Search Results (32,969)

This review article’s primary aim is to discuss different thin-film deposition technique methods and their important uses. The histories of thin-film technology, thin-film growth, thin-film classification, and thin-film preparation techniques are also covered in this review article. The preparation and characterization of functional thin films and nanostructured materials, as well as various devices based on these materials and recent developments are also focused on in this review. The properties of the materials and several thin-film deposition techniques are also covered in this article. This review article also discusses the classification and application of thin-film sensors. Furthermore, the formation of thin films and their physical properties are impacted by deposition conditions such as pH, temperature, deposition time, and deposition parameters, which are analyzed. This article discusses how a wide range of potential uses in structural, mechanical, and protective coatings; sensing; energy storage systems; catalysis; optoelectronics; and biomedicine are made possible by the special qualities of thin films and nanostructured materials, including their high surface area to volume ratio, structure, surface charge, anisotropic nature, and tunable functionalities. Full article

Methylene blue (MB), a widely used organic dye, poses significant environmental challenges due to its stability and persistence in aquatic ecosystems. This study employs density functional theory (DFT) to investigate the demethylation mechanisms of MB mediated by reactive oxygen species (ROS), a critical initial step in its photocatalytic degradation. Computational analyses reveal that demethylation is energetically favorable, particularly when mediated by hydroxyl radicals (^•OH) and hydroxyl ions (OH⁻) with reaction energies of −154 kcal/mol and −214 kcal/mol, respectively. These pathways lead to the formation of key intermediates, such as Azure B, methanol (CH₃OH), and formaldehyde (CH₂O), which align with experimentally detected degradation byproducts. The study further demonstrates that the dissociation of hydrogen peroxide species (H₂O₂, H₂O₂⁻, H₂O₂⁺) plays a fundamental role in generating the ROS required for MB degradation. Potential energy surface analyses confirm that these ROS-driven processes are thermodynamically and kinetically viable. The findings provide a theoretical framework that bridges existing knowledge gaps in MB degradation, reinforcing the role of ROS in advanced photocatalytic systems and contributing to the optimization of wastewater treatment strategies. This work underscores the importance of integrating computational and experimental approaches to develop more effective strategies for the remediation of recalcitrant pollutants in wastewater. Full article

Global energy issues have spurred the development of energy storage technology, and gravity-based energy storage (GBES) technology has attracted much attention. This comprehensive review examines the principles, applications, and prospects of GBES technology, a promising solution for mitigating the intermittency of renewable energy sources and enhancing grid stability. GBES harnesses potential energy by elevating solid or liquid mediums, offering distinct advantages over other energy storage technologies such as pumped hydro storage and batteries. The study examines various GBES configurations, emphasizing the importance of system design, control strategies, and efficiency. This review also evaluates the economic, environmental, and social benefits of GBES, emphasizing its cost-effectiveness and potential for local economic growth. The need for policy support, technological innovation, and a robust regulatory framework is highlighted to promote the widespread adoption of GBES, which holds significant potential for enhancing grid stability and supporting the integration of renewable energy. Full article

The amount of non-revenue water, mostly due to leakage, is around 126 billion cubic meters annually worldwide. A more efficient wastewater management strategy would use a parametric design for on-demand, customized pipe fittings, following the principles of distributed manufacturing. To fulfill this need, this study introduces an open-source parametric design of a 3D-printable easy-connect pipe fitting that offers compatibility with different dimensions and materials of pipes available on the market. Custom pipe fittings were 3D printed using a RepRap-class fused filament 3D printer, with polylactic acid (PLA), polyethylene terephthalate glycol (PETG), acrylonitrile styrene acrylate (ASA), and thermoplastic elastomer (TPE) as filament feedstocks for validation. The 3D-printed connectors underwent hydrostatic water pressure tests to ensure that they met the standards for residential, agricultural, and renewable energy production applications. All the printed parts passed numerous hydrostatic pressure tests. PETG couplings can tolerate up to 4.551 ± 0.138 MPa of hydrostatic pressure, which is eight times greater than the highest standard water pressure in the residential sector. Based on the economic analysis, the cost of 3D printing a pipe coupling is from three to seventeen times lower than purchasing a commercially available pipe fitting of a similar size. The new open-source couplings demonstrate particular potential for use in developing countries and remote areas. Full article

As a widely used clean energy source, solar energy has demonstrated significant promise across various applications due to its wide spectral range and efficient absorption performance. This study introduces a cross-structured, ultra-broadband solar absorber utilizing titanium (Ti) and titanium dioxide (TiO₂) as its foundational materials. The absorber exhibits over 90% absorption within the 280–4000 nm wavelength range and surpasses 95% absorption in the broader spectrum from 542 to 3833 nm through the cavity coupling effect of incident light excitation and the subsequent initiation of the surface plasmon resonance mechanism, thus successfully achieving the goal of broadband high absorption. Through the finite difference time domain method (FDTD) simulation, the average absorption efficiency reaches 97.38% within the range from 280 nm to 4000 nm, and it is 97.75% in the range from 542 nm to 3833 nm. At the air mass of 1.5 (AM 1.5), the average absorption efficiency of solar energy is 97.46%, and the loss of solar energy is 2.54%, which has extremely high absorption efficiency. In addition, thanks to the material considerations, the absorber adopts a variety of high-temperature resistant materials, making the thermal radiation efficiency in a high-temperature environment still good; specifically, at the temperature of 900 K, its thermal radiation efficiency can reach 97.27%, and at the extreme 1800 K temperature, it can still maintain 97.52% of high efficiency thermal radiation, further highlighting its excellent thermal stability and comprehensive performance. The structure exhibits excellent optical absorption and thermal radiation properties, which give it broad applicability as an ideal absorber or thermal emitter. More importantly, the absorber is insensitive to the polarization state of the light and can effectively handle the incident light lines in the wide-angle range. In addition, its photothermal conversion efficiency (Hereafter referred to as pc efficiency) can sustain an elevated level under various temperature conditions, which enables it to flexibly adapt to diverse environmental conditions, especially suitable for the integration and application of solar photovoltaic systems, and further broaden its potential application range in the field of renewable energy. Full article

Epitaxial layers of water-soluble Sr₃Al₂O₆ were fabricated as sacrificial layers on SrTiO₃ (100) single-crystal substrates using the Pulsed Laser Deposition technique. This approach envisages the possibility of developing a new generation of micro-Solid Oxide Fuel Cells and micro-Solid Oxide Electrochemical Cells for portable energy conversion and storage devices. The sacrificial layer technique offers a pathway to engineering free-standing membranes of electrolytes, cathodes, and anodes with total thicknesses on the order of a few nanometers. Furthermore, the ability to etch the SAO sacrificial layer and transfer ultra-thin oxide films from single-crystal substrates to silicon-based circuits opens possibilities for creating a novel class of mixed electronic and ionic devices with unexplored potential. In this work, we report the growth mechanism and structural characterization of the SAO sacrificial layer. Epitaxial samarium-doped ceria films, grown on SrTiO3 substrates using Sr₃Al₂O₆ as a buffer layer, were successfully transferred onto silicon wafers. This demonstration highlights the potential of the sacrificial layer method for integrating high-quality oxide thin films into advanced device architectures, bridging the gap between oxide materials and silicon-based technologies. Full article

The development of efficient and sustainable armor systems is crucial for protecting bodies and vehicles. In this study, epoxy composites reinforced with natural lignocellulosic fibers (NLFs) from carnauba (Copernicia prunifera) were produced with 0, 10, 20, 30, and 40% fiber volume fractions. Their ballistic performance was evaluated by measuring residual velocity and absorbed energy after impact with 7.62 mm ammunition, as well as their application in a multilayer armor system (MAS). Scanning electron microscopy (SEM) was used to analyze fracture regions, and explicit dynamic simulations were performed for comparison with experimental tests. Residual velocity tests indicated a limit velocity (V_L) between 213 and 233 m/s and absorbed energy (E_abs) between 221 and 264 J, surpassing values reported for aramid fabric. All formulations showed indentation depths below the National Institute of Justice (NIJ) limit, with the 40% fiber sample achieving the lowest depth (31.2 mm). The simulation results correlated well with the experimental data, providing insight into deformation mechanisms during a level III ballistic event. These findings demonstrate the high potential of carnauba fibers in epoxy-based polymer composites, particularly as an intermediate layer in MAS, offering a sustainable alternative for ballistic protection. Full article

In this research work, the mechanical performance of a thermoformed clear dental aligner is studied. Its performance is evaluated under the cyclic compression test, which is designed to simulate the occlusal forces applied on the aligner during swallowing operations for its entire usage period. The mechanical results show that the aligner exhibit stable energy absorption and stiffness behaviour throughout its use period and thus can potentially be used for clinical applications. The microplastic released from the aligner due to the fatigue-like damage is analysed using optical microscopy. Most of the microplastics released have larger dimensions, which may be excreted from the gastrointestinal tracts and have less possibility to pass through the epithelium passively. Therefore, the use of aligner may not pose any cytotoxic health risks. Full article

Underground cold storage gives rise to special challenges that require innovative solutions to ensure maximum energy efficiency. Conventional energy systems tend to be based on high energy use, so sustainable solutions are crucial. This study explores the novel idea of biomimetics and how it might be used in the planning and building of underground cold storage facilities as well as other infrastructure projects. Biomimetic strategies, inspired by termite mounds, gentoo penguin feathers, and beehive structures, are applied to minimize reliance on energy-intensive cooling systems. These natural models offer efficient thermal regulation, airflow optimization, and passive cooling mechanisms such as geothermal energy harvesting. The integration of naturally driven convection and ventilation ensures stable internal temperatures under varying conditions. Biomimicry was employed in Revit Architecture, coupled with structural optimization, to eliminate urban space’s limitations and further increase energy efficiency. The analytical work for this paper utilized a set of formulas that represent heat flow, thermal resistance, R-value, thermal transmittance, U-value, solar absorption, and G-value. The results pointed to very good insulation, with exterior walls having an R-value of 10.2 m²K/W and U-value of 0.98 W/m²K. Among the chosen 3-layer ETFE cushion with a U-value of 1.96 W/m²K, with a G-value of 0.50, showed good heat regulation and daylight management. Furthermore, bagasse-cement composites with a very low thermal conductivity of 0.10–0.30 W/m·K provided good insulation. This research proposes a scalable and sustainable approach in the design of underground cold storage by merging modelling based on Revit with thermal simulations. Biomimicry has been demonstrated to have the potential for changing subterranean infrastructure, conserving energy consumption, and creating eco-friendly construction practices. Full article

Background/Objectives: Addressing the risk of malnutrition at an early stage is crucial to preventing its development, which can have a detrimental impact on physical and mental health status. This study investigates the potential role of biochemical biomarkers such as sirtuin 1 (SIRT-1), melatonin, cholecystokinin-8 (CCK-8), and total antioxidant capacity (TAC) in identifying the risk of malnutrition. Methods: This cross-sectional study assessed malnutrition risk in 153 community-dwelling older adults using the Mini Nutritional Assessment (MNA). Serum levels of SIRT-1, melatonin, and CCK-8 were analyzed with enzyme-linked immunosorbent assay (ELISA), and total antioxidant capacity (TAC) was measured using the ferric reducing ability of plasma (FRAP) method. Results: Serum levels of TAC and CCK-8 were significantly positively correlated with grip strength and visceral adipose tissue, with TAC levels also showing associations with appendicular skeletal muscle mass index (ASMI), total body water, total energy expenditure, fat-free mass index, and fat mass index (p < 0.001). CCK-8 emerged as a strong predictor of malnutrition risk (AUC = 0.58 in females, AUC = 0.64 in males), whereas SIRT-1 (AUC = 0.57 for both sexes), melatonin (AUC = 0.46 for females, AUC = 0.51 for males), and TAC (AUC = 0.42 for females, AUC = 0.54 for males) exhibited weaker predictive abilities. A multivariate model incorporating CCK-8 demonstrated excellent predictive accuracy (AUC = 0.84, 95% CI: 0.77–0.90) and indicated a potential association between elevated CCK-8 levels and a higher risk of malnutrition. Conclusions: In conclusion, this study highlights the effectiveness of a multi-parameter model incorporating CCK-8 as a reliable approach for assessing malnutrition risk in older adults, offering a comprehensive evaluation of the condition. However, further research is needed to confirm its applicability and accuracy in diverse elderly populations and clinical settings. Full article

The electrocatalytic reduction of CO₂ (ECO₂RR) to syngas with tunable CO/H₂ ratios offers a promising route for sustainable energy conversion and chemical production. Here, we report a series of N-doped carbon black (NCBx) catalysts with tailored nitrogen species that enable precise control over the composition of syngas. Among the catalysts, NCB3 exhibits the optimal performance, achieving high CO selectivity (64.14%) and activity (1.9 mA cm⁻²) in an H-type cell at −0.9 V. Furthermore, NCB3 produces syngas with a wide range of CO/H₂ ratios (0.52 to 4.77) across the applied potentials (−0.5 to −1.0 V). Stability tests confirm the robust durability of NCB3, which maintains consistent activity and selectivity over prolonged electrolysis. This work demonstrates the critical role of nitrogen species in tuning ECO₂RR pathways and establishes a strategy for designing efficient and stable carbon-based catalysts for CO₂ utilization and syngas production. Full article

A virtual power plant (VPP) is a potential alternative that aggregates the distributed energy resources (DERs) and addresses the prosumer’s power availability, quality, and reliability requirements. This paper reports the optimized scheduling of an interconnected VPP in a multi-area framework established through a tie-line connection comprising multiple renewable resources. The scheduling was initially performed on a day ahead (hourly basis) interval, followed by an hour ahead interval (intra-hour and real time), i.e., a 15 min and 5 min time interval for the developed VPP in a multi-area context. The target objective functions for the selected problem were two-fold, i.e., net profit and emission, for which maximization was performed for the former and reduction for the later, respectively. Since renewables are involved in the energy mix and the developed problem was complex in nature, the proposed multi-area-based VPP was tested with an advanced nature-inspired metaheuristic technique. Moreover, the proposed formulation was extended to a multi-objective context, and multiple scheduling strategies were performed to reduce the generated emissions and capitalize on the cumulative profit associated with the system by improving the profit margin simultaneously. Furthermore, a comprehensive numeric evaluation was performed with different optimization intervals, which revealed the rapid convergence in minimal computational time to reach the desired solution. Full article

This study explores how the variation of Gravity Waves (GWs) is modified and intensified during tropical cyclones using high-resolution ERA5 reanalysis data. GWs play a vital role in understanding tropical cyclone dynamics due to their connection with energy and momentum transfer in the atmosphere. Different issues related to six tropical cyclones in the Bay of Bengal from 2019 to 2022, spanning different intensities and seasonal conditions, are analyzed. Using temperature and pressure data across 37 vertical levels, several variables like perturbation temperature and potential energy $E_p$ profiles associated with GWs are computed. Spatial temperature distributions and $E_p$ exhibit spiral formations resembling cyclone structures with significant altitude-dependent variations. Temperature signatures are observed at altitudes between 1.4 km and 5.8 km, with Pressure Levels (PLs) of 850 hPa and 500 hPa, respectively, varying by season and intensity, while $E_p$ signatures are prominent between 15.25 km and and 20.77 km, with PLs of 125 hPa and PL 50 hPa, respectively, peaking at 16.58 km and PL 100 hPa for most cyclones, except Cyclone Fani, which peaked at 18.72 km with a PL of 70 hPa. $E_p$ values range from 10 to 25 J/kg, reflecting strong GW–cyclone interactions. These findings highlight the influence of cyclone intensity, seasonality, and atmospheric dynamics on GW behavior, enhancing the understanding of energy transfer processes in the upper troposphere and lower stratosphere. Full article

This study explores the sustainable design and optimization of processes for creating special cross-section welded profiles using the roll forming compression method. This technique is recognized for its efficiency in producing complex profiles while minimizing material waste, making it a valuable approach to environmentally friendly manufacturing. The research examines key factors such as material selection, process settings, and welding techniques to improve energy efficiency and reduce environmental impact. Finite Element Analysis (FEA) was employed to simulate the forming process, helping to predict the profiles’ behavior and ensure they meet structural and dimensional requirements. Experimental tests were conducted to validate the simulation results and assess the performance of the profiles under practical conditions. The findings highlight the potential for saving both materials and energy while maintaining consistent quality, demonstrating the benefits of sustainable manufacturing in advanced profile production. Full article

Prenatal exposure to metals can influence fetal programming via DNA methylation and has been linked to adverse birth outcomes and long-term consequences. Epigenetic clocks estimate the biological age of a given tissue based on DNA methylation and are potential health biomarkers. This study leveraged the Extremely Low Gestational Age Newborn (ELGAN) study (n = 265) to evaluate associations between umbilical cord tissue concentrations of 11 metals as single exposures as well as mixtures in relation to (1) placental epigenetic gestational age acceleration (eGAA) and the (2) methylation status of the Robust Placental Clock (RPC) CpGs. Linear mixed effect regression models were stratified by infant sex. Both copper (Cu) and manganese (Mn) were significantly associated with a decelerated placental eGA of −0.98 (95% confidence interval (CI): −1.89, −0.07) and −0.90 weeks (95% CI: −1.78, −0.01), respectively, in male infants. Cu and Mn levels were also associated with methylation at RPC CpGs within genes related to processes including energy homeostasis and inflammatory response in placenta. Overall, these findings suggest that prenatal exposures to Cu and Mn impact placental eGAA in a sex-dependent manner in ELGANs, and future work could examine eGAA as a potential mechanism mediating in utero metal exposures and later life consequences. Full article