Search Results (25,656)

The electrochemical conversion of glycerol into high-value chemicals through the selective glycerol oxidation reaction (GOR) holds importance in utilizing the surplus platform chemical component of glycerol. Nevertheless, it is still very limited in producing three-carbon chain (C₃) chemicals, especially glyceric acid/glycerate, through the direct oxidation of its primary hydroxyl group. Herein, Pd microstructure electrodeposited on the Ni foam support (Pd/NF) is designed and fabricated to achieve a highly efficient GOR, exhibiting a superior current density of ca. 120 mA cm⁻² at 0.8 V vs. reversible hydrogen electrode (RHE), and high selectivity of glycerate at ca. 70%. The Faradaic efficiency of C₃ chemicals from GOR can still be maintained at ca. 80% after 20 continuous electrolysis runs, and the conversion rate of glycerol can reach 95% after 10-h electrolysis. It is also clarified that the dual-component interfaces constructed by the adjacent Pd and Ni sites are responsible for this highly efficient GOR. Specifically, Ni sites can effectively strengthen the generative capacity of the active adsorbed hydroxyl (OH_ad) species, which can steadily immigrate to the Pd sites, so that the surface adsorbed glycerol species are quickly oxidized into C₃ chemicals, rather than breaking the C–C bond of glycerol; thus, neither form the C₂/C₁ species. This study may yield fresh perspectives on the electrocatalytic conversion of glycerol into high-value C₃ chemicals, such as glyceric acid/glycerate. Full article

Biosensors are a new type of sensor that utilize biologically sensitive materials and microbially active analytes to measure a variety of biological signals. The purpose of monitoring is achieved by combining these sensitive materials with analytes such as proteins, cells, viruses, and bacteria, inducing changes in their physical or chemical properties. The use of nanomaterials in fabricating surface acoustic wave (SAW) biosensors is particularly noteworthy for the label-free detection of organisms due to their compact size, portability, and high sensitivity. Recent advancements in the manufacturing techniques of SAW biosensors have significantly enhanced sensor performance and reliability. These techniques not only ensure precise control over sensor dimensions and material properties but also facilitate scalable and cost-effective production processes. As a result, SAW biosensors are poised to become powerful tools for various clinical and rapid detection applications. Full article

High-value resources beyond oil extraction for the olive industry need to be developed due to increased olive production. Soluble dietary fibers (SDFs) and olive proteins (OPIs) are important components of olives. However, the commercial production process partially damages OPIs’ emulsifying and foaming properties. Thus, the preparation of SDF-OPI complexes would help protect and even improve the emulsifying and foaming properties. The effects of pH and thermal–ultrasonic treatment on the complexation were explored, which showed that the SDF-OPI complexes prepared at pH 5 exhibited superior solubility (p < 0.05). SDF addition noticeably improved OPI thermal stability, emulsifying properties, and foaming properties. Moreover, the complexes prepared by thermal–ultrasonic treatment exhibited higher emulsion stability and lower emulsification activity than those prepared without thermal–ultrasonic treatment. In the acidic system, the electrostatic interaction was considered the main driving factor, assisted by the hydrophobic interaction. Additionally, after thermal–ultrasonic treatment, the covalent binding was observed by infrared spectroscopy. These results revealed the interaction mechanism between SDF and OPI, and the complexes significantly enhanced the functional properties of OPI. This study provides a reference for the high-value utilization of olives, thus broadening their potential uses in the food sector and beyond. Full article

In this study, we prepared Mg-9Gd-2Nd-0.5Zr, referred to as alloy I, and Mg-9Gd-2Nd-1.5Zn–0.5Zr, referred to as alloy II. The effects of a long-period stacking ordered (LPSO) phase induced by Zn addition on the high-temperature mechanical properties and fracture morphology of alloy I and alloy II at different temperatures (25 °C, 200°C, 225 °C, and 250 °C) were studied using optical microscopy (OM), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), electron backscatter diffraction (EBSD), and transmission electron microscopy (TEM). The results indicate that Mg₅RE at the crystal boundary of the as-cast alloy I transformed into (MgZn)₃RE (as-cast alloy II) by the addition of Zn. After solid solution treatment, the secondary phase in alloy I completely disappeared, and there were still residual secondary phases in block-like and needle-like structures in alloy II, while layered LPSO phases precipitated in the matrix. During the high-temperature tensile test, the yield and tensile strength of alloy I decreased significantly with the increase in temperature, while the elongation increased. Compared to alloy I, the yield strength of alloy II with an LPSO phase showed an increasing trend at 25 °C~200 °C and then decreased when the temperature reached around 250 °C. The thermal stability was significantly enhanced, and the elongation was also higher than that of alloy I. As the temperature increased, the fracture surface of alloy I showed increased folding, bending of scratches, and crack enlargement. However, the fracture surface of alloy II remained largely unchanged, with only minor wrinkles and cracks appearing at temperatures reaching 250 °C. Full article

In response to the environmental pollution caused by transportation and accumulation of large-scale shield muck, the on-site reutilization of shield muck is an effective approach. This study explored the feasibility of silty clay muck to prepare muck grout. Through orthogonal experiments, the effects of cement, fly ash, shield muck, admixture, and the water–solid ratio on the fresh properties and mechanical properties of muck grout were studied. The performance prediction model was established Additionally, the intrinsic relationships between the compressive strength and microstructure of shield muck grouting materials were explored through multi-technology microstructural characterization. The results indicate that the content of muck and the water–solid ratio have a greater significant influence on the bleeding ratio, flowability, setting time, and volume shrinkage rate of muck grout compared to other factors. Cement has a greater significant influence on the compressive strength of muck grout than other factors. An optimal mix proportion (12% for cement, 18% for fly ash, 50% for muck, 0.465 for water–solid ratio, 19.5% for river sand, and 0.5% for bentonite) can produce grouting materials that meet performance requirements. The filling effect of cementitious substances and the particle agglomeration effect reduce the internal pores of grouting materials, improving their internal structure and significantly enhancing their compressive strength. Utilizing shield muck as a raw material for shield synchronous grouting is feasible. Full article

This work presents the results of research on the effect of a pulsed plasma treatment on the structure, phase composition, hardness, roughness, and elemental composition of Fe-TiB₂-CrB₂-based coatings. The Fe-TiB₂-CrB₂ coating was applied via the detonation method. Fe-TiB₂-CrB₂ powder mixtures were used for coating on AISI 1017 steel substrate with the coating surface being modified using a pulsed plasma treatment. The effects of the pulsed plasma treatment on the microstructure, phase composition, and mechanical properties of Fe-TiB₂-CrB₂ detonation coatings were investigated using an optical microscope, X-ray diffraction (XRD), scanning electron microscopy (SEM), a nanohardness tester, and a Leica 3D profilometer. The mechanical test results showed that the hardness of the Fe-TiB₂-CrB₂ coating increased from 8.22 Gpa to 15.6 GPa after the pulsed plasma treatment. The results of the tribological tests show that after the pulsed plasma treatment of Fe-TiB₂-CrB₂ coatings, a wear-resistant modified layer consisting of (Ti,Cr)B₂ and alpha-Fe formed on its surface. It is determined that the surface modified coating layer has a low porosity compared to the coating base. In addition, it is determined that after the pulsed plasma treatment, a decrease in the average pore size is observed in the subsurface layer of the coating. The pulsed plasma treatment resulted in a decrease in the roughness parameter (R_a) from 12.2 μm to 6.6 μm, which is due to the melting of protruding particles. Full article

Mg–8Al–1Zn magnesium alloy was successfully processed using deferential speed rolling (DSR) at temperatures of 400 and 450 °C for thickness reduction of 30, 50, and 70% with no significant grain growth and dynamic recrystallization. Using optical microscopy (OM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), the rolled microstructures were examined. Although the results indicate a slight reduction in grain size from the initial condition, the DSR processing of alloy at an elevated temperature was associated with a significant number of twins and a distribution of the fine particles of the second phase. The strength in terms of microhardness measurements and strain hardening in terms of shear punch testing was significantly improved in the rolled microstructure at room temperature. The existence of twins and widely distributed second-phase fine particles at twin boundaries reflected positively on the extent of the elongations in terms of shear displacements when microstructures were tested at elevated temperatures in the shear punch testing. Full article

The effects of lophatherum gracile brongn flavonoids on the multiscale structure and functional properties of wheat dough were investigated. Wheat dough samples with varying contents of lophatherum gracile brongn flavonoids were analyzed to assess changes in thermal-mechanical rheological properties, microstructure, chemical interactions, water distribution, and macropolymer formation by Mixolab mixer, fluorescence microscopy, and low-field nuclear magnetic resonance (LF-NMR). The findings revealed that lophatherum gracile brongn flavonoids disrupted the three-dimensional network of gluten proteins in the wheat dough, leading to decreased water-binding capacity and reduced gluten protein crosslinking while enhancing thermal stability and inhibiting the starch retrogradation of the dough. This study provided important insights into the interaction mechanisms between lophatherum gracile brongn flavonoids and the proteins/starch in wheat dough, offering theoretical guidance for the development of novel wheat-based products for industrialization and practical production. Full article

Aluminium finds wide application in mechanical engineering due to its low density and corrosion resistance. In this research, aluminium was subjected to two different metal forming technologies—cold forging (upsetting) and equal channel angular pressing (ECAP)—to obtain improvement in its exploitation properties. Parallel to changing mechanical properties by using these two processes, there was a change in the microstructure of the material. The resulting microstructures were examined using an optical microscope. A different treated aluminium was subjected to erosion wear in various time intervals. Wear testing was conducted for two different impingement angles causing abrasive wear and impact wear. The erosion mechanisms were examined by scanning electron microscopy. These results showed that there is no statistically significant difference in erosion wear for different states at the same impingement angle. However, the difference is noticeable at different wear angles. The significance of the difference in wear of the samples treated with the forging and ECAP techniques was validated by statistical analysis with tests of different sensitivities. The results of the t-test showed that ECAPed samples present a statistically significant difference in the loss of mass due to variations in erosion angle during the 30, 45, and 60 min wearing. A substantial difference in the change in sample mass is also visible for the forged state worn for 60 min. Full article

This study employed a two-step Mendelian randomization analysis to explore the causal relationship between telomere length, as a marker of aging, and anorexia nervosa and to evaluate the mediating role of changes in the white matter microstructure across different brain regions. We selected genetic variants associated with 675 diffusion magnetic resonance imaging phenotypes representing changes in brain white matter. F-statistics confirmed the validity of the instruments, ensuring robust causal inference. Sensitivity analyses, including heterogeneity tests, horizontal pleiotropy tests, and leave-one-out tests, validated the results. The results show that telomere length is significantly negatively correlated with anorexia nervosa in a unidirectional manner (p = 0.017). Additionally, changes in specific white matter structures, such as the internal capsule, corona radiata, posterior thalamic radiation, left cingulate gyrus, left longitudinal fasciculus, and left forceps minor (p < 0.05), were identified as mediators. These findings enhance our understanding of the neural mechanisms, underlying the exacerbation of anorexia nervosa with aging; emphasize the role of brain functional networks in disease progression; and provide potential biological targets for future therapeutic interventions. Full article

A high-alloy (Cr-Mo-V) cold-work tool steel was manufactured by laser powder-bed fusion (PBF-LB) without preheating and by electron-beam powder-bed fusion (PBF-EB) with the build temperature set at 850 °C. The solidification rates, cooling, and thermal cycles that the material was subjected to during manufacturing were different in the laser powder-bed fusion than electron-beam powder-bed fusion, which resulted in very different microstructures and properties. During the solidification of the PBF-LB steel, a cellular–dendritic structure was formed. The primary cell size was 0.28–0.32 µm, corresponding to a solidification rate of 2.0–2.5 × 10⁶ °C/s. No coarse primary carbides were observed in the microstructure. Further rapid cooling resulted in the formation of a martensitic microstructure with high amounts of retained austenite. The high-retained austenite explained the low hardness of 597 ± 38 HV. Upon solidification of the PBF-EB tool steel, dendrites with well-developed secondary arms and a carbide network in the interdendritic space were formed. Secondary dendrite arm spacing was in the range of 1.49–3.10 µm, which corresponds to solidification rates of 0.5–3.8 × 10⁴ °C/s. Cooling after manufacturing resulted in the formation of a bainite needle-like microstructure within the dendrites with a final hardness of 701 ± 17 HV. These findings provide a background for the selection of a manufacturing method and the development of the post-treatment of a steel to obtain a desirable final microstructure, which ensures that the final tool’s performance is up to specification. Full article

Hexagonal close-packed (HCP) metals, particularly Zirconium (Zr), Titanium (Ti), and Magnesium (Mg) alloys, have attracted significant attention due to their unique properties and wide-ranging applications in the aerospace, biomedical, and energy industries. This review paper provides a comprehensive analysis of the microstructural and textural evolution in these HCP materials under various conditions, including rolling, extrusion, drawing, and annealing. The focus of the present work lies on the deformed microstructure and texture development in HCP metals, thus elucidating the fundamental mechanisms that govern their response to mechanical stress. The interaction between dislocation movements, twinning, and slip systems is discussed in detail, illustrating how these factors contribute to the anisotropic behavior characteristic of low-symmetry HCP structures. Unlike high-symmetry metals, deformation in Zr alloys depends on the activation of various slips and twin deformation modes, which are sensitive to crystallographic orientation and strain. Like Zr, Ti alloys present a more complex deformation behavior, heavily influenced by their crystallographic orientation. The most common deformation textures in Ti alloys include split-transverse direction (split-TD), split-rolling direction (split-RD), and normal direction (ND) symmetric basal fiber textures. These textures emerge due to the activation of multiple slip systems and twinning, which are dependent on external factors such as temperature, strain rate, and alloy composition. For Mg alloys, the poor formability and brittleness associated with the dominance of the basal slip system under ambient conditions is a critical material development challenge. The activation of non-basal slip systems introduces complexities in controlling texture and microstructure. However, their activation is crucial for optimizing mechanical properties such as strength and fatigue resistance. The tendency for twinning in Mg alloys further complicates their deformation behavior, leading to challenges in ensuring uniform mechanical performance. Modifying the alloy composition, grain size, and texture can additionally influence the activation of these deformation mechanisms. This review further explores the roles of dynamic recrystallization and grain growth in tailoring mechanical properties, with a particular focus on microstructure and texture evolution during annealing. Through this detailed review, we aim to present a thorough understanding of the microstructural and textural evolution in HCP materials, thereby guiding future research and industrial applications. Full article

Nomex honeycomb composites are widely recognized for their advanced structural applications in the aerospace, automotive and defense industries. These materials are distinguished by exceptional characteristics such as thin cell walls and a hexagonal structure, as well as layers made of phenolic resins and aramid fibers. However, complex machining and the maintenance of high quality at a large scale presents considerable challenges. This study provides a comprehensive review of the literature on the processing of Nomex composites, highlighting the design challenges related to processing technologies, the impact of conventional and ultrasonic processing methods, and the associated mechanical properties and microstructural topographies. Moreover, it reviews research advances in machining techniques, current challenges, and future perspectives, thereby providing valuable guidance to ensure the optimal cutting of Nomex honeycomb composite structures (NHCs). Full article

To further enhance the performance of the fast tool servo (FTS) system in terms of stroke, load capacity, and application area, this paper proposes a novel fast tool servo device driven by a voice coil motor (VCM), based on a three-segment uniform corrugated flexure (CF) guiding mechanism, with a large stroke, high accuracy, and high dynamics. To describe the unified static characteristics of such device, the compliance matrix method is applied to establish its model, where the influence of CF beam structural parameters on the FTS device is investigated in detail. Furthermore, resolution and positioning accuracy tests are conducted to validate the features of the system. The testing results indicate that the maximum stroke of the FTS device is up to 3.5 mm and the positioning resolution values are 3.6 μm and 2.4 μm for positive and negative stroke, respectively, which further verifies the device’s effectiveness and promising application prospect in ultra-precision microstructure machining. Full article

This paper investigates the tensile properties and microstructures of Cu/Al clad sheets with an SUS304 interlayer after cryorolling and subsequent annealing and compares them with hot-rolled samples. The experimental results show that the inhibition of dynamic recovery by cryorolling enables the Cu/Al clad sheets to achieve a tensile strength of 302 MPa. After annealing, the tensile strength sharply drops to 159 MPa, while the elongation recovers to 29.0%. Compared with hot-rolled samples, the tensile strength of cryorolled samples is increased by 13.1% due to the effect of fine-grain strengthening. During the annealing process, the cryorolled samples exhibit improved elongation under a comparable strength with the hot-rolled samples, profiting from the higher degree of recrystallization and a higher proportion of annealing twins. The tensile properties of Cu/Al clad sheet with an SUS304 interlayer are strengthened by cryorolling and subsequent annealing, providing a new method for the fabrication of high-performance Cu/Al clad sheets. Full article