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Keywords = workover operation

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16 pages, 11348 KiB  
Article
Thermal Degradation Study of Hydrogel Nanocomposites Based on Polyacrylamide and Nanosilica Used for Conformance Control and Water Shutoff
by Aleksey Telin, Farit Safarov, Ravil Yakubov, Ekaterina Gusarova, Artem Pavlik, Lyubov Lenchenkova and Vladimir Dokichev
Gels 2024, 10(12), 846; https://doi.org/10.3390/gels10120846 - 22 Dec 2024
Viewed by 673
Abstract
The application of nanocomposites based on polyacrylamide hydrogels as well as silica nanoparticles in various tasks related to the petroleum industry has been rapidly developing in the last 10–15 years. Analysis of the literature has shown that the introduction of nanoparticles into hydrogels [...] Read more.
The application of nanocomposites based on polyacrylamide hydrogels as well as silica nanoparticles in various tasks related to the petroleum industry has been rapidly developing in the last 10–15 years. Analysis of the literature has shown that the introduction of nanoparticles into hydrogels significantly increases their structural and mechanical characteristics and improves their thermal stability. Nanocomposites based on hydrogels are used in different technological processes of oil production: for conformance control, water shutoff in production wells, and well killing with loss circulation control. In all these processes, hydrogels crosslinked with different crosslinkers are used, with the addition of different amounts of nanoparticles. The highest nanoparticle content, from 5 to 9 wt%, was observed in hydrogels for well killing. This is explained by the fact that the volumes of injection of block packs are counted only in tens of cubic meters, and for the sake of trouble-free workover, it is very important to preserve the structural and mechanical properties of block packs during the entire repair of the well. For water shutoff, the volumes of nanocomposite injection, depending on the well design, are from 50 to 150 m3. For conformance control, it is required to inject from one to several thousand cubic meters of hydrogel with nanoparticles. Naturally, for such operations, service companies try to select compositions with the minimum required nanoparticle content, which would ensure injection efficiency but at the same time would not lose economic attractiveness. The aim of the present work is to develop formulations of nanocomposites with increased structural and mechanical characteristics based on hydrogels made of partially hydrolyzed polyacrylamide crosslinked with resorcinol and paraform, with the addition of commercially available nanosilica, as well as to study their thermal degradation, which is necessary to predict the lifetime of gel shields in reservoir conditions. Hydrogels with additives of pyrogenic (HCSIL200, HCSIL300, RX380) and hydrated (white carbon black grades: ‘BS-50’, ‘BS-120 NU’, ‘BS-120 U’) nanosilica have been studied. The best samples in terms of their structural and mechanical properties have been established: nanocomposites with HCSIL200, HCSIL300, and BS-120 NU. The addition of hydrophilic nanosilica HCSIL200 in the amount of 0.4 wt% to a hydrogel consisting of partially hydrolyzed polyacrylamide (1%), resorcinol (0.04%), and paraform (0.09%) increased its elastic modulus by almost two times and its USS by almost three times. The thermal degradation of hydrogels was studied at 140 °C, and the experimental time was converted to the exposure time at 80 °C using Van’t Hoff’s rule. It was found that the nanocomposite with HCSIL200 retains its properties at a satisfactory level for 19 months. Filtration studies on water-saturated fractured reservoir models showed that the residual resistance factor and selectivity of the effect of nanocomposites with HCSIL200 on fractures are very high (226.4 and 91.6 for fracture with an opening of 0.05 cm and 11.0 for porous medium with a permeability of 332.3 mD). The selectivity of the isolating action on fractured intervals of the porous formation was noted. Full article
(This article belongs to the Special Issue Chemical and Gels for Oil Drilling and Enhanced Recovery)
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15 pages, 3747 KiB  
Article
Development of a Hybrid AI Model for Fault Prediction in Rod Pumping System for Petroleum Well Production
by Aoxue Zhang, Yanlong Zhao, Xuanxuan Li, Xu Fan, Xiaoqing Ren, Qingxia Li and Leishu Yue
Energies 2024, 17(21), 5422; https://doi.org/10.3390/en17215422 - 30 Oct 2024
Viewed by 641
Abstract
Rod pumping systems are widely used in oil wells. Accurate fault prediction could reduce equipment fault rate and has practical significance in improving oilfield production efficiency. This paper analyzed the production journal of rod pumping wells in block X of Xinjiang Oilfield. According [...] Read more.
Rod pumping systems are widely used in oil wells. Accurate fault prediction could reduce equipment fault rate and has practical significance in improving oilfield production efficiency. This paper analyzed the production journal of rod pumping wells in block X of Xinjiang Oilfield. According to the production journal, oil well maintenance operations are primarily caused by five types of faults: scale, wax, corrosion, fatigue, and wear. These faults make up approximately 90% of all faults. 1354 oil wells in the block that experienced workover operations as a result of the aforementioned factors were chosen as the research objects for this paper. To lower the percentage of data noise, wavelet threshold denoising and variational mode decomposition were used. Based on the bidirectional long short-term memory network, an intelligent model for fault prediction was built. It was trained and verified with the help of the sparrow search algorithm. Its efficacy was demonstrated by testing various deep learning models in the same setting and with identical parameters. The results show that the prediction accuracy of the model is the highest compared with other 11 models, reaching 98.61%. It is suggested that the model using artificial intelligence can provide an accurate fault warning for the oilfield and offer guidance for the maintenance of the rod pumping system, which is meant to reduce the occurrence of production stagnation and resource waste. Full article
(This article belongs to the Special Issue New Advances in Oil, Gas and Geothermal Reservoirs: 2nd Edition)
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14 pages, 2468 KiB  
Article
Phase Behavior of Fluid Composition in Coalbed Methane Wells Pre- and Post-Workover: An Examination of the Panzhuang Block, Qinshui Basin, Shanxi, China
by Qingwei Wang, Qiang Yan, Yan Zhang, Xiafan Xing and Cailian Hao
Appl. Sci. 2024, 14(16), 7207; https://doi.org/10.3390/app14167207 - 16 Aug 2024
Viewed by 732
Abstract
Workover operations significantly impact the service life and gas production capacity of coalbed methane (CBM) wells and are crucial for optimizing resource exploitation. To investigate workover operations’ impact on coal seam reservoirs, the authors designed a series of experiments and obtained the following [...] Read more.
Workover operations significantly impact the service life and gas production capacity of coalbed methane (CBM) wells and are crucial for optimizing resource exploitation. To investigate workover operations’ impact on coal seam reservoirs, the authors designed a series of experiments and obtained the following results: (1) The workover operation induced a phase transition in the solid-liquid composition produced by the CBM well, indicating changes in the coal reservoir’s internal structure. (2) During the stable production stage before and after the workover, the proportion of Na+, Cl, Ca2+, and Total Dissolved Solids (TDS) in the water samples showed a downward trend as a whole, while the HCO3; after the workover, the Na+, Cl, Ca2+, and TDS all increased suddenly, while the HCO3 decreased. (3) While inorganic minerals predominated in the precipitation material during the stable production stage pre-workover, their proportion decreased post-workover, with a noticeable shift in their qualitative composition. (4) It is an indisputable fact that workover operations cause physical and chemical damage to coal seam reservoirs. During workover operation, how to avoid damage and conduct benign reconstruction to the reservoir will be the direction of our future efforts. The experimental results provide valuable insights that can guide the optimization of CBM workover operations and inform the strategic planning of subsequent drainage activities. Full article
(This article belongs to the Special Issue Advances in Unconventional Natural Gas: Exploration and Development)
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13 pages, 2744 KiB  
Article
Plugging Efficiency in Fractured Carbonate Gas Reservoirs Using Fuzzy-Ball Fluids Combined with Solid Plugging Agents
by Fanghui Zhu, Lihui Zheng, Yang Zhao, Qifan Chang, Jiahui Li and Qinhao Zhang
Energies 2023, 16(18), 6688; https://doi.org/10.3390/en16186688 - 18 Sep 2023
Cited by 1 | Viewed by 1117
Abstract
Loss encountered during workover operation is a common challenge in the development of fractured carbonate gas reservoirs. Fuzzy-ball fluid, a non-solid phase plugging material developed based on Fuzzy Sealaplugging Theory, has been widely used in killing the well. However, in the plugging of [...] Read more.
Loss encountered during workover operation is a common challenge in the development of fractured carbonate gas reservoirs. Fuzzy-ball fluid, a non-solid phase plugging material developed based on Fuzzy Sealaplugging Theory, has been widely used in killing the well. However, in the plugging of fractured carbonate gas reservoirs, a substantial volume of Fuzzy-ball fluid is required and the pressurization process is time-consuming, which greatly impairs its application. In this study, solid plugging agents including calcium carbonate and fibers are introduced into Fuzzy-ball fluids to improve the plugging efficiency of large-scale macro-fractures. In particular, the plugging performance was evaluated by the indoor plugging of a synthetic core containing a 5 mm wide wedge-shaped fracture, as well as by field trials in two wells. The results show that the plugging ability of the new fluid increases as the concentration of calcium carbonate or fiber increases. Moreover, a more significant enhancement of plugging efficiency was achieved by fibers. In field applications, the use of Fuzzy-ball fluids with calcium carbonate or fibers reduced the volume of fluid consumed by 33~74% and decreased the pressurization time by 33~69%. Therefore, by combining solid plugging agents with Fuzzy-ball fluids, the dual demand for plugging efficiency and cost-effectiveness for fractured carbonate gas reservoirs is achieved simultaneously, which provides an alternative technique for addressing fluid loss in fractured carbonate gas reservoirs. Full article
(This article belongs to the Special Issue Enhanced Oil Recovery with the Assistance of Sealaplugology)
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12 pages, 2736 KiB  
Article
Optimization of the Well Start-Up Procedure and Operating Parameters for ESP Gas Well Dewatering
by Xiaolei Wang, Xuezhang Feng, Jinbo Liu, Jiangling Hong, Jinsong Yao, Honglei Liu, Zelin Liu and Guoqing Han
Sustainability 2023, 15(2), 1498; https://doi.org/10.3390/su15021498 - 12 Jan 2023
Viewed by 3302
Abstract
The Electrical Submersible Pump (ESP) systems were deployed in two gas wells for the dewatering of the gas reservoir. However, problems, such as the failure to start up the ESP, and changes in reservoir parameters occurred during the production. For the first problem, [...] Read more.
The Electrical Submersible Pump (ESP) systems were deployed in two gas wells for the dewatering of the gas reservoir. However, problems, such as the failure to start up the ESP, and changes in reservoir parameters occurred during the production. For the first problem, the well start-up operation records indicate that the ESP’s gas locking happened. To avoid this, an optimization method of the well start-up procedure for the ESP well with a check valve was correspondingly proposed, which can solve the problem without any workovers. Secondly, based on the working characteristics of the ESP and the nodal analysis method, a set of optimization methods for the operating parameters of ESPs were introduced to achieve the inflow and outflow balance. For one well, the original ESP system was planned to be installed after hydraulic fracturing. Traditionally, the ESP operating parameters were designed based on the production rate. However, in this case, the production rate and the ESP operating frequency were designed simultaneously to maximize the pump efficiency. Full article
(This article belongs to the Special Issue Numerical Analysis of Rock Mechanics and Crack Propagation)
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17 pages, 3110 KiB  
Article
Frictional Pressure Drop for Gas–Liquid Two-Phase Flow in Coiled Tubing
by Shihui Sun, Jiahao Liu, Wan Zhang and Tinglong Yi
Energies 2022, 15(23), 8969; https://doi.org/10.3390/en15238969 - 27 Nov 2022
Cited by 2 | Viewed by 2564
Abstract
Coiled tubing (CT) is widely used in drilling, workover, completion, fracturing and stimulation in the field of oil and gas exploration and development. During CT operation, the tubing will present a gas–liquid two-phase flow state. The prediction of frictional pressure drop for fluid [...] Read more.
Coiled tubing (CT) is widely used in drilling, workover, completion, fracturing and stimulation in the field of oil and gas exploration and development. During CT operation, the tubing will present a gas–liquid two-phase flow state. The prediction of frictional pressure drop for fluid in the tube is an important part of hydraulic design, and its accuracy directly affects the success of the CT technique. In this study, we analyzed the effects of the gas void fraction, curvature ratio and fluid inlet velocity on frictional pressure drop in CT, numerically. Experimental data verified simulated results. Flow friction sensitivity analysis shows the frictional pressure drop reaches its peak at a gas void fraction of 0.8. The frictional pressure gradient increases with the increase in curvature ratio. As the strength of secondary flow increases with the increase in inlet velocity, the increased trend of gas–liquid two-phase flow friction is aggravated. The correlation of friction factor for gas–liquid two-phase flow in coiled tubing is developed by regression analysis of simulation results. The research results can support high quality CT hydraulics design, through which the success of CT operations can be guaranteed. Full article
(This article belongs to the Section K: State-of-the-Art Energy Related Technologies)
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10 pages, 1875 KiB  
Article
Study on Key Parameters for Jet Impacting Pulverized Coal Deposited in Coal-Bed Methane Wells
by Hongying Zhu, Likun Xue, Fenna Zhang, Yaoguang Qi, Junwei Zhao and Dehua Feng
Coatings 2022, 12(10), 1454; https://doi.org/10.3390/coatings12101454 - 1 Oct 2022
Cited by 1 | Viewed by 1621
Abstract
Cleaning out the pulverized coal deposited at the bottom of a coalbed methane (CBM) well is key to achieving continuous CBM drainage and prolonging the workover period. In this study, Fluent is used in conjunction with the standard k-ε model and the Eulerian-Eulerian [...] Read more.
Cleaning out the pulverized coal deposited at the bottom of a coalbed methane (CBM) well is key to achieving continuous CBM drainage and prolonging the workover period. In this study, Fluent is used in conjunction with the standard k-ε model and the Eulerian-Eulerian model to simulate and analyse jet erosion of deposited pulverized coal particles. The depth and width of the stable erosion pit that is formed by jet-impacting deposited pulverized coal under different conditions are determined and provide a theoretical basis for the cleanout of pulverized coal in the bottom of a CBM well. In this paper, the three parameters of the jet target distance, nozzle diameter and nozzle outlet flow velocity are selected to perform an orthogonal simulation. The change trends in the depth and width of the scouring pit with time are determined. The results show that jet impacting of deposited pulverized coal can be categorised into four stages, periods of rapid growth, stability, jet swing and dynamic stability. A sensitivity analysis shows that the nozzle outlet flow velocity has the strongest influence on the depth of the scouring pit among the selected parameters. The depth of the jet impact pit can reach the maximum depth at t = 3 s, while the width of the impact pit can reach the maximum after t = 7 s. This can provide key design parameters for CBM well pulverized coal impacting operation. It is of great significance for capacity damage control during CBM well workover operation. Full article
(This article belongs to the Special Issue Deposition and Applications of Protective Films and Coatings)
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18 pages, 3721 KiB  
Article
A Fuzzy Inference System for Detection of Positive Displacement Motor (PDM) Stalls during Coiled Tubing Operations
by Rafael Augusto Galo Fernandes, Paloma Maria Silva Rocha Rizol, Andreas Nascimento and José Alexandre Matelli
Appl. Sci. 2022, 12(19), 9883; https://doi.org/10.3390/app12199883 - 30 Sep 2022
Cited by 2 | Viewed by 2076
Abstract
Positive Displacement Motors (PDM) are extensively used in the oilfield, either in drilling or in coiled tubing (CT) operations. They provide a higher rate of penetration and the possibility of drilling horizontal wells. For coiled tubing operations, PDMs can mill through obstructions and [...] Read more.
Positive Displacement Motors (PDM) are extensively used in the oilfield, either in drilling or in coiled tubing (CT) operations. They provide a higher rate of penetration and the possibility of drilling horizontal wells. For coiled tubing operations, PDMs can mill through obstructions and enable shut-in wells to work again. One of the major challenges while using these tools is the motor stalling, which can lead to serious damage to the PDM and lost time events in drilling and workover rigs. These events result in total losses of hundreds of thousands of dollars, and their avoidance mostly depends on trained and fully aware equipment operators. If a PDM starts to stall, the pumping needs to be halted immediately or the tool may fail. This paper describes the use of a Fuzzy Inference System (FIS) to detect the stalling events as they start to happen using the acquisition data from the coiled tubing unit, the output of the FIS could then trigger an alarm for the operator to take the proper action or remotely stop the pump. The FIS was implemented in Python and tested with real CT milling acquisition data. When tested using real data, the system analyzed 68,458 acquisition points and detected 94% of the stalling events across this data during its first seconds, whereas, during the real job, a CT operator could take longer to notice this event and take the proper action, or even take no action. If the FIS was applied on a real coiled tubing acquisition system, it could reduce PDMs over-pressurization due to stalling, leading to an increase on its useful life and decrease on premature failure. As of now there is no similar system in the market or published and this kind of operation is fully performed using human supervision only. Full article
(This article belongs to the Topic Artificial Intelligence and Fuzzy Systems)
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10 pages, 1352 KiB  
Article
The Development of Forecasting Technique for Cyclic Steam Stimulation Technology Effectiveness in Near-Wellbore Area
by Sergey Krivoshchekov, Alexander Kochnev and Kirill Vyatkin
Fluids 2022, 7(2), 64; https://doi.org/10.3390/fluids7020064 - 3 Feb 2022
Cited by 4 | Viewed by 2435
Abstract
The analytical review has shown that the scientific inquiry for effective technologies for high-viscosity oil field development is a critical task of the present-day oil industry. The paper presents a technique for determining the expediency and effectiveness of deploying the near-wellbore cyclic steam [...] Read more.
The analytical review has shown that the scientific inquiry for effective technologies for high-viscosity oil field development is a critical task of the present-day oil industry. The paper presents a technique for determining the expediency and effectiveness of deploying the near-wellbore cyclic steam stimulation technology for oil recovery enhancement. The method involves the calculation of process parameters of the technology cycle and the comparative analysis of cumulative oil production before the treatment (base case) and after its deployment. Separately, the work focuses on studying the impact of dynamic oil viscosity over the entire temperature range on the technology effectiveness and expediency. The laboratory studies showed dynamic viscosity correlation dependencies for six different oils of the Nozhovskaya group of oil fields (Russian Federation) characterized as viscous and highly viscous. As a case study of the proposed method application, a numerical simulation of the technology deployment was carried out for six oil samples. The calculations determined inexpediency of cyclic steam stimulation for one of the samples since oil well downtime for workover operation prevailed over the time of near-wellbore cooling. Full article
(This article belongs to the Special Issue Multiphase Flow in Pipes with and without Porous Media)
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15 pages, 3844 KiB  
Article
Well Killing Technology before Workover Operation in Complicated Conditions
by Dmitry V. Mardashov, Mikhail K. Rogachev, Yury V. Zeigman and Vyacheslav V. Mukhametshin
Energies 2021, 14(3), 654; https://doi.org/10.3390/en14030654 - 28 Jan 2021
Cited by 48 | Viewed by 4756
Abstract
Well killing is an important technological stage before conducting workover operation, one of the tasks of which is to preserve and restore the natural filtration characteristics of the bottomhole formation zone (BFZ). Special attention should be paid to the choice of well killing [...] Read more.
Well killing is an important technological stage before conducting workover operation, one of the tasks of which is to preserve and restore the natural filtration characteristics of the bottomhole formation zone (BFZ). Special attention should be paid to the choice of well killing technologies and development of wells in complicated conditions, which include abnormally low reservoir pressure, high oil-gas ratio and carbonate reservoir type. To preserve the filtration characteristics of the productive formation and prevent fluid losses in producing wells during well killing operation, blocking compositions are used. At the same time, an informed choice of the most effective well killing technologies is required. Consequently, there is a need to conduct laboratory physicochemical and coreflood experiments simulating geological, physical, and technological conditions of field development, as similar as possible to actual reservoir conditions. The article presents the results of experimental studies on the development well killing technologies of producing wells during workover operation in various geological, physical, and technological conditions of oil field development. Physicochemical and coreflood laboratory experiments were carried out with the simulation of the processes of well killing and development of wells in reservoir conditions with the use of modern high-technology equipment in the Enhanced Oil Recovery Laboratory of the Department of Development and Operation of Oil and Gas Fields at St. Petersburg Mining University. As a result of the experimental studies, new compositions of well killing and stimulation fluids were developed, which ensure to prevent fluid loss, gas breakthrough, as well as the preservation, restoration and improvement of the filtration characteristics of the BFZ in the conditions of terrigenous and carbonate reservoirs at different stages of oil field development. It is determined that the developed process fluids, which include surfactants (YALAN-E2 and NG-1), have a hydrophobic effect on the porous medium of reservoir rocks, which ultimately contributes to the preservation, restoration and improvement of the filtration characteristics of the BFZ. The value of the presented research results is relevant for practice and confirmed by the fact that, as a result of field tests of the technology for blocking the BFZ with the composition of inverse water–oil emulsion during well killing before workover operation, an improvement in the efficiency of wells operation was obtained in the form of an increase in their oil production rate by an average of 5–10 m3/day, reducing the time required for the well to start operating up to 1–3 days and reducing the water cut of formation fluid by 20–30%. Full article
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17 pages, 9515 KiB  
Article
Integrating Fiber Optic Data in Numerical Reservoir Simulation Using Intelligent Optimization Workflow
by Giuseppe Feo, Jyotsna Sharma and Stephen Cunningham
Sensors 2020, 20(11), 3075; https://doi.org/10.3390/s20113075 - 29 May 2020
Cited by 5 | Viewed by 3716
Abstract
A novel workflow is presented for integrating fiber optic Distributed Temperature Sensor (DTS) data in numerical simulation model for the Cyclic Steam Stimulation (CSS) process, using an intelligent optimization routine that automatically learns and improves from experience. As the steam–oil relationship is the [...] Read more.
A novel workflow is presented for integrating fiber optic Distributed Temperature Sensor (DTS) data in numerical simulation model for the Cyclic Steam Stimulation (CSS) process, using an intelligent optimization routine that automatically learns and improves from experience. As the steam–oil relationship is the main driver for forecasting and decision-making in thermal recovery operations, knowledge of downhole steam distribution across the well over time can optimize injection and production. This study uses actual field data from a CSS operation in a heavy oil field in California, and the value of integrating DTS in the history matching process is illustrated as it allows the steam distribution to be accurately estimated along the entire length of the well. The workflow enables the simultaneous history match of water, oil, and temperature profiles, while capturing the reservoir heterogeneity and the actual physics of the injection process, and ultimately reducing the uncertainty in the predictive models. A novel stepwise grid-refinement approach coupled with an evolutionary optimization algorithm was implemented to improve computational efficiency and predictive accuracy. DTS surveillance also made it possible to detect a thermal communication event due to steam channeling in real-time, and even assess the effectiveness of the remedial workover to resolve it, demonstrating the value of continuous fiber optic monitoring. Full article
(This article belongs to the Section Optical Sensors)
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19 pages, 5479 KiB  
Article
Prevention of Barite Sag in Water-Based Drilling Fluids by A Urea-Based Additive for Drilling Deep Formations
by Abdelmjeed Mohamed, Saad Al-Afnan, Salaheldin Elkatatny and Ibnelwaleed Hussein
Sustainability 2020, 12(7), 2719; https://doi.org/10.3390/su12072719 - 30 Mar 2020
Cited by 29 | Viewed by 4295
Abstract
Barite sag is a challenging phenomenon encountered in deep drilling with barite-weighted fluids and associated with fluid stability. It can take place in vertical and directional wells, whether in dynamic or static conditions. In this study, an anti-sagging urea-based additive was evaluated to [...] Read more.
Barite sag is a challenging phenomenon encountered in deep drilling with barite-weighted fluids and associated with fluid stability. It can take place in vertical and directional wells, whether in dynamic or static conditions. In this study, an anti-sagging urea-based additive was evaluated to enhance fluid stability and prevent solids sag in water-based fluids to be used in drilling, completion, and workover operations. A barite-weighted drilling fluid, with a density of 15 ppg, was used with the main drilling fluid additives. The ratio of the urea-based additive was varied in the range 0.25–3.0 vol.% of the total base fluid. The impact of this anti-sagging agent on the sag tendency was evaluated at 250 °F using vertical and inclined sag tests. The optimum concentration of the anti-sagging agent was determined for both vertical and inclined wells. The effect of the urea-additive on the drilling fluid rheology was investigated at low and high temperatures (80 °F and 250 °F). Furthermore, the impact of the urea-additive on the filtration performance of the drilling fluid was studied at 250 °F. Adding the urea-additive to the drilling fluid improved the stability of the drilling fluid, as indicated by a reduction in the sag factor. The optimum concentration of this additive was found to be 0.5–1.0 vol.% of the base fluid. This concentration was enough to prevent barite sag in both vertical and inclined conditions at 250 °F, with a sag factor of around 0.5. For the optimum concentration, the yield point and gel strength (after 10 s) were improved by around 50% and 45%, respectively, while both the plastic viscosity and gel strength (after 10 min) were maintained at the desired levels. Moreover, the anti-sagging agent has no impact on drilling fluid density, pH, or filtration performance. Full article
(This article belongs to the Special Issue Sustainability in Oil, Gas and Energy Resources)
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13 pages, 2398 KiB  
Article
New Environmentally Friendly Acid System for Iron Sulfide Scale Removal
by Hany Gamal, Khaled Abdelgawad and Salaheldin Elkatatny
Sustainability 2019, 11(23), 6727; https://doi.org/10.3390/su11236727 - 27 Nov 2019
Cited by 15 | Viewed by 6428
Abstract
Iron sulfide scale is a common problem in the oil and gas industry. The precipitation of the iron sulfide scale on the well completion tools or inside surface flow lines restricts the flow of the produced fluids and might affect the integrity of [...] Read more.
Iron sulfide scale is a common problem in the oil and gas industry. The precipitation of the iron sulfide scale on the well completion tools or inside surface flow lines restricts the flow of the produced fluids and might affect the integrity of the pipelines or the surface and subsurface tools. Failure of the downhole completions tools will not only reduce the production rates but it might require workover and remedial operations that will add extra cost. The main objective of this paper is to evaluate a new environmentally friendly acid system (NEFAS) for iron sulfide scale removal using an actual field sample. The scale sample collected from a natural gas well is dominated by pyrrhotite (55%) in addition to calcite (21%), pyrite (8%), and torilite (6%) with minor traces of hibbingite, siderite, geothite, akaganeite, and mackinawite. High-temperature solubility tests were performed by soaking 2 g of the scale field sample with 20 cm3 of the NEFAS under static condition at 125 °C for different time periods (2, 6, 12, 18, and 24 h). The solubility results were compared with commercial solutions for iron sulfide scale removal such as hydrochloric acid (15 wt.%), glutamic acid diacetic acid (GLDA, 20 wt.%), and high density converters (HDC-3) under the same conditions. The corrosion test was performed at 125 °C for the developed solution after mixing with 2 wt.% corrosion inhibitor (CI) and 2 wt.% corrosion intensifier (CIN). The results were compared with HCl (15 wt.%) under the same conditions. NEFAS consists of 75 wt.% biodegradable acid at pH of 0.04. NEFAS achieved 83 g/L solubility of iron sulfide scale after 6 h at 125 °C under static conditions. The solubility efficiency was very close to 15 wt.% HCl after 24 h where the solubility was 82 and 83 g/L for NEFAS and HCl, respectability. HDC-3 and GLDA (20 wt.%) achieved a lower scale solubility; 18 g/L and 65 g/L respectively, after 24 h. NEFAS achieved a corrosion rate of 0.211 kg/m2 after adding the CI and and CIN compared to 0.808 kg/m2 for HCl. The new environmentally friendly biodegradable acid system provides efficient performance for the scale removal without harming the environment and causing any side effects to the operation. Full article
(This article belongs to the Special Issue Green and Sustainable Solutions for the Environment)
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