Search Results (248)

Spectral peak purity evaluations are often used to control inadequate selectivity issues appearing in liquid chromatography separations coupled with UV-Vis photodiode detection, despite known limitations related to (a) the lack of characteristic absorption bands in UV-Vis for target analytes and overlapping related impurities; (b) increased similarity between the spectral characteristics of co-eluting compounds; (c) large concentration differences between overlapping compounds; (d) perfect co-elution cases. We propose an alternative protocol to evaluate differences between spectra collected over a peak’s elution interval. After normalizing the acquired spectra, linear regression was applied between each pair of spectra, resulting in slope, intercepts, and correlation coefficient sets, from each comparison. The means and standard deviations of each variable are thus computed. An ellipsoid in the 3D Cartesian space illustrates these computations, having the mean coordinates as center and 2 × standard deviations of the variables as the axes. The volume of the ellipsoid should be related to the similarity between the compared spectra; a smaller volume indicates a higher spectral similarity. This approach was evaluated with respect to the (a) concentration of the analytes; (b) spectral acquisition parameters (spectral resolution, spectral frequency acquisition); (c) spectral similarity between overlapping peaks; (d) perfect co-elution situation; (e) influence of spectral processing (derivation, wavelength rationing), using test solutions of carbamazepine (a,b), acetyl cysteine and enalapril maleate (c), or nitrazepam and diazepam (d,e). Full article

Tunable perfect acoustic absorption at subwavelength thickness has been a prominent topic in scientific research and engineering applications. Although metamaterials such as labyrinthine metasurfaces and coiling-up-space metamaterials can achieve subwavelength low-frequency acoustic absorption, efficiently realizing tunable absorption under uniform and limited size conditions remains challenging. In this paper, we introduce a folded slit to enhance the micro-slit acoustic absorber, effectively improving its low-frequency acoustic absorption performance and successfully achieving a perfect acoustic absorption coefficient of 0.99 at a thickness of only 3.1 cm. By adjusting just two parameters of the folded area, we can efficiently achieve a tunable resonant frequency ranging from 525 to 673 Hz and a tunable acoustic absorption bandwidth of 56.5% to 60.2%, simultaneously maintaining uniform external dimensions. Additionally, the folded-slit absorber demonstrates a broader acoustic absorption bandwidth at lower frequencies, enhancing broadband absorption capabilities in the low-frequency domain. These results hold significant potential for the design of highly efficient, thin and tunable acoustic absorbers. Full article

Currently, perfect absorption properties of metamaterials have attracted widespread interest in the area of solar energy. Ultra-broadband absorption, incidence angle insensitivity, and polarization independence are key performance indicators in the design of the absorbers. In this work, we proposed a metamaterial absorber based on the absorption mechanism with multiple resonances, including propagation surface plasmon resonance (PSPR), localized surface plasmon resonance (LSPR), electric dipole resonance (EDR), and magnetic dipole resonance (MDR). The absorber, consisting of composite nanocylinders and a microcavity, can perform solar energy full-spectrum absorption. The proposed absorber obtained high absorption (>95%) from 272 nm to 2742 nm at normal incidence. The weighted absorption rate of the absorber at air mass 1.5 direct in the wavelength range of 280 nm to 3000 nm exceeds 98.5%. The ultra-broadband perfect absorption can be ascribed to the interaction of those resonances. The photothermal conversion efficiency of the absorber reaches 85.3% at 375 K. By analyzing the influence of the structural parameters on the absorption efficiency, the absorber exhibits excellent fault tolerance. In addition, the designed absorber is insensitive to polarization and variation in ambient refractive index and has an absorption rate of more than 80% at the incident angle of 50°. Our proposed absorber has great application potential in solar energy collection, photothermal conversion, and other related areas. Full article

In this article, we present a terahertz (THz) metamaterial absorber that blends two types of coordinated materials: Dirac semimetals and vanadium dioxide. Compared to other absorbers on the market, which are currently non-adjustable or have a single adjustment method, our absorber is superior because it has two coordinated modes with maximum adjustment ranges of 80.7% and 0.288 THz. The device contains four flawless absorption peaks (M1, M2, M3, and M4) spanning the frequency range of 2.0 THz to 6.0 THz, all with absorption rates greater than 99%. After calculation, the relative impedance of the device matches with that in free space, resulting in perfect absorption. In addition, our absorber has extremely excellent polarization insensitivity but is highly sensitive to changes in the environmental refractive index, with the highest environmental refractive index sensitivity of 716 GHz/RIU (gigahertz per refractive index unit). To sum up, the terahertz metamaterial absorber we showed has four perfect absorption peaks, high sensitivity, and stable polarization. This means it could be useful in areas like changing electromagnetic waves, making new sensors, and switching. Full article

Ultrathin titanium nitride (TiN) is a novel material platform for constructing active metasurfaces in the near-infrared region (NIR). Here, we realized tunable polarization-selective absorption by gating ultrathin TiN in an Ultrathin TiN Grating Metasurface (UTGM) and a gold resonator/TiN film Hybrid Metasurface (GTHM), respectively. The TM wave absorption (0.96) was much larger than that of the TE wave in the UTGM. When the carrier density decreased by 12%, the near-perfect TM absorption peak blue-shifted by 0.3 μm. Similarly, the linear dichroism (0.96) peak in GTHM blue-shifted by 0.12 μm when gating ultrathin TiN film. Active metasurfaces with tunable polarization-selective absorption have huge potential in dynamic integrated electro-optic devices in NIR. Full article

Infrared metamaterial absorbers underpin many entrenched scientific and technical applications, including radiative cooling, energy harvesting, infrared detectors, and microbolometers. However, achieving both perfect and ultra-broadband absorption remains an unmet scientific challenge because the traditional metamaterial absorber strategy suffers from complex multi-sized resonators and multiple meta-element patterns. We demonstrate a simple ultra-broadband infrared metamaterial absorber consisting of tilted graphite wires and an Al reflector. The proposed tilted wires-based metamaterial (TWM) absorber exhibits absorption of above 0.95 across the middle to very long-wavelength infrared spectrum (3–30 µm). By increasing the aspect ratio, the bandwidth can be expanded and achieve near-perfect absorption in the 3–50 μm spectral range. The excellent infrared absorptance performance primarily originates from the ohmic loss induced by the electromagnetic coupling between neighboring tilted wires. Furthermore, we propose a typical three-layer equivalent model featuring a resonator/insulator/reflector configuration that requires more than 84 resonant cavities to obtain comparable infrared absorptance. Our high-performance TWM absorber could accelerate the development of next-generation infrared thermal emitters and devices and other technologies that require infrared absorption. Full article

The flotation effect of lean coal is crucial for its clean utilization. Therefore, the flotation characteristics of difficult-to-float lean coal were studied. The analysis results of the feed properties showed that the ash content of the feed was high and the particle size was very fine. The minerals in the gangue mainly included sericite, kaolinite, quartz, white mica, and other substances. After flotation, the functional groups of the coal particles in the tailings decreased, and the absorption peak intensity weakened. Furthermore, the results of multi-factor flotation experiments showed that the dosages of the collector and the frother were significant factors affecting the yield of clean coal. The clean coal yield gradually increased with an increase in the two factors. The ash content of the clean coal increased with an increase in the frother dosage. Within the range of feed concentrations used in this work, the feed concentration was not a significant factor affecting the clean coal’s yield and ash content. Prediction models for the clean coal yield and ash content were proposed. Under optimized experimental conditions, the clean coal yield and the flotation perfection index were 72.15% and 46.63%, respectively, indicating a good flotation effect. Full article

In the present study, the hydrogen-absorption properties of the LaNi₅ and the La_0.7Ce_0.1Ga_0.3Ni₅ compounds were determined and compared. This work is therefore divided into two parts: an experimental part that presents and discusses the kinetics and isotherms of hydrogen absorption in the two compounds at two different temperatures (298 K and 318 K). In addition, the temperature variations inside the hydride bed were determined. In the second section, the experimental isotherms were compared to a numerical model processed using statistical physics. Following that, thanks to the perfect agreement between the experimental data and the proposed model, the stereographic and energetic parameters associated with the hydrogen absorption reaction, such as the number of hydrogen atoms per receptor site (n₁, n₂), the densities of the sites (N_m1, N_m2), the half-saturation pressures (P₁, P₂) and the absorption energies (ΔE₁, ΔE₂) for each receptor site, were calculated. All of these parameters are acquired by making numerical adjustments to the experimental data. Thermodynamic functions, such as internal energy and Gibbs energy, which regulate the absorption process, were then identified using these parameters. For both compounds, all of the aforementioned were compared and discussed in relation to initial temperature and pressure. The results demonstrated that the hydrogen-storage properties in LaNi₅ are enhanced by more than 30% of stored mass and kinetics when Ce and Ga are substituted at the La sites. Full article

In this study, an ultra-wideband absorber spanning from UV-B to middle-IR was designed and analyzed using a novel structure. The multilayer metamaterial, arranged from bottom to top, consisted of an Al metal layer, a lower SiO₂ layer, a graphite layer, another SiO₂ layer, a thin Ti layer, and a top SiO₂ layer. The top layer of SiO₂ had a 200 nm square cavity etched out, and then a square Ti nanopillar and a square Ti hollow outside a Ti nanopillar were embedded. This specific arrangement was chosen to maximize the absorption properties across a broad spectrum. The absorption spectrum of the designed absorber was thoroughly analyzed using the commercial finite element analysis software COMSOL Multiphysics^® (version 6.0). This analysis confirmed that the combination of these various components achieved perfect absorption and an ultra-wideband response. The synergistic interaction between the layers and the nanopillars structure contributed significantly to the absorber’s efficiency, making it a promising candidate for applications requiring broad-spectrum absorption. The comprehensive analyses of the parameters for different structures demonstrated that the effects of guided-mode resonance, coupling resonance, optical impedance matching, and propagating surface plasmon resonance existed in the investigated structure. The optimal model, determined through analyses using COMSOL Multiphysics^®, showed that the broadband absorption in the range of 270 to 3600 nm, spanning from UV-B to middle-IR, exceeded 90.0%. The average absorption rate within this range was 0.967, with the highest reaching a near-perfect absorptivity of 99.9%. We also compared three absorption spectra in this study: the t1–t6 flat structure, the t1–t5 flat structure with t6 featuring a square cavity, and the structure proposed in this study. This demonstrates that a square nanopillar and a square hollow embedded in a square cavity can enhance the absorptive properties of the absorber. Full article

Metasurfaces have emerged as a unique group of two-dimensional ultra-compact subwavelength devices for perfect wave absorption due to their exceptional capabilities of light modulation. Nonetheless, achieving high absorption, particularly with multi-band broadband scalability for specialized scenarios, remains a challenge. As an example, the presence of atmospheric windows, as dictated by special gas molecules in different infrared regions, highly demands such scalable modulation abilities for multi-band absorption and filtration. Herein, by leveraging the hybrid effect of Fabry–Perot resonance, magnetic dipole resonance and electric dipole resonance, we achieved multi-broadband absorptivity in three prominent infrared atmospheric windows concurrently, with an average absorptivity of 87.6% in the short-wave infrared region (1.4–1.7 μm), 92.7% in the mid-wave infrared region (3.2–5 μm) and 92.4% in the long-wave infrared region (8–13 μm), respectively. The well-confirmed absorption spectra along with its adaptation to varied incident angles and polarization angles of radiations reveal great potential for fields like infrared imaging, photodetection and communication. Full article

Black GaAs nanotip arrays (NTs) with 3300 nm lengths were fabricated via self-masked plasma etching. We show, both experimentally and numerically, that these NTs, with three gradient refractive index layers, effectively suppress Fresnel reflections at the air–GaAs interface over a broad range of wavelengths. These NTs exhibit exceptional UV-Vis light absorption (up to 99%) and maintain high NIR absorption (33–60%) compared to bare GaAs. Moreover, possessing a graded layer with a low refractive index (n = 1.01 to 1.12), they achieve angular and polarization-independent antireflection properties exceeding 80° at 632.8 nm, aligning with perfect antireflective coating theory predictions. This approach is anticipated to enhance the performance of optoelectronic devices across a wide range of applications. Full article

A terahertz metamaterial microfluidic sensing chip for ultrasensitive detection is proposed to investigate the response of substances to terahertz radiation in liquid environments and enhance the molecular fingerprinting of trace substances. The structure consists of a cover layer, a metal microstructure, a microfluidic channel, a metal reflective layer, and a buffer layer from top to bottom, respectively. The simulation results show that there are three obvious resonance absorption peaks in the range of 1.5–3.0 THz and the absorption intensities are all above 90%. Among them, the absorption intensity at M1 = 1.971 THz is 99.99%, which is close to the perfect absorption, and its refractive index sensitivity and Q-factor are 859 GHz/RIU and 23, respectively, showing excellent sensing characteristics. In addition, impedance matching and equivalent circuit theory are introduced in this paper to further analyze the physical mechanism of the sensor. Finally, we perform numerical simulations using refractive index data of normal and cancer cells, and the results show that the sensor can distinguish different types of cells well. The chip can reduce the sample pretreatment time as well as enhance the interaction between terahertz waves and matter, which can be used for early disease screening and food quality and safety detection in the future. Full article

The main development direction for current solar technology is to improve absorption efficiency and stability. To bridge this gap, we design in this paper a structure consisting of two multilayer disc stacks of different radii, one topped by a TiO₂ disc and the other by a cascade disc stack composed of SiO₂-Ti, for use in thermal emitters and solar absorbers. The innovation of our work is the exploitation of multiple Fabry–Perot resonances in SiO₂-Ti cascade optical cavities to develop absorber bandwidths while investigating it in the field of thermal emission and many aspects affecting the efficiency of the absorber. The finite difference time domain method (FDTD) results show absorption averages as high as 96.68% with an absorption bandwidth of 2445 nm (A > 90%) at 280 nm–3000 nm solar incidence and even higher weighted averages as high as 98.48% at 1.5 solar air mass (AM) illumination. In order to investigate the physical mechanisms of our designed absorber in a high absorption state, we analyzed the electric field distributions of its four absorption peaks and concluded that its high absorption is mainly caused by the coupling of multiple Fabry–Perot resonance modes in the cascaded optical cavity. While considering this high efficiency, we also investigated the effect of complex environments such as extreme high temperatures and changes in the angle of incidence of the absorber, and the results show that the thermal radiation efficiency of the emitter is 96.79% at an operating temperature of 1700 K, which is higher than its thermal radiation efficiency of 96.38% at an operating temperature of 1500 K, which is a perfect result. On the other hand, we conclude that the designed structure is independent of polarization, while the absorber still has 88.22% absorption at incidence angles of up to 60°, both in transverse electric (TE) and transverse magnetic (TM) modes. The results of this study can help improve the performance of future solar absorbers and expand their application areas. Full article

Aiming at the limitations of single-functionality, limited-applicability, and complex designs prevalent in current metasurfaces, we propose a terahertz multifunctional and multiband tunable metasurface utilizing a VO₂-metal hybrid structure. This metasurface structure comprises a top VO₂-metal resonance layer, a middle polyimide dielectric layer, and a gold film reflective layer at the bottom. This metasurface exhibits multifunctionality, operating independently of polarization and incident angle. The varying conductivity states of the VO₂ layers, enabling the metasurface to achieve various terahertz functionalities, including single-band absorption, broadband THz absorption, and multiband perfect polarization conversion for linear (LP) and circularly polarized (CP) incident waves. Finally, we believe that the functional adaptability of the proposed metasurface expands the repertoire of options available for future terahertz device designs. Full article

GaN on Si plays an important role in the integration and promotion of GaN-based wide-gap materials with Si-based integrated circuits (IC) technology. A series of GaN film materials were grown on Si (111) substrate using a unique plasma assistant molecular beam epitaxy (PA-MBE) technology and investigated using multiple characterization techniques of Nomarski microscopy (NM), high-resolution X-ray diffraction (HR-XRD), variable angular spectroscopic ellipsometry (VASE), Raman scattering, photoluminescence (PL), and synchrotron radiation (SR) near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. NM confirmed crack-free wurtzite (w-) GaN thin films in a large range of 180–1500 nm. XRD identified the w- single crystalline structure for these GaN films with the orientation along the c-axis in the normal growth direction. An optimized 700 °C growth temperature, plus other corresponding parameters, was obtained for the PA-MBE growth of GaN on Si, exhibiting strong PL emission, narrow/strong Raman phonon modes, XRD w-GaN peaks, and high crystalline perfection. VASE studies identified this set of MBE-grown GaN/Si as having very low Urbach energy of about 18 meV. UV (325 nm)-excited Raman spectra of GaN/Si samples exhibited the GaN E₂(low) and E₂(high) phonon modes clearly without Raman features from the Si substrate, overcoming the difficulties from visible (532 nm) Raman measurements with strong Si Raman features overwhelming the GaN signals. The combined UV excitation Raman–PL spectra revealed multiple LO phonons spread over the GaN fundamental band edge emission PL band due to the outgoing resonance effect. Calculation of the UV Raman spectra determined the carrier concentrations with excellent values. Angular-dependent NEXAFS on Ga K-edge revealed the significant anisotropy of the conduction band of w-GaN and identified the NEXAFS resonances corresponding to different final states in the hexagonal GaN films on Si. Comparative GaN material properties are investigated in depth. Full article