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Keywords = one-class classification

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25 pages, 2699 KiB  
Article
Accurate Power Consumption Predictor and One-Class Electricity Theft Detector for Smart Grid “Change-and-Transmit” Advanced Metering Infrastructure
by Atef Bondok, Omar Abdelsalam, Mahmoud Badr, Mohamed Mahmoud, Maazen Alsabaan, Muteb Alsaqhan and Mohamed I. Ibrahem
Appl. Sci. 2024, 14(20), 9308; https://doi.org/10.3390/app14209308 (registering DOI) - 12 Oct 2024
Viewed by 331
Abstract
The advanced metering infrastructure (AMI) of the smart grid plays a critical role in energy management and billing by enabling the periodic transmission of consumers’ power consumption readings. To optimize data collection efficiency, AMI employs a “change and transmit” (CAT) approach. This approach [...] Read more.
The advanced metering infrastructure (AMI) of the smart grid plays a critical role in energy management and billing by enabling the periodic transmission of consumers’ power consumption readings. To optimize data collection efficiency, AMI employs a “change and transmit” (CAT) approach. This approach ensures that readings are only transmitted when there is enough change in consumption, thereby reducing data traffic. Despite the benefits of this approach, it faces security challenges where malicious consumers can manipulate their readings to launch cyberattacks for electricity theft, allowing them to illegally reduce their bills. While this challenge has been addressed for supervised learning CAT settings, it remains insufficiently addressed in unsupervised learning settings. Moreover, due to the distortion introduced in the power consumption readings due to using the CAT approach, the accurate prediction of future consumption for energy management is a challenge. In this paper, we propose a two-stage approach to predict future readings and detect electricity theft in the smart grid while optimizing data collection using the CAT approach. For the first stage, we developed a predictor that is trained exclusively on benign CAT power consumption readings, and the output of the predictor is the actual readings. To enhance the prediction accuracy, we propose a cluster-based predictor that groups consumers into clusters with similar consumption patterns, and a dedicated predictor is trained for each cluster. For the second stage, we trained an autoencoder and a one-class support vector machine (SVM) on the benign reconstruction errors of the predictor to classify instances of electricity theft. We conducted comprehensive experiments to assess the effectiveness of our proposed approach. The experimental results indicate that the prediction error is very small and the accuracy of detection of the electricity theft attacks is high. Full article
(This article belongs to the Section Transportation and Future Mobility)
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16 pages, 12099 KiB  
Article
Application of the Semi-Supervised Learning Approach for Pavement Defect Detection
by Peng Cui, Nurjihan Ala Bidzikrillah, Jiancong Xu and Yazhou Qin
Sensors 2024, 24(18), 6130; https://doi.org/10.3390/s24186130 - 23 Sep 2024
Viewed by 592
Abstract
Road surface quality is essential for driver comfort and safety, making it crucial to monitor pavement conditions and detect defects in real time. However, the diversity of defects and the complexity of ambient conditions make it challenging to develop an effective and robust [...] Read more.
Road surface quality is essential for driver comfort and safety, making it crucial to monitor pavement conditions and detect defects in real time. However, the diversity of defects and the complexity of ambient conditions make it challenging to develop an effective and robust classification and detection algorithm. In this study, we adopted a semi-supervised learning approach to train ResNet-18 for image feature retrieval and then classification and detection of pavement defects. The resulting feature embedding vectors from image patches were retrieved, concatenated, and randomly sampled to model a multivariate normal distribution based on the only one-class training pavement image dataset. The calibration pavement image dataset was used to determine the defect score threshold based on the receiver operating characteristic curve, with the Mahalanobis distance employed as a metric to evaluate differences between normal and defect pavement images. Finally, a heatmap derived from the defect score map for the testing dataset was overlaid on the original pavement images to provide insight into the network’s decisions and guide measures to improve its performance. The results demonstrate that the model’s classification accuracy improved from 0.868 to 0.887 using the expanded and augmented pavement image data based on the analysis of heatmaps. Full article
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14 pages, 1620 KiB  
Article
Interpretable Support Vector Machine and Its Application to Rehabilitation Assessment
by Woojin Kim, Hyunwoo Joe, Hyun-Suk Kim and Daesub Yoon
Electronics 2024, 13(18), 3584; https://doi.org/10.3390/electronics13183584 - 10 Sep 2024
Viewed by 309
Abstract
This paper does present an interpretable support vector machine (SVM) and its application to rehabilitation assessment. We introduce the concept of nearest boundary point to standardize the one-class SVM decision function and determine the shortest path for data from abnormal cases to become [...] Read more.
This paper does present an interpretable support vector machine (SVM) and its application to rehabilitation assessment. We introduce the concept of nearest boundary point to standardize the one-class SVM decision function and determine the shortest path for data from abnormal cases to become those from normal cases. This analytical approach is computationally simple and provides a unique solution. The nearest boundary point of abnormal data can also be used to analyze the cause of abnormal classification and indicate countermeasures for normalization. These properties render the proposed interpretable SVM valuable for medical assessment applications and other problems that require careful consideration of classification results for treatment. Simulation and application results demonstrate the feasibility and effectiveness of the proposed method. Full article
(This article belongs to the Section Bioelectronics)
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21 pages, 2375 KiB  
Article
Mutation-Based Multivariate Time-Series Anomaly Generation on Latent Space with an Attention-Based Variational Recurrent Neural Network for Robust Anomaly Detection in an Industrial Control System
by Seungho Jeon, Kijong Koo, Daesung Moon and Jung Taek Seo
Appl. Sci. 2024, 14(17), 7714; https://doi.org/10.3390/app14177714 - 1 Sep 2024
Viewed by 981
Abstract
Anomaly detection involves identifying data that deviates from normal patterns. Two primary strategies are used: one-class classification and binary classification. In Industrial Control Systems (ICS), where anomalies can cause significant damage, timely and accurate detection is essential, often requiring analysis of time-series data. [...] Read more.
Anomaly detection involves identifying data that deviates from normal patterns. Two primary strategies are used: one-class classification and binary classification. In Industrial Control Systems (ICS), where anomalies can cause significant damage, timely and accurate detection is essential, often requiring analysis of time-series data. One-class classification is commonly used but tends to have a high false alarm rate. To address this, binary classification is explored, which can better differentiate between normal and anomalous data, though it struggles with class imbalance in ICS datasets. This paper proposes a mutation-based technique for generating ICS time-series anomalies. The method maps ICS time-series data into a latent space using a variational recurrent autoencoder, applies mutation operations, and reconstructs the time-series, introducing plausible anomalies that reflect multivariate correlations. Evaluations of ICS datasets show that these synthetic anomalies are visually and statistically credible. Training a binary classifier on data augmented with these anomalies effectively mitigates the class imbalance problem. Full article
(This article belongs to the Special Issue Methods and Applications of Data Management and Analytics)
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14 pages, 4112 KiB  
Article
A Feasibility Study of a Respiratory Rate Measurement System Using Wearable MOx Sensors
by Mitsuhiro Fukuda, Jaakko Hyry, Ryosuke Omoto, Takunori Shimazaki, Takumi Kobayashi and Daisuke Anzai
Information 2024, 15(8), 492; https://doi.org/10.3390/info15080492 - 16 Aug 2024
Viewed by 488
Abstract
Accurately obtaining a patient’s respiratory rate is crucial for promptly identifying any sudden changes in their condition during emergencies. Typically, the respiratory rate is assessed through a combination of impedance change measurements and electrocardiography (ECG). However, impedance measurements are prone to interference from [...] Read more.
Accurately obtaining a patient’s respiratory rate is crucial for promptly identifying any sudden changes in their condition during emergencies. Typically, the respiratory rate is assessed through a combination of impedance change measurements and electrocardiography (ECG). However, impedance measurements are prone to interference from body movements. Conversely, a capnometer coupled with a ventilator offers a method of measuring the respiratory rate that is unaffected by body movements. However, capnometers are mainly used to evaluate respiration when using a ventilator or an Ambu bag by measuring the CO2 concentration at the breathing circuit, and they are not used only to measure the respiratory rate. Furthermore, capnometers are not suitable as wearable devices because they require intubation or a mask that covers the nose and mouth to prevent air leaks during the measurement. In this study, we developed a reliable system for measuring the respiratory rate utilizing a small wearable MOx sensor that is unaffected by body movements and not connected to the breathing circuit. Subsequently, we conducted experimental assessments to gauge the accuracy of the rate estimation achieved by the system. In order to avoid the effects of abnormal states on the estimation accuracy, we also evaluated the classification performance for distinguishing between normal and abnormal respiration using a one-class SVM-based approach. The developed system achieved 80% for both true positive and true negative rates. Our experimental findings reveal that the respiratory rate can be precisely determined without being influenced by body movements. Full article
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19 pages, 6986 KiB  
Article
Ensemble One-Class Support Vector Machine for Sea Surface Target Detection Based on k-Means Clustering
by Shichao Chen, Xin Ouyang and Feng Luo
Remote Sens. 2024, 16(13), 2401; https://doi.org/10.3390/rs16132401 - 29 Jun 2024
Cited by 3 | Viewed by 782
Abstract
Sea surface target detection is a key stage in a typical target detection system and directly influences the performance of the whole system. As an effective discriminator, the one-class support vector machine (OCSVM) has been widely used in target detection. In OCSCM, training [...] Read more.
Sea surface target detection is a key stage in a typical target detection system and directly influences the performance of the whole system. As an effective discriminator, the one-class support vector machine (OCSVM) has been widely used in target detection. In OCSCM, training samples are first mapped to the hypersphere in the kernel space with the Gaussian kernel function, and then, a linear classification hyperplane is constructed in each cluster to separate target samples from other classes of samples. However, when the distribution of the original data is complex, the transformed data in the kernel space may be nonlinearly separable. In this situation, OCSVM cannot classify the data correctly, because only a linear hyperplane is constructed in the kernel space. To solve this problem, a novel one-class classification algorithm, referred to as ensemble one-class support vector machine (En-OCSVM), is proposed in this paper. En-OCSVM is a hybrid model based on k-means clustering and OCSVM. In En-OCSVM, training samples are clustered in the kernel space with the k-means clustering algorithm, while a linear decision hyperplane is constructed in each cluster. With the combination of multiple linear classification hyperplanes, a complex nonlinear classification boundary can be achieved in the kernel space. Moreover, the joint optimization of the k-means clustering model and OCSVM model is realized in the proposed method, which ensures the linear separability of each cluster. The experimental results based on the synthetic dataset, benchmark datasets, IPIX datasets, and SAR real data demonstrate the better performance of our method over other related methods. Full article
(This article belongs to the Special Issue Radar Signal Processing and Imaging for Ocean Remote Sensing)
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19 pages, 1411 KiB  
Article
Malware Detection for Internet of Things Using One-Class Classification
by Tongxin Shi, Roy A. McCann, Ying Huang, Wei Wang and Jun Kong
Sensors 2024, 24(13), 4122; https://doi.org/10.3390/s24134122 - 25 Jun 2024
Cited by 1 | Viewed by 616
Abstract
The increasing usage of interconnected devices within the Internet of Things (IoT) and Industrial IoT (IIoT) has significantly enhanced efficiency and utility in both personal and industrial settings but also heightened cybersecurity vulnerabilities, particularly through IoT malware. This paper explores the use of [...] Read more.
The increasing usage of interconnected devices within the Internet of Things (IoT) and Industrial IoT (IIoT) has significantly enhanced efficiency and utility in both personal and industrial settings but also heightened cybersecurity vulnerabilities, particularly through IoT malware. This paper explores the use of one-class classification, a method of unsupervised learning, which is especially suitable for unlabeled data, dynamic environments, and malware detection, which is a form of anomaly detection. We introduce the TF-IDF method for transforming nominal features into numerical formats that avoid information loss and manage dimensionality effectively, which is crucial for enhancing pattern recognition when combined with n-grams. Furthermore, we compare the performance of multi-class vs. one-class classification models, including Isolation Forest and deep autoencoder, that are trained with both benign and malicious NetFlow samples vs. trained exclusively on benign NetFlow samples. We achieve 100% recall with precision rates above 80% and 90% across various test datasets using one-class classification. These models show the adaptability of unsupervised learning, especially one-class classification, to the evolving malware threats in the IoT domain, offering insights into enhancing IoT security frameworks and suggesting directions for future research in this critical area. Full article
(This article belongs to the Special Issue AI Technology for Cybersecurity and IoT Applications)
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10 pages, 4839 KiB  
Communication
Identifying Minerals from Image Using Out-of-Distribution Artificial Intelligence-Based Model
by Xiaohui Ji, Kaiwen Liang, Yang Yang, Mei Yang, Mingyue He, Zhaochong Zhang, Shan Zeng and Yuzhu Wang
Minerals 2024, 14(6), 627; https://doi.org/10.3390/min14060627 - 20 Jun 2024
Viewed by 993
Abstract
Deep learning has increasingly been used to identify minerals. However, deep learning can only be used to identify minerals within the distribution of the training set, while any mineral outside the spectrum of the training set is inevitably categorized erroneously within a predetermined [...] Read more.
Deep learning has increasingly been used to identify minerals. However, deep learning can only be used to identify minerals within the distribution of the training set, while any mineral outside the spectrum of the training set is inevitably categorized erroneously within a predetermined class from the training set. To solve this problem, this study introduces the approach that combines a One-Class Support Vector Machine (OCSVM) with the ResNet architecture for out-of-distribution mineral detection. Initially, ResNet undergoes training using a training set comprising well-defined minerals. Subsequently, the first two layers obtained from the trained ResNet are employed to extract the discriminative features of the mineral under consideration. These extracted mineral features then become the input for OCSVM. When OCSVM discerns the mineral in the training set’s distribution, it triggers the subsequent layers within the trained ResNet, facilitating the accurate classification of the mineral into one of the predefined categories encompassing the known minerals. In the event that OCSVM identifies a mineral outside of the training set’s distribution, it is categorized as an unclassified or ‘unknown’ mineral. Empirical results substantiate the method’s capability to identify out-of-distribution minerals while concurrently maintaining a commendably high accuracy rate for the classification of the 36 in-distribution minerals. Full article
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16 pages, 11727 KiB  
Article
Toward Interpretable Cell Image Representation and Abnormality Scoring for Cervical Cancer Screening Using Pap Smears
by Yu Ando, Junghwan Cho, Nora Jee-Young Park, Seokhwan Ko and Hyungsoo Han
Bioengineering 2024, 11(6), 567; https://doi.org/10.3390/bioengineering11060567 - 4 Jun 2024
Viewed by 757
Abstract
Screening is critical for prevention and early detection of cervical cancer but it is time-consuming and laborious. Supervised deep convolutional neural networks have been developed to automate pap smear screening and the results are promising. However, the interest in using only normal samples [...] Read more.
Screening is critical for prevention and early detection of cervical cancer but it is time-consuming and laborious. Supervised deep convolutional neural networks have been developed to automate pap smear screening and the results are promising. However, the interest in using only normal samples to train deep neural networks has increased owing to the class imbalance problems and high-labeling costs that are both prevalent in healthcare. In this study, we introduce a method to learn explainable deep cervical cell representations for pap smear cytology images based on one-class classification using variational autoencoders. Findings demonstrate that a score can be calculated for cell abnormality without training models with abnormal samples, and we localize abnormality to interpret our results with a novel metric based on absolute difference in cross-entropy in agglomerative clustering. The best model that discriminates squamous cell carcinoma (SCC) from normals gives 0.908±0.003 area under operating characteristic curve (AUC) and one that discriminates high-grade epithelial lesion (HSIL) 0.920±0.002 AUC. Compared to other clustering methods, our method enhances the V-measure and yields higher homogeneity scores, which more effectively isolate different abnormality regions, aiding in the interpretation of our results. Evaluation using an external dataset shows that our model can discriminate abnormality without the need for additional training of deep models. Full article
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17 pages, 541 KiB  
Article
Utilizing Nearest-Neighbor Clustering for Addressing Imbalanced Datasets in Bioengineering
by Chih-Ming Huang, Chun-Hung Lin, Chuan-Sheng Hung, Wun-Hui Zeng, You-Cheng Zheng and Chih-Min Tsai
Bioengineering 2024, 11(4), 345; https://doi.org/10.3390/bioengineering11040345 - 31 Mar 2024
Viewed by 931
Abstract
Imbalance classification is common in scenarios like fault diagnosis, intrusion detection, and medical diagnosis, where obtaining abnormal data is difficult. This article addresses a one-class problem, implementing and refining the One-Class Nearest-Neighbor (OCNN) algorithm. The original inter-quartile range mechanism is replaced with the [...] Read more.
Imbalance classification is common in scenarios like fault diagnosis, intrusion detection, and medical diagnosis, where obtaining abnormal data is difficult. This article addresses a one-class problem, implementing and refining the One-Class Nearest-Neighbor (OCNN) algorithm. The original inter-quartile range mechanism is replaced with the K-means with outlier removal (KMOR) algorithm for efficient outlier identification in the target class. Parameters are optimized by treating these outliers as non-target-class samples. A new algorithm, the Location-based Nearest-Neighbor (LBNN) algorithm, clusters one-class training data using KMOR and calculates the farthest distance and percentile for each test data point to determine if it belongs to the target class. Experiments cover parameter studies, validation on eight standard imbalanced datasets from KEEL, and three applications on real medical imbalanced datasets. Results show superior performance in precision, recall, and G-means compared to traditional classification models, making it effective for handling imbalanced data challenges. Full article
(This article belongs to the Special Issue Computer Vision and Machine Learning in Medical Applications)
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25 pages, 7014 KiB  
Article
Machinery Fault Signal Detection with Deep One-Class Classification
by Dosik Yoon and Jaehong Yu
Appl. Sci. 2024, 14(1), 221; https://doi.org/10.3390/app14010221 - 26 Dec 2023
Viewed by 977
Abstract
Fault detection of machinery systems is a fundamental prerequisite to implementing condition-based maintenance, which is the most eminent manufacturing equipment system management strategy. To build the fault detection model, one-class classification algorithms have been used, which construct the decision boundary only using normal [...] Read more.
Fault detection of machinery systems is a fundamental prerequisite to implementing condition-based maintenance, which is the most eminent manufacturing equipment system management strategy. To build the fault detection model, one-class classification algorithms have been used, which construct the decision boundary only using normal class. For more accurate one-class classification, signal data have been used recently because the signal data directly reflect the condition of the machinery system. To analyze the machinery condition effectively with the signal data, features of signals should be extracted, and then, the one-class classifier is constructed with the features. However, features separately extracted from one-class classification might not be optimized for the fault detection tasks, and thus, it leads to unsatisfactory performance. To address this problem, deep one-class classification methods can be used because the neural network structures can generate the features specialized to fault detection tasks through the end-to-end learning manner. In this study, we conducted a comprehensive experimental study with various fault signal datasets. The experimental results demonstrated that the deep support vector data description model, which is one of the most prominent deep one-class classification methods, outperforms its competitors and traditional methods. Full article
(This article belongs to the Special Issue Artificial Intelligence in Fault Diagnosis and Signal Processing)
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28 pages, 9848 KiB  
Article
Efficient One-Class False Data Detector Based on Deep SVDD for Smart Grids
by Hany Habbak, Mohamed Mahmoud, Mostafa M. Fouda, Maazen Alsabaan, Ahmed Mattar, Gouda I. Salama and Khaled Metwally
Energies 2023, 16(20), 7069; https://doi.org/10.3390/en16207069 - 12 Oct 2023
Cited by 3 | Viewed by 1496
Abstract
In the smart grid, malicious consumers can hack their smart meters to report false power consumption readings to steal electricity. Developing a machine-learning based detector for identifying these readings is a challenge due to the unavailability of malicious datasets. Most of the existing [...] Read more.
In the smart grid, malicious consumers can hack their smart meters to report false power consumption readings to steal electricity. Developing a machine-learning based detector for identifying these readings is a challenge due to the unavailability of malicious datasets. Most of the existing works in the literature assume attacks to compute malicious data. These detectors are trained to identify these attacks, but they cannot identify new attacks, which creates a vulnerability. Very few papers in the literature tried to address this problem by investigating anomaly detectors trained solely on benign data, but they suffer from these limitations: (1) low detection accuracy and high false alarm; (2) the need for knowledge on the malicious data to compute good detection thresholds; and (3) they cannot capture the temporal correlations of the readings and do not address the class overlapping issue caused by some deceptive attacks. To address these limitations, this paper presents a deep support vector data description (DSVDD) based unsupervised detector for false data in smart grid. Time-series readings are transformed into images, and the detector is exclusively trained on benign images. Our experimental results demonstrate the superior performance of our detectors compared to existing approaches in the literature. Specifically, our proposed DSVDD-based schemes have exhibited improvements of 0.5% to 3% in terms of recall and 3% to 9% in terms of the Area Under the Curve (AUC) when compared to existing state-of-the-art detectors. Full article
(This article belongs to the Section A1: Smart Grids and Microgrids)
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23 pages, 2611 KiB  
Article
Fuzzy CNN Autoencoder for Unsupervised Anomaly Detection in Log Data
by Oleg Gorokhov, Mikhail Petrovskiy, Igor Mashechkin and Maria Kazachuk
Mathematics 2023, 11(18), 3995; https://doi.org/10.3390/math11183995 - 20 Sep 2023
Cited by 1 | Viewed by 1566
Abstract
Currently, the task of maintaining cybersecurity and reliability in various computer systems is relevant. This problem can be solved by detecting anomalies in the log data, which are represented as a stream of textual descriptions of events taking place. For these purposes, reduction [...] Read more.
Currently, the task of maintaining cybersecurity and reliability in various computer systems is relevant. This problem can be solved by detecting anomalies in the log data, which are represented as a stream of textual descriptions of events taking place. For these purposes, reduction to a One-class classification problem is used. Standard One-class classification methods do not achieve good results. Deep learning approaches are more effective. However, they are not robust to outliers and require a lot of computational effort. In this paper, we propose a new robust approach based on a convolutional autoencoder using fuzzy clustering. The proposed approach uses a parallel convolution operation to feature extraction, which makes it more efficient than the currently popular Transformer architecture. In the course of the experiments, the proposed approach showed the best results for both the cybersecurity and the reliability problems compared to existing approaches. It was also shown that the proposed approach is robust to outliers in the training set. Full article
(This article belongs to the Special Issue Mathematical Modeling, Optimization and Machine Learning, 2nd Edition)
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20 pages, 716 KiB  
Article
One-Class Machine Learning Classifiers-Based Multivariate Feature Extraction for Grid-Connected PV Systems Monitoring under Irradiance Variations
by Zahra Yahyaoui, Mansour Hajji, Majdi Mansouri and Kais Bouzrara
Sustainability 2023, 15(18), 13758; https://doi.org/10.3390/su151813758 - 15 Sep 2023
Cited by 5 | Viewed by 1251
Abstract
In recent years, photovoltaic (PV) energy production has witnessed overwhelming growth, which has inspired the search for more effective operations. Nevertheless, different PV faults may appear, which leads to various degradation stages. Furthermore, under different irradiance levels, these faults may be misclassified as [...] Read more.
In recent years, photovoltaic (PV) energy production has witnessed overwhelming growth, which has inspired the search for more effective operations. Nevertheless, different PV faults may appear, which leads to various degradation stages. Furthermore, under different irradiance levels, these faults may be misclassified as a healthy mode owing to the high resemblances between them, thus provoking serious challenges in terms of power losses and maintenance costs. Hence, interposing the irradiance variation in grid-connected PV (GCPV) systems modeling is important for monitoring tasks to ensure the effective operation of these systems, to increase their reliability and to prevent false alarms. Therefore, in this paper, a fault detection and diagnosis (FDD) method for the GCPV systems using machine learning (ML) based on principal component analysis (PCA) is proposed in order to ensure the reliability and security of the whole system under irradiance variations. The proposed strategy consists of three main steps: (i) introduce the irradiance variations in PV system modeling because of its great impact on power production; (ii) feature extraction and selection through PCA; and (iii) fault classification using ML techniques. In this study, we generate a database that is used to compare the proposed strategy with the standard strategy (considering a fixed irradiance during FDD), to make, at first, a complete and significant comparative assessment of fault diagnosis and to demonstrate the efficiency of the proposed strategy. The achieved results show the high effectiveness of the proposed one-class classification-based approach to detect and diagnose PV array anomalies, reaching an accuracy up to 99.68%. Full article
(This article belongs to the Section Energy Sustainability)
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14 pages, 2201 KiB  
Article
Quantification and Detection of Ground Garlic Adulteration Using Fourier-Transform Near-Infrared Reflectance Spectra
by Michal Daszykowski, Michal Kula and Ivana Stanimirova
Foods 2023, 12(18), 3377; https://doi.org/10.3390/foods12183377 - 8 Sep 2023
Cited by 1 | Viewed by 1291
Abstract
This study demonstrates the rapid and cost-effective possibility of quantifying adulterant amounts (corn flour or corn starch) in ground and dried garlic samples. Prepared mixtures with different concentrations of selected adulterant were effectively characterized using Fourier-transform near-infrared reflectance spectra (FT-NIR), and multivariate calibration [...] Read more.
This study demonstrates the rapid and cost-effective possibility of quantifying adulterant amounts (corn flour or corn starch) in ground and dried garlic samples. Prepared mixtures with different concentrations of selected adulterant were effectively characterized using Fourier-transform near-infrared reflectance spectra (FT-NIR), and multivariate calibration models were developed using two methods: principal component regression (PCR) and partial least squares regression (PLSR). They were constructed for optimally preprocessed FT-NIR spectra, and PLSR models generally performed better regarding model fit and predictions than PCR. The optimal PLSR model, built to estimate the amount of corn flour present in the ground and dried garlic samples, was constructed for the first derivative spectra obtained after Savitzky–Golay smoothing (fifteen sampling points and polynomial of the second degree). It demonstrated root mean squared errors for calibration and validation samples equal to 1.8841 and 1.8844 (i.e., 1.88% concerning the calibration range), respectively, and coefficients of determination equal to 0.9955 and 0.9858. The optimal PLSR model constructed for spectra after inverse scattering correction to assess the amount of corn starch had root mean squared errors for calibration and validation samples equal to 1.7679 and 1.7812 (i.e., 1.77% and 1.78% concerning the calibration range), respectively, and coefficients of determination equal to 0.9961 and 0.9873. It was also possible to discriminate samples adulterated with corn flour or corn starch using partial least squares discriminant analysis (PLS-DA). The optimal PLS-DA model had a very high correct classification rate (99.66%), sensitivity (99.96%), and specificity (99.36%), calculated for external validation samples. Uncertainties of these figures of merit, estimated using the Monte Carlo validation approach, were relatively small. One-class classification partial least squares models, developed to detect the adulterant type, presented very optimistic sensitivity for validation samples (above 99%) but low specificity (64% and 45.33% for models recognizing corn flour or corn starch adulterants, respectively). Through experimental investigation, chemometric data analysis, and modeling, we have verified that the FT-NIR technique exhibits the required sensitivity to quantify adulteration in dried ground garlic, whether it involves corn flour or corn starch. Full article
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