Search Results (99)

This paper presents a comprehensive analysis of supercritical carbon dioxide (sCO₂)-enhanced geothermal systems (EGSs) in Poland, focusing on their energetic performance through process modeling and optimization. EGSs harness the potential of geothermal energy by utilizing supercritical carbon dioxide as the working fluid, offering promising avenues for sustainable power generation. This study investigates two distinct configurations of sCO₂-EGS: one dedicated to power generation via a binary system with an organic Rankine cycle and the other for combined power and heat production through a direct sCO₂ cycle. Through accurate process modeling and simulation, key parameters influencing system efficiency and performance are identified and optimized. The analysis integrates thermodynamic principles with geological and operational constraints specific to the Polish context. The results highlight the potential of sCO₂-EGSs to contribute to the country’s energy transition, offering insights into the optimal design and operation of such systems for maximizing both power and thermal output while ensuring economic viability and environmental sustainability. Full article

Carbon dioxide (CO₂) has been recognized as one of the potential working fluids to operate power generation cycles, either in supercritical or transcritical configuration. However, a small concentration of some of the additives to CO₂ have shown promising improvements in the overall performance of the cycle. The current study is motivated by the newly proposed additive silicon tetrachloride (SiCl₄), and so we perform a detailed investigation of SiCl₄ along with a few well-known additives to CO₂-based binary mixtures as a working fluid in transcritical organic Rankine cycle setup with internal heat regeneration. The additives selected for the study are pentane, cyclopentane, cyclohexane, and silicon tetrachloride (SiCl₄). A comprehensive study on the energy and exergy performance of the cycle for warm regions is conducted at a turbine inlet temperature of 250 °C. The performance of the heat recovery unit is also assessed to highlight its importance in comparison to a simple configuration of the cycle. This study shows that the cycle operating with binary mixtures performs significantly better than with pure CO₂, which is mainly due to its better heat recovery in the heat recovery unit. The results show that the optimal molar concentration of the additives is in between 20% and 25%. Besides having better thermal stability, SiCl₄ shows an improvement in the cycle thermal efficiency by 6% points which is comparable to cyclopentane (7.3% points) and cyclohexane (7.8% points). The optimal cycle pressure ratio for SiCl₄ is also relatively lower than for other additives. The energy efficiency of the cycle with pure CO₂ is around 45% which is also increased to 58%, 63%, 64%, 60% with pentane, cyclopentane, cyclohexane, and SiCl₄, respectively. These results suggest that additives like SiCl₄ could make CO₂-based cycles more viable for power generation in warm regions. Full article

The corrosion of structural materials is a crucial issue of the application of supercritical carbon dioxide in the Brayton power cycle system. The oxidation and carburization behaviors of typical alloy materials in high-temperature CO₂ environments are studied based on thermodynamic analysis technology, including the analysis of the oxidation and carburization performance of the CO₂ atmosphere as well as the corrosion behaviors of alloy elements under 500 °C, 600 °C, and 650 °C. In addition, the oxide film characteristics of T91 and 800H alloys, including phase composition and morphology structure, are studied at 500 °C and 650 °C. Research has found that for the T91, FeCr₂O₄ and Fe₃O₄ can form a continuous oxide film layer with coverage and SiO₂, VO, and MnCr₂O₄ oxides are mainly in the inner layer of the oxide film. For the 800H, Cr₂O₃ and MnCr₂O₄ can form flakes of oxide film layers, while Al₂O₃, TiO₂, and SiO₂ are distributed as scattered grains near the interface between the oxide film and the matrix material. Both T91 and 800H will produce chromium carbides, which will reduce the toughness of the material. Full article

Small nuclear power plants are a promising direction of research for the development of carbon-free energy in isolated power systems and in remote regions with undeveloped infrastructure. Improving the efficiency of power units integrated with small modular reactors will improve the prospects for the commercialization of such projects. Power cycles based on supercritical carbon dioxide are an effective solution for nuclear power plants that use reactor facilities with an initial coolant temperature above 550 °C. However, the presence of low temperature rejected heat sources in closed Bryton cycles indicates a potential for energy saving. This paper presents a comprehensive thermodynamic analysis of the integration of an additional low-temperature organic Rankine cycle for heat recovery to supercritical carbon dioxide cycles. A scheme for sequential heat recovery from several sources in S-CO₂ cycles is proposed. It was found that the use of R134a improved the power of the low-temperature circuit. It was revealed that in the S-CO₂ Brayton cycle with a recuperator, the ORC add-on increased the net efficiency by an average of 2.98%, and in the recompression cycle by 1.7–2.2%. With sequential heat recovery in the recuperative cycle from the intercooling of the compressor and the main cooler, the increase in efficiency from the ORC superstructure will be 1.8%. Full article

Low-carbon electricity and heat production is essential for keeping the decarbonization targets and climate mitigation goals. Thus, an accurate understanding of the potential environmental impacts constitutes a key aspect not only for the reduction in greenhouse gas emissions but also for other environmental categories. Life cycle assessment allows us to conduct an overall evaluation of a given process or system through its whole lifetime across various environmental indicators. This study focused on construction, operation and maintenance, and end-of-life phases, which were analyzed based on the ReCiPe 2016 method. Within this work, authors assessed the environmental performance of one of the renewable energy sources—Enhanced Geothermal Systems, which utilize supercritical carbon dioxide as a working fluid to produce electricity and heat. Heat for the process is extracted from hot, dry rocks, typically located at depths of approximately 4–5 km, and requires appropriate stimulation to enable fluid flow. Consequently, drilling and site preparation entail significant energy and material inputs. This stage, based on conducted calculations, exhibits the highest global warming potential, with values between 5.2 and 30.1 kgCO₂eq/MWh_el, corresponding to approximately 65%, 86%, and 94% in terms of overall impacts for ecosystems, human health, and resources categories, respectively. Moreover, the study authors compared the EGS impacts for the Polish and Norwegian conditions. Obtained results indicated that due to much higher electricity output from the Norwegian plant, which is sited offshore, the environmental influence remains the lowest, at a level of 11.9 kgCO₂eq/MWh_el. Polish cases range between 38.7 and 54.1 kgCO₂eq/MWh_el of global warming potential in terms of electricity production. Regarding power generation only, the impacts in the case of the Norwegian facility are two to five times lower than for the installation in the Polish conditions. Full article

The gas turbine is a crucial piece of equipment in the energy and power industry. The exhaust gas has a sufficiently high temperature to be recovered for energy cascade use. The supercritical carbon dioxide (S-CO₂) Brayton cycle is an advanced power system that offers benefits in terms of efficiency, volume, and flexibility. It may be utilized for waste heat recovery (WHR) in gas turbines. This study involved the design of a 5 MW S-CO₂ recompression cycle specifically for the purpose of operational control. The dynamic models for the printed circuit heat exchangers, compressors, and turbines were developed. The stability and dynamic behavior of the components were validated. The suggested control strategies entail utilizing the cooling water controller to maintain the compressor inlet temperature above the critical temperature of CO₂ (304.13 K). Additionally, the circulating mass flow rate is regulated to modify the output power, while the exhaust gas flow rate is controlled to ensure that the turbine inlet temperature remains within safe limits. The simulations compare the performance of PI controllers tuned using the SIMC rule and ADRC controllers tuned using the bandwidth method. The findings demonstrated that both controllers are capable of adjusting operating conditions and effectively suppressing fluctuations in the exhaust gas. The ADRC controllers exhibit a superior control performance, resulting in a 55% reduction in settling time under the load-tracking scenario. Full article

The supercritical carbon dioxide (S-CO₂) Brayton cycle efficiency increases as the compressor inlet condition approaches the critical point. However, the thermodynamic properties of CO₂ vary dramatically near the critical point, and phase change is most likely to happen. Both cavitation and condensation bring about significant adverse effects on the performance of compressors. In this paper, the quantitative effects of nonequilibrium condensation and cavitation on the performance of an S-CO₂ centrifugal compressor with different inlet-relative entropy values are investigated. The properties of CO₂ were provided by the real-gas property table, and the nonequilibrium phase-change model was adopted. The numerical simulation method with the nonequilibrium phase-change model was validated in the Lettieri nozzle and Sandia compressor. Furthermore, simulations were carried out in a two-stage centrifugal compressor under conditions of various inlet-relative entropy values. The type of nonequilibrium phase change can be distinguished by inlet-relative entropy. Cavitation makes the choke mass flow rate decrease due to the drop in the speed of sound. Condensation mainly occurs on the leading edge of the main blade at a large mass flow rate, but cavitation occurs on the splitter. The condensation is more evenly distributed on the main blade, but the cavitation is mainly centered on the leading edge. Full article

Supercritical carbon dioxide (sCO₂) can be mixed with dopants such as titanium tetrachloride (TiCl₄), hexafluoro-benzene (C₆F₆), and sulphur dioxide (SO₂) to raise the critical temperature of the working fluid, allowing it to condense at ambient temperatures in dry solar field locations. The resulting transcritical power cycles have lower compression work and higher thermal efficiency. This paper presents the aerodynamic flow path design of a utility-scale axial turbine operating with an 80–20% molar mix of CO₂ and SO₂. The preliminary design is obtained using a mean line turbine design method based on the Aungier loss model, which considers both mechanical and rotor dynamic criteria. Furthermore, steady-state 3D computational fluid dynamic (CFD) simulations are set up using the k-ω SST turbulence model, and blade shape optimisation is carried out to improve the preliminary design while maintaining acceptable stress levels. It was found that increasing the number of stages from 4 to 14 increased the total-to-total efficiency by 6.3% due to the higher blade aspect ratio, which reduced the influence of secondary flow losses, as well as the smaller tip diameter, which minimised the tip clearance losses. The final turbine design had a total-to-total efficiency of 92.9%, as predicted by the CFD results, with a maximum stress of less than 260 MPa and a mass flow rate within 1% of the intended cycle’s mass flow rate. Optimum aerodynamic performance was achieved with a 14-stage design where the hub radius and the flow path length are 310 mm and 1800 mm, respectively. Off-design analysis showed that the turbine could operate down to 88% of the design reduced mass flow rate with a total-to-total efficiency of 80%. Full article

There is a general agreement among researchers that supercritical carbon dioxide (sCO₂) cycles will be part of the next generation of thermal power plants, especially in concentrating solar power (CSP) plants. While certain studies focus on maximizing the efficiency of these cycles in the hope of achieving a reduction in electricity costs, it is important to note that this assumption does not always hold true. This work provides a comprehensive analysis of the differences between minimizing the cost and maximizing the efficiency for the most remarkable sCO₂ cycles. The analysis considers the most important physical uncertainties surrounding CSP and sCO₂ cycles, such as turbine inlet temperature, ambient temperature, pressure drop and turbomachinery efficiency. Moreover, the uncertainties related to cost are also analyzed, being divided into uncertainties of sCO₂ component costs and uncertainties of heating costs. The CSP system with partial cooling (sometimes with reheating and sometimes without it) is the cheapest configuration in the analyzed cases. However, the differences in cost are generally below 5% (and sometimes neglectable), while the differences in efficiency are significantly larger and below 15%. Besides the much lower efficiency of systems with simple cycle, if the heating cost is low enough, their cost could be even lower than the cost of the system with partial cooling. Systems with recompression cycles could also achieve costs below systems with partial cooling if the design’s ambient temperature and the pressure drop are low. Full article

This work explores technical feasibility in hot isostatic pressing (HIP) manufacturing of an integral bimetallic component using steel and Ni alloy powder for supercritical carbon dioxide (sCO₂) turbomachinery. Lab-scale bimetallic HIP specimens using HAYNES^® 282^® and SS316L or SS415 powder are investigated in powder configuration, heat treatment, microstructure, and tensile properties up to 400 °C. Interdiffusion profiles at dissimilar alloy interfaces caused by HIP cycle is predicted by DICTRA simulations and validated by electron probe microanalysis (EPMA). The interdiffusion distance of most elements is around 100 μm, while C and N have a higher interdiffusion distance. Dense distribution of Ti-rich carbonitrides and alumina particles are found to decorate prior particle boundaries near joining interface on the 282 side, affecting tensile strength across interface as well as tensile failure location. A higher amount of excessive carbonitride formation near interface is observed in SS316L/282 than in SS415/282, which is consistent with the predicted greater degree of interdiffusion effect in SS316L/282. Typical HAYNES^® 282^® heat treatment condition is applicable to 282/SS316L and 282/SS415 combinations, resulting in a higher strength than cast CF8M and CA6NM. A pilot-scale bimetallic SS415/282 pipe is then demonstrated to show the promise of scaleup. Full article

Printed circuit heat exchangers (PCHEs) are widely used as recuperators in the supercritical carbon dioxide (S-CO₂) Brayton cycle design. The variation of heat sources will have a great impact on the heat transfer effect of the recuperator. It is of interest to study the fast calculation of flow and heat transfer performance of PCHEs under different operating conditions to obtain the optimal comprehensive performance and provide guidance for the operation control strategy analysis. Herein, a fast calculation method is established through a one-dimensional model of a PCHE based on Modelica. The effects of working medium mass flow rate and inlet temperature on the flow and heat transfer process are analyzed from the three aspects of heat transfer rate, flow pressure drop, and comprehensive performance, and the mass flow rate matching optimization is realized. The results show that increased mass flow rate increases heat transfer rate and flow pressure drop. The efficiency evaluation coefficient (EEC) has a maximum value at which the mass flow rate values of the cold and hot channels are best matched, and the comprehensive performance is optimal. When the mass flow rate of the heat channel is 4.8 g/s, the maximum EEC is 1.42, corresponding to the mass flow rate of the cold channel, 4.2 g/s. Compared with the design condition, the heat transfer rate increases by 62.1%, and the total pump power increases by 14.2%. When the cold channel inlet temperature increases, EEC decreases rapidly, whereas EEC increases when the hot channel inlet temperature increases. The conclusions can provide theoretical support for the design and operation of PCHEs. Full article

Super-critical Carbon dioxide (s-CO₂) power plants are considered to be efficient and environmentally friendly compared to the traditional Rankine cycle-based steam power plants and Brayton cycle-based gas turbine power plants. In this work, the system design of a coal-fired 100 MWe double reheat s-CO₂ power plant is presented. The system is also optimized for efficiency with turbine inlet pressures and the recompression ratio as the variables. The components needed, mass flow rates of various streams and their pressures at various locations in the system have been established. The plant has been studied based on 1st and 2nd laws at full load and at part loads of 80%, 60% and 40%. Operating parameters such as mass flow rate, pressure and temperature have considerably changed in comparison to full load operation. It was also observed that the 1st law efficiency is 53.96%, 53.93%, 52.63% and 50% while the 2nd law efficiency is 51.88%, 51.86%, 50.61% and 48.1% at 100%, 80%, 60% and 40% loads, respectively. The power plant demonstrated good performance even at part loads, especially at 80% load, while the performance deteriorated at lower loads. At full load, the highest amount of exergy destruction is found in the main heater (36.6%) and re-heaters (23.2% and 19.6%) followed by the high-temperature recuperator (5.7%) and cooler (4.1%). Similar trends were observed for the part load operation. It has been found that the recompression ratio should be kept high (>0.5) at lower loads in order to match the performance at higher loads. Combustion and heat exchange due to finite temperature differences are the main causes of exergy destruction, followed by pressure drop. Full article

Gas turbine power plants have important roles in the global power generation market. This paper, for the first time, thermodynamically examines the impact of steam injection for a combined cycle, including a gas turbine cycle with a two-stage turbine and carbon dioxide recompression. The combined cycle is compared with the simple case without steam injection. Steam injection’s impact was observed on important parameters such as energy efficiency, exergy efficiency, and output power. It is revealed that the steam injection reduced exergy destruction in components compared to the simple case. The efficiencies for both cases were obtained. The energy and exergy efficiencies, respectively, were found to be 30.4% and 29.4% for the simple case, and 35.3% and 34.1% for the case with steam injection. Also, incorporating steam injection reduced the emissions of carbon dioxide. Full article

Efficiency and compactness are core strengths of the supercritical carbon dioxide (sCO${}_2$) Brayton cycle, which is considered an alternative to the steam Rankine cycle for moderate-temperature heat sources (350–800 °C). Numerical investigations on system design and analysis have received considerable attention, with the aim of improving the sCO${}_2$ cycle from the viewpoint of thermodynamics. This paper reviews and compares previous studies in the literature to survey different cycle layouts, operating parameters, and working fluids of the sCO${}_2$ cycle. Performance enhancement approaches are categorized into three classes according to characteristics: conventional methods, CO${}_2$ mixtures, and combined cycles. The strengths, weaknesses, and limitations of each categorized method are discussed. This research is expected to provide a roadmap for performance improvement that meets the interests of researchers. Full article

A Printed Circuit Heat Exchanger (PCHE) is a compact heat exchanger with high temperature and pressure resistance and is considered one of the best choices for the recuperators in the Supercritical Carbon dioxide (S-CO₂) Brayton cycle. The flow and heat transfer performance of sinusoidal channel PCHE were analyzed and a second-order regression model was established based on the response surface method to improve the performance of the continuous channel PCHE. It was found that reducing the channel diameter, increasing the channel amplitude, and reducing the channel pitch can increase the average value of the heat transfer coefficient and pressure drop per unit length. Moreover, sensitivity coefficient analysis was used to investigate the influence of various structural parameters on flow performance, heat transfer performance, and comprehensive performance. In addition, the structure of the sinusoidal channel PCHE was optimized using a multi-objective genetic algorithm, and three sets of Pareto optimal solutions were obtained. The corresponding optimal channel diameter D, channel amplitude A, and channel pitch Lp were in the range of 1.0–1.7 mm, 2.4–3.0 mm, and 15.1–17.0 mm, respectively, which can provide theoretical basis for the design of PCHE. Full article