Search Results (17,459)

In Japan, when people take their waste bottle caps to designated recycling companies, JPY 5/kg is donated to developing countries for polio vaccine dissemination activities. The waste volume of plastic bottles and caps is increasing every year, and there is not a day that goes by that we do not see more bottles and caps. PET bottles are more easily recycled, as the bottle body is made of a single material. However, bottle caps are made of two different materials (PP and PE), which are difficult to identify perfectly when utilising the existing NIR technology in the recycling field. This is because the designs and colours of PP and PE bottle caps are becoming more diverse, with black and dark-coloured caps being difficult to sort using NIR technology. In addition, their specific gravity is almost the same; therefore, it is difficult to separate them by their water-based specific gravity, which is an approach commonly used by recyclers. Unidentified caps are sent for thermal recycling, which runs counter to the need for decarbonisation. They may also be mixed with identified caps and sold as recycled raw material, resulting in a reduction in the purity of the recycled plastic. If PP and PE caps can be identified using simple technology, it is expected to promote high resource recycling. Therefore, in order to develop such a sorting process, this study proposes a new method for the material identification of waste caps using terahertz waves. Therefore, this research aims to identify a new identification method for waste plastic caps, which has been a challenge both domestically and internationally. Specifically, we describe the limitations of the conventional methods for identifying PP and PE bottle caps according to their weight, specific gravity, and melting point and propose an identification method using terahertz waves, demonstrating its measurement-related merits and high identification accuracy. Full article

Thermokarst lakes are shallow bodies of freshwater that develop in permafrost regions, and they are an essential focus of international permafrost research. However, research regarding the mechanisms driving temperature fluctuations in thermokarst lakes and the factors that influence these changes is limited. We aimed to analyze seasonal variations in the surface water temperature, clarify historical trends in the phenological characteristics of lake ice, and predict future temperature changes in surface water of the thermokarst lakes using the air2water model. The results indicated that in comparison with air temperature, the thermokarst lake’s surface water temperature showed a certain lag and significantly higher values in the warm season. The warming rate of the thermokarst lake’s average surface water temperature based on historical data from 1957 to 2022 was 0.21 °C per decade, with a notably higher rate in August (0.42 °C per decade) than in other months. Furthermore, the ice-covered period steadily decreased by 2.12 d per decade. Based on the Coupled Model Intercomparison Project 6 projections, by 2100, the surface water temperatures of thermokarst lakes during the warm season are projected to increase by 0.38, 0.46, and 2.82 °C (under scenarios SSP126, SSP245, and SSP585), respectively. Compared with typical tectonic lakes on the Qinghai–Tibet Plateau, thermokarst lakes have higher average surface water temperatures during ice-free periods, and they exhibit a higher warming rate (0.21 °C per decade). These results elucidate the response mechanisms of thermokarst lakes’ surface water temperature and the phenological characteristics of lake ice in response to climate change. Full article

The phenomenon of pore blockage caused by injected suspended particles significantly impacts the efficiency of water injection and production capacity release in offshore oilfields, leading to increased additional resistance during the injection process. To enhance water injection volumes in injection wells, it is essential to quantitatively study the additional resistance caused by suspended particle blockage during water injection. However, there is currently no model for calculating the additional resistance resulting from suspended particle blockage. Therefore, this study establishes a permeability decline model based on the microscopic dispersion kinetic equation of particle transport. The degree of blockage is characterized by the reduction in fluid volume, and the additional resistance caused by particle migration and blockage during water injection is quantified based on the fluid volume decline. This study reveals that over time, suspended particles do not continuously migrate deeper into the formation but tend to deposit near the wellbore, blocking pores and increasing additional resistance. Over time, the concentration of suspended particles near the wellbore approaches the initial concentration of the injected water. An increase in seepage velocity raises the peak concentration of suspended particles, but when the seepage velocity reaches a certain threshold, its effect on particle migration stabilizes. The blockage location of suspended particles near the wellbore is significantly influenced by seepage velocity and time. An increase in particle concentration and size accelerates blockage formation but does not change the blockage location. As injection time increases, the fitted injection volume and permeability exhibit a power-law decline. Based on the trend of injection volume reduction, the additional resistance caused by water injection is calculated to range between 0 and 3.85 MPa. Engineering cases indicate that blockages are challenging to remove after acidification, and the reduction in additional resistance is limited. This study provides a quantitative basis for understanding blockage patterns during water injection, helps predict changes in additional resistance, and offers a theoretical foundation for targeted treatment measures. Full article

The seeds of Zanthoxylum bungeanum seeds, a high-quality vegetable protein source, encounter application limitations due to their high molecular weight and anti-nutritional factors. This study focused on optimizing the fermentation process by investigating key parameters such as inoculation amount, inoculation ratio, material-to-liquid ratio, fermentation temperature, and fermentation time. Both single-factor experiments and response surface methodology were used to determine the optimal conditions. The effects of fermentation on particle size, surface morphology (scanning electron microscopy), water holding capacity, oil holding capacity, solubility, and emulsification properties of Zanthoxylum bungeanum seed protein were analyzed. In addition, acute toxicity was investigated at doses of 1.5 g/kg, 3 g/kg, 6 g/kg, and 12 g/kg. The results showed that the optimal fermentation conditions were an inoculum concentration of 10%, a ratio of Bacillus subtilis to Lactobacillus plantarum of 1:1, a material-to-liquid ratio of 0.8:1, a temperature of 35 °C, and a fermentation period of 4 days. Under these optimized conditions, the soluble protein content reached 153.1 mg/g. After fermentation, the functional properties of Zanthoxylum bungeanum seed protein improved significantly: the water holding capacity increased by 89%, the oil holding capacity by 68%, while the emulsifying activity and stability indices improved by 6% and 17%, respectively. The macromolecular proteins in the seeds of Zanthoxylum bungeanum were effectively broken down into smaller fragments during fermentation, resulting in a more folded and porous surface structure. In acute toxicity tests, all mice treated with fermented Zanthoxum seed protein survived for more than 7 days after injection, and there were no significant differences in body weight, organ index, and hematological tests between groups, but FZBSP of 1.5 g/kg~12 g/kg caused varying degrees of steatosis and inflammatory damage in the heart and liver. In conclusion, this study confirms that follow-up pilot studies using 1.5 g/kg FZBSP have the potential for further development and utilization. Full article

This paper offers an in-depth review of adsorbable organic halogens (AOXs), a group of halogenated organic compounds that can be adsorbed from water onto activated carbon. AOXs are emerging contaminants derived from various industrial and household products containing active halogens. Significant concentrations of AOXs are commonly detected in wastewater originating from industries such as the paper and pulp, textile, tannery, chemical and pharmaceutical industries. The standard method for AOX determination is defined in UNI EN ISO 9562:2004. The technical literature indicates that the reliability of AOX measurements can be affected by various factors. This study investigated the possible toxicity of AOXs on wastewater treatment plants, an aspect that has received limited attention in terms of its impact on aerobic biological processes. To bridge this gap, respiratory tests were performed on different aerobic biomasses sourced from large-scale wastewater treatment facilities to evaluate potential inhibitory effects. The results underscore the importance of adopting a case-by-case approach when assessing the risks associated with these contaminants. Full article

Background: Despite incidence rates and complications, the clinical management of xerostomia lacks guidelines. Aim: The aim of this overview is to summarize the clinical experience over the past 10 years of treating xerostomia using non-pharmacological interventions. Materials and Methods: A literature search was conducted across PubMed, EMBASE, Web of Science, ScienceDirect, and Google Scholar databases, covering publications from 1 January 2013 to 30 January 2023. Results: Topical therapies are the mainstays in cases of longstanding oral dryness. Their aim is to relieve oral discomfort by retaining mouth moisture. Macro-molecular lubricants were largely used in xerostomia due to radiotherapy for Head and Neck cancer (HNC) and xerostomia due to the chronic use of drugs. However, none of them provided stable relief for dry mouth. Traditional Medicine (TM), through the administration of different medicinal herbs and plants, has recently been evaluated against xerostomia in clinical trials. Matricaria chamomilla L., Linum usitatissimum, and Malva sylvestris L. together with Althea digitata Boiss, Licorice root, and Salvia Officinalis are among the most used compounds. They were formulated as water extracts with health benefits that are attributed to the presence of polyphenols. However, the low number of clinical evaluations represents the greatest limitation for validating the efficacy of TM against xerostomia. Regarding acupuncture, it did not show significant effects in the trials in comparison to the control groups. Further, electrostimulation, photo-biomodulation and hyperbaric therapy need more randomized clinical evaluations to effectively demonstrate their ability to relieve dry mouth. Conclusions: No topical treatment has shown stable relief of xerostomia. Consequently, the management of xerostomia and its devastating complications remain a significant void in daily clinical practice. Full article

Electrodialysis (ED) has already been applied to recover nickel in galvanizing processes, allowing nickel recovery and the production of a treated effluent with demineralized water quality. However, the growth in ED use is still limited by the production and commercialization of ion-selective membranes, currently limited to a few large companies. Therefore, this paper presents the development of homogeneous cationic and anionic membranes made from poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) for ED use. Cationic membranes were prepared by the sulfonation reaction of PPO under different experimental conditions (PPO:H₂SO₄ molar ratio and reaction time). Anionic membranes were prepared by the bromination reaction of PPO, followed by the amination reaction. The membranes were characterized for their chemical and electrochemical properties, including ion exchange capacity, conductivity, thermal stability, and surface morphology. The optimal conditions for cationic membrane sulfonation were achieved with a 1:4.4 PPO:H₂SO₄ molar ratio, and a reaction time of 0.5 h. For anionic membranes, the best results were obtained with bromination, with a PPO:NBS (N-Bromosuccinimide) molar ratio of 1:0.5, followed by 14 days of amination. Overall, 91.8% chloride, 90.9% sulfate, and 85.5% nickel ion extraction was achieved, highlighting PPO as a promising polymer for the development of anionic and cationic ion-selective membranes for ED. Full article

Shipping, as the most efficient, cheapest, and most widespread mode of transporting goods, also generates significant exhaust emissions. This has led to the adoption of stringent regulatory restrictions on emissions from ship propulsion systems. Consequently, the education and training of marine engineers can significantly impact their understanding of how emissions are generated and their potential for reduction. The engine room simulator is an indispensable tool in the training of marine engineers. Since operating conditions and parameters have the greatest impact on NOx emissions, this forms the primary focus of this research. This study tests the accuracy and precision of the engine room simulator in simulating emissions and evaluating the influence of operating conditions on them. Furthermore, the implementation and testing of NOx emission reduction technologies are vital for promoting sustainable shipping, ensuring regulatory compliance, and training personnel to support environmentally conscious maritime operations. Using the example of a two-stroke marine diesel engine, the results obtained are compared with test bench data from similar engines. Special emphasis is placed on simulating the operation of a two-stroke diesel engine at low speed, or low load, where secondary NOx reduction methods cannot be used. Therefore, the simulator is tested using two available technologies: water–fuel emulsion and altering the fuel injection timing to reduce NOx emissions. The simulation results for the water–fuel emulsion show high accuracy in predicting NOx emission trends when changing the water content in the emulsion at nominal power. However, at low load, the results show significant deviations. Testing the effect of altering fuel injection timing under low load using the engine room simulator shows significant differences compared to available research. Nonetheless, research on NOx emissions in this engine mode is limited, presenting a potential area for further study. When comparing the results for nominal power operation, the simulation provides more accurate results, particularly in terms of the influence of fuel injection timing on NOx emissions. However, engine tests on the test bench still reveal more substantial changes in emissions than those obtained using the engine room simulator. Full article

Food processing is a fundamental requirement for extending the shelf life of food products, but it often involves heat treatment, which can compromise organoleptic quality while improving food safety. Infrared (IR) radiation has emerged as a transformative technology in food processing, offering a rapid, energy-efficient method for inactivating microbial cells and spores while preserving the nutritional and sensory attributes of food. Unlike traditional heating methods, IR technology enhances heating homogeneity, shortens processing time, and reduces energy consumption, making it an environmentally friendly alternative. Additionally, IR processing minimizes water usage, prevents undesirable solute migration, and maintains product quality, as evidenced by its effectiveness in applications ranging from drying fruits and vegetables to decontaminating meat and grains. The advantages of IR heating, including its precise and even heat diffusion, ability to retain color and nutrient content, and capacity to improve the microbial safety of food, position it as a promising tool in modern food preservation. Nevertheless, there are gaps in knowledge with respect to optimal application of IR in foods, especially in the maintenance product quality and the impact of factors such as IR power level, temperature, wavelength (λ), food depth, and target microorganisms on the applicability of this novel technology in food systems. Recent research has attempted to address challenges to the application of IR in food processing such as its limited penetration depth and the potential for surface burns due to high energy which has delayed the widespread utilization of this technology in food processing. Thus, this review critically evaluates the application of IR in food safety and quality, focusing on factors that affect its effectiveness and its use to moderate food quality and safety while comparing its advantages/disadvantages over traditional thermal processing methods. Full article

Drought stress is a major environmental constraint that limits rice (Oryza sativa L.) production worldwide. In this study, we investigated the effects of drought stress at the booting stage on rice leaf physiological characteristics and yield. The results showed that drought stress would lead to a significant decrease in chlorophyll content and photosynthesis in rice leaves, which would affect rice yield. Three different rice varieties were used in this study, namely Hanyou73 (HY73), Huanghuazhan (HHZ), and IRAT109. Under drought stress, the chlorophyll content of all cultivars decreased significantly: 11.1% and 32.2% decreases in chlorophyll a and chlorophyll b in HHZ cultivars, 14.1% and 28.5% decreases in IRAT109 cultivars, and 22.9% and 18.6% decreases in HY73 cultivars, respectively. In addition, drought stress also led to a significant decrease in leaf water potential, a significant increase in antioxidant enzyme activity, and an increase in malondialdehyde (MDA) content, suggesting that rice activated a defense mechanism to cope with drought-induced oxidative stress. This study also found that drought stress significantly reduced the net photosynthetic rate and stomatal conductance of rice, which, in turn, affected the yield of rice. Under drought stress, the yield of the HHZ cultivars decreased most significantly, reaching 30.2%, while the yields of IRAT109 and HY73 cultivars decreased by 13.0% and 18.2%, respectively. The analysis of yield composition showed that the number of grains per panicle, seed-setting rate, and 1000-grain weight were the key factors affecting yield formation. A correlation analysis showed that there was a significant positive correlation between yield and net photosynthetic rate, stomatal conductance, chla/chlb ratio, Rubisco activity, and Fv/Fm, but there was a negative correlation with MDA and non-photochemical quenching (NPQ). In summary, the effects of drought stress on rice yield are multifaceted, involving changes in multiple agronomic traits. The results highlight the importance of selecting and nurturing rice varieties with a high drought tolerance, which should have efficient antioxidant systems and high photosynthetic efficiency. Future research should focus on the genetic mechanisms of these physiological responses in order to develop molecular markers to assist in the breeding of drought-tolerant rice varieties. Full article

Optimizing maize irrigation strategies is essential for improving water use efficiency and crop yields in arid regions. However, limited quantitative research exists on these optimizations. This study focuses on the Heihe River Basin in China, aiming to (1) optimize maize irrigation strategies using a differential evolution (DE) algorithm integrated with the AquaCrop model and remote sensing data; (2) compare the DE algorithm’s performance with the traditional Nelder–Mead (fmin) algorithm regarding yield improvement and irrigation water use; and (3) assess the benefits of different irrigation strategies under limited water availability. Covering 22 irrigation management zones in Zhangye City, Gansu Province, the study utilized soil, weather, and crop data from Google Earth Engine to drive the AquaCrop model. Results indicate that the DE algorithm achieved higher simulated maize yields, increasing by 0.5 to 1 t/ha on average compared to the fmin algorithm, albeit with a 30% rise in irrigation water usage. The integration of both the DE and fmin algorithms with the AquaCrop model facilitates the development of tailored irrigation strategies, providing a scientific foundation for sustainable agricultural water management. These findings can guide efficient irrigation management plans in the region and similar arid systems. Full article

Metal–organic frameworks (MOFs) represent a category of crystalline materials formed by the combination of metal ions or clusters with organic linkers, which have emerged as a prominent research focus in the field of photocatalysis. Owing to their distinctive characteristics, including structural diversity and configurations, significant porosity, and an extensive specific surface area, they provide a flexible foundation for various potential applications in photocatalysis. In recent years, researchers have tackled many issues in the MOF-based photocatalytic yield. However, limited light adsorption regions, lack of active sites and active species, and insufficient efficiency of photogenerated charge carrier separation substantially hinder the photocatalytic performance. In this review, we summarized the strategies to improve the photocatalytic performance and recent developments achieved in MOF and MOF-based photocatalysis, including water splitting, CO₂ conversion, photocatalytic degradation of pollutants, and photocatalytic nitrogen fixation into ammonia. In conclusion, the existing challenges and prospective advancements in MOF-based photocatalysis are also discussed. Full article

Background/Objectives: The unique properties of iron oxide nanoparticles have attracted significant interest within the biomedical community, particularly for magnetic hyperthermia applications. Various synthesis methods have been developed to optimize these nanoparticles. Methods: In this study, we employed a powdered coconut water (PCW)-assisted sol–gel method to produce magnetite nanoparticles for the first time. A comprehensive analysis of the thermal (differential thermal analysis and thermogravimetry), structural (X-ray diffraction), morphological (scanning electron microscopy with energy dispersive spectroscopy), magnetic (vibrating sample magnetometer and hyperthermia), and biological (cytotoxicity essays) properties was conducted to assess their potential for magnetic hyperthermia. Results: Samples heat-treated at 700 °C and 400 °C (washed powder) for 4 h under argon presented only magnetite in their composition. The micrometer-sized particles exhibited ferrimagnetic behavior, with saturation magnetization values of 37, 76, and 10 emu/g and specific absorption rates (SAR) of 27.1, 19.9, and 14.1 W/g, respectively, for treatments at 350 °C (48 h), 700 °C (4 h), and 400 °C (washed powder, 4 h) under an argon atmosphere. Biological tests showed no cytotoxicity below 10 mg/mL. Conclusions: The findings highlight the potential of PCW-assisted synthesis as a sustainable and efficient strategy for producing pure magnetite, with powder washing preceding the heat treatment enabling the attainment of this phase at lower temperatures. Nevertheless, the micrometer-scale dimensions is observed in the morphological analysis limit their suitability for biomedical applications. Full article

Rhein is a natural active ingredient in traditional Chinese medicine that has attracted much attention due to its wide range of pharmacological activities. However, its clinical application is limited by low water solubility, poor oral absorption, and potential toxicity to the liver and kidneys. Recently, advanced extraction and synthesis techniques have made it possible to develop derivatives of rhein, which have better pharmacological properties and lower toxicity. This article comprehensively summarizes the biological activity and action mechanism of rhein. Notably, we found that TGF-β1 is the target of rhein improving tissue fibrosis, while NF-κB is the main target of its anti-inflammatory effect. Additionally, we reviewed the current research status of the pharmacokinetics, toxicology, structural optimization, and potential drug applications of rhein and found that the coupling and combination therapy of rhein and other active ingredients exhibit a synergistic effect, significantly enhancing therapeutic efficacy. Finally, we emphasize the necessity of further studying rhein’s pharmacological mechanisms, toxicology, and development of analogs, aiming to lay the foundation for its widespread clinical application as a natural product and elucidate its prospects in modern medicine. Full article

Due to imbalanced demand favoring egg whites, the egg industry faces a surplus of egg yolk, limiting overall growth. This study designed a feasible process for the crude extraction of livetins and phosvitin (PV) and revealed the related separation mechanisms. Our method utilized a 1:9 egg yolk dilution at pH 6.15–6.29, incubated at 4–7.5 °C, to reduce the dispersibility of lipoproteins in the water-soluble fraction (WSF). Adding 0.04–0.05% (w/v) sodium alginate to WSF at pH 5.40 effectively removed suspended low-density lipoprotein (LDL) through electrostatic complexation, increasing livetins electrophoretic bands from 51.90% to 91.04%. The dispersion of the high-density lipoprotein (HDL)-PV complex was jointly affected by NaCl and pH, with phosphocalcic bridges fully disrupted when NaCl concentration exceeded 7.5% (w/v). Na⁺ and Ca²⁺ were adsorbed onto the negatively charged protein surface at pH 5–8, inducing strong hydration repulsion, thereby resulting in the individual dispersion of HDL and PV. Based on the solubility difference in low ionic strength solutions at neutral pH, HDL could be effectively removed after dialysis, increasing PV electrophoretic bands from 8.45% to 61.50%. This simple and feasible separation process may provide a reliable foundation for further purification via membrane filtration and chromatography. Full article