Search Results (1,170)

Many volatile fatty acids (VFAs) are produced after wet air oxidation, which could be a potential carbon source. In this study, we investigated the impact of NaOH on the removal of hazardous organics and the changes in the produced carbon source. The total and soluble chemical oxygen demand (SCOD) removal rates decreased to 47.9% and 55.3% with 51.6% NaOH addition. The removal rates of total suspended solids (82–85%) and volatile suspended solids (97–99%) remained stable under all conditions. Additionally, the concentrations of acetic acid and isovaleric acid increased with a high pH value. Fluorescent substances closely related to aromatic protein and fulvic acid-like substances were identified and degraded significantly with the addition of NaOH. Moreover, 41.3% NaOH addition (initial pH 13.0) could yield a VFAs/SCOD ratio of 30.5%, demonstrating the good biocompatibility of the carbon source. The effect of the nitrogen element was also considered, with the ratio of the 5-day biological oxygen demand to the total nitrogen being 7.2, indicating that the oxidation solution could provide an abundant carbon source. Thus, the sludge-derived carbon source is suitable to supply biological treatment units for municipal wastewater. Full article

Aquatic ecosystems play a crucial role in sustaining life and supporting key green and blue economic sectors globally. However, the growing population and increasing anthropogenic pressures are significantly degrading terrestrial water resources, threatening their ability to provide essential socioeconomic services. To safeguard these ecosystems and their benefits, it is critical to continuously monitor changes in water quality. Remote sensing technologies, which offer high-resolution spatial and temporal data over large geographic areas, including surface water bodies, have become indispensable for these monitoring efforts. They enable the observation of various physical, chemical, and biological water quality indicators, which are essential for assessing ecosystem health. Machine learning algorithms are well suited to handle the complex and often non-linear relationships between remote sensing data and water quality parameters. By integrating remote sensing with machine learning techniques, it is possible to develop predictive models that enhance the accuracy and efficiency of water quality assessments. These models can identify and predict trends in water quality, supporting timely interventions to protect aquatic ecosystems. This paper provides a thorough review of the major remote sensing techniques for estimating water quality indicators (e.g., chlorophyll-a, turbidity, temperature, total nitrogen and total phosphorous, dissolved organic, total suspended solids, dissolved oxygen, and hydrogen power). It examines how machine learning can improve water quality assessments. Additionally, it identifies key research gaps in current methodologies and suggests future directions to address challenges in water quality monitoring, aiming to improve the precision and scope of these critical efforts. Full article

In the current global context of the natural resource crisis and the need for environmental protection, sustainable economy strategies are becoming imperative. These strategies aim to optimize wastewater treatment processes, with a particular focus on the removal of biological and chemical quality indicators such as BOD, COD and TSS. By developing and implementing advanced technologies and effective resource management methods, this article explores ways the industry can reduce its negative environmental impact and contribute to a sustainable future. The proposed research investigates the impact of 40% ferric chloride on the purification processes of domestic wastewater using biological contactors. The study evaluates the efficiency of pollutant removal through measurements such as biochemical oxygen demand over 5 days (BOD), chemical oxygen demand (COD) and total suspended solids (TSS). Through the statistical analysis of the obtained results, the research identifies opportunities for innovative strategies in the sustainable economy, thus contributing to the optimization of purification process efficiency and significantly reducing pollution’s impact on the environment. In conclusion, this research highlights the use of 40% ferric chloride as an effective and sustainable method to improve the efficiency of wastewater treatment processes, focusing on BOD, COD and TSS removal. The findings demonstrate significant pollutant reduction and environmental impact mitigation, underlining its potential for Sustainable Development Goals. The study supports innovative strategies for optimizing water quality and recommends further evaluation of long-term impacts on human and environmental health. Full article

Pneumatic conveying technology is an efficient, energy-saving and environmentally friendly means of solid feed conveying. In the process of pneumatic conveying, wind speed has a decisive influence on conveying characteristics. Here, computational fluid dynamics coupled with a discrete element method simulation and experiment were combined, and the conveying wind speed was used as the experimental variable to study the conveying characteristics of the conveying material in the tube, such as particle distribution state, solid phase mass concentration, coupling force on solid feed, average speed and pressure drop of solid feed in the pipe. The results show that when the conveying wind speed increases from 18 m/s to 20.6 m/s, the solid feed changes from sedimentary flow to suspended flow, the particle accumulation gradually decreases and the conveying efficiency is significantly improved. The particle slug greatly reduces the collision and friction between the internal particles and the pipe and reduces the crushing rate to a certain extent. When the conveying wind speed is about 23.2 m/s, there are almost no trapped particles in the pipeline, which can achieve rapid feed delivery, and conveying efficiency is greatly improved. Therefore, this paper provides a good theoretical basis for improving conveying efficiency and reducing crushing rate in the process of pneumatic conveying. Full article

Decentralized wastewater treatment systems (DWTS) are significant contributors to the eutrophication of surface water bodies due to a lack of treatment mechanisms that target dissolved phosphorus removal. Existing advanced treatment systems are expensive to operate, large in nature, and require frequent maintenance, making them unattractive to DWTS owners. This study aims to investigate the development of a continuous flow treatment system that uses electrocoagulation (EC) to remove dissolved phosphorus from small wastewater streams such as septic tank effluent (STE). Operational parameters, including system hydraulic retention time (HRT), applied current density, and wastewater composition, were optimized to maximize total phosphorus (TP) removal most cost-effectively. Using an HRT of 10 min, an applied current density of 2.0 mA/cm², and an influent concentration of 20 mg/L, the orthophosphate (OP) and TP removal percentages achieved were 99.9 and 88.1%, respectively. Under these conditions, the average effluent Al³⁺ concentration in the treated effluent was measured to be 1.0 mg/L while the total suspended solids concentration was measured to be 51 mg/L. The operation cost was estimated to be 0.056 CAD/m³. The results demonstrate that the EC reactor is effective in removing dissolved phosphorus from wastewater and is therefore a viable option in mitigating the risk of downstream eutrophication caused by inadequately treated STE. Full article

Gelled fuels are rheologically complex, non-Newtonian fluids. They combine the benefits of both liquid and solid states, reducing risks of leakage, spilling, and sloshing during storage while maintaining the ability to be sprayed inside a combustion chamber. Additionally, suspending energetic particles, such as metal powders of aluminum and boron, can significantly enhance their energy density compared to conventional liquid fuels. In this study, several kerosene-based and ethanol-based formulations were experimentally investigated, using both organic and inorganic gelling agents. The compositions were optimized in terms of the gellant amount and manufacturing process. Some of the most promising gellants for kerosene include fatty acids, such as Thixcin^® R or THIXATROL^® ST, and metallic soaps, such as aluminum stearate and zinc stearate. The effects of various co-solvents were assessed, including ketones (methyl isoamyl ketone, methyl ethyl ketone, and acetone) and alcohols (ethanol and octadecanol). Sugar polymers like hydroxypropyl cellulose were tested as gelling agents for ethanol. A preliminary rheological analysis was conducted to characterize their behavior at rest and under shear stress. Finally, a novel approach was introduced to study the stability of the gels under vibration, which was derived from a realistic mission profile of a ramjet. Finally, the ideal gravimetric specific impulse was evaluated through ideal thermochemical computations. The results showed that promising formulations can be found in both kerosene-based and ethanol-based gels. Such compositions are of interest in practical airbreathing applications as they have demonstrated excellent stability under vibration, ideal combustion properties, and pronounced shear-thinning behavior. Full article

Short-chain fatty acids (SCFAs) are valuable metabolic intermediates that are produced during dark fermentation of sludge, which, when capitalized on, can be used as chemical precursors for biotechnological applications. However, high concentrations of solids with SCFAs in hydrolyzed sludge can be highly detrimental to downstream recovery processes. This pilot-scale study addresses this limitation and explores the recovery of SCFAs from primary sludge into a particle-free permeate through a combination of chamber filter-press (material: polyester; mesh size: 100 µm) and cross-flow microfiltration (material: α-Al₂O₃; pore size: 0.2 µm; cross-flow velocity: 3 m∙s⁻¹; pressure = 2.2 bars). Firstly, primary sludge underwent dark fermentation yielding a hydrolyzate with a significant concentration of SCFAs along with total solids (TS) concentration in the range of 20 to 30 g∙L⁻¹. The hydrolyzate was conditioned with hydroxypropyl trimethyl ammonium starch (HPAS), and then dewatered using a filter press, reducing TS by at least 60%, resulting in a filtrate with a suspended solids concentration ranging from 100 to 1300 mg∙L⁻¹. Despite the lower suspended solids concentration, the microfiltration membrane underwent severe fouling due to HPAS’s electrostatic interaction. Two methods were optimized for microfiltration: (1) increased backwashing frequency to sustain a permeate flux of 20 L∙m⁻²∙h⁻¹ (LMH), and (2) surface charge modification to maintain the flux between 70 and 80 LMH. With backwashing, microfiltration can filter around 900 L∙m_eff⁻² (without chemical cleaning), with the flux between 50 and 60 LMH under semi-continuous operation. Evaluating the particle-free permeate obtained from the treatment chain, around 4 gC_SCFAs∙capita⁻¹∙d⁻¹ can be recovered from primary sludge with a purity of 0.85 to 0.97 C_SCFAs∙DOC⁻¹. Full article

The electrochemical corrosion of a single-suction centrifugal water pump impeller made of gray cast iron operating at 85 °C was investigated in two industrial water media, i.e., groundwater extracted from a borehole and treated wastewater. Open circuit potential (OCP) measurement plus potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques elucidated the electrochemical corrosion performance and inductively coupled plasma-optical emission spectroscopy (ICP-OES) characterized the water samples. The retired and brand-new impellers were studied using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and visual and metallographic examinations. Impeller trailing edges were vulnerable to corrosion damage due to increased total fluid pressure, velocity, and temperature. The groundwater was more contaminated with Ca, Mg, Na, Si, and S elements and possessed higher conductivity, pH, and suspended solids than the treated wastewater. The impeller was more susceptible to graphitic corrosion in the groundwater due to emerging microgalvanic cells. A kinetic control electrochemical mechanism was elucidated as the corrosion rate-controlling step in the wastewater. A mixed kinetic and diffusion control mechanism was predominant in the groundwater because a short Warburg impedance element emerged. This study showcased the significance of integrated industrial water management and treatment strategies to protect pumps’ integrity and uptime in critical industrial units implementing a zero-liquid discharge program. Full article

Biological foaming is a major problem in activated sludge (AS) wastewater treatment systems. In this study, four wastewater treatment plants (WWTPs) (a total of six AS treatment systems) were investigated. The microscopic examination shows that foaming was mainly caused by gram-positive short branch microorganisms, sludge fragments, and/or other microorganisms, while the long unbranched filamentous was easy to cause bulking. The high throughput sequencing (HTS) and Linear discriminant analysis effect Size (LEfSe) identified the significant discrepancy of bacteria in foams compared to normal AS. Mycobacterium, Mycobacteriaceae, Nocardiaceae, Actinomycetales, Chryseobacterium, Flavobacterium, Ormithobacterium, Flavobacteriaceae, and Portibacter were considered as the dominant foaming-potential bacteria but not the most abundant bacteria in the foams. The excessive growth of foaming bacteria (including Haliscomentbacter, Saprospiraceae, and Tetrasphra) directly led to bulking with a high sludge volume index and was positively correlated with sludge retention time (SRT) and negatively correlated with dissolved oxygen (DO), which means long SRT and low DO may lead bulking instead of foaming. It also found that the foaming bacteria (including Skermania, Comamonadaceae, Cloacibacterium, Flavobacterium, and Chryseobacterium) had significant positive correlations with suspended solids and mixed liquid suspended solids, and negative correlations with temperature and DO concentration. Full article

The utilization of membrane technologies in winemaking has revolutionized various stages of production, offering precise and efficient alternatives to traditional methods. Membranes, characterized by their selective permeability, play a pivotal role in enhancing wine quality across multiple processes. In clarification, microfiltration and ultrafiltration membranes, such as ceramic or polymeric membranes (e.g., polyethersulfone or PVDF), effectively remove suspended solids and colloids, resulting in a clearer wine without the need for chemical agents. During stabilization, membranes such as nanofiltration and reverse osmosis membranes, often made from polyamide composite materials, enable the selective removal of proteins, polysaccharides, and microorganisms, thereby improving the wine’s stability and extending its shelf life. Additionally, in dealcoholization, membranes like reverse osmosis and pervaporation membranes, typically constructed from polydimethylsiloxane (PDMS) or other specialized polymers, facilitate the selective removal of ethanol while preserving the wine’s flavor and aroma profile, addressing the increasing consumer demand for low-alcohol and alcohol-free wines. This article provides a comprehensive analysis of the advancements and applications of membrane technologies in winemaking. Full article

Technical retrofit Sustainable Drainage Systems (SuDSs) are a suitable option in the numerous mitigation measures to reduce the amount of tyre wear entering the environment. In the study presented here, such a filter system was tested under extreme conditions at the ADAC Driving Safety Centre Berlin-Brandenburg. Despite a technical separation limit of 125 or 250 µm of the filter systems, particles > 6 µm were measured in the retained masses. In addition, the marker SBR was used to determine the residues of tyre wear in the filter system using the TED-GC-MS analysis method. The highest concentrations were found in the 20–63 µm fraction. The results indicate that tyre wear particles become smaller due to high forces generated by braking and cornering. Test stand investigations indicate a retention efficiency of the filter system of 2/3 of the tyre wear. Furthermore, the results show that the parameter ‘Total Suspended Solids < 63 µm’ (TSS₆₃) is a relevant evaluation parameter for the road runoff. Full article

An adaptable, low-cost, and easy-to-operate biological treatment system for pollutant abatement in aquaculture water at the field pond scale needs to be developed. In this study, the pollutant removal capacity of a stable bioreactor for aquaculture wastewater was assessed, and the related mechanism was elucidated via an analysis of the microbial community’s characteristics and functions. The average removal efficiencies of chemical oxygen demand, suspended solids, total nitrogen, and total phosphorus were 40%, 86.22%, 38.62%, and 53.74%, respectively. The effluent quality meets the Requirement for Water Discharge from Freshwater Aquaculture Pond, SC/T9101-2007. The results indicate that the fillers under anaerobic conditions could attract Denitratisoma and unclassified_Rhodocyclaceae, promoting the denitrification reaction. This aligns with the characteristic that total nitrogen in aquaculture sewage mainly exists in the form of nitrate nitrogen. An anaerobic atmosphere helps degrade organic contaminants at liquid interfaces and remove nitrogen in the solid phase. The fillers under anaerobic conditions could attract Bacteroidota and promote the production of polysaccharides to form biofilms, which may be associated with phosphorus removal. The results indicate that the anaerobic stage can promote the formation of biofilm on the fillers to remove pollutants, thus achieving higher aquaculture sewage treatment efficiency. Full article

The oil and gas industry’s view of water production, once regarded primarily as a waste stream, has shifted in recent years due to the growing environmental and economic challenges. Industries now recognize the substantial volumes of water produced during production operations and are actively exploring alternative water management strategies. Among these, water treatment stands out as a leading approach, aimed at purifying the water to achieve specific element concentrations suited for targeted applications. The produced water from oil and gas reservoirs is a complex mixture of various organic and inorganic compounds, as well as dissolved and suspended solids. It is considered a highly contaminated waste stream, making effective treatment essential to meet future critical water demand. The physical and chemical properties of the produced water vary depending on the extraction location, geological formations, and type of hydrocarbon produced. This review examines multiple treatment methods used for the beneficial reuse of produced water, covering physical, chemical, and biological techniques, along with examples demonstrating their effectiveness in field case studies. Full article

Sludge management is a very relevant aspect in the operation of Wastewater Treatment Plants (WWTPs). In activated sludge systems, it is common to have daily (or continuous) monitoring of total suspended solids in the aeration tank (MLSS). If such control is not properly performed, it can cause solids to wash out in the secondary sedimentation tank or significantly impact BOD (Biochemical Oxygen Demand) and nitrogen removal. There are many commercially available systems which can provide real-time monitoring of solids (mainly optical or ultrasound sensors). Even though commercially available (usually with a high cost), there are still issues related to the use of such sensors. The most important one is the progressive accumulation of solids, which cause measurement errors. In this work, the authors investigated the application of a low-cost US sensor for MLSS (mixed-liquor suspended solids) monitoring in two full-scale activated sludge WWTPs. The tested sensor was similar to a previously described device, which had been previously employed in a pilot-scale UASB reactor in Brazil. The main differences were related to an integrated treatment and acquisition system which allowed real-time treatment of the US wave as well as data acquisition at a predefined time. The values generated by the sensor were compared with a commercial optical sensor installed in the same WWTP and double-checked with periodic gravimetric tests. The results at a Leeuwarden WWTP showed that the measurements of the US sensor, the optical sensor, and gravimetric test did not present significant differences during the test period at a significance level of 5%. Absolute errors were on average 0.04% (US sensor) and 0.03% (optic sensor) of MLSS compared to the gravimetric test. Although the use of the tested US sensor for monitoring solids in WWTP is promising, there are still several improvements that need to be made to the sensor. These include implementing a more precise calibration frequency, establishing a cleaning routine, and preventing sensor fouling. Furthermore, the sensor still needs a more thorough cost–benefit analysis, which would help assess the practicality of implementing this technology in various WWTPs. Full article

River ecosystems are integral to sustainable environmental development, playing a crucial role in understanding suspended solid matter (SSM) transport dynamics and soil conservation. Accurate monitoring of SSM concentrations in watersheds is foundational for these studies. This research introduces and evaluates a novel HHSW·NUG-1 photoelectric sand meter, specifically designed for SSM measurement. Its reliability was validated at three hydrological stations, including Xiaolangdi. The instrument, based on light scattering principles, is optimized for environments with high SSM loads and rapid flow rates. Laboratory tests indicate a measuring range of 0 to 730 kg/m³, and field trials show effective operation within 0 to 375 kg/m³, meeting the monitoring needs of hydrological stations. Through comparative analysis of measurement data, we established conversion relationships for various SSM concentration ranges, confirming that the instrument’s system error is less than 1%. The photoelectric sand meter adheres to standards outlined in the “Guidelines for SSM Test in Rivers”, demonstrating stability in reliability, calibration methods, observation accuracy, real-time monitoring, data storage, and continuous operation. For optimal use, adherence to relevant hydrological instrument standards is recommended, particularly in stations requiring SSM analysis. Standard sampling and calibration of conversion coefficients should be conducted, and proper sensor installation is crucial to avoid interference from flow conditions. In conclusion, the HHSW·NUG-1 optoelectronic sand meter exhibits stable and reliable performance in practical applications, with broad potential for rapid deployment in other river hydrological stations. Full article