Search Results (1,069)

This study examines the effects of different addition levels of tungsten (W) content on the microstructure, corrosion resistance, wear resistance, microhardness, and phase composition of coatings made from FeCoCrNiAl high-entropy alloy (HEA) using the laser cladding technique. Using a preset powder method, FeCoCrNiAlW_x (where x represents the molar fraction of W, x = 0.0, 0.2, 0.4, 0.6, 0.8) HEA coatings were cladded onto the surface of 45 steel. The different cladding materials were tested for dry friction by using a reciprocating friction and wear testing machine. Subsequently, the detailed analysis of the microstructure, phase composition, corrosion resistance, wear traces, and hardness characteristics were carried out using a scanning electron microscope (SEM), X-ray diffractometer (XRD), electrochemical workstation, and microhardness tester. The results reveal that as the W content increases, the macro-morphology of the FeCoCrNiAlW_x HEA cladding coating deteriorates; the microstructure of the FeCoCrNiAlW_x HEA cladding coating, composed of μ phase and face-centered cubic solid solution, undergoes an evolution process from dendritic crystals to cellular crystals. Notably, with the increase in W content, the average microhardness of the cladding coating shows a significant upward trend, with FeCoCrNiAlW_0.8 reaching an average hardness of 756.83 HV_0.2, which is 2.97 times higher than the 45 steel substrate. At the same time, the friction coefficient of the cladding coating gradually decreases, indicating enhanced wear resistance. Specifically, the friction coefficients of FeCoCrNiAlW_0.6 and FeCoCrNiAlW_0.8 are similar, approximately 0.527. The friction and wear mechanisms are mainly adhesive and abrasive wear. In a 3.5 wt.% NaCl solution, the increase in W content results in a positive shift in the corrosion potential of the cladding coating. The FeCoCrNiAlW_0.8 exhibits a corrosion potential approximately 403 mV higher than that of FeCoCrNiAl. The corrosion current density significantly decreases from 5.43 × 10⁻⁶ A/cm² to 5.26 × 10⁻⁹ A/cm², which suggests a significant enhancement in the corrosion resistance of the cladding coating. Full article

Linear Fresnel concentrators (LFR) are widely seen by the scientific community as one of the most promising systems for the production of solar energy via thermal plants or concentrated photovoltaics. The produced energy depends on the optical efficiency of the LFR, which is mainly dictated by the geometry of the plant. For this reason, the analysis of LFR geometry and its effects on optical behavior is a crucial step in the design and optimization of a Fresnel plant. The theoretical and computational tools used to model the optics of a LFR are fundamental in research on energy production. In this review, geometrical aspects of the optics of linear Fresnel concentrators are presented, with a detailed discussion of the parameters required to define the geometry of a plant and of the main optical concepts. After an overview of the literature on the subject, the main part of the review is dedicated to summarising useful formulas and outlining general procedures for optical simulations. These include (i) a ray-tracing procedure to simulate a mirror field, and (ii) a fast quasi-analytical method useful for optimizations and on-the-fly computations. Full article

Deploying 5G networks in mountainous rural regions can be challenging due to its unique and challenging characteristics. Attaching a transmitter to a UAV to enable connectivity requires a selection of suitable propagation models in such conditions. This research paper comprehensively investigates the signal propagation and performance under multiple frequencies, from mid-band to mmWaves range (3.5, 6, 28, and 60 GHz). The study focuses on rural mountainous regions, which were empirically simulated based on the Skardu, Pakistan, region. A complex 3D ray tracing method carefully figures out the propagation paths using the geometry of a 3D environment and looks at the effects in line-of-sight (LOS) and non-line-of-sight (NLOS) conditions. The analysis considers critical parameters such as path loss, received power, weather loss, foliage loss, and the impact of varying UAV heights. Based on the analysis and regression modeling techniques, quadratic polynomials were found to accurately model the signal behavior, enabling signal strength predictions as a function of distances between the user and an elevated drone. Results were analyzed and compared with suburban areas with no mountains but more compact buildings surrounding the Universiti Kebangsaan Malaysia (UKM) campus. The findings highlight the need to identify the optimal height for the UAV as a base station, characterize radio channels accurately, and predict coverage to optimize network design and deployment with UAVs as additional sources. The research offers valuable insights for optimizing signal transmission and network planning and resolving spectrum-management difficulties in mountainous areas to enhance wireless communication system performance. The study emphasizes the significance of visualizations, statistical analysis, and outlier detection for understanding signal behavior in diverse environments. Full article

The article describes in detail the equipment and method for measuring the Doppler frequency shift (DFS) on an inclined radio path, based on the principle of the phase-locked loop using an SDR receiver for the investigation of seismogenic and man-made disturbances in the ionosphere. During the two M7.8 earthquakes in Nepal (25 April 2015) and Turkey (6 February 2023), a Doppler ionosonde detected co-seismic and pre-seismic effects in the ionosphere, the appearances of which are connected with the various propagation mechanisms of seismogenic disturbance from the lithosphere up to the ionosphere. One day before the earthquake in Nepal and 90 min prior to the main shock, an increase in the intensity of Doppler bursts was detected, which reflected the disturbance of the ionosphere. A channel of geophysical interaction in the system of lithosphere–atmosphere–ionosphere coupling was traced based on the comprehensive monitoring of the DFS of the ionospheric signal, as well as of the flux of gamma rays in subsoil layers of rocks and in the ground-level atmosphere. The concept of lithosphere–atmosphere–ionosphere coupling, where the key role is assigned to ionization of the atmospheric boundary layer, was confirmed by a retrospective analysis of the DFS records of an ionospheric signal made during underground nuclear explosions at the Semipalatinsk test site. A simple formula for reconstructing the velocity profile of the acoustic pulse from a Dopplerogram was obtained, which depends on only two parameters, one of which is the dimension of length and the other the dimension of time. The reconstructed profiles of the acoustic pulses from the two underground nuclear explosions, which reached the height of the reflection point of the sounding radio wave, are presented. Full article

Research of the depositional environment using geological mapping, petrography, gamma-ray (GR) log, palynology, and foraminifera fossils of the Bojongmanik Formation has led to the formation of several different conclusions about the transition to the marine environment, which are attractive to revisit. The expected results of this research are to determine the paleoenvironment of the Bojongmanik and Serpong Formations based on elemental geochemistry, the development of paleoenvironment proxies based on portable X-ray fluorescence (pXRF) in fluvial to transitional environments studies, and the contribution of paleoenvironment analysis to GR-log facies interpretation. The research methodology starts with GR-log facies analysis, Pearson’s correlation, paleoenvironment analysis based on elemental affinity and elemental ratio, and comparing the paleoenvironment with GR-log-based facies. The paleoenvironment analysis based on elemental geochemistry resulted in the Bojongmanik Formation in the research area deposited at the tidal point bar, lagoon, and shoreface, while the Serpong Formation was deposited at the fluvial point bar and floodplain. Compared to previous research, the Bojongmanik Formation in the research area could be stratigraphically related to the upper Bojongmanik Formation. Proxies based on elemental geochemical affinities of carbonate-associated, carbonate-productivity, terrigenous-associated elements, and redox-sensitive trace elements show contrast changes between facies. Proxies based on the specific ratio show a detailed paleoenvironment for paleoclimate (Sr/Cu), paleosalinity (Sr/Ba), paleoredox (Cu/Zn), paleo-hydrodynamics and water depth (Zr/Rb and Fe/Mn), sediment provenance (Cr/Zr), and siliciclastic-dominated (Zr + Rb)/Sr. Adding a geochemistry element-based paleoenvironment analysis benefits from a more specific justification for GR-log facies interpretation. Full article

Thermoresponsive shape memory polymers (SMPs) have garnered increasing interest for their exceptional ability to retain a temporary shape and recover the original configuration through temperature changes, making them promising in various applications. The SMP shape change and recovery that happen due to a combination of mechanical loading and appropriate temperatures are related to its particular microstructure. The deformation process leads to the formation and growth of micro-cracks in the SMP structure, whereas the subsequent heating over its glass transition temperature T_g leads to the recovery of its original shape and properties. These processes also affect the SMP microstructure. In addition to the observed macroscopic shape recovery, the healing of micro-crazes and micro-cracks that have nucleated and developed during the loading occurs. Therefore, our study delves into the microscopic aspect, specifically addressing the healing of micro-cracks in the cyclic loading process. The proposed research concerns a thermoplastic polyurethane shape memory polymer (PU-SMP) MM4520 with a T_g of 45 °C. The objective of the study is to investigate the effect of the number of tensile loading-unloading cycles and thermal shape recovery on the evolution of the PU-SMP microstructure. To this end, comprehensive research starting from structural characterization of the initial state and at various stages of the PU-SMP mechanical loading was conducted. Dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), wide-angle X-ray scattering (WAXS) and scanning electron microscopy (SEM) were used. Moreover, the shape memory behavior in the thermomechanical loading program was investigated. The obtained average shape fixity value was 99%, while the shape recovery was 92%, which confirmed good shape memory properties of the PU-SMP. Our findings reveal that even during a single loading-unloading tension cycle, crazes and cracks nucleate on the surface of the PU-SMP specimen, whereas the subsequent temperature-induced shape recovery process carried out at the temperature above T_g enables the healing of micro-cracks. Interestingly, the surface of the specimen after three and five loading-unloading cycles did not exhibit crazes and cracks, although some traces of cracks were visible. The traces disappeared after exposing the material to heating at T_g + 20 °C (65 °C) for 30 min. The crack closure phenomenon during deformation, even without heating over T_g, occurred within three and five subsequent cycles of loading-unloading. Notably, in the case of eight loading-unloading cycles, cracks appeared on the surface of the PU-SMP and were healed only after thermal recovery at the particular temperature over T_g. Upon reaching a critical number of cycles, the proper amount of energy required for crack propagation was attained, resulting in wide-open cracks on the material’s surface. It is worth noting that WAXS analysis did not indicate strong signs of typical highly ordered structures in the PU-SMP specimens in their initial state and after the loading history; however, some orientation after the cyclic deformation was observed. Full article

The global concern over trace and heavy metal contamination in aquatic environments necessitates the development of effective remediation strategies. Using aquatic plants for heavy metal removal is a relatively economical and sustainable technology worldwide. This study involved collecting sediment and aquatic plant samples (Acanthus ilicifolius, Typha elephantina, and Cynodon dactylon) from a highly urbanized estuary to analyze metal concentrations in sediment, assess ecological risks, and explore the phytoremediation potential. Trace and heavy metals were detected using Energy Dispersive X-ray Fluorescence Spectroscopy (EDXRF). The sediment metal concentrations were found in decreasing order of Fe, Ti, Mn, Rb, Zr, Zn, Sr, Cu, Co, and As. Fe, Sr, and As concentrations were below certified values, whereas Cu, Zn, and Rb exceeded them. Cumulatively, the pollution load index (PLI) values were close to 1 (0.845), indicating that the study area is likely experiencing metal pollution. The Contamination Factor (CF) values, ranging from 1 to 3, indicated a moderate degree of sediment pollution for Ti, Mn, Cu, Zn, and Rb. The Enrichment Factor (EF) values similarly showed moderate enrichment for these metals, with Cu exhibiting the highest degree of enrichment. Ecological risk assessment highlighted the only metal, Cu, as posing the greatest risk among the studied metals. In terms of phytoremediation potential, the bioconcentration factor (BCF) followed the decreasing order of C. dactylon > A. ilicifolius > T. elephantina for most metals, with low BCF values (<1) indicating low accumulator potential. However, the translocation factor (TF) values for Zn (1.464) and Rb (1.299) in A. ilicifolius species were greater than 1, indicating low accumulation potential but hyper-metabolizing capabilities, allowing the plant to accumulate metals in its aerial parts, making it effective for phytostabilization. Full article

When synthesizing the versatile precursors (NMe₄)[Ni(CF₃)₃(MeCN)] we recently encountered the problem that marked amounts of C₂F₅ were incorporated instead of CF₃ under the chosen reaction conditions forming mixed-ligand nickelates [Ni(CF₃)x(C₂F₅)y(MeCN)]⁻ (x + y = 3). We studied the three products with y = 0, 1, or 2, using ¹⁹F nuclear magnetic resonance (NMR) spectroscopy and single-crystal X-ray diffraction. We were able to trace the reaction mechanism and solve the problem by modifying the experimental conditions. Full article

Linear Fresnel reflectors are a versatile solar concentration technology, suitable for a wide range of industrial processes and thermal conditioning applications. Such collectors entail a certain footprint, generating shading on the surface where they are installed. This effect is rarely quantified but may play an indirect role on the surface below. When installed on a roof, the solar radiation heats the building less. In places where the annual heating demand is higher than the cooling demand, this constitutes an asset. However, this becomes a disadvantage when the cooling demand is higher annually than the heating demand. Essentially, the reduced solar radiation allows for the growth of plants that would not grow without the shade provided by the collector. The present paper is a quantitative analysis of such shading based on the linear Fresnel reflector of the Cyprus Institute. The work was conducted using the Tonatiuh++ ray-tracing software to determine the annual radiation blocking. A total of four years of actual meteorological measurements were applied directly to the ray-tracing model. Full article

Modeling and simulating the underwater optical imaging process can assist in optimizing the configuration of underwater optical imaging technology. Based on the Monte Carlo (MC) method, we propose an optical imaging model which is tailored for deep-sea luminescent objects. Employing GPU parallel acceleration expedites the speed of MC simulation and ray-tracing, achieving a three-order-of-magnitude speedup over a CPU-based program. A deep-sea single-lens imaging system is constructed in the model, composed of a luminescent object, water medium, double-convex lens, aperture diaphragm, and sensor. The image of the luminescent object passing through the imaging system is generated using the forward ray-tracing method. This model enables an intuitive analysis of the inherent optical properties of water and imaging device parameters, such as sensor size, lens focal length, field of view (FOV), and camera position on imaging outcomes in the deep-sea environment. Full article

Highly intense bunches of protons and ions with energies of several MeV/u can be generated with ultra-short laser pulses focused on solid targets. In the most common interaction regime, target normal sheath acceleration, the spectra of these particles are spread over a wide range following a Maxwellian distribution. We report on the design and testing of a magnetic chicane for the selection of protons within a limited energy window. This consisted of two successive, anti-parallel dipole fields generated by cost-effective permanent C-magnets with customized configuration and longitudinal positions. The chicane was implemented into the target vessel of a petawatt laser facility with constraints on the direction of the incoming laser beam and guidance of the outgoing particles through a vacuum port. The separation of protons and carbon ions within distinct energy intervals was demonstrated and compared to a ray tracing code. Measurements with radiochromic film stacks indicated the selection of protons within [2.4, 6.9] MeV, [5.0, 8.4] MeV, or ≥6.9 MeV depending on the lateral dispersion. A narrow peak at 4.8 MeV was observed with a time-of-flight detector. Full article

Within the geophysical exploration utilising seismic methods, it is well known that if the explored distances are much greater than the wavelength of the seismic waves with which the exploration is carried out, the ray approach of the wave theory can be used. In this way, when the rays travel through an inhomogeneous medium, they follow curved trajectories, which is imperative to determine the geological features that produce reflection and refraction phenomena. In this paper, a simple algorithm for the calculation of the trajectory of a seismic beam through an inhomogeneous stratum is presented. For this, the construction of a pseudo-Riemannian metric is required from the function of P-wave velocities of the geological stratum. Thus, the problem is inverted because instead of finding the curved trajectory of the seismic beam in a background with a Euclidean metric, it is proposed that the beam follows a geodesic of a curved space-time specific to each stratum, becoming a simple and automatic process using the differential geometry apparatus. For the reader to gain insight into this tool, different geological setups from idealised ones up to a salt dome are presented. Full article

Prior tropospheric information, especially zenith tropospheric delay (ZTD), is particularly important in GNSS data processing. The two types of ZTD models, those that require and do not require meteorological parameters, are the most commonly used models, whether the non-difference or double-difference mode is applied. To improve the accuracy of prior tropospheric information, the Vienna Mapping Functions (VMFs) data server provides a gridded set of global tropospheric products based on the ray-tracing technique using Numerical Weather Models (NWMs). Note that two types of gridded tropospheric products are provided: the VMF3_OP for the post-processing applications and the VMF3_FC for real-time applications. To explore the accuracy and adaptability of these two grid products, a comprehensive analysis and discussion were conducted in this study using the ZTD data from 255 stations of the Crustal Movement Observation Network of China (CMONOC) as references. The numerical results indicate that both VMF3_FC and VMF3_OP exhibit high accuracy, with RMSE/Bias values of 17.53/2.25 mm and 14.62/2.67 mm, respectively. Both products displayed a temporal trend, with larger RMSE values occurring in summer and smaller values in winter, along with a spatial trend of higher values in the southeast of China and lower values in the northwest of China. Additionally, VMF3_OP demonstrated superior performance to VMF3_FC, with smaller RMSE values for each month and each hour. For the RMSE difference between these two products, 108 stations had a difference of more than 3 mm, and the number of stations with a difference exceeding 1 mm reached 217. Moreover, the difference was more significant in the southeast than in the northwest. This study contributes to the understanding of the differences between the two precision products, aiding in the selection of suitable ZTD products based on specific requirements. Full article

A critical comprehension of the impact of snow cover on urban bidirectional reflectance is pivotal for precise assessments of energy budgets, radiative forcing, and urban climate change. This study develops a numerical model that employs the Monte Carlo ray-tracing technique and a snow anisotropic reflectance model (ART) to simulate spectral albedo and bidirectional reflectance, accounting for urban structure and snow anisotropy. Validation using three flat surfaces and MODIS data (snow-free, fresh snow, and melting snow scenarios) revealed minimal errors: the maximum domain-averaged BRDF bias was 0.01% for flat surfaces, and the overall model-MODIS deviation was less than 0.05. The model’s performance confirmed its accuracy in reproducing the reflectance spectrum. A thorough investigation of key factors affecting bidirectional reflectance in snow-covered urban canyons ensued, with snow coverage found to be the dominant influence. Urban coverage, building height, and soot pollutant concentration significantly impact visible and infrared reflectance, while snow grain size has the greatest effect on shortwave infrared. The bidirectional reflectance at backward scattering angles (0.5–0.6) at 645 nm is lower than forward scattering (around 0.8) in the principal plane as snow grain size increases. These findings contribute to a deeper understanding of snow-covered urban canyons’ reflectance characteristics and facilitate the quantification of radiation interactions, cloud-snow discrimination, and satellite-based retrieval of aerosol and snow parameters. Full article

Stellar and black hole feedback heat and disperse surrounding cold gas clouds, launching gas flows off circumnuclear and galactic disks, producing a dynamic interstellar medium. On large scales bordering the cosmic web, feedback drives enriched gas out of galaxies and groups, seeding the intergalactic medium with heavy elements. In this way, feedback shapes galaxy evolution by shutting down star formation and ultimately curtailing the growth of structure after the peak at redshift 2–3. To understand the complex interplay between gravity and feedback, we must resolve both the key physics within galaxies and map the impact of these processes over large scales, out into the cosmic web. The Advanced X-ray Imaging Satellite (AXIS) is a proposed X-ray probe mission for the 2030s with arcsecond spatial resolution, large effective area, and low background. AXIS will untangle the interactions of winds, radiation, jets, and supernovae with the surrounding interstellar medium across the wide range of mass scales and large volumes driving galaxy evolution and trace the establishment of feedback back to the main event at cosmic noon. This white paper is part of a series commissioned for the AXIS Probe mission concept; additional AXIS white papers can be found at the AXIS website. Full article