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Keywords = dielectric barrier discharge

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16 pages, 7106 KiB  
Article
Experimental Analysis of Flow Separation Control by a Dielectric Barrier Discharge Plasma Actuator in Burst-in-Burst Actuation Mode
by Rodrigo Viguera, Yasuo Sasaki and Taku Nonomura
Actuators 2024, 13(11), 435; https://doi.org/10.3390/act13110435 - 29 Oct 2024
Viewed by 276
Abstract
This study investigated the effectiveness of a dielectric barrier discharge (DBD) plasma actuator operating in burst-in-burst (BIB) mode for flow separation control on a NACA 0015 airfoil. Time-resolved particle image velocimetry measurements were conducted at a Reynolds number of 66,000 and 13° angle [...] Read more.
This study investigated the effectiveness of a dielectric barrier discharge (DBD) plasma actuator operating in burst-in-burst (BIB) mode for flow separation control on a NACA 0015 airfoil. Time-resolved particle image velocimetry measurements were conducted at a Reynolds number of 66,000 and 13° angle of attack. Various BIB signal configurations were tested, with actuation periods of 70 ms and 150 ms, non-actuation periods ranging from 5 ms to 50 ms, and burst frequencies of 300 Hz and 600 Hz. Proper orthogonal decomposition was applied to analyze the flow field dynamics. The results showed that BIB actuation maintained flow attachment with reduced power consumption compared with continuous burst actuation. However, the effectiveness was highly sensitive to the BIB parameters, with some configurations failing to achieve consistent reattachment and becoming unstable. This study reveals complex interactions between actuation vortices and separation processes, highlighting both the potential and challenges of intermittent plasma actuation for efficient flow control. Full article
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15 pages, 2502 KiB  
Article
Inactivation Efficiency of Bacillus atrophaeus Spores on Seeds of Barley, Wheat, Lupine and Rapeseed by Direct Cold Atmospheric Pressure Plasma
by Nicola Wannicke, Jasmin Martins Dias, Thalita M. C. Nishime and Henrike Brust
Appl. Sci. 2024, 14(21), 9793; https://doi.org/10.3390/app14219793 - 26 Oct 2024
Viewed by 380
Abstract
The objective of this study was to evaluate the antimicrobial effect of direct cold atmospheric plasma (CAPP) treatment for pre-harvest application using four different crop species: Hordeum vulgare L. (barley), Triticum aestivum L. (wheat), Brassica napus L. (rapeseed) and Lupinus angustifolius L. (lupine). [...] Read more.
The objective of this study was to evaluate the antimicrobial effect of direct cold atmospheric plasma (CAPP) treatment for pre-harvest application using four different crop species: Hordeum vulgare L. (barley), Triticum aestivum L. (wheat), Brassica napus L. (rapeseed) and Lupinus angustifolius L. (lupine). The model bacterium Bacillus atrophaeus served as a proxy for spore-forming plant pathogens on the seed surface. After semi-dry inoculation of spores onto the seeds, treatment with two different plasma sources, a volume-dielectric barrier discharge and a corona discharge, and different exposure times was carried out. Subsequently, recovery of viable spores from the seeds’ surfaces was performed. Moreover, seed viability was determined based on maximum germination, as well as water contact angle as a measure for seed surface hydrophilicity. Direct CAPP treatment was efficient in reducing viable spores of B. atrophaeus with no significant differences between the plasma sources, reaching a mean inactivation of 1 log10 CFU/mL across all treatment times and crops species. Maximum germination of seeds was not negatively affected under any treatment condition. Seed hydrophilicity was increased for both plasma sources tested. Overall, this study provides valuable information on the efficiency of direct CAPP treatment of seeds with the purpose of seed hygienization with the premise of unaltered seed vitality and evaluates the potential application in comparison with previous investigated CAPP methods. Full article
(This article belongs to the Section Agricultural Science and Technology)
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16 pages, 3844 KiB  
Article
Impact of DBD Plasma Jet Treatment on the Enamel Surface of Primary Teeth
by Michał Kwiatkowski, Joanna Pawłat, Agnieszka Starek-Wójcicka, Marta Krajewska, Piotr Terebun, Dawid Zarzeczny, Monika Machoy, Agnieszka Mazur-Lesz, Narumol Matsuyama, Tomoyuki Murakami, Nobuya Hayashi and Elżbieta Grządka
Materials 2024, 17(21), 5173; https://doi.org/10.3390/ma17215173 - 24 Oct 2024
Viewed by 462
Abstract
The impact of cold atmospheric plasma (CAP) treatment on the enamel of twelve primary teeth (incisors, canines, and molars) collected from six children was examined in order to evaluate the possibility of using the CAP technique in dental applications. A radio-frequency dielectric barrier [...] Read more.
The impact of cold atmospheric plasma (CAP) treatment on the enamel of twelve primary teeth (incisors, canines, and molars) collected from six children was examined in order to evaluate the possibility of using the CAP technique in dental applications. A radio-frequency dielectric barrier discharge (DBD) plasma jet operating at a voltage of 3.25 kV using a mixture of helium and oxygen as the working gas was used for the generation of plasma as part of the electro-technological method for the treatment of biological material. The plasma exposure time for the primary teeth was 5, 10, and 20 min. The properties of tooth enamel (color, contact angles, surface roughness, surface topography, elemental composition) were examined before (control) and after the plasma treatment. As shown by the results, the plasma treatment time is a key parameter that can induce desired features, such as whitening or improved wettability. However, with prolonged plasma treatment (20 min), the enamel surface may be permanently damaged. The cold-plasma-treated samples were characterized by a higher value of the brightness L* parameter and thus a lighter color, compared to the CAP-untreated teeth. It was also evidenced that the plasma treatment increased the hydrophilicity of tooth surfaces, and the contact angles effectively decreased with the time of the CAP treatment. The tooth surface also became much more heterogeneous and rough with much greater amplitudes in heights. The surface of the primary teeth after the CAP treatment lost its homogeneity, as evidenced by the SEM micrographs. The analysis of the elemental composition revealed only minor changes after the plasma process, which may suggest that the observed morphological changes in the enamel surface are mainly physical and are not a consequence of chemical reactions between the enamel and the reactive components of the cold plasma. Plasma treatment of teeth opens up new possibilities of using this method as an alternative to whitening or pre-treatment before other dental procedures. Full article
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21 pages, 5749 KiB  
Article
Improving the Mechanical, Thermoelectric Insulations, and Wettability Properties of Acrylic Polymers: Effect of Silica or Cement Nanoparticles Loading and Plasma Treatment
by Seenaa I. Hussein, Saba J. Kadhem, Nadai A. Ali, Alhafez M. Alraih and Alaa M. Abd-Elnaiem
Polymers 2024, 16(21), 2965; https://doi.org/10.3390/polym16212965 - 23 Oct 2024
Viewed by 428
Abstract
The acrylic polymer composites in this study are made up of various weight ratios of cement or silica nanoparticles (1, 3, 5, and 10 wt%) using the casting method. The effects of doping ratio/type on mechanical, dielectric, thermal, and hydrophobic properties were investigated. [...] Read more.
The acrylic polymer composites in this study are made up of various weight ratios of cement or silica nanoparticles (1, 3, 5, and 10 wt%) using the casting method. The effects of doping ratio/type on mechanical, dielectric, thermal, and hydrophobic properties were investigated. Acrylic polymer composites containing 5 wt% cement or silica nanoparticles had the lowest abrasion wear rates and the highest shore-D hardness and impact strength. The increase in the inclusion of cement or silica nanoparticles enhanced surface roughness, water contact angle (WCA), and thermal insulation. Acrylic/cement composites demonstrated higher mechanical, electrical, and thermal insulation properties than acrylic/silica composites because of their lower particle size and their low thermal/electrical conductivity. Furthermore, to improve the surface hydrophobic characteristics of acrylic composites, the surface was treated with a dielectric barrier discharge (DBD) plasma jet. The DBD plasma jet treatment significantly enhanced the hydrophobicity of acrylic polymer composites. For example, the WCA of acrylic composites containing 5 wt% silica or cement nanoparticles increased from 35.3° to 55° and 44.7° to 73°, respectively, by plasma treatment performed at an Ar flow rate of 5 L/min and for an exposure interval of 25 s. The DBD plasma jet treatment is an excellent and inexpensive technique for improving the hydrophobic properties of acrylic polymer composites. These findings offer important perspectives on the development of materials coating for technical applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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15 pages, 7812 KiB  
Article
Effects of Discharge Parameters on the Thawing Characteristics and Physicochemical Properties of Beef in a Dielectric Barrier Discharge (DBD) System
by Jie Zhang, Rui Zhao, Yaming Zhang, Huixin Wang, Zhiqing Song, Ru Xing, Jingli Lu and Changjiang Ding
Foods 2024, 13(21), 3360; https://doi.org/10.3390/foods13213360 - 23 Oct 2024
Viewed by 478
Abstract
Traditional thawing techniques can cause certain losses to beef quality. Due to the increasing demand for high-quality beef, there is an urgent need to research new thawing techniques. Dielectric barrier discharge (DBD), as an innovative non-thermal thawing technology, still has a lot of [...] Read more.
Traditional thawing techniques can cause certain losses to beef quality. Due to the increasing demand for high-quality beef, there is an urgent need to research new thawing techniques. Dielectric barrier discharge (DBD), as an innovative non-thermal thawing technology, still has a lot of work to be studied. In order to explore the influence of DBD on the thawing characteristics and quality of beef, different discharge parameters were used for thawing. The results show that voltage and needle distance have significant effects on ion wind speed and composition. Ion wind can improve the thawing rate, and the thawing time of DBD is 50% shorter than that of natural thawing. DBD improved the water-holding capacity, nutritional components, and color of beef, and the ordered structure of beef protein could be improved by 6.25% at most. The plasma emission spectrum shows that the plasma produced by DBD is mainly active substances of nitrogen and oxygen, which can reduce the fat oxidation of thawed beef and improve the quality of beef. This work provides the theoretical basis and practical guidance for deeply understanding the influencing parameters and thawing mechanism of DBD thawing technology. Full article
(This article belongs to the Section Food Quality and Safety)
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14 pages, 1203 KiB  
Article
Atmospheric Cold Plasma to Maintain Sea Bass Quality: An Opportunity for International Fish Trade
by Şafak Ulusoy, Tamer Akan, Sehban Kartal, Didem Üçok, Şehnaz Yasemin Tosun, Hande Doğruyol, Serap Coşansu, Kamil Bostan and Sühendan Mol
Processes 2024, 12(11), 2318; https://doi.org/10.3390/pr12112318 - 23 Oct 2024
Viewed by 382
Abstract
Whole chilled sea bass is an essential product for the European food market, and Türkiye is the foremost supplier. The importance of sea bass in the world food trade reveals the significance of food safety risks that may arise during or after harvest. [...] Read more.
Whole chilled sea bass is an essential product for the European food market, and Türkiye is the foremost supplier. The importance of sea bass in the world food trade reveals the significance of food safety risks that may arise during or after harvest. This study aimed to examine the impact of atmospheric cold plasma (ACP) on delaying the spoilage of sea bass. The ACP is generated by an original device that produces a dielectric barrier discharge plasma using an alternating current (AC) power supply, applying a 30 kV high voltage with a sinusoidal frequency of 20 kHz. Whole sea bass samples were treated for 1 min (ACP1) or 7 min (ACP7), and then stored at 2 ± 1 °C. Sensory scores of plasma-treated sea bass were higher throughout the storage period. Both treatments decreased the initial bacterial load and delayed bacterial growth (p ≤ 0.05) during storage. The mesophilic aerobic bacteria count of control samples exceeded 6 log CFU/g on the second day of storage. However, ACP1 and ACP7 did not reach this value until the third and fourth days. The control samples had higher TMA-N and TBARS (p ≤ 0.05) than plasma-treated groups. The treatment did not significantly change the texture. Although ΔE was higher in ACP samples, a discoloration that could affect acceptability was not reported during the sensory test. Cold plasma can improve the overall market value by maintaining quality, benefiting the global fish trade. It has been shown that cold plasma has promising potential in the fresh fish industry. Full article
(This article belongs to the Special Issue Advances in Seafood Science and Processing)
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14 pages, 4584 KiB  
Article
Degradation of Atrazine in Water by Dielectric Barrier Discharge Combined with Periodate Oxidation: Enhanced Performance, Degradation Pathways, and Toxicity Assessment
by Han Zhang, Jinping Duan, Pengcheng Luo, Luxiang Zhu and Yanan Liu
Toxics 2024, 12(10), 746; https://doi.org/10.3390/toxics12100746 - 14 Oct 2024
Viewed by 496
Abstract
The widespread occurrence of atrazine (ATZ) in water environments presents a considerable risk to human health and ecosystems. Herein, the performance of dielectric barrier discharge integrated with periodate (DBD/PI) for ATZ decomposition was evaluated. Results demonstrated that the DBD/PI system improved ATZ decomposition [...] Read more.
The widespread occurrence of atrazine (ATZ) in water environments presents a considerable risk to human health and ecosystems. Herein, the performance of dielectric barrier discharge integrated with periodate (DBD/PI) for ATZ decomposition was evaluated. Results demonstrated that the DBD/PI system improved ATZ decomposition efficiency by 18.2–22.5% compared to the sole DBD system. After 10 min treatment, the decomposition efficiency attained 82.4% at a discharge power of 68 W, a PI dosage of 0.02 mM, and an initial ATZ concentration of 10 mg/L. As the PI dosage increased, the decomposition efficiency exhibited a trend of initially increasing, followed by a decrease. Acidic conditions were more favorable for ATZ removal compared to alkaline and neutral conditions. Electron paramagnetic resonance (EPR) was adopted for characterizing the active species produced in the DBD/PI system, and quenching experiments revealed their influence on ATZ decomposition following a sequence of 1O2 > O2• > IO3• > OH•. The decomposition pathways were proposed based on the theoretical calculations and intermediate identification. Additionally, the toxic effects of ATZ and its intermediates were assessed. This study demonstrates that the DBD/PI treatment represents an effective strategy for the decomposition of ATZ in aquatic environments. Full article
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17 pages, 6507 KiB  
Article
Sublethal Damage Caused by Cold Plasma on Bacillus cereus Cells: Impact on Cell Viability and Biofilm-Forming Capacity
by Laura Eced-Rodríguez, Michael Beyrer, Dolores Rodrigo, Alejandro Rivas, Consuelo Esteve and Maria Consuelo Pina-Pérez
Foods 2024, 13(20), 3251; https://doi.org/10.3390/foods13203251 - 13 Oct 2024
Viewed by 535
Abstract
The Bacillus cereus group represents a serious risk in powdered and amylaceous foodstuffs. Cold plasma (the fourth state of matter) is emerging as an alternative effective nonthermal technology for pasteurizing a wide range of matrices in solid, liquid, and powder form. The present [...] Read more.
The Bacillus cereus group represents a serious risk in powdered and amylaceous foodstuffs. Cold plasma (the fourth state of matter) is emerging as an alternative effective nonthermal technology for pasteurizing a wide range of matrices in solid, liquid, and powder form. The present study aims to evaluate the mechanisms involved in Bacillus cereus inactivation via cold plasma, focusing on (i) the technology’s ability to generate damage in cells (at the morphological and molecular levels) and (ii) studying the effectiveness of cold plasma in biofilm mitigation through the direct effect and inhibition of the biofilm-forming capacity of sublethally damaged cells post-treatment. Dielectric barrier discharge cold plasma (DBD-CP) technology was used to inactivate B. cereus, B. thuringiensis, and B. mycoides under plasma power settings of 100, 200, and 300 W and treatment times ranging from 1 to 10 min. Inactivation levels were achieved in 2–7 log10 cycles under the studied conditions. Percentages of sublethally damaged cells were observed in a range of 45–98%, specifically at treatment times below 7 min. The sublethally damaged cells showed poration, erosion, and loss of integrity at the superficial level. At the molecular level, proteins and DNA leakage were also observed for B. cereus but were minimal for B. mycoides. Biofilms formed by B. cereus were progressively disintegrated under the DBD-CP treatment. The greater the CP treatment intensity, the greater the tearing of the bacteria’s biofilm network. Additionally, cells sublethally damaged by DBD-CP were evaluated in terms of their biofilm-forming capacity. Significant losses in the damaged cells’ biofilm network density and aggregation capacity were observed when B. cereus was recovered after inactivation at 300 W for 7.5 min, compared with the untreated cells. These results provide new insights into the future of tailored DBD-CP design conditions for both the inactivation and biofilm reduction capacity of B. cereus sensu lato species, demonstrating the effectiveness of cold plasma and the risks associated with sublethal damage generation. Full article
(This article belongs to the Special Issue Emerging Technologies in Food Safety Intervention)
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22 pages, 11015 KiB  
Article
Plasma-Functionalized Liquids for Decontamination of Viable Tissues: A Comparative Approach
by Alexander Pogoda, Yuanyuan Pan, Monika Röntgen and Sybille Hasse
Int. J. Mol. Sci. 2024, 25(19), 10791; https://doi.org/10.3390/ijms251910791 - 8 Oct 2024
Viewed by 526
Abstract
Plasma-functionalized liquids (PFLs) are rich in chemical species, such as ozone, hydrogen peroxide, singlet oxygen, hydroxyl radical and nitrogen oxides, commonly referred to as reactive oxygen and nitrogen species (RONS). Therefore, manifold applications are being investigated for their use in medicine, agriculture, and [...] Read more.
Plasma-functionalized liquids (PFLs) are rich in chemical species, such as ozone, hydrogen peroxide, singlet oxygen, hydroxyl radical and nitrogen oxides, commonly referred to as reactive oxygen and nitrogen species (RONS). Therefore, manifold applications are being investigated for their use in medicine, agriculture, and the environment. Depending on the goal, a suitable plasma source concept for the generation of PFLs has to be determined because the plasma generation setup determines the composition of reactive species. This study investigates three PFL-generating plasma sources—two spark discharges and a flow dielectric barrier discharge (DBD) system—for their efficacy in eliminating microbial contaminants from tissue samples aiming to replace antibiotics in the rinsing process. The final goal is to use these tissues as a cell source for cell-based meat production in bioreactors and thereby completely avoid antibiotics. Initially, a physicochemical characterization was conducted to better understand the decontamination capabilities of PFLs and their potential impact on tissue viability. The results indicate that the flow DBD system demonstrated the highest antimicrobial efficacy due to its elevated reactive species output and the possibility of direct treatment of tissues while tissue integrity remained. Achieving a balance between effective large-scale decontamination and the biocompatibility of PFLs remains a critical challenge. Full article
(This article belongs to the Special Issue New Processes and Applications of Plasma in Liquids)
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25 pages, 55903 KiB  
Article
Control of a Circular Jet with a Disk-Type Bluff Body Using a Dielectric Barrier Discharge Plasma Actuator
by Masato Akimoto, Hiroyuki Nakagawa and Motoaki Kimura
Aerospace 2024, 11(9), 783; https://doi.org/10.3390/aerospace11090783 - 23 Sep 2024
Viewed by 488
Abstract
In this study, a disk-type bluff body was installed at the upper part of a nozzle exit, and the circular jet inside the nozzle was controlled using a dielectric barrier discharge (DBD) plasma actuator (DBD-PA). The effects of the changes in the excitation [...] Read more.
In this study, a disk-type bluff body was installed at the upper part of a nozzle exit, and the circular jet inside the nozzle was controlled using a dielectric barrier discharge (DBD) plasma actuator (DBD-PA). The effects of the changes in the excitation frequency of the jet induced by the DBD-PA on the jet diffusion were elucidated. The experiments included visualization of the jet cross-section, particle image velocimetry analysis, and velocity measurements using an I-type hot-wire anemometer. When the DBD-PA was driven at a specific burst frequency (900–1400 Hz), a lock-in phenomenon occurred, in which the frequency of vortices generated in the initial jet coincided with the burst frequency. This lock-in phenomenon suppressed the merging of vortices by generating vortices at regular intervals. When vortex merging was suppressed, the jet was less likely to be entrained into the recirculation flow generated by the bluff body, thereby increasing the downstream jet width and average flow rate. Full article
(This article belongs to the Special Issue Dielectric Barrier Discharge Plasma Actuator)
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31 pages, 13947 KiB  
Review
Prediction and Control of Broadband Noise Associated with Advanced Air Mobility—A Review
by Jie Hua and Reda R. Mankbadi
Appl. Sci. 2024, 14(18), 8455; https://doi.org/10.3390/app14188455 - 19 Sep 2024
Viewed by 755
Abstract
This review presents an overview of advanced air mobility broadband noise (BBN) prediction and control techniques, highlighting significant advancements in various prediction models. Methods such as the semi-empirical Brooks–Pope–Marcolini (BPM) model, analytical Amiet model, and time-domain models based on the FW-H equation have [...] Read more.
This review presents an overview of advanced air mobility broadband noise (BBN) prediction and control techniques, highlighting significant advancements in various prediction models. Methods such as the semi-empirical Brooks–Pope–Marcolini (BPM) model, analytical Amiet model, and time-domain models based on the FW-H equation have been extensively studied. Machine learning (ML) shows promise in BBN prediction but requires extensive data training and application to noise source mechanisms. Passive control methods, such as leading and trailing edge serrations and blade tip designs, have been partially successful but often compromise the aerodynamic performance. Active control methods, like suction and blowing control, trim adjustments, and dielectric barrier discharge (DBD) plasma actuators, show great potential, with the latter two being particularly effective for reducing BBN in thin propeller structures. Overall, while progress has been made in understanding and predicting BBN, further research is needed to refine these methods and develop comprehensive noise control strategies. These advancements hold significant promise for effective and efficient noise mitigation in future AAM vehicles. Full article
(This article belongs to the Section Transportation and Future Mobility)
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13 pages, 9283 KiB  
Article
Methylene Blue Degradation Using Non-Thermal Plasma
by Hae Kwang Kim, Geon Woo Yang and Yong Cheol Hong
Plasma 2024, 7(3), 767-779; https://doi.org/10.3390/plasma7030040 - 19 Sep 2024
Viewed by 512
Abstract
Methylene blue (C16H18ClN3) dye can be decomposed using non-thermal plasma. However, there is a problem in that the maintenance of electrodes and dielectrics is necessary due to the durability and heat generation problems due to the high [...] Read more.
Methylene blue (C16H18ClN3) dye can be decomposed using non-thermal plasma. However, there is a problem in that the maintenance of electrodes and dielectrics is necessary due to the durability and heat generation problems due to the high temperatures. Therefore, in this study, a comparative experiment was performed between the flat DBD plasma module and the diffuser DBD module under the same conditions. For methylene blue decomposition, the characteristic changes in the air flow rate, ozone production rate, energy consumption rate, and decomposition rate were compared. In the experiment, 7 L water was placed in a 15 L reactor, and measurements were performed for approximately 1 h. We performed the same process by setting the initial methylene blue concentration to 143 mg/L. According to the results, the flat DBD module achieved a decomposition rate of 100% in 40 min, an energy yield of 46.7 g/kWh, and an ozone generation amount of 6.5 g/h. The diffuser DBD module achieved a decomposition rate of 90%, an energy production of 24.6 g/kWh, and an ozone generation of 1.97 g/h in 60 min. Full article
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16 pages, 5445 KiB  
Article
Pharmaceutically Active Compound (PhAC) Degradation by Means of Cold Plasma Jet Treatment
by Alkistis Kanteraki, Ekavi Aikaterini Isari, Eleni Grilla, Konstantinos Giotis, Ioannis Kalavrouziotis and Panagiotis Svarnas
Plasma 2024, 7(3), 733-748; https://doi.org/10.3390/plasma7030038 - 16 Sep 2024
Viewed by 598
Abstract
The occurrence of emerging micropollutants of pharmaceutically active compounds (PhACs) in the environment poses a public health concern. Due to PhAC persistence and toxicity even at low concentrations, advanced oxidation processes (AOPs) have gained interest as effective treatment methods. In this context, the [...] Read more.
The occurrence of emerging micropollutants of pharmaceutically active compounds (PhACs) in the environment poses a public health concern. Due to PhAC persistence and toxicity even at low concentrations, advanced oxidation processes (AOPs) have gained interest as effective treatment methods. In this context, the present study focuses on the application of a dielectric barrier discharge (DBD)-based plasma jet to Diclofenac (DCF) and Sulfamethoxazole (SMX) degradation in aqueous media. Plasma is sustained by continuous-wave sinusoidal high-voltage of audio frequencies, and negligible total harmonic distortion, in a helium–air mixture. The target pharmaceuticals are chosen based on anticipation of their occurrence due to rehabilitation center (DCF) and hospital (SMX) effluents in sewage systems. The degradation rates are determined by Liquid Chromatography Triple-Quadrupole Mass Spectroscopy (LC-MS/MS). Removal efficiency close to 100%, after 20 min of plasma treatment in the case of DCF at an initial concentration of 50 ppb, is achieved. The post-treatment action of the plasma-induced reactants on PhAC degradation over a day-scale period is studied. The results provide an insight into the dynamic degradation (kinetics) of both DCF and SMX, and they overall highlight the potentiality of the process under consideration for sewage remediation. Full article
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12 pages, 2110 KiB  
Article
The Influence of the Structure of Organochlorine Compounds on Their Decomposition Process in a Dielectric Barrier Discharge
by Bogdan Ulejczyk
Reactions 2024, 5(3), 623-634; https://doi.org/10.3390/reactions5030031 - 11 Sep 2024
Viewed by 614
Abstract
The decomposition efficiency of C2HCl3 and CHCl3 in a barrier discharge is very different, even though these compounds differ little in chemical composition. In both compounds, there are three chlorine atoms and one hydrogen atom. The difference between them [...] Read more.
The decomposition efficiency of C2HCl3 and CHCl3 in a barrier discharge is very different, even though these compounds differ little in chemical composition. In both compounds, there are three chlorine atoms and one hydrogen atom. The difference between them is the presence of one carbon atom in CHCl3 and two carbon atoms connected by a double bond in C2HCl3 and the higher polarizability of C2HCl3. The polarizability of C2HCl3 is 10.21 Å3 and that of CHCl3 is 8.39 Å3. As a result of these differences, the C2HCl3 conversion was two to three times higher than the CHCl3 conversion. The main product of CHCl3 decomposition containing chlorine was ClO2, while Cl2, COCl2, HCl, CCl4, and Cl were formed in smaller amounts. The main products of C2HCl3 decomposition, which contain chlorine, were COCl2, HCl, and Cl. CCl4 was not formed. Cl2 and ClO2 were formed in smaller amounts. Pathways of C2HCl3 and CHCl3 decomposition are shown in this paper. The process was carried out at low power (0.2–0.8 W) in air. The gas flow was 10 L/h, and the concentration of the decomposed compound was 0.4%. The volume of the gas space of the reactor (plasma zone) was 27 cm3. Full article
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21 pages, 4141 KiB  
Article
Proposing an Affordable Plasma Device for Polymer Surface Modification and Microbial Inactivation
by William Chiappim, Felipe Vicente de Paula Kodaira, Gisele Fátima Soares de Castro, Diego Morais da Silva, Thayna Fernandes Tavares, Ana Carla de Paula Leite Almeida, Bruno Henrique Silva Leal, Antje Quade, Cristiane Yumi Koga-Ito and Konstantin Georgiev Kostov
Molecules 2024, 29(17), 4270; https://doi.org/10.3390/molecules29174270 - 9 Sep 2024
Viewed by 783
Abstract
This study proposes an affordable plasma device that utilizes a parallel-plate dielectric barrier discharge geometry with a metallic mesh electrode, featuring a straightforward 3D-printed design. Powered by a high-voltage supply adapted from a cosmetic plasma device, it operates on atmospheric air, eliminating the [...] Read more.
This study proposes an affordable plasma device that utilizes a parallel-plate dielectric barrier discharge geometry with a metallic mesh electrode, featuring a straightforward 3D-printed design. Powered by a high-voltage supply adapted from a cosmetic plasma device, it operates on atmospheric air, eliminating the need for gas flux. Surface modification of polyethylene treated with this device was characterized and showed that the elemental composition after 15 min of plasma treatment decreased the amount of C to ~80 at% due to the insertion of O (~15 at%). Tested against Candida albicans and Staphylococcus aureus, the device achieved a reduction of over 99% in microbial load with exposure times ranging from 1 to 10 min. Simultaneously, the Vero cell viability remained consistently high, namely between 91% and 96% across exposure times. These results highlight this device’s potential for the surface modification of materials and various infection-related applications, boasting affordability and facilitating effective antimicrobial interventions. Full article
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