep 2024
Viewed by 284
Abstract
The integration of unmanned aerial vehicles or uncrewed aerial vehicles (UAVs)—commonly known as drones—into medical logistics offers transformative potential for the transportation of sensitive medical materials, such as blood samples. Traditional car transportation is often hindered by traffic delays, road conditions, and geographic [...] Read more.
The integration of unmanned aerial vehicles or uncrewed aerial vehicles (UAVs)—commonly known as drones—into medical logistics offers transformative potential for the transportation of sensitive medical materials, such as blood samples. Traditional car transportation is often hindered by traffic delays, road conditions, and geographic barriers, which can compromise timely delivery. This study provides a comprehensive analysis comparing high-speed drone transportation with traditional car transportation. Blood samples, including EDTA whole blood, serum, lithium-heparin plasma, and citrate plasma tubes, were transported via both methods across temperatures ranging from 4 to 20 degrees Celsius. The integrity of the samples was assessed using a wide array of analytes and statistical analyses, including Passing–Bablok regression and Bland–Altman plots. The results demonstrated that drone transportation maintains blood sample integrity comparable to traditional car transportation. For serum samples, the correlation coefficients (r) ranged from 0.830 to 1.000, and the slopes varied from 0.913 to 1.111, with minor discrepancies in five analytes (total bilirubin, calcium, ferritin, potassium, and sodium). Similar patterns were observed for EDTA, lithium-heparin, and citrate samples, indicating no significant differences between transportation methods. Conclusions: These findings highlight the potential of drones to enhance the efficiency and reliability of medical sample transport, particularly in scenarios requiring rapid and reliable delivery. Drones could significantly improve logistical operations in healthcare by overcoming traditional transportation challenges. Full article
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12 pages, 4062 KiB  
Article
Parametrization of Fluid Models for Electrical Breakdown of Nitrogen at Atmospheric Pressure
by Shirshak Kumar Dhali
Plasma 2024, 7(3), 721-732; https://doi.org/10.3390/plasma7030037 - 10 Sep 2024
Viewed by 380
Abstract
In the transient phase of an atmospheric pressure discharge, the avalanche turns into a streamer discharge with time. Hydrodynamic fluid models are frequently used to describe the formation and propagation of streamers, where charge particle transport is dominated by the creation of space [...] Read more.
In the transient phase of an atmospheric pressure discharge, the avalanche turns into a streamer discharge with time. Hydrodynamic fluid models are frequently used to describe the formation and propagation of streamers, where charge particle transport is dominated by the creation of space charge. The required electron transport data and rate coefficients for the fluid model are parameterized using the local mean energy approximation (LMEA) and the local field approximation (LFA). In atmospheric pressure applications, the excited species produced in the electrical discharge determine the subsequent conversion chemistry. We performed the fluid model simulation of streamers in nitrogen gas at atmospheric pressure using three different parametrizations for transport and electron excitation rate data. We present the spatial and temporal development of several macroscopic properties such as electron density and energy, and the electric field during the transient phase. The species production efficiency, which is important to understand the efficacy of any application of non-thermal plasmas, is also obtained for the three different parametrizations. Our results suggest that at atmospheric pressure, all three schemes predicted essentially the same macroscopic properties. Therefore, a lower-order method such as LFA, which does not require the solution of the energy conservation equation, should be adequate to determine streamer macroscopic properties to inform most plasma-assisted applications of nitrogen-containing gases at atmospheric pressure. Full article
(This article belongs to the Special Issue Processes in Atmospheric Pressure Plasmas)
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11 pages, 2119 KiB  
Article
Assessment of the Atmospheric Deposition of Potentially Toxic Elements Using Moss Pleurozium schreberi in an Urban Area: The Perm (Perm Region, Russia) Case Study
by Evgeniya Gatina, Inga Zinicovscaia, Nikita Yushin, Omari Chaligava, Marina Frontasyeva and Alina Sharipova
Plants 2024, 13(17), 2353; https://doi.org/10.3390/plants13172353 - 23 Aug 2024
Viewed by 440
Abstract
Assessment of air quality in urban areas is very important because pollutants affect both the environment and human health. In Perm (Russia), a moss biomonitoring method was used to assess the level of air pollution. The concentrations of 15 elements in 87 samples [...] Read more.
Assessment of air quality in urban areas is very important because pollutants affect both the environment and human health. In Perm (Russia), a moss biomonitoring method was used to assess the level of air pollution. The concentrations of 15 elements in 87 samples of moss Pleurozium schreberi in the city territory were determined using a direct mercury analyzer and an inductively coupled plasma atomic emission spectroscopy. Using factor and correlation analyses, the grouping of elements and their relationship with emission sources were established. The main sources of emissions of potentially toxic elements are the transportation (road and rail), metallurgical, and chemical industries. The level of atmospheric air pollution was assessed by calculating the environmental risk index, pollutant load index, and pollution coefficient. Based on the values of the pollution index, the level of atmospheric air pollution in Perm varies from unpolluted to highly polluted, with moderate environmental risk. Full article
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16 pages, 600 KiB  
Review
Dissipative Kinematics in Binary Neutron Star Mergers
by Sreemoyee Sarkar and Souvik Priyam Adhya
Universe 2024, 10(7), 303; https://doi.org/10.3390/universe10070303 - 22 Jul 2024
Viewed by 582
Abstract
We highlight the recent progress in the calculation of transport coefficients pertinent to binary neutron star mergers. Specifically, we analyze the bulk viscosity coefficient driven by both the DURCA and MURCA processes and electron transport coefficients in dense and hot plasma relevant to [...] Read more.
We highlight the recent progress in the calculation of transport coefficients pertinent to binary neutron star mergers. Specifically, we analyze the bulk viscosity coefficient driven by both the DURCA and MURCA processes and electron transport coefficients in dense and hot plasma relevant to the merger scenario. The study considers high temperatures (T>6×1010 K) and dense environments (nBn03n0). Bulk viscosity exhibits resonant behavior, with peak values and peak positions dependent on particle interaction rates and thermodynamic susceptibilities. Susceptibilities are calculated by modeling the nuclear matter in the density functional approach. The bulk viscosity coefficient peaks at T1011 K, with a compression–rarefaction oscillation dissipation time scale of 20–50 ms. Electrical transports incorporate frequency-dependent dynamical screening in quantized electron–ion scattering rates. Consequently, dynamical screening reduces the maxima of electrical and thermal conductivities, shortening corresponding dissipation time scales. These results highlight the crucial role of dissipation coefficients in understanding binary neutron star mergers. Full article
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13 pages, 1169 KiB  
Article
Aquaporin 2 in Cerebral Edema: Potential Prognostic Marker in Craniocerebral Injuries
by Wojciech Czyżewski, Jan Korulczyk, Michał Szymoniuk, Leon Sakwa, Jakub Litak, Dominik Ziemianek, Ewa Czyżewska, Marek Mazurek, Michał Kowalczyk, Grzegorz Turek, Adrian Pawłowski, Radosław Rola and Kamil Torres
Int. J. Mol. Sci. 2024, 25(12), 6617; https://doi.org/10.3390/ijms25126617 - 16 Jun 2024
Viewed by 804
Abstract
Despite continuous medical advancements, traumatic brain injury (TBI) remains a leading cause of death and disability worldwide. Consequently, there is a pursuit for biomarkers that allow non-invasive monitoring of patients after cranial trauma, potentially improving clinical management and reducing complications and mortality. Aquaporins [...] Read more.
Despite continuous medical advancements, traumatic brain injury (TBI) remains a leading cause of death and disability worldwide. Consequently, there is a pursuit for biomarkers that allow non-invasive monitoring of patients after cranial trauma, potentially improving clinical management and reducing complications and mortality. Aquaporins (AQPs), which are crucial for transmembrane water transport, may be significant in this context. This study included 48 patients, with 27 having acute (aSDH) and 21 having chronic subdural hematoma (cSDH). Blood plasma samples were collected from the participants at three intervals: the first sample before surgery, the second at 15 h, and the third at 30 h post-surgery. Plasma concentrations of AQP1, AQP2, AQP4, and AQP9 were determined using the sandwich ELISA technique. CT scans were performed on all patients pre- and post-surgery. Correlations between variables were examined using Spearman’s nonparametric rank correlation coefficient. A strong correlation was found between aquaporin 2 levels and the volume of chronic subdural hematoma and midline shift. However, no significant link was found between aquaporin levels (AQP1, AQP2, AQP4, and AQP9) before and after surgery for acute subdural hematoma, nor for AQP1, AQP4, and AQP9 after surgery for chronic subdural hematoma. In the chronic SDH group, AQP2 plasma concentration negatively correlated with the midline shift measured before surgery (Spearman’s ρ −0.54; p = 0.017) and positively with hematoma volume change between baseline and 30 h post-surgery (Spearman’s ρ 0.627; p = 0.007). No statistically significant correlation was found between aquaporin plasma levels and hematoma volume for AQP1, AQP2, AQP4, and AQP9 in patients with acute SDH. There is a correlation between chronic subdural hematoma volume, measured radiologically, and serum AQP2 concentration, highlighting aquaporins’ potential as clinical biomarkers. Full article
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14 pages, 15013 KiB  
Review
Theoretical Perspectives on Viscous Nature of Strongly Interacting Systems
by Kinkar Saha
Universe 2024, 10(6), 259; https://doi.org/10.3390/universe10060259 - 11 Jun 2024
Cited by 1 | Viewed by 699
Abstract
Matter prevailing during the early stages of the Universe or under extreme conditions in high-energy heavy-ion experiments supposedly possesses a rich phase structure. During the evolution of such a system, the complicated pictures of transitions among various phases are studied as part of [...] Read more.
Matter prevailing during the early stages of the Universe or under extreme conditions in high-energy heavy-ion experiments supposedly possesses a rich phase structure. During the evolution of such a system, the complicated pictures of transitions among various phases are studied as part of hydrodynamics. This system, on most occasions, is considered to be non-viscous. However, various theoretical studies reveal the importance of incorporating viscous effects into the analysis. Here, the paper discusses the behavioral patterns of transport coefficients with varying temperatures and chemical potentials to obtain a qualitative, if not quantitative, picture of the same. Discussions are also shared regarding their impacts on such an exotic system for different energies, as explored in the experimental domain. This theoretical analysis, made using the structure of the Polyakov–Nambu–Jona-Lasinio (PNJL) model with a 2+1-flavor quark–antiquark system reveals important aspects of the inclusion of viscous effects in the hydrodynamic studies of QGP. Full article
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11 pages, 3803 KiB  
Article
Wave-Particle Interactions in Astrophysical Plasmas
by Héctor Pérez-De-Tejada
Galaxies 2024, 12(3), 28; https://doi.org/10.3390/galaxies12030028 - 6 Jun 2024
Viewed by 487
Abstract
Dissipation processes derived from the kinetic theory of gases (shear viscosity and heat conduction) are employed to examine the solar wind that interacts with planetary ionospheres. The purpose of this study is to estimate the mean free path of wave-particle interactions that produce [...] Read more.
Dissipation processes derived from the kinetic theory of gases (shear viscosity and heat conduction) are employed to examine the solar wind that interacts with planetary ionospheres. The purpose of this study is to estimate the mean free path of wave-particle interactions that produce a continuum response in the plasma behavior. Wave-particle interactions are necessary to support the fluid dynamic interpretation that accounts for the interpretation of various features measured in a solar wind–planet ionosphere region; namely, (i) the transport of solar wind momentum to an upper ionosphere in the presence of a velocity shear, and (ii) plasma heating produced by momentum transport. From measurements conducted in the solar wind interaction with the Venus ionosphere, it is possible to estimate that in general terms, the mean free path of wave-particle interactions reaches λH ≥ 1000 km values that are comparable to the gyration radius of the solar wind particles in their Larmor motion within the local solar wind magnetic field. Similar values are also applicable to conditions measured by the Mars ionosphere and in cometary plasma wakes. Considerations are made in regard to the stochastic trajectories of the plasma particles that have been implied from the measurements made in planetary environments. At the same time, it is as possible that the same phenomenon is applicable to the interaction of stellar winds with the ionosphere of exoplanets, and also in regions where streaming ionized gases reach objects that are subject to rotational motion in other astrophysical problems (galactic flow–plasma interactions, black holes, etc.). Full article
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9 pages, 2185 KiB  
Communication
Heavy Flavor Physics at the sPHENIX Experiment
by Zhaozhong Shi
Universe 2024, 10(3), 126; https://doi.org/10.3390/universe10030126 - 6 Mar 2024
Cited by 1 | Viewed by 1309
Abstract
The sPHENIX experiment is a state-of-the-art jet and heavy flavor physics detector, which successfully recorded its first Au + Au collision data at 200 GeV at the Relativistic Heavy Ion Collider (RHIC). sPHENIX will provide heavy flavor physics measurements at RHIC, covering an [...] Read more.
The sPHENIX experiment is a state-of-the-art jet and heavy flavor physics detector, which successfully recorded its first Au + Au collision data at 200 GeV at the Relativistic Heavy Ion Collider (RHIC). sPHENIX will provide heavy flavor physics measurements at RHIC, covering an unexplored kinematic region and unprecedented precision, to probe the parton energy loss mechanism, parton transport coefficients in quark–gluon plasma, and the hadronization process under various medium conditions. At the center of sPHENIX, the monolithic active pixel sensor (MAPS)-based VerTeX detector (MVTX) is a high-precision silicon pixel detector. The MVTX provides excellent position resolution and the capability of operating in continuous streaming readout mode, allowing precise vertex determination and recording a large data sample, both of which are particularly crucial for heavy flavor physics measurements. In this work, we will show the general performance of heavy-flavor hadron reconstruction. In addition, we will discuss the commissioning experience with sPHENIX. Finally, we will provide the projection of b-hadron and jet observables and discuss the estimated constraints on theoretical models. Full article
(This article belongs to the Special Issue Multiparticle Dynamics)
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17 pages, 10031 KiB  
Article
Lattice Dynamics, Transport and Thermoelectric Properties of Bi-Sb Alloys Obtained by Mechanical Alloying and Spark Plasma Sintering
by Romain Viennois, Laurent Alvarez, Loïc Coulomb, Yassine El Mastour, Marco Fabbiani, Benjamin Villeroy, David Bérardan, Adrien Moll and Mickaël Beaudhuin
Metals 2024, 14(1), 40; https://doi.org/10.3390/met14010040 - 29 Dec 2023
Viewed by 1082
Abstract
We report on the successful synthesis of Bi1−xSbx alloys via mechanical alloying followed by sintering via spark plasma sintering, and the study of their lattice dynamics by Raman spectroscopy as well as their transport and thermoelectric properties. We observed an [...] Read more.
We report on the successful synthesis of Bi1−xSbx alloys via mechanical alloying followed by sintering via spark plasma sintering, and the study of their lattice dynamics by Raman spectroscopy as well as their transport and thermoelectric properties. We observed an upshift of the frequency of the Raman-active Eg vibrational mode with increasing Sb content but no significant change for the frequency of the Raman-active A1g vibrational mode. Conversely, the linewidth of the Eg vibrational mode did not change significantly with increasing Sb content, whereas a twofold increase was observed for the A1g vibrational mode. Moreover, we confirm the emergence of several new vibrational modes with Sb alloying that could be associated with Bi-Sb and Sb-Sb vibrations. Rather large magnetoresistance was observed for all samples at room temperature. From the Seebeck coefficients, we determined the energy bandgaps in our samples, which are larger than those in bulk compounds, presumably due to the electronic confinement effect. We report a rather large thermoelectric power factor of 2–3 mW/m.K2 and thermoelectric figure of merit ZT of 0.15–0.23 at room temperature. However, ZT values were not improved at room temperature compared to prior works because of the rather large thermal conductivity of 3.75–4.5 W/m.K at room temperature. We find a larger resistivity, Seebeck coefficient, and power factor for the samples sintered at 200 °C for 5 min than for the samples sintered at 220 °C for 15 min, but similar thermal conductivity, resulting in larger ZT for the samples obtained in the first conditions. The samples with low Sb content x = 0.05 have a lower power factor and larger thermal conductivity than the samples with x = 0.12 and x = 0.15 for the same sintering conditions, which results in lower ZT for x = 0.05. Full article
(This article belongs to the Section Powder Metallurgy)
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28 pages, 20130 KiB  
Article
Study on Aerodynamic Drag Reduction by Plasma Jets for 600 km/h Vacuum Tube Train Sets
by Ang Li, Hongjiang Cui, Ying Guan, Jichen Deng, Ying Zhang and Wu Deng
Machines 2023, 11(12), 1078; https://doi.org/10.3390/machines11121078 - 8 Dec 2023
Cited by 1 | Viewed by 1355
Abstract
In order to break through the speed bottleneck, researchers envision using tubes to cover high-speed maglev trains and extract some of the air inside the tubes, creating a low-density environment on the ground, greatly reducing the aerodynamic drag of the trains, and in [...] Read more.
In order to break through the speed bottleneck, researchers envision using tubes to cover high-speed maglev trains and extract some of the air inside the tubes, creating a low-density environment on the ground, greatly reducing the aerodynamic drag of the trains, and in a relatively economical and feasible way, making high subsonic (600 km/h and above) and even supersonic ground transportation possible. The faster the running speed of high-speed trains, the greater the impact of aerodynamic drag on their energy consumption. Studying the aerodynamic characteristics of trains with a speed of 600 km/h can help optimize the aerodynamic shape of the train, reduce aerodynamic drag, and reduce energy consumption. This has positive implications for improving train energy efficiency, reducing energy consumption, and environmental impact. This paper adopts the numerical simulation method to study the drag reduction effect of the plasma arrangement and different excitation speeds on the train set in four positions when the incoming wind speed is 600 km/h, to analyze the mechanism of drag reduction, and then to analyze the combination of working conditions in order to investigate the drag reduction effect of plasma on the vacuum tube train set with an ambient pressure of 10,000 Pa. The findings demonstrate that the plasma induces the directional flow of the gas close to the wall to move the flow separation point backward and delay the separation of the flow, thereby reducing the front and rear differential pressure drag of the train set and lowering the aerodynamic drag coefficient of the entire train. The plasma arrangement is located at the rear of the flow separation point and in close proximity to the flow separation point. The pneumatic drag reduction effect peaks when the excitation speed reaches 0.2 times the train speed and the pneumatic drag reduction ratio is around 0.88%; the pneumatic drag reduction ratio of the rear car peaks when the excitation speed reaches 0.25 times the train speed and the pneumatic drag reduction ratio is 1.62%. The SDBD (Surface Dielectric Barrier Discharge) device is installed at the flow separation point around the nose tip of the rear car. Full article
(This article belongs to the Section Machines Testing and Maintenance)
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20 pages, 10312 KiB  
Article
Plasma Actuators for Cycloidal Rotor Thrust Vectoring Enhancement in Airships
by Amine Benmoussa, Frederico F. Rodrigues and José C. Páscoa
Actuators 2023, 12(12), 436; https://doi.org/10.3390/act12120436 - 24 Nov 2023
Cited by 1 | Viewed by 1642
Abstract
Airships are a method of transportation with reduced fuel consumption and great potential for different applications. However, these aerial vehicles still present considerable control and maneuverability problems. To overcome these issues, in the current work, we propose the use of plasma-enhanced cycloidal rotor [...] Read more.
Airships are a method of transportation with reduced fuel consumption and great potential for different applications. However, these aerial vehicles still present considerable control and maneuverability problems. To overcome these issues, in the current work, we propose the use of plasma-enhanced cycloidal rotor thrusters to increase the controllability and maneuverability of airships. Numerical simulations are carried out to demonstrate the potential of plasma actuators to enhance the efficiency and thrust vectoring capabilities of cycloidal rotors. The fluid dynamics of the flow effects created via the operation of the cycloidal rotor is analyzed with and without plasma actuation. In addition, smart combined plasma actuation is proposed to further optimize the plasma-coupled cycloidal rotor device. The results demonstrated that by using this novel approach, the lift coefficient was increased by about 27%. To summarize, the obtained results for a rotational speed of 100 rpm are compared with results for 200 rpm, and it is demonstrated that for lower rotational speeds, the plasma effect is increased and more significant. This allows us to conclude that airships are an ideal application for plasma-enhanced cycloidal rotors, because since the lift is mostly generated via aerostatic principles, the plasma-enhanced thruster can be operated at lower rotational speeds and effectively increase the controllability and maneuverability of the aerial vehicle. Full article
(This article belongs to the Section Aircraft Actuators)
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24 pages, 5349 KiB  
Article
The Interplay of Permeability, Metabolism, Transporters, and Dosing in Determining the Dynamics of the Tissue/Plasma Partition Coefficient and Volume of Distribution—A Theoretical Investigation Using Permeability-Limited, Physiologically Based Pharmacokinetic Modeling
by Lu Gaohua, Mian Zhang, Caroline Sychterz, Ming Chang and Brian James Schmidt
Int. J. Mol. Sci. 2023, 24(22), 16224; https://doi.org/10.3390/ijms242216224 - 12 Nov 2023
Cited by 1 | Viewed by 1880
Abstract
A permeability-limited physiologically based pharmacokinetic (PBPK) model featuring four subcompartments (corresponding to the intracellular and extracellular water of the tissue, the residual plasma, and blood cells) for each tissue has been developed in MATLAB/SimBiology and applied to various what-if scenario simulations. This model [...] Read more.
A permeability-limited physiologically based pharmacokinetic (PBPK) model featuring four subcompartments (corresponding to the intracellular and extracellular water of the tissue, the residual plasma, and blood cells) for each tissue has been developed in MATLAB/SimBiology and applied to various what-if scenario simulations. This model allowed us to explore the complex interplay of passive permeability, metabolism in tissue or residual blood, active uptake or efflux transporters, and different dosing routes (intravenous (IV) or oral (PO)) in determining the dynamics of the tissue/plasma partition coefficient (Kp) and volume of distribution (Vd) within a realistic pseudo-steady state. Based on the modeling exercise, the permeability, metabolism, and transporters demonstrated significant effects on the dynamics of the Kp and Vd for IV bolus administration and PO fast absorption, but these effects were not as pronounced for IV infusion or PO slow absorption. Especially for low-permeability compounds, uptake transporters were found to increase both the Kp and Vd at the pseudo-steady state (Vdss), while efflux transporters had the opposite effect of decreasing the Kp and Vdss. For IV bolus administration and PO fast absorption, increasing tissue metabolism was predicted to elevate the Kp and Vdss, which contrasted with the traditional derivation from the steady-state perfusion-limited PBPK model. Moreover, metabolism in the residual blood had more impact on the Kp and Vdss compared to metabolism in tissue. Due to its ability to offer a more realistic description of tissue dynamics, the permeability-limited PBPK model is expected to gain broader acceptance in describing clinical PK and observed Kp and Vdss, even for certain small molecules like cyclosporine, which are currently treated as perfusion-limited in commercial PBPK platforms. Full article
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15 pages, 16131 KiB  
Article
Green Synthesis and Morphological Evolution for Bi2Te3 Nanosystems via a PVP-Assisted Hydrothermal Method
by Fang Zhou, Weichang Zhou, Yujing Zhao and Li Liu
Nanomaterials 2023, 13(21), 2894; https://doi.org/10.3390/nano13212894 - 1 Nov 2023
Viewed by 1432
Abstract
Bi2Te3 has been extensively used because of its excellent thermoelectric properties at room temperature. Here, 230–420 nm of Bi2Te3 hexagonal nanosheets has been successfully synthesized via a “green” method by using ethylene glycol solution and applying polyvinyl [...] Read more.
Bi2Te3 has been extensively used because of its excellent thermoelectric properties at room temperature. Here, 230–420 nm of Bi2Te3 hexagonal nanosheets has been successfully synthesized via a “green” method by using ethylene glycol solution and applying polyvinyl pyrrolidone (PVP) as a surfactant. In addition, factors influencing morphological evolution are discussed in detail in this study. Among these parameters, the reaction temperature, molar mass of NaOH, different surfactants, and reaction duration are considered as the most essential. The results show that the existence of PVP is vital to the formation of a plate-like morphology. The reaction temperature and alkaline surroundings played essential roles in the formation of Bi2Te3 single crystals. By spark plasma sintering, the Bi2Te3 hexagonal nanosheets were hot pressed into solid-state samples. We also studied the transport properties of solid-state samples. The electrical conductivity σ was 18.5 × 103 Sm1 to 28.69 × 103 Sm1, and the Seebeck coefficient S was −90.4 to −113.3 µVK1 over a temperature range of 300–550 K. In conclusion, the observation above could serve as a catalyst for future exploration into photocatalysis, solar cells, nonlinear optics, thermoelectric generators, and ultraviolet selective photodetectors of Bi2Te3 nanosheet-based photodetectors. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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18 pages, 31481 KiB  
Article
The Transport and Optical Characteristics of a Metal Exposed to High-Density Energy Fluxes in Compressed and Expanded States of Matter
by Nikolay B. Volkov and Alexander I. Lipchak
Condens. Matter 2023, 8(3), 70; https://doi.org/10.3390/condmat8030070 - 11 Aug 2023
Cited by 1 | Viewed by 1374
Abstract
This article presents a theoretical study of the optical and transport properties of metals. Iron, as an example, was used to discuss, through a theoretical description, the peculiarities of these properties in the compressed and expanded states under the influence of high-density energy [...] Read more.
This article presents a theoretical study of the optical and transport properties of metals. Iron, as an example, was used to discuss, through a theoretical description, the peculiarities of these properties in the compressed and expanded states under the influence of high-density energy fluxes. By solving the semi-classical Boltzmann equation for conduction electrons for a broad range of densities and temperatures, the expressions of electrical conductivity, electronic thermal conductivity, and thermoelectric coefficient calculations were derived. The real and imaginary parts of the iron permittivity and the energy absorption coefficient for the first and second harmonics of Nd:YAG laser radiation were obtained. The calculation peculiarities of the metal’s optical characteristics of matter in an expanded state in a broad range of densities and temperatures were considered. The analysis of the obtained results shows their agreement with the theoretical description for cases of ideal non-degenerate and dense degenerate electron plasmas. It is shown that the behavior of the electrical conductivity and optical characteristics in the critical and supercritical regions of density and temperature are in agreement with the known experimental results. Full article
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