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Keywords = molasse zone

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26 pages, 9518 KiB  
Article
Microbial Biomass in Mesophilic and Thermophilic High-Rate Biodigestion of Sugarcane Vinasse: Similar in Quantity, Different in Composition
by Lucas Tadeu Fuess, Matheus Neves de Araujo, Flávia Talarico Saia, Gustavo Bueno Gregoracci, Marcelo Zaiat and Piet N. L. Lens
Processes 2024, 12(7), 1356; https://doi.org/10.3390/pr12071356 - 29 Jun 2024
Viewed by 1218
Abstract
This study compared the behavior of the biomass in two fixed-film anaerobic reactors operated under equivalent organic loading rates but at different temperatures, i.e., 30 °C (RMM) and 55 °C (RMT). The reactors were fed with sugarcane vinasse and molasses (both fermented) in [...] Read more.
This study compared the behavior of the biomass in two fixed-film anaerobic reactors operated under equivalent organic loading rates but at different temperatures, i.e., 30 °C (RMM) and 55 °C (RMT). The reactors were fed with sugarcane vinasse and molasses (both fermented) in a simulation of sequential periods of season and off-season. The dynamics of biomass growth and retention, as well as the microbial composition, were assessed throughout 171 days of continuous operation, coupled with an additional 10-day test assessing the microbial activity in the bed region. Despite the different inoculum sources used (mesophilic granular vs. thermophilic flocculent sludge types), the biomass growth yield was identical (0.036–0.038 g VSS g−1COD) in both systems. The retention rates (higher in RMT) were regulated according to the initial amount of biomass provided in the inoculation, resulting in similar amounts of total retained biomass (46.8 vs. 43.3 g VSS in RMT and RMM) and biomass distribution patterns (30–35% in the feeding zone) at the end of the operation. Meanwhile, hydrogenotrophic methanogenesis mediated by Methanothermobacter coupled to syntrophic acetate oxidation prevailed in RMT, while the Methanosaeta-mediated acetoclastic pathway occurred in RMM. The results show that different anaerobic consortia can behave similarly in quantitative terms when subjected to equivalent organic loads, regardless of the prevailing methane-producing pathway. The community grows and reaches a balance (or a given cell activity level) defined by the amount of substrate available for conversion. In other words, while the metabolic pathway may differ, the endpoint (the amount of biomass) remains the same if operational stability is maintained. Full article
(This article belongs to the Special Issue Biomass and Waste Treatment Based on Anaerobic Digestion)
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23 pages, 4823 KiB  
Article
Does the Amount of Pre-Sowing Nitrogen Fertilization Affect Sugar Beet Root Yield and Quality of Different Genotypes?
by Ivana Varga, Antonela Markulj Kulundžić, Monika Tkalec Kojić and Manda Antunović
Nitrogen 2024, 5(2), 386-408; https://doi.org/10.3390/nitrogen5020025 - 8 May 2024
Viewed by 1595
Abstract
There has always been a specific focus on nitrogen fertilization in sugar beet production due to its important effect on sugar beet root yield and quality. For stable sugar beet growth and satisfactory root yield and quality, balanced N fertilization is crucial. Thus, [...] Read more.
There has always been a specific focus on nitrogen fertilization in sugar beet production due to its important effect on sugar beet root yield and quality. For stable sugar beet growth and satisfactory root yield and quality, balanced N fertilization is crucial. Thus, this study aimed to investigate spring N fertilization in two seasons as the following treatments: N0—control, N1—only pre-sowing fertilization, and N2—pre-sowing with topdressing. Four different genotypes were included in the study (Serenada, Colonia, Fred, and Danton). The experiment was set up in a plain area, belonging to the temperate climate zone in Eastern Croatia (Županja and Vrbanja), with the long-term mean (LTM) (March–October) air temperature around 16 °C and the total precipitation of 515 mm. Pre-sowing N fertilization had a smaller impact on root yield in the year with higher precipitation (31% higher than LTM). Therefore, the average yields with pre-sowing fertilization (N1) and pre-sowing fertilization with top dressing (N2) were very similar and were only 7% higher than those of the control. In a season with less rainfall (29% less than LTM), pre-sowing fertilization with top dressing (N2) had a more pronounced effect on the increase in sugar beet root yield, which was 17% higher compared to that of the control treatment. The sugar beet sucrose content and quality parameters (brei impurities, loss of sugar in molasses, extractable sugar) differed when N fertilization was applied among locations in both seasons. The white sugar yield was the highest at N2 treatment with pre-sowing and topdressing N fertilization. In general, according to the average of all locations and years of research, the Serenada hybrid achieved the highest average root yield (81.1 t ha−1), while Colonia exhibited the highest root sugar content (14.5%) and white sugar yield (9.7 t ha−1). Full article
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25 pages, 5547 KiB  
Article
Interdisciplinary Approach and Geodynamic Implications of the Goutitir Geothermal System (Eastern Meseta, Morocco)
by El Mehdi Jeddi, Ahmed Ntarmouchant, Maria do Rosário Carvalho, Telmo M. Bento dos Santos, Eduardo Anselmo Ferreira da Silva, Mustapha Elabouyi, Youssef Driouch, Brahim Mali, Nahla Ntarmouchant, My Hachem Smaili, Beatriz Cotrim and Mohamed Dahire
Water 2023, 15(6), 1109; https://doi.org/10.3390/w15061109 - 14 Mar 2023
Cited by 2 | Viewed by 2911
Abstract
Morocco has an important geothermal potential materialized by its several thermal springs which constitute an essential surface geothermal indicator. These springs are dispersed throughout the country and present in every major structural domain. However, a significant amount is concentrated in the northern and [...] Read more.
Morocco has an important geothermal potential materialized by its several thermal springs which constitute an essential surface geothermal indicator. These springs are dispersed throughout the country and present in every major structural domain. However, a significant amount is concentrated in the northern and northeastern areas. Associated with the great hydrothermal system of eastern Morocco, the thermal spring of Goutitir emerges in the Meso-Cenozoic sedimentary formations located east of the Guercif Basin, composed of a mixture of clays, carbonates, and marls, covered in unconformity by Quaternary tabular molasses. The upflow of the thermal water is dependent of Alpine faults systems with N30 and N100 directions, which are probable reactivated Hercynian structures that facilitate its circulation to the surface. The Goutitir spring has been studied by an interdisciplinary approach to identify the origin of the thermal water, the rock–water interactions, and the reservoir temperatures, contributing to the establishment of the conceptual model of the associated hydrothermal system. This thermal water is of chloride-sodium type with a hyperthermal character (43–47 °C). The isotopic composition (δ18O = −8.7 to −8.35‰; δ2H = −58.6 to −54.3‰) indicates a meteoric origin and a recharging zone located at around 2000 m of altitude. The chemical composition allows to classify the water as chloride-sodium hydrochemical facies, stabilized at ~100 °C in crystalline basement rocks, which, according to seismic data, are located at ~3 km depth. The concentrations, patterns, and correlations of trace elements point out water–rock interaction processes between the deep water and basic magmatic rocks. The integration of the chemical and isotopic data and the surface geological context shows that the Goutitir water flows within a hydrothermal zone were basic to ultrabasic lamprophyres rich in gabbroic xenoliths outcrop, witnessing the existence, at depth, of basic plutons. Moreover, near the source, these veins are strongly altered and hydrothermalized, showing late recrystallization of centimetric-sized biotites. The chloride-sodium composition of this water may also be a testimony to the presence and reaction with the overlying Triassic saline and gypsiferous and Meso-Cenozoic mainly carbonated formations. Full article
(This article belongs to the Special Issue The Use of Environmental Isotopes in Hydrogeology)
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17 pages, 2350 KiB  
Article
Comparison of Geogases in Two Cenozoic Sedimentary Basins
by Gabriele M. Berberich and Martin B. Berberich
Geosciences 2022, 12(10), 388; https://doi.org/10.3390/geosciences12100388 - 19 Oct 2022
Cited by 6 | Viewed by 1897
Abstract
We investigated fault gases (helium, radon, CO2) in two seismically active Cenozoic sedimentary basins: (a) Meinweg (in 2015), at a tectonically quiescent horst structure in the Lower Rhine Embayment; and (b) Bodanrück (in 2012; Lake of Constance), in the Molasse Basin [...] Read more.
We investigated fault gases (helium, radon, CO2) in two seismically active Cenozoic sedimentary basins: (a) Meinweg (in 2015), at a tectonically quiescent horst structure in the Lower Rhine Embayment; and (b) Bodanrück (in 2012; Lake of Constance), in the Molasse Basin and part of the seismically active Freiburg–Bonndorf–Bodensee Fault Zone (FBBFZ). Both study areas were selected because recent “GeoBio-Interactions” findings showed that red wood ants (RWA) are biological indicators of otherwise undetected degassing systems. We combined presence/absence data of RWA nests, their spatial pattern analysis (prototype lines), seismicity and known tectonic settings with soil gas analyses (a total of 817 samples) to unveil geochemical anomalies related to tectonic developments unknown so far. Currently, Meinweg can be considered “no ants land” due to the very low background-level of geogas concentrations. Thus, anomalies (Rn-CO2) weakly trending in NE-SW extension direction emerged. This could probably indicate the onset of (re)activation of the NE-SW-trending (Variscan) structures or the development of new fractures as an aftershock process of the 1992 Roermond earthquake that occurred about 15 km to the west. Results at Bodanrück (three RWA clusters and two RWA-free corridors) revealed degassing patterns in NW-SE and NNE-SSW directions in the clusters corresponding to re-activated and recent strike-slip fault systems. No gas anomalies were found in RWA-free corridors. The RWA nest distribution was shown to be a valuable tool for identifying areas of even actively degassing spotty anomalies caused by macro- and microscale brittle deformation masked by sediment cover. Full article
(This article belongs to the Special Issue Geogases in Fault Zones)
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16 pages, 5179 KiB  
Article
The Thermographic Analysis of the Agglomeration Process in the Roller Press of Pillow-Shaped Briquettes
by Andrzej Uhryński and Michał Bembenek
Materials 2022, 15(8), 2870; https://doi.org/10.3390/ma15082870 - 14 Apr 2022
Cited by 9 | Viewed by 2052
Abstract
When the briquetting process of fine-grained material takes place in the roller press unit, the pressure reached is over a hundred megapascals. This parameter is a result, among other factors, of the geometry of a compaction unit and also the properties of the [...] Read more.
When the briquetting process of fine-grained material takes place in the roller press unit, the pressure reached is over a hundred megapascals. This parameter is a result, among other factors, of the geometry of a compaction unit and also the properties of the consolidated material. The pressure of the unit is not constant and the changes in value depend on a given place on the molding surface. By the process of generating different types of pressure on the surface of briquettes, their compaction is different as well. The distribution of temperature on the surface of the briquettes may determine the pressure used locally on them. Nevertheless, the distribution of stress in the briquetting material is still a subject of scientific study. However, it is known that the pressure exerted on the briquette is different for different compaction systems. The article includes authors’ further thermography studies on the classical pillow-shaped briquetting process (instead of the saddle-shaped ones that were previously conducted) of four materials (calcium hydroxide and water mixture, mill scale, charcoal fines and starch mixture, as well as a mixture of EAFD, scale, fine coke breeze, molasses, and calcium hydroxide). Immediately after the briquettes left the compaction zone, thermal images were taken of them, as well as forming rollers. Thermograms that were obtained and the variability of temperature at characteristic points of the surface of pillow-shaped briquettes were analyzed. They showed differences in temperature on the surface of briquettes. In all four cases, the highest briquette temperatures were recorded in their upper part, which proves their better densification in this part. The temperature differences between the lower and upper part of the briquettes ranged from 1.8 to 9.7 °C, depending on the mixture. Full article
(This article belongs to the Special Issue Thermography Technique in Materials Science)
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24 pages, 8099 KiB  
Article
The Impact of Clay Minerals on the Building Technology of Vernacular Earthen Architecture in Eastern Austria
by Hubert Feiglstorfer and Franz Ottner
Heritage 2022, 5(1), 378-401; https://doi.org/10.3390/heritage5010022 - 21 Feb 2022
Cited by 2 | Viewed by 3762
Abstract
The vernacular architecture in many regions in Eastern Austria was characterized by the use of unfired clay, at least until the 19th century, and in some areas until the 20th century. Farmhouses and associated farm buildings, such as storage buildings or press houses [...] Read more.
The vernacular architecture in many regions in Eastern Austria was characterized by the use of unfired clay, at least until the 19th century, and in some areas until the 20th century. Farmhouses and associated farm buildings, such as storage buildings or press houses for the production of wine and cider, were erected using different earth construction techniques. The study area stretches from the Weinviertel, a region located in the province of Lower Austria in the north-east of Austria, to the Burgenland, a region located in the south-east of Austria, which belonged to Western Hungary until 1921. From a geological point of view, in the east of Austria—in the Vienna Basin and the Molasse Zone—huge areas of Tertiary clay are covered with loess deposits, which is the best-known basic material used in local earth-building traditions. A core question in the research on vernacular earthen heritage focuses on the impact of the geological conditions in Eastern Austria on the local earth-building techniques. The mineralogical composition of the different clays had an impact on the local building techniques. From a material-culture point of view, research on the relationship between the mineralogical properties of clay resources and local building techniques sheds light on the factors which influenced the evolution of certain vernacular building features. Tertiary clays and loess from the Pleistocene favoured the making of earth lumps, cob walls and adobe bricks over the whole Eastern Austrian region. Contrarily, regions in Burgenland with a high amount of gravel preferred, by tradition, to make walls by ramming. The clay mineral smectite acts as a binding agent in earth-building techniques over the whole investigated region—Weinviertel, Burgenland and Western Hungary. Full article
(This article belongs to the Special Issue Geological Materials and Culture Heritage: Past, Present and Future)
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34 pages, 3441 KiB  
Article
Hydrochemical Zoning and Chemical Evolution of the Deep Upper Jurassic Thermal Groundwater Reservoir Using Water Chemical and Environmental Isotope Data
by Florian Heine, Kai Zosseder and Florian Einsiedl
Water 2021, 13(9), 1162; https://doi.org/10.3390/w13091162 - 22 Apr 2021
Cited by 17 | Viewed by 4750
Abstract
A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ [...] Read more.
A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ18O and 87Sr/86Sr were obtained from groundwater of 24 deep Upper Jurassic geothermal wells and coupled with a few analyses of noble gases (3He/4He, 40Ar/36Ar) and noble gas infiltration temperatures. Hierarchical cluster analysis revealed three major water types and allowed a hydrochemical zoning of the SGMB, while exploratory factor analyses identified the hydrogeological processes affecting the water chemical composition of the thermal water. Water types 1 and 2 are of Na-[Ca]-HCO3-Cl type, lowly mineralised and have been recharged under meteoric cold climate conditions. Both water types show 87Sr/86Sr signatures, stable water isotopes values and calculated apparent mean residence times, which suggest minor water-rock interaction within a hydraulically active flow system of the Northeastern and Southeastern Central Molasse Basin. This thermal groundwater have been most likely subglacially recharged in the south of the SGMB in close proximity to the Bavarian Alps with a delineated northwards flow direction. Highly mineralised groundwater of water type 3 (Na-Cl-HCO3 and Na-Cl) occurs in the Eastern Central Molasse Basin. In contrast to water types 1 and 2, this water type shows substantial water-rock interaction with terrestrial sediments and increasing 40Ar/36Ar ratios, which may also imply a hydraulic exchange with fossil formation waters of overlying Tertiary sediments. Full article
(This article belongs to the Section Hydrology)
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20667 KiB  
Article
Integrated 3D Geological Modeling to Gain Insight in the Effects of Hydrothermal Alteration on Post-Ore Deformation Style and Strain Localization in the Flin Flon Volcanogenic Massive Sulfide Ore System
by Ernst Schetselaar, Doreen Ames and Eric Grunsky
Minerals 2018, 8(1), 3; https://doi.org/10.3390/min8010003 - 25 Dec 2017
Cited by 7 | Viewed by 6534
Abstract
3D geological modeling of lithogeochemical and geological data provides insight into the role of the sulfide ore horizon and associated footwall hydrothermal alteration in localizing shear strain in the Flin Flon volcanogenic massive sulfide deposits, Canada, as deformation evolved from brittle-ductile to ductile [...] Read more.
3D geological modeling of lithogeochemical and geological data provides insight into the role of the sulfide ore horizon and associated footwall hydrothermal alteration in localizing shear strain in the Flin Flon volcanogenic massive sulfide deposits, Canada, as deformation evolved from brittle-ductile to ductile regimes during collisional stages of the 1.9–1.8 Ga Trans-Hudson orogeny. 3D spatial characterization of hydrothermal alteration based on the Ishikawa index (AI) and normative corundum percentages outline sericite + chlorite-rich high strain zones, consisting of Al-enriched and Na-depleted felsic and mafic volcanic rocks in the footwall of the sulfide ore horizon. The hydrothermal vent complex, from which these sheared alteration zones originated, was stacked together with the ore horizon by W-vergent thrust faults during an early collisional deformation regime, imbricating molasse-type clastic sediments with the ore-hosting volcanic and volcaniclastic rocks of the Flin Flon arc assemblage. Chlorite-rich planar zones marked by high values of the Carbonate–chlorite–pyrite index (CCPI) are laterally more extensive and outline a later system of ductile shear zones, in which phyllosilicates, quartz and chalcopyrite in stringer zones localized shear strain and enhanced transposition of the hydrothermal vent stockwork. The contrasting deformation styles of these two thrusting events and their localization within the ore horizon and hydrothermal vent stockwork have important implications for vectoring towards undiscovered ore in this mature mining camp that are possibly also relevant to other strongly deformed VMS ore systems. Full article
(This article belongs to the Special Issue Geological Modelling)
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35996 KiB  
Article
Landslide Displacement Monitoring Using 3D Range Flow on Airborne and Terrestrial LiDAR Data
by Sajid Ghuffar, Balázs Székely, Andreas Roncat and Norbert Pfeifer
Remote Sens. 2013, 5(6), 2720-2745; https://doi.org/10.3390/rs5062720 - 29 May 2013
Cited by 67 | Viewed by 11690
Abstract
An active landslide in Doren, Austria, has been studied by multitemporal airborne and terrestrial laser scanning from 2003 to 2012. To evaluate the changes, we have determined the 3D motion using the range flow algorithm, an established method in computer vision, but not [...] Read more.
An active landslide in Doren, Austria, has been studied by multitemporal airborne and terrestrial laser scanning from 2003 to 2012. To evaluate the changes, we have determined the 3D motion using the range flow algorithm, an established method in computer vision, but not yet used for studying landslides. The generated digital terrain models are the input for motion estimation; the range flow algorithm has been combined with the coarse-to-fine resolution concept and robust adjustment to be able to determine the various motions over the landslide. The algorithm yields fully automatic dense 3D motion vectors for the whole time series of the available data. We present reliability measures for determining the accuracy of the estimated motion vectors, based on the standard deviation of components. The differential motion pattern is mapped by the algorithm: parts of the landslide show displacements up to 10 m, whereas some parts do not change for several years. The results have also been compared to pointwise reference data acquired by independent geodetic measurements; reference data are in good agreement in most of the cases with the results of range flow algorithm; only some special points (e.g., reflectors fixed on trees) show considerably differing motions. Full article
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703 KiB  
Article
Spread of a Gammabaculovirus within Larval Populations of Its Natural Balsam Fir Sawfly (Neodiprion abietis) Host Following Its Aerial Application
by Roger Graves, Christopher J. Lucarotti and Dan T. Quiring
Insects 2012, 3(4), 912-929; https://doi.org/10.3390/insects3040912 - 28 Sep 2012
Cited by 4 | Viewed by 6163
Abstract
Field trials and assessments of the balsam fir sawfly (Neodiprion abietis) nucleopolyhedrovirus (NeabNPV: Baculoviridae, Gammabaculovirus) against its natural host were conducted in July and August 2002 near Corner Brook, Newfoundland and Labrador, Canada, in naturally regenerated, precommercially thinned stands [...] Read more.
Field trials and assessments of the balsam fir sawfly (Neodiprion abietis) nucleopolyhedrovirus (NeabNPV: Baculoviridae, Gammabaculovirus) against its natural host were conducted in July and August 2002 near Corner Brook, Newfoundland and Labrador, Canada, in naturally regenerated, precommercially thinned stands dominated by balsam fir (Abies balsamea). Two experimental blocks, each with its own untreated control, were established. The purpose of the Island Pond block was to examine the spread of NeabNPV from a 313-ha aerial treatment block out into adjacent populations of balsam fir sawflies. The purpose of the Old Man’s Pond block (2,093 ha) was to determine whether NeabNPV could disperse into populations of balsam fir sawflies within a 200-m zone between spray swaths. NeabNPV was applied to treatment blocks by a Cessna 188B AgTruck aircraft equipped with MicronAir AU4000 rotary atomizers at an application rate equivalent to 1 × 109 NeabNPV occlusion bodies/ha in 2.5 L of 20% aqueous molasses. At Island Pond, NeabNPV infection increased with time following the spray, especially for individuals close to the treatment block, and infection rate decreased to a measured distance of 400 m from the treatment block. At Old Man’s Pond, NeabNPV infection rose higher (80% vs. 15%) and sawfly densities declined more (84% vs. 60%) in the area between spray swaths than in the control block. Full article
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