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Chemistry

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The document provides a standardized test practice workbook to help students prepare for exams. It covers topics from a Glencoe Chemistry textbook.

The workbook is designed to strengthen students' knowledge of the National Science Content Standards and provide additional chapter review for the Glencoe Chemistry textbook.

The workbook provides chapter review for Chapters 1 through 24 of the Glencoe Chemistry textbook.

Standardized Test Practice Student Edition

Features and Benets


Prepares students for standardized tests Covers objectives in the National Science Content Standards Includes answer sheet master and correlations to the National Science Content Standards

Copyright The McGraw-Hill Companies, Inc. All rights reserved. Permission is granted to reproduce material contained herein on the condition that such material be reproduced only for classroom use; and be provided to students, teachers, and families without charge; and be used solely in conjunction with Glencoe Chemistry: Matter and Change. Any other reproduction, for use or sale, is prohibited without written permission of the publisher. Send all inquiries to: Glencoe/McGraw-Hill 8787 Orion Place Columbus, OH 43240-4027 ISBN: 978-0-07-878759-1 MHID: 0-07-878759-9 Printed in the United States of America 1 2 3 4 5 6 7 8 9 045 11 10 09 08 07

CONTENTS
To the Student ......................................................................................iv Chapter 1: Introduction to Chemistry.................................................1 Chapter 2: Analyzing Data ...................................................................3 Chapter 3: MatterProperties and Changes .......................................5 Chapter 4: The Structure of the Atom .................................................7 Chapter 5: Electrons in Atoms .............................................................9 Chapter 6: The Periodic Table and Periodic Law ................................11 Chapter 7: Ionic Compounds and Metals ...........................................13 Chapter 8: Covalent Bonding...............................................................15 Chapter 9: Chemical Reactions ............................................................17 Chapter 10: The Mole ...........................................................................19 Chapter 11: Stoichiometry ...................................................................21 Chapter 12: States of Matter .................................................................23 Chapter 13: Gases ..................................................................................25 Chapter 14: Mixtures and Solutions ....................................................27 Chapter 15: Energy and Chemical Change .........................................29 Chapter 16: Reaction Rates...................................................................31 Chapter 17: Chemical Equilibrium ......................................................33 Chapter 18: Acids and Bases.................................................................35 Chapter 19: Redox Reactions ...............................................................37 Chapter 20: Electrochemistry ...............................................................39 Chapter 21: Hydrocarbons ...................................................................41 Chapter 22: Substituted Hydrocarbons and Their Reactions .............43 Chapter 23: The Chemistry of Life ......................................................45 Chapter 24: Nuclear Chemistry ............................................................47

iii

To the Student
Welcome to Chemistry Standardized Test Practice
This workbook is designed to strengthen your knowledge of the NSCS (National Science Content Standards) and provide additional chapter review of your Glencoe textbook, Chemistry: Matter and Change. For each chapter in the Glencoe textbook, Chemistry: Matter and Change, two pages of chapter review questions have been provided. These questions are designed to test your comprehension of chapter content and provide you with practice in the related skills specified in the NSCS. All of the questions are in a multiple-choice format. Your teacher will provide you with copies of an answer sheet to use when answering the questions. To keep track of your answers, you should always fill in the chapter number for the set of review questions you are answering. Every chapter has between eight and eleven review questions, so not every row of answer bubbles will always be used. Remember, this workbook should not be used as an alternative to reviewing the material in your textbook. This workbook will be of greatest advantage to you when used as a refresher after you have reviewed each chapter.

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

iv

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 1

Introduction TK Chapter Titleto Chemistry


Name: Date:

Use the label below to answer question 1.


Nutrition Facts Cereal (59 g)
Nutrient Fat Sodium Potassium Carbohydrate

Cereal with Nonfat Milk (250 mL)


2% 3% 12% 18%

A sample of water is being heated from 20 degrees Celsius to 30 degrees Celsius, and the temperature is recorded every two minutes. Which table would be most appropriate for recording the data?
Time (min) 0 2 4 6 8 10 Temp (C) Time (min) 20 22 24 26 28 30 Temp (C)

% Daily Value* % Daily Value* 2% 0% 6% 16%

*Percent Daily Values are based on a 2000-Calorie diet. Your daily values may be higher or lower, depending on your Calorie needs.

A
Temp (C) 0 2 4 6 8 10 Time (min) Temp (C) 20 22 24 26 28 30

B
Time (min)

According to this label, which nutrient is NOT found in cereal? A Fat

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

B C

Sodium Potassium

D Carbohydrate

4 2 For an experiment in which you are determining the freezing point of an unknown chemical, you record the temperature every minute for 20 minutes. In this example, time is the . A control B C dependent variable independent variable

During a laboratory activity, a student combined two solutions. In the laboratory report, the student wrote A yellow color appeared. The statement represents the students recorded . A conclusion B C observation hypothesis

D hypothesis

D theory

Chemistry Standardized Test Practice

Chemistry: Matter and Change

CHAPTER 1

Introduction to Chemistry, continued

Name:

Date:

In the chemistry lab, chemicals that you are finished working with should be . A poured into the sink B C returned to their original containers mixed together and dumped in a designated container

Which of the following is an example of applied research? A Colliding nuclei to discover the smallest particles that make up matter B C Using the results of DNA profiling as evidence in a court of law Sending spacecraft to Mars to search for other life forms

D disposed of as directed by your teacher

D Testing chemicals to replace CFCs in air conditioners and refrigerators

A scientist observes that the number of coyote sightings in suburban areas has increased over the last four years. In the process of forming a hypothesis as to why this number has increased, she would . A make a set of controlled observations B C decide which variables can be controlled

Test Tube 1

Test Tube 2

Test Tube 3

Test Tube 4

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

pose a tentative hypothesis explaining what was observed 20ml

10ml 20ml

15ml 20ml

20ml 20ml

D analyze data to explain what was observed

Sterile Beef Broth 7 Which of these pieces of laboratory glassware should NEVER be heated with a Bunsen burner? A Beaker B C Graduated cylinder Flask

Chemical X

A biochemist is performing an experiment to determine the effects of Chemical X on the growth of bacteria. Which is the control? A Test tube 1 B C Test tube 2 Test tube 3

D Test tube

D Test tube 4

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 2

Analyzing Data Chapter Title TK


Name: Date:

Use the graph below to answer questions 1 and 2.


Mass of Sodium Nitrate that Can Be Dissolved in 100 mL of Water

Based on the information in the graph, what is the approximate number of grams of sodium nitrate that can be dissolved at a temperature of 90C? A 150 g B C 155 g 160 g

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0 0 10 20 30 40 50 60 70 80 90 100


Temperature (C)

D 165 g

In chemistry lab, a student was instructed to find the density of a rectangular piece of aluminum. After careful measurement, he recorded a mass of 31.44 g and a volume of 11.7 cm3. Using the formula density = mass volume and a calculator, his answer was 2.6871794 g/cm3. Which of these is the correct answer to report for the density of the aluminum? A 2.7 g/cm3 B C 2.69 g/cm3 2.687 g/cm3

Mass (g)

D 2.68 g/cm3

According to these data, what is the approximate number of grams of sodium nitrate that can be dissolved at a temperature of 50C? A 95 g B C 105 g 115 g

D 125 g

Chemistry Standardized Test Practice

Chemistry: Matter and Change

CHAPTER 2

Analyzing Data, continued

Name:

Date:

Use the table below to answer questions 4 and 5.


Boiling Point Data Collected by Student Groups

What is the product of 2.324 centimeters and 1.11 centimeters expressed to the correct number of significant digits? A 2.58 cm2 B C 2.5780 cm2 2.5796 cm2

Group A Group B Group C Group D Trial 1 Trial 2 Trial 3 Average


4

79C 78C 83.5C 80.2C

82C 84.5C 79C 81.8C

75C 83C 78.5C 78.8C

80C 80.5C 79.5C 80C

D 2.57964 cm2

The table shows the data obtained by four groups of students during a lab investigation designed to determine the boiling point of methanol. The accepted value for the boiling point of methanol is 78.5C. Whose data was the most accurate? A Group A B C Group B Group C

A student told the class that she takes 500 mg of vitamin C every day. What is this mass expressed in grams? A 0.05 g B C 0.5 g 5.0 g
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D 500,000 g

D Group D

8 5 Whose data was the most precise? A Group A B C Group B Group C

Expressed to the correct number of significant digits, the sum of two masses is 445.2 grams. Which two masses produce this answer? A 210.10 g + 235.100 g B C 210.100 g + 235.10 g 210.1 g + 235.1 g

D Group D

D 210.10 g + 235.10 g

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 3

MatterProperties and Changes


Date:
4 In the periodic table, a series of elements that is arranged in a horizontal row is called a . A cluster B C family period

Name:
1 Choose a physical change from the following: A synthesizing B C dissolving burning

D decomposing

D group

Choose the property from the list that is not a physical property. A solubility B C color density

Distillation is a separation technique that . involves A using a porous barrier to separate a solid from a liquid B C separating dissolved substances based on their tendency to be drawn across a surface the formation of pure, solid particles of a substance from a solution containing the dissolved substance

D electronegativity

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Which of these phase changes does NOT involve the absorption of heat energy? A boiling B C condensation melting

D separating two or more liquids based on differences in their boiling points

D vaporization

Chemistry Standardized Test Practice

Chemistry: Matter and Change

CHAPTER 3

MatterProperties and Changes, continued

Name:

Date:

Use the diagram below to answer questions 6 and 7.


36.5 g 58.5 g sodium chloride ?g

Characteristics of a substance can be classified as physical properties or chemical properties. Which of the following is a chemical property? A Boils at 56C

40.0 g

HCl
hydrochloric acid

+ NaOH
sodium hydroxide

NaCl + H2O
water

B C

Tastes sour Has a density of 2.9 g/cm3

D Reacts with acid to produce hydrogen gas 6 The diagram shows a chemical equation representing a chemical reaction. The name and mass of each substance involved in the chemical reaction are also shown. Which of these are the reactants? A HCl and NaOH B C NaCl and H2O HCl and H2O

Use the diagrams below to answer question 9.

D NaOH and NaCl

Q
9

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Each diagram shows the particles of a substance in a closed container. Which of these shows the substance that is most easily compressed? A Q B C R S

According to the law of conservation of mass, mass is neither created nor destroyed during a chemical reaction. On the basis of this law, what mass of water was produced in this reaction? A 16.0 g B C 18.0 g 20.0 g

D T

D 22.0 g

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 4

The Structure of the Atom


Name: Date:

Use the diagram below to answer question 1.


+ + + + 92 p + +
146 n + + +

Use the chart below to answer questions 3 and 4.

proton (p) neutron (n)

++

2p 2n

Element Atomic Isotope # hydrogen 1 carbon 6 hydrogen-1 hydrogen-2 carbon-12 carbon-13 carbon-14 oxygen-16 oxygen-17 oxygen-18 copper-63 copper-65

% Atomic mass of isotope abundance 1.01 amu 2.01 amu 12.00 amu 13.00 amu 14.00 amu 15.99 amu 17.00 amu 18.00 amu 62.94 amu 64.93 amu 99.985 0.015 98.90 1.09 0.01 98.90 0.038 0.200 69.17 30.83

uranium-238 nucleus daughter (parent nucleus) nucleus

helium-4 nucleus (alpha particle)

The diagram above illustrates a nuclear reaction in which uranium-238 emits an alpha particle. How many protons and neutrons will the daughter nucleus have? A 90 p and 144 n B C 92 p and 142 n 92 p and 150 n 3

oxygen 8 copper 29

D 94 p and 148 n
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

The chart shows isotopes of some common elements. Which property is used to name the isotopes? A Atomic number B Atomic mass Mass number

In his latest dig, Dr. Butrell found an abundance of lead (Pb) in some ancient artifacts. What is the atomic number of lead? A 80 B C 81 82 4

D Percent natural occurrence

D 83

The atomic mass of an element is the weighted average mass of the isotopes of that element. Based on this definition, which of these does NOT show the correct atomic mass for an element? A Hydrogen: 1.008 amu B C Carbon: 12.011 amu Oxygen: 15.999 amu

D Copper: 63.017 amu

Chemistry Standardized Test Practice

Chemistry: Matter and Change

CHAPTER 4

The Structure of the Atom, continued

Name:

Date:

Use the diagram below to answer question 5.


alpha particle

Use the diagram below to answer question 7.


rays

nucleus of gold atom paths of alpha particles


+ +

rays rays

+ +

The diagram above shows the results of Rutherfords experiment in which he used a radioactive source to shoot alpha particles at a thin sheet of gold foil. Based on these results, what were Rutherfords conclusions? A Atoms are solid matter with positive and negative charges scattered throughout. B Atoms are solid, positively charged matter with negatively charged electrons scattered throughout. Atoms are mostly empty space with small, dense, positively charged centers.

lead shield

radioactive substance

The diagram above shows how alpha, beta, and gamma rays are affected by two electrically charged plates. Based on the paths the rays follow, what are the respective charges of alpha, beta, and gamma rays? A negative, positive, none B C positive, negative, none negative, none, positive

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D Atoms are mostly empty space with small, dense, negatively charged centers.

D positive, none, negative

An atom

Most of the mass of an atom is A in the electrons B C in the protons in the neutrons

A is much larger than its nucleus B C is much lighter than its nucleus is much denser than its nucleus

D has a higher positive charge than its nucleus

D in the nucleus

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 5

Electrons in Atoms
Name: Date:

Use the diagram below to answer question 1.


+ + + -

+ +

+ + +

+ - + +

+ + +

When a potassium compound is placed in a flame, energy is released and a violet color is produced. This energy release is due . to A the release of gamma rays from the nucleus B C the return of excited electrons to lower energy levels the movement of electrons to higher energy levels

+ -

electron
1

positive ion

D the absorption of photons by the electrons The diagram represents the arrangement of atoms in a metallic solid. Scientists believe that electrons in the outer energy levels of the bonding metallic atoms are free to move from one atom to the next. As a result, electricity will flow quite easily. This means that metals are good . A capacitors B
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

The Lewis dot structure for oxygen is shown below. What is the electron configuration for oxygen?

conductors resistors

D insulators A 1s22s2 B 2 The electron has . C 1s22s22p2 1s22s22p4

A high mass and is negatively charged B C high mass and is positively charged low mass and is positively charged

D 1s22s22p63s2

D low mass and is negatively charged

Chemistry Standardized Test Practice

Chemistry: Matter and Change

CHAPTER 5

Electrons in Atoms, continued

Name:

Date:

Which of these is the ground-state electron configuration for an atom of fluorine (atomic number = 9)? A 1s22s2 B C 1s22s22p3 1s22s22p4

Which of these orbital diagrams represents a chlorine atom in the ground state? Chlorine has an atomic number of 17. A

1s 2s

2p

D 1s22s22p5

1s 2s

2p

1s 2s
6 Niels Bohrs model of the atom helped to explain . A particles passing through foil B C spectral lines the formation of isotopes D

2p

3s

3p

1s 2s

2p

3s

3p

D the properties of hydrogen


Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

The arrangement of electrons in an atom of an element determines the chemical properties of that element. Our present-day understanding of how electrons are arranged in an atom is the result of all of these scientific contributions EXCEPT . A Rutherfords gold foil experiment that proved the existence of the nucleus. B C Bohrs orbits that explained hydrogens quantized energy states. De Broglies equation that led to thinking of electrons as both particles and waves.

D Schrdingers wave equation that predicted atomic orbitals.

10

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 6

The Periodic Table and Periodic Law


Date:

Name:

Use the graph below to answer questions 13.

Why are there no electronegativity values for the elements with atomic numbers 2, 10, and 18? A The noble gases form very few compounds because they are gases. B C The noble gases form very few compounds because they are rare. The noble gases form very few compounds because they are radioactive.

5
Electronegativity

4 3 2 1 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Atomic Number

D The noble gases form very few compounds because their electron configurations are very stable.

The electronegativity of an element indicates the relative ability of its atoms to attract electrons to form chemical bonds. According to the graph, as you move across a period in the periodic table . A the atomic number increases and the electronegativity increases B C the atomic number increases and the electronegativity decreases the atomic number decreases and the electronegativity increases

Metal is to malleable as nonmetal is to . A brittle B C solid dull

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D gaseous

D the atomic number decreases and the electronegativity decreases 5 Elements in the same group of the periodic table have similar chemical properties because they have . A the same number of orbitals B C the same number of valence electrons atomic numbers that are multiples of each other

According to the graph, which of the following elements has the strongest attraction for electrons? A aluminum (atomic number = 13) B C boron (atomic number = 5) oxygen (atomic number = 8)

D the same principal energy levels

D sulfur (atomic number = 16)

Chemistry Standardized Test Practice

Chemistry: Matter and Change

11

CHAPTER 6

The Periodic Table and Periodic Law, continued

Name:

Date:

Use the graph below to answer questions 6 and 7.


600 550 500 450 400 350 300 250 200 150 100 50 0 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Mendeleev left blank spaces in his periodic table where he thought elements that had not yet been discovered should go. He was able to predict the properties of these elements by . A studying the spectra of stars that contained them B C testing their properties such as melting point, density, and valence noting periodic trends in the properties of known elements that surrounded the blank spaces in the periodic table

Ionization Energy (kcal/mol)

Atomic Number

D studying the new elements produced by radioactive decay

The graph shows the first ionization energy for elements with atomic numbers 320. According to the graph, what is the approximate first ionization energy for the element with atomic number 16? A 300 kcal/mol B C 250 kcal/mol 240 kcal/mol

Use the diagram below to answer question 9.


PERIODIC TABLE
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

18 2 13 14 15 16 17

D 190 kcal/mol 7 Elements with atomic numbers 4, 12, and 20 are in the same group in the periodic table. As you move down a group . A the principal energy level increases and the first ionization energy increases B C the principal energy level increases and the first ionization energy decreases the principal energy level decreases and the first ionization energy increases 9

Y Y Y Y Y Y Y

Y Y Y Y Y Y

Z Z Z Z

W W Z Z Z Z Z Z Z Z Z W Z Z Z Z Z Z Z Z Z W Z Z Z Z Z Z Z Z Z W Z Z
4 5 6 7 8 9 10 11 12

W W W W W

W W W W W

W W W W W

W W W W W

Y W W W W W

X X X X X X X X X X X X X X X X X X X X X X X X X X X X

D the principal energy level decreases and the first ionization energy decreases

The periodic table has an unusual shape because it is divided into blocks representing the energy sublevel being filled with valence electrons. In the periodic table shown in the diagram, which sequence lists these blocks in s-p-d-f order? A Y, W, Z, X B C W, Y, X, Z Y, Z, W, X

D X, Y, Z, W 12
Chemistry: Matter and Change Chemistry Standardized Test Practice

CHAPTER 7

Ionic Compounds and Metals


Date:

Name:

Which of these is NOT a cation? A NH4+ B C Cl Mg2+

Use the table below to answer question 4.


Compound NaCl KBr LiF MgO
4

D K+

Lattice Energy (kJ/mol) 769 671 1030 3795

When atoms of sodium (Na) and chlorine (Cl) combine to form salt (NaCl), the Na+ ion is smaller than the Na atom, while the Cl ion is larger than the Cl atom. Why? A The Na and Cl atoms both lost electrons. B C The Na and Cl atoms both gained electrons. The Na atom lost an electron, while the Cl atom gained an electron.

The table shows the lattice energy for some ionic compounds. Based on these data, which of these compounds would require the most energy to separate the bonded ions? A NaCl B C KBr LiF

D MgO

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D The Na atom gained an electron, while the Cl atom lost an electron. 5 A metallic bond is formed between A a metal atom and a hydrogen atom 3 An atom with the electron configuration 1s22s22p6 3s23p64s2 is most likely A a metal that forms a positive ion B C a metal that forms a negative ion a nonmetal that forms a positive ion B . C a metal atom and a nonmetallic atom a metal atom and a noble gas .

D two metal atoms

D a nonmetal that forms a negative ion

Chemistry Standardized Test Practice

Chemistry: Matter and Change

13

CHAPTER 7

Ionic Compounds and Metals, continued

Name:

Date:

Use the diagram below to answer question 6.

Salts are compounds that form a crystal lattice. Which types of bonds are responsible for this lattice formation. A covalent B C hydrogen ionic

D polar

Ionic Compound

What is the chemical formula for a compound formed from calcium ions (Ca2+) and chloride ions (Cl)? A CaCl B C Ca2Cl CaCl2
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

This apparatus was most likely designed to show that . A the formation of an ionic compound is an exothermic reaction B C ionic compounds are electrolytes all molecules have an electrical charge 9

D Ca2Cl2

D water is a good conductor of electricity

Most transition metals have more than one oxidation number because . A they may lose d electrons when forming positive ions B C they may lose f electrons when forming ions their electron arrangements are unstable

D their electrons are closer to the nucleus

14

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 8

Covalent Bonding
Name: Date:

A molecule is formed when two or more atoms form a covalent bond. According to this definition, which of these is NOT a molecule? A NaCl B C H2 HCl

In the polyatomic ion NH4+, the formation of a coordinate covalent bond between nitrogen and hydrogen involves . A hydrogen transferring a pair of electrons to nitrogen B C nitrogen transferring a pair of electrons to hydrogen hydrogen donating a pair of electrons to be shared with nitrogen

D NH3

D nitrogen donating a pair of electrons to be shared with hydrogen

Use the table below to answer question 2.


Number Number of Atoms Prefix of Atoms Prefix 1 2 3 4 5
2

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

monoditritetrapenta-

6 7 8 9 10

hexaheptaoctanonadeca-

When hydrogen and fluorine combine, a polar covalent bond is formed. Which of these formulas is the best way to express this relationship? A B

HF

The table shows some of the prefixes used to name binary covalent compounds. What name would be given to the compound PBr5? A Phosphorus tetrabromide B C Monophosphorus pentabromide Phosphorus pentabromide

+ H F
H F
HF

C D

D Phosphorus hexabromide

Chemistry Standardized Test Practice

Chemistry: Matter and Change

15

CHAPTER 8

Covalent Bonding, continued

Name:

Date:

At room temperature, iodine (I2) is a solid and bromine (Br2) is a liquid. These molecules have different melting points because of stronger . A covalent bonds in iodine B C covalent bonds in bromine intermolecular forces in iodine

Which of these is the chemical formula for sulfurous acid? A H2S B C H2SO3 H2SO4

D H2S

D intermolecular forces in bromine

Use the diagram below to answer question 6.


Normal 1s 2s 1s 2p Hybridized

The bond that holds two fluorine atoms together in an F2 molecule would be classified as nonpolar covalent because . A both atoms are different and the difference in electronegativity is large B C both atoms are different and the difference in electronegativity is zero both atoms are the same and the difference in electronegativity is large
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

The diagram shows the electron configuration of a carbon atom and the rearrangement of electrons to form four new identical orbitals in a hybridized carbon atom. This type of hybrid orbital is called an . A s2 orbital B C sp orbital sp2 orbital

D both atoms are the same and the difference in electronegativity is zero

D sp3 orbital

16

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 9

Chemical Reactions
Name: Date:

Refer to the diagram below to answer questions 16.


Zn(s) + HCl(aq) ZnCl2(aq) + H2(g)

The chemical reaction represented by the equation would be classified as a A synthesis reaction B C decomposition reaction single-replacement reaction

The skeleton equation represents a chemical reaction. Which of these are the reactants? A Zn and HCl B C ZnCl2 and H2 HCl and ZnCl2 4

D double-replacement reaction

D Zn and H2

HCl(aq) and ZnCl2(aq) both exist as ions in aqueous solutions. Which of these is the complete ionic equation for this chemical reaction? A Zn(aq) + 2H+(aq) + Cl(aq) Zn2+(aq) + Cl(aq) + H2(g)

2
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

The skeleton equation for this chemical reaction violates the law of conservation of mass. Which of these is the correct balanced chemical equation? A 2Zn(s) + HCl(aq) 2ZnCl2(aq) + H2(g) B C Zn(s) + 2HCl(aq) ZnCl2(aq) + 2H2(g) Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g)

B C

Zn(s) + 2H+(aq) + 2Cl(aq) Zn2+(aq) + 2Cl(aq) + H2(g) 2Zn(s) + H+(aq) + Cl(aq) 2Zn2+(aq) + Cl(aq) + H2(g)

D Zn(aq) + 2H+(aq) + 2Cl(aq) Zn2+(s) + Cl(aq) + 2H2(g)

D 2Zn(s) + 2HCl(aq) 2ZnCl2(aq) + H2(g)

Chemistry Standardized Test Practice

Chemistry: Matter and Change

17

CHAPTER 9

Chemical Reactions, continued

Name:

Date:

Which of these is a spectator ion in this chemical reaction? A Cl(aq) B C H+(aq) H2(g)

Use the diagram below to answer question 8.


K Ca Na Mg Al Zn Fe Pb H Cu Ag

D Zn2+(aq)

Increasing ease of discharge

OH I Br Cl NO3 SO4

Increasing ease of discharge

Which of these is the net ionic equation for this chemical reaction? A Zn(s) + 2Cl(aq) Zn2+(aq) + 2Cl(aq) B C Zn2+(aq) + 2H+(aq) Zn(s) + H2(g) 2H+(aq) + 2Cl(aq) 2HCl(aq) 8 The diagram shows the activity series of some metals (left) and nonmetals (right). A student set up four beakers, each containing 100 mL of dilute hydrochloric acid (HCl[aq]). She added 5 g of a metal to each beaker in this order: aluminum (Al), copper (Cu), sodium (Na), and zinc (Zn). Which metal will NOT react with the acid?
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D Zn(s) + 2H+(aq) Zn2+(aq) + H2(g)

A Aluminum B 7 Which of these does NOT describe evidence of a chemical reaction? A An iron nail changes to a brownish-orange color. B C An ice cube melts into liquid water. An antacid tablet produces bubbles of gas when placed in water. C Copper Sodium

D Zinc

D A piece of zinc raises the temperature of an acid upon mixing.

18

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 10

The Mole
Name: Date:

How many moles of nitrogen atoms are contained in one mole of Ba(NO3)2? A 1 B C 2 6

Mole is to atom as gram is to A amu B C mass molecule

D particle

D 9

5 2 The molecular formula of a compound is X6Y3. What is the empirical formula for this compound? A X6Y B C
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

What is the total number of atoms contained in 2.00 moles of helium? A 15.999 B C 32.0 6.02 1023

XY3 X2Y

D 1.20 1024

D XY2

6 3 Zinc is used as a coating on iron and steel to prevent corrosion. What is the mass, in grams, of 0.0650 mol Zn? A 3.25 g B C 3.90 g 3.94 g

A compound has the formula MgSO47H2O. Its chemical name is . A aqueous magnesium sulfate B C magnesium sulfate pentahydrate magnesium sulfate heptahydrate

D magnesium sulfate decahydrate

D 4.25 g

Chemistry Standardized Test Practice

Chemistry: Matter and Change

19

CHAPTER 10

The Mole, continued

Name:

Date:

Indium (In) is a relatively rare element that never occurs as a free metal. It is usually found in a compound that contains 70.48% In and 29.52% S. What is the empirical formula for this compound? A InS B C In2S3 In3S5

Potassium nitrate, also known as saltpeter, is used in matches. What is the percent by mass of potassium (K) in potassium nitrate (KNO3)? A 38.67% B C 45.94% 55.71%

D 56.58 %

D In6S9

10 8 A student measures 10.0 g of hydrated sodium carbonate (Na2CO3xH2O) and places it in a crucible. After heating, 3.7 g of anhydrous sodium carbonate (Na2CO3) remains. What is the formula for the hydrate? A Na2CO32H2O B C Na2CO35H2O Na2CO38H2O

Baking soda is the common name for sodium hydrogen carbonate (NaHCO3). What is the mass in grams of 2.75 moles of sodium hydrogen carbonate? A 63.2 g B C 84 g 210 g
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D 231 g

D Na2CO310H2O 11 A mole of of A 12 kg B C 12 g 12 amu


12 C 6

atoms will have a total mass

D 6 amu

20

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 11

Stoichiometry
Name: Date:

Number of Mole Ratios

A chemist is about to synthesize tetraphosphorus decoxide by combining X grams of phosphorus with sufficient oxygen to react completely with the phosphorus. If he wants to determine the amount of tetraphosphorus decoxide that will be produced, which of the following does not need to be answered? A What is the balanced chemical equation for this reaction? B C What are the number of moles for each reactant? What is the mole ratio of the two reactants?

Use the graph below to answer question 4.

Number of Mole Ratios per Number of Reactants and Products


100 80 60 40 20 0

D Which is the limiting reactant and which is the excess reactant? 4

3 5 6 7 8 4 Number of Species in Equation

2
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Three atoms of iron (Fe) are to be combined with four molecules of oxygen (O2). How many total iron atoms and oxygen molecules will be combined during the formation of Fe3O4? A 3 B C 4 7 5

This graph shows the number of mole ratios that can be determined given the number of reactants and products of a chemical reaction. If this trend continues, how many mole ratios can be formed with a chemical reaction that has a sum of eight reactants and products? A 54 B C 56 58

D 60 Chemists normally use an excess of one reactant in a chemical reaction because . A the reaction will continue until all of the limiting reactant is consumed B C the reaction will continue until all of the excess reactant is consumed reactions do not take place unless there are unequal amounts of reactants

D 10

2Al(s) + 3Br2(l)
3

2AlBr3(s)

The above equation represents the reaction of aluminum and bromine to form aluminum bromide. Which of these is NOT a mole ratio for this reaction? A 2 mol Al : 3 mol Br2 B C 2 mol AlBr3 : 2 mol AlBr3 3 mol Br2 : 2 mol Al

D reactions occur too quickly if equal amounts of reactants are used

D 2 mol AlBr3 : 3 mol Br2


Chemistry Standardized Test Practice Chemistry: Matter and Change

21

CHAPTER 11

Stoichiometry, continued

Name:

Date:

Use the graph below to answer question 6.

Which piece of information about an element on the periodic table is most necessary in order to compute the mass of a given molecule? A The symbol of the elements in the molecule B The atomic number of each element in the molecule The number of electrons at each energy level for each element

final yield

Production Yield

final yield

Time Theoretical Yield

D The average atomic mass of one atom of each element in the molecule
Actual Yield

According to this graph, during a chemical reaction . A the actual yield is higher than the theoretical yield B C the calculated percent yield of product will be less than 100% the theoretical and actual yields are equal

Three moles of carbon dioxide are produced when one mole of propane gas is burned. How many moles of carbon dioxide will be produced if 30 moles of propane gas are burned? A 10 moles B C 30 moles 90 moles
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D the percent yield of product is more than 100% 10

D 120 moles In the movie The Wacky World of Chemistry, a chemist wrote down the following equation on a chalkboard: Ti + C + 2Cl2 TiCl3 + C. This equation is NOT correct because . A the titanium atoms are not equal on both sides of the equation B C there are not enough chlorine atoms on the right side of the equation the carbon atoms are equal on both sides of the equation

Stoichiometry is the study of quantitative relationships between amounts of A the reactants and products of a chemical reaction relative to time B C the products of a chemical reaction only the reactants and products of a chemical reaction

D the reactants of a chemical reaction only

D the right side of the equation should have a greater number of atoms than the left side

22

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 12

States of Matter
Name: Date:

Which of the following is defined as a measure of the average kinetic energy of particles in a given sample of matter? A velocity B C diffusion temperature

Marta and her father often skip stones across a pond. What type of intermolecular force creates the surface tension that allows the stones to skip? A metallic forces B C dipoledipole forces dispersion forces

D partial pressure

D hydrogen bonding

Energy release is to condensation as energy . input is to A deposition B C sublimation freezing

For a substance to reach its boiling point, a substantial amount of energy must be added. The boiling point occurs when the . A temperature increases B C vapor pressure equals atmospheric pressure particle velocity equals the boiling point

D dispersion
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D vapor pressure reaches the critical point

Which of the following is NOT a characteristic of liquids? A no significant attraction between particles B C less fluid than gases more dense than gases

During evaporation, certain liquid molecules become vapor molecules because they have greater than average . A lattice energy B C viscosity kinetic energy

D exhibits viscosity

D fluidity

Chemistry Standardized Test Practice

Chemistry: Matter and Change

23

CHAPTER 12

States of Matter, continued

Name:

Date:

Ionic solids such as sodium chloride are easily shattered, but metallic solids such as copper can be easily bent and shaped. This difference occurs because . A ionic solids have low melting points B C atoms in metallic solids are not arranged in a regular pattern covalent bonding between sodium and chlorine keeps the solid rigid

Use the diagram below to answer question 10.

s team

liquid water

ice

D mobile electrons in the copper can shift without disrupting the solid 10 The diagram shows how liquid water is transformed into a solid and a vapor. Which of these labels should be placed above each of the arrows in the diagram? A Energy added over the gray arrow; energy released over the black arrow B Particle velocity decreased over the gray arrow; particle velocity increased over the black arrow Energy released over the gray arrow; energy added over the black arrow

The process of hydrogen bonding involves hydrogen atoms bonding with . A either oxygen, carbon, or silicon B C either nitrogen, boron, or hydrogen either fluorine, oxygen, or nitrogen

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D either fluorine, hydrogen, or sodium

D Density increased over the gray arrow; density decreased over the black arrow

Diffusion is the term used to describe the movement of one material through another. The diffusion of gases can be explained by . A relative molar masses B C differences in volume evaporation

D random motion

24

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 13

Gases
Name: Date:

Charless Law explains the relationship between the temperature and volume of a gas. Which graph best represents this relationship?
Volume

You are given a balloon filled with a known volume of helium gas. You place the balloon inside a freezer for an hour. How will the balloon look after being in the freezer?

Temperature (K)
Volume

Temperature (K)
Volume

Temperature (K)
Volume

C
Temperature (K)

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D 2 Which of these decreases as a given volume of gas increases? A Number of gas particles B C Temperature Pressure

D Kinetic energy

Chemistry Standardized Test Practice

Chemistry: Matter and Change

25

CHAPTER 13

Gases, continued

Name:

Date:

Physicians can use liquid nitrogen to freeze and destroy warts and other skin growths. Knowing the assumptions of the universal gas law, this should surprise you most because . A if a gas can liquefy, that would imply that gases experience intermolecular forces B C all gases are volatile and cant be used indoors gas particles are too small to be condensed

Which of the following is a gasgas behavior relationship? A Helium gas is heated and its volume increases. B C Oxygen gas is compressed and its temperature increases. Nitrogen gas is placed in a container and the molecules settle to the bottom.

D if a gas can freeze, that would imply that gases can be kept at cold temperatures

D Hydrogen gas is cooled and its pressure increases.

7 5 David has two containers of two different gases at the same temperature and pressure. David could assume all of following EXCEPT . A when the temperature is increased, the volume of both containers will increase B C when the pressure is increased, the volume of both containers will decrease both containers contain the same number of gas particles

Which question cannot be answered scientifically? A How many particles do two gases at the same temperature and pressure contain? B C What happens to a gas at standard temperature and pressure? How does a gas react when heated to 100C?
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D What happens to a sample of gas at absolute zero?

D when the pressure is decreased, the temperature of both containers will increase

26

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 14

Mixtures and Solutions


Name: Date:

A beaker contains a saturated solution of water and NaCl at 25C. How could the amount of NaCl that can be dissolved in the solution be increased? A Add more NaCl. B C Heat the solution. Add a second salt.

Suppose 8 mol of solute is dissolved in 2 L of solution. What is the molarity of the solution? A 2M B C 4M 8M

D 16M

D Transfer the solution to a larger beaker.

Use the table below to answer question 5.


2 Which of these decreases as the amount of solute particles in a solution increases? A Boiling point B C
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Solute Effect on Waters Boiling Point Solute NaCl KMnO4 Na2CO3 C6H12O6 5 Quantity Boiling point elevation 1 mol 1.024C 1 mol 1.024C 1 mol 1.536C 1 mol 1.512C

Osmotic pressure Freezing point

D Molality

Breaking a large solid into smaller pieces increases its rate of solvation in a solvent. This process accelerates the rate because . A greater surface area increases the likelihood of collisions B C it makes the solid immiscible greater surface area decreases the likelihood of collisions

The table above shows the effects of various solutes in a given volume of water. Without knowing the actual values, which of these is the most likely reason that the Na2CO3 will cause the greatest boiling point elevation? A Na2CO3 is the only solute that exhibits the Tyndall effect. B C Na2CO3 produces the smallest number of moles in solution. Na2CO3 has the greatest heat of enthalpy.

D Na2CO3 produces the largest number of solute particles in solution.

D it creates an adiabatic environment

Chemistry Standardized Test Practice

Chemistry: Matter and Change

27

CHAPTER 14

Mixtures and Solutions, continued

Name:

Date:

Use the table below to answer questions 6 and 7.


Mass of Sodium Nitrate that Can Be Dissolved in 100 mL of Water Temperature (C) 0 20 40 60 80 Mass (g) 74 88 105 125 148

Janet wants to dissolve carbon dioxide in water. The rate of solvation could be most improved by . A decreasing the temperature and increasing the pressure B C increasing the temperature and decreasing the pressure decreasing the temperature and decreasing the pressure

D increasing the temperature and increasing the pressure

The table shows that the amount of sodium nitrate that can be dissolved in water . A increases as the temperature increases B C increases as the surface area of molecules of sodium nitrate increases decreases as molarity increases 9 Which of the following is required in order for a solute to achieve maximum solubility in a solvent? A The crystallization rate must exceed the rate of solvation. B C The colligative properties of the solute must be at a maximum. The solvation rate must exceed the rate of crystallization.
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D decreases as the pressure increases

According to these data, approximately how many grams of sodium nitrate can be dissolved at 70 degrees Celsius? A 115 g B C 125 g 131 g

D Seed crystals must be added to the solvent.

D 137 g

28

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 15

Energy and Chemical Change


Name: Date:

A student performed the following experiment. He drew and labeled the graph below based on his results. Which best describes his results?
Chemical Reaction Diagram
Activation energy (Methane + O2) Heat of reaction (CO2 + H2O)

Use the equation below to answer question 3.

H 2 O(l)

H 2 O(g) Hvap = + 40.7 kJ

The equation shows the change in enthalpy when one mole of liquid water vaporizes into water vapor. This is called the molar heat of vaporization. Given this information, which of these is the proper value for the molar heat of condensation? A Hcond = -40.7 kJ B C Hcond = 0 kJ Hcond = -571.6 kJ

A The reaction is endothermic. B C The reaction is exothermic. The reaction requires no energy.

D The reaction shows no entropy.

D Hcond = +571.6 kJ

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

When you eat a slice of pizza, the crust is often less hot than the toppings or sauce. This most likely occurs because the toppings and sauce have a greater . A molar enthalpy of formation B C specific heat heat of fusion

Which of these is required for a reaction to be called exothermic? A The enthalpy of the reactants must be less than that of the products. B C The sign of the change in enthalpy for the reaction must be positive. The enthalpy of the products must be less than that of the reactants.

D mass

D Heat must flow from the surroundings into the system.

Chemistry Standardized Test Practice

Chemistry: Matter and Change

29

CHAPTER 15

Energy and Chemical Change, continued

Name:
5 Fusion, or melting, is an endothermic process because it . A requires heat to be transferred from system to surroundings and has a H that is negative B requires heat to be transferred from surroundings to system and has a H that is positive involves a decrease in entropy 8

Date:
The rate of a reaction can be described by . calculating A evidence of reactant depletion B C evidence of product formation the increase in the concentration of the reactants with time

D the increase in the concentration of the products with time

D involves a decrease in kinetic energy

9 6 How does a catalyst increase the rate of a chemical reaction? A by increasing the concentrations of the reactants B C by increasing the speed of the molecules by lowering the energy of the products

The reaction rate of a substance is shown below. What does this graph illustrate?
Reaction Rate and Temperature
40 35
Relative reaction rate (330 K,32)

30 25
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

20 15 10 5
(290 K,2)

(320 K,16) (310 K,8)

D by lowering the activation energy

0 280

290

300

310

320

330

Temperature (K)

Professor Bothwell determined from the wrapper the number of calories in a candy bar. He then burned the entire candy bar and measured the amount of heat released. His experiment was most likely designed to demonstrate . A the law of conservation of matter B C the law of disorder the law of conservation of energy

A As the concentration increases, the reaction rate decreases. B C As the temperature increases, the reaction rate increases. As the pressure increases, the reaction rate decreases.

D The reaction rate stays constant.

D the law of constant composition

30

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 16

Reaction Rates
Name:
1 Which of these is required to calculate the rate of a reaction? A The change in enthalpy over time for the reaction Energy B C The time it takes for the reaction to go halfway to completion The change in concentration of either the product or reactant over time
Reactants

Date: Use the diagram below to answer question 4.

Products

D The change in temperature for the reaction over time 4

Reaction Progress

How would the addition of a catalyst affect this reaction? A The presence of a catalyst would decrease the activation energy. B C The catalyst would increase the activation energy. The presence of a catalyst would make the reaction more spontaneous.

Which of these decreases as the activation energy for a reaction increases? A Number of inactivated complexes B Entropy Amount of reactants

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D Reaction rate

D The catalyst would be consumed during the reaction and make more product.

The collision theory explains why reactions occur and how certain factors increase or decrease the rate of reaction. The collision theory involves all . of the following EXCEPT that A reacting substances must collide with the correct orientation B C reacting substances must collide reacting substances must collide spontaneously

At equilibrium in a saturated solution of sodium chloride . A the salt crystal has stopped dissolving B C the ions in solution have stopped crystallizing the rate of solvation is greater than the rate of crystallization

D the rate of solvation equals the rate of crystallization

D reacting substances must collide with enough energy to form the activated complex

Chemistry Standardized Test Practice

Chemistry: Matter and Change

31

CHAPTER 16

Reaction Rates, continued

Name: Use the formula below to answer question 6.

Date: Use the table below to answer question 9.


Sample size 10 g Sugar cube 15 g Sugar crys tals 25 g Sugar cube 20 g Sugar crys tals

Rate = k [NO]2[Cl2]
Student
6 The formula shows the rate law for a certain reaction. Which of the following gives the correct result when the concentration of NO is doubled? A The reaction rate is unaffected. B C The reaction rate doubles. The reaction rate triples.

Temperature (C) 0C 30C 100C 95C

Hema Aaron Nikki Erick

D The reaction rate quadruples.

9 7 The rate of reaction can never proceed faster than that of the rate-determining step because . A the rate-determining step must exceed the rate of reaction B C all rate-determining steps require a catalyst the rate-determining step is always the first step in any reaction

The table above shows the various conditions used when four students dissolved sugar. The student whose sample will dissolve the fastest is most likely . A Hema B C Aaron
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Nikki

D Erick

D the rate of reaction is always limited by the slowest overall step 10 Which of the following would NOT increase the rate of a reaction? A an increase in the concentration of reactants 8 Reactions may be classified with an overall order, as well as orders with respect to the individual substances reacting. Which of these is classified as third order overall? A Rate = k[A]2[B][C] B C Rate = k[A]3[B] Rate = k[A]2[B] B C the removal of a catalyst an increase in solvent volume

D an increase in temperature

D Rate = k[B]3[C]

32

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 17

Chemical Equilibrium
Name:
1 Which statement most accurately describes the state of a reaction after it has reached chemical equilibrium? A At chemical equilibrium, equal amounts of products and reactants are present. B C The forward and reverse reactions are producing equal concentrations. The forward and reverse reactions are occurring at equal rates.

Date: Use the equation below to answer question 3.

2SO 2(g) + O 2(g)

2SO 3(g) Hrxn = 198 kJ

The reaction above is exothermic. To produce less product, what experimental change would be most effective? A Decrease volume B C Decrease the temperature Increase pressure

D At equilibrium, the reaction is continuing in either the forward or reverse direction.

D Increase the temperature

Use the equation below to answer question 2.


Cu(OH) 2 (s)
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Cu 2+ (aq) + 2OH(aq)

Use the table below to answer question 4.


Solubility Product Constants at 298K Compound PbBr 2 Ag 2 S PbCl2 MgCO3
4

Which of these is the correct way to express the equilibrium constant expression for the reaction above? A K = [Cu2+][OH]2 B C K = [Cu2+][OH]2 [Cu(OH)2] K = [Cu2+][OH2]

Ksp Value 6.6 x 106 8.0 x 1051 1.7 x 105 6.8 x 106

D K = [Cu2+][OH2] [Cu(OH2)]

According to this table, which compound has the greatest solubility in pure water? A PbBr2 B C Ag2S PbCl2

D MgCO3

Chemistry Standardized Test Practice

Chemistry: Matter and Change

33

CHAPTER 17

Reaction Rates, continued

Name:

Date:

Ksp values can be compared with the ion product, Qsp, to determine whether or not a precipitate will form for a given solution. How would you describe a solution of AgCl with Qsp = 1.4 1010 and Ksp = 1.8 1010? A Supersaturated B C Unsaturated Saturated

Le Chteliers principle demonstrates the effect of disturbances on chemical equilibrium. Le Chteliers principle can also help predict whether or not disturbances will affect the equilibrium constant, Keq. None of these will affect the equilibrium constant EXCEPT the . A addition of more product B C decrease in volume increase in pressure

D Precipitated

D increase in temperature

The common ion effect alters the amount of solid that will dissociate in solution. The addition of solid silver chromate to an aqueous solution of potassium chromate will affect the silver chromates solubility because . A solids are always subject to the common ion effect in solution B the ion chromate is common to both solutions and will decrease silver chromates solubility the combination of two common metals, silver and potassium, will decrease solubility

Use the equation below to answer question 8.


N2(g) + 3H2(g)
8

2NH3(g)
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Which experimental disturbance will produce more NH3 (ammonia) in the above reaction? A Decrease in pressure B C Addition of more ammonia Decrease in volume

D the ion chromate is common to both solutions and will increase solubility

D Addition of a catalyst

34

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 18

Acids and Bases


Name: Date:

Which of these decreases as the pH of a solution increases? A The basicity of a solution B C Number of hydrogen ions The value of Kw

Strong acids or bases make the best electrolytes because they . A do not ionize in solution B C react in an equilibrating manner ionize completely in solution

D Number of hydroxide ions

D have extremely small ionization constants

Acid rain is extremely harmful to the environment. All of the following are ways that acid rain affects the environment EXCEPT . A eroding buildings B C promoting hydroxide deposits leaching mineral ions from the soil

The neutralization of a strong acid by a strong . base always involves the products A water and a salt B C an anion and a salt water and an ion

D a weak acid and a strong base

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D altering biological molecules necessary for aquatic life

Black coffee has a pH of approximately 5.0. What is the pOH of black coffee? A 7.0 B C 19.0 3.0

A Brnsted-Lowry base is to a hydrogen-ion acceptor as a Brnsted-Lowry acid is to . A a hydroxide-ion producer

D 9.0 B C a hydroxide-ion donor an electron-pair donor

D a hydrogen-ion donor

Chemistry Standardized Test Practice

Chemistry: Matter and Change

35

CHAPTER 18

Acids and Bases, continued

Name:

Date:

Use the table below to answer question 7.


pH of Various Solutions Solution Gas tric Juice Vinegar Human Blood Baking Soda 7 pH 1.5 2.8 7.4 8.5

Use the equation below to answer question 9.


HBr(aq) + NH3(aq)
9

NH4+(aq) + Br(aq)

According to this chemical equation, which of the following represents a conjugate acidbase pair? A NH4+(aq) and Br(aq)

The pH scale is used to rank the hydronium ion concentration of a given substance. Which of the following sequences shows these solutions from least acidic to most acidic? A Gastric juice, vinegar, human blood, baking soda B C Baking soda, human blood, vinegar, gastric juice Baking soda, vinegar, human blood, gastric juice 10

B C

HBr(aq) and NH4+(aq) NH3(aq) and HBr(aq)

D HBr(aq) and Br(aq)

Which of the following does NOT represent a balanced equation for an acidbase neutralization reaction? A HCl + NaOH NaCl + H2O B C CH4 + 2O2 CO2 + 2H2O 2HBr + Ca(OH)2 2H2O + CaBr2

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D Gastric juice, human blood, vinegar, baking soda

D Mg(OH)2 + 2HCl MgCl2 + 2H2O 8 Buffers in your body are constantly working to prevent harmful increases or decreases in the pH of your blood, urine, and other fluids. In order to resist such changes, a buffer is composed of . A a strong acid and a strong base B C a weak acid and its conjugate base, or a weak base and its conjugate acid a strong base and a weak acid

D a strong acid and a weak base

36

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 19

Redox Reactions
Name: Date:

Which of the following characterizes the oxidationreduction relationship? A Element losing electrons is losing oxygen, element gaining electrons is gaining oxygen. B C Element gaining electrons is oxidized, element losing electrons is reduced. Element gaining electrons is losing hydrogen, element losing electrons is gaining hydrogen.

What kind of process is represented by this reaction? Na Na+ + e A oxidation B C reduction redox

D neutralization

D Element losing electrons is oxidized, element gaining electrons is reduced.

Use the equation below to answer question 4.


2Mg(s) + O2(g) 2MgO(s)

Use the equation below to answer question 2.


Zn(s)
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Zn2+(aq) + 2e

The chemical equation above shows a redox reaction. Which of these best represents what has occurred? A Magnesium is the oxidizing agent and was reduced. B C Oxygen is the reducing agent and was oxidized. Magnesium is the reducing agent and was oxidized.

The chemical equation above shows a corrosive half-reaction for zinc. Which of these best represents what is occurring? A Zinc is reduced and is acting as the oxidizing agent. B C Zinc is oxidized and is losing electrons. Zinc is reduced and is losing electrons.

D Oxygen is the oxidizing agent and was oxidized.

D Zinc is oxidized and is gaining electrons.

Chemistry Standardized Test Practice

Chemistry: Matter and Change

37

CHAPTER 19

Redox Reactions, continued

Name:

Date:

Use the equation below to answer question 5.


Si(s) + 2Cl 2 (g) SiCl 4 (l)

What is the reduction half-reaction of this redox reaction? Ni + Cl2 NiCl2 A Ni + e Ni+ B Cl2 + 2e 2Cl Ni Ni+ + e

The redox reaction above can be used to determine the change in oxidation numbers for chlorine and silicon. According to this equation, what changes occurred? A Silicon went from +1 to +4, and chlorine went from +2 to -4. B C Silicon went from 0 to -4, and chlorine went from 0 to +1. Silicon went from +1 to -4, and chlorine went from +4 to -4. 8

D Cl2 + e Cl2

Corrosion, a type of redox reaction, can cause cars and buildings to rust. Rusting happens when iron is oxidized by oxygen in the air. This process happens when . A oxygen acts as the reducing agent and gains electrons B C iron acts as the reducing agent and loses electrons oxygen acts as the oxidizing agent and loses electrons

D Silicon went from 0 to +4, and chlorine went from 0 to -1.

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

The purpose of a salt bridge in an electrochemical cell is to A transfer electrons B C transfer water transfer protons

D iron acts as the oxidizing agent and gains electrons

D transfer positive and negative ions

38

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 20

Electrochemistry
Name: Date:

After a voltaic cell has been set up with a zinc anode, copper cathode, and a salt bridge, which way will electron flow proceed? A From the copper cathode to the zinc anode B C From the salt bridge to the zinc anode From the zinc anode to the copper cathode

Which of these is NOT a trait of a secondary battery? A Generates electrical current by a chemical reaction B C Uses a redox reaction that cannot easily be reversed Recharges by reversing the net cell reaction

D From the copper cathode to the salt bridge

D Is also referred to as a storage battery

In order to develop building materials that are resistant to corrosion, manufacturers must be . aware of ways to promote A anodic inhibition, which prevents the reduction of the metal B cathodic reactions, which allow reduction of the metal anodic inhibition, which prevents the oxidation of the metal

Use the diagram below to answer question 4.

Voltmeter anode cathode

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D cathodic reactions, which allows oxidation of the metal 4 The diagram shows a students setup for a voltaic cell. Which change would help ensure that electron flow would continue indefinitely? A The student should place a salt bridge between the two beakers. B C Both electrodes should be made of the same metal. The student should connect the voltmeter to a salt bridge.

D The anode should be in the same beaker as the cathode.

Chemistry Standardized Test Practice

Chemistry: Matter and Change

39

CHAPTER 20

Electrochemistry, continued

Name:

Date:

Which of these is required for electric charge to flow in an electrochemical cell? A Galvanic difference B C Electroplating difference Concentration difference

Electrolysis can be used to drive nonspontaneous . redox reactions because it A uses chemical energy to cause an electrical reaction B C equilibrates the electromotive force uses electrical energy to cause a chemical reaction

D Electric potential difference

D acts as a sacrificial anode

Some silverware is not made entirely of silver but is electroplated, or coated, with silver. The process of electroplating a fork would involve the migration of . A silver ions oxidized at the anode and depositing on the fork, which acts as the cathode B C ions oxidized from the fork (cathode) and depositing on the silver metal (anode) silver ions reduced at the anode and depositing on the fork, which acts as the cathode

Use the equation below to answer question 8.


Cu(s) + Zn2+(aq) Cu2+(aq) + Zn(s) E 0 = 1.10V

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

According to this information, this reaction . A is spontaneous B C requires heat is nonspontaneous

D ions oxidized from the fork (anode) and depositing on the silver metal (cathode)

D gives off heat

40

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 21

Hydrocarbons
Name: Date:

Chemists have identified a substance in a laboratory as decane. How many hydrogen atoms can be found bonded to the carbon atoms in the sample of decane? A 10 B C 20 22

Use the structural formula below to answer question 4.


H H C C C H H C H H

D 24 4 The model shows the structural formula of 1-butyne. Which of these is the proper condensed structural formula for 1-butyne? A CH B C CH2 CH3C CCH2CH3 CHCH2CH3 CCH3 CH

What is the suffix for the name of a carbon-chain molecule containing a double bond? A -ane B C -ene -yne

D CH3C

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D -amide

5 3 Before Friedrich Wohler, chemists believed that organic compounds created by living organisms could not be synthesized in the laboratory. They believed that organisms possessed a mysterious force that enabled them to create carbon compounds. This idea that chemists accepted was . called A organism force theory B C vitalism hydrocarbonism

The process of fractional distillation involves boiling crude oil in order to . A increase its stored energy B C separate it into its usable components create petroleum oil

D change its viscosity

D vivalism

Chemistry Standardized Test Practice

Chemistry: Matter and Change

41

CHAPTER 21

Hydrocarbons, continued

Name:

Date:

Many aromatic compounds, such as benzopyrene, are carcinogenic, meaning that . A they may cause tuberculosis B C they are not very water soluble they may cause cancer

Use the compound below to answer question 9.

CH 3

D their molecular structure is similar to that of human genes

An ether has a functional group of A CHO B C CO O

CH 3
9 This compound may be classified as aromatic because .
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D OH

A it has two methyl groups B C 8 When lubricating oil is poured into water, the two liquids separate almost instantly. This happens because the lubricating oil molecules have greater . A attraction toward the water molecules B C mass weight than the water molecules attraction toward other lubricating oil molecules it contains a propene ring it has 10 carbon atoms

D it has a benzene ring

D charge than the water molecules

42

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 22

Substituted Hydrocarbons and Their Reactions


Date:

Name:

A chemist performed some experiments with alkyl halides, comparing their boiling point temperatures. All of the following elements may have influenced the results of his experiments EXCEPT . A Cl B C F Pb

Chlorofluorocarbons have been replaced with hydrofluorocarbons in refrigerators and air conditioners because of CFCs potential to . A interfere with Earths gravity B C create noxious gas fumes damage the ozone layer

D contaminate ground water

D Br 2 Which of these is NOT an example of a hydrocarbon or substituted hydrocarbon with a boiling point above 0C? A Pentane B C Ethanol Chloroethane 5 OH is to alcohols as NH2 is to A ethers B C aldehydes ketones .

D Ethane
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D amines

Use the structural formula below to answer question 3.


Br H C1 H F C2 H Cl C3 H H C4 H H

Which of the following is a condensation polymer? A polyvinyl chloride B C polypropylene polyethylene

The model shows the structural formula of a specific substituted hydrocarbon. Which of these is the proper name for this compound? A bromo-chloro-fluorobutane B C 1-bromo-3-chloro-2-fluorobutane 1-dibromo-3-trichloro-2-tetrafluorobutane

D nylon

D 3-bromo-1-chloro-2-fluorobutane

Chemistry Standardized Test Practice

Chemistry: Matter and Change

43

CHAPTER 22

Substituted Hydrocarbons and Their Reactions, continued

Name: Use the diagram below to answer question 7.


Addition Reaction with Alkenes
H OH H C C H

Date:

H H C

H C H

Water H2O
H C H Alkene C H H

Hydrogen H2

H H Alcohol

H H Alkane H H C X C H

Hydrogen Halide HX Halogen X2


H

X C

X C H

H H Alkylhalide

H H Alkyldihalide

According to this information, which of these is NOT necessary for these addition reactions to take place? A water B C alkyldihalide hydrogen halide

Which group of molecules makes up the R group of the amino acid alanine, show below?

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

CH3 H2N C COOH

D hydrogen

A CH3 B C COO H

D NH3+ 8 The process of polymerization involves the . bonding together of A simple organic molecules called monomers B C nylon and dacron alcohol and water

D a polymer and a monomer

44

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 23

The Chemistry of Life


Name: Date:

Use the diagram below to answer question 1.


H N H R1 C H C O OH + H H N R2 C H C O OH H H N R1 C H C O H N R2 C H C O OH + H2O

Which of these two groups provide the bonding sites when the two amino acids shown above combine? A Carboxyl and hydrogen B C Aldehyde and amino Ketone and amino

D Amino and carboxyl

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

Use the equation below to answer question 2.


6CO2 + 6H2O + light energy C6 H12 O6 + 6O2

Which of these is NOT a protein? A hemoglobin B C insulin lysine

This chemical equation shows the process of . A catabolism B C fermentation photosynthesis 4

D collagen

D cellular respiration

The process of alcoholic fermentation involves the breaking down of glucose. This reaction produces . A fructose, carbon dioxide, and energy B C oxygen, ethanol, and benzene ethanol, carbon dioxide, and energy

D lysine, ethanol, and carbon dioxide

Chemistry Standardized Test Practice

Chemistry: Matter and Change

45

CHAPTER 23

The Chemistry of Life, continued

Name:
5 Which of these is required for cellular respiration to occur? A glucose B C DNA triglyceride C 8

Date:
How does anabolism help us to survive? A It helps produce ATP. B It helps us break down complex biological molecules such as proteins. It helps to synthesize complex proteins from amino acids.

D water

D It helps the body extract energy from nutrients.

Lipids contain saturated and unsaturated fatty acids and can be either liquid or solid. Which of these lipids is an example of a triglyceride mixture that contains mostly saturated fatty acids? A corn oil B C butter olive oil

In 1953, James Watson and Francis Crick determined that the structure of DNA was a double helix. This discovery best helped them . A determine that the sequence of nitrogen bases in DNA is different for every organism B C identify the nitrogen bases contained in DNA determine that RNA contains the sugar ribose

D peanut oil

Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D understand how DNA copies genetic information 7 When we exercise strenuously, we sometimes feel pain in our muscles because our muscles cells produce . A carbon monoxide B C lactic acid ethanol

D energy

46

Chemistry: Matter and Change

Chemistry Standardized Test Practice

CHAPTER 24

Nuclear Chemistry
Name: Date:

Use the graph below to answer question 1.

Use the diagram below to answer question 3.

Uranium-238 Decay Series


92 91 90

U Pa Th Ra Rn Po Bi Pb
Stable Isotope

Th

Atomic number

89 88 87 86 85 84 83 82 80

Po Bi Pb

Po

Alpha decay Beta decay

Pb

200 202 204 206 208 210 212 214 216 218 220 222 224 226 228 230 232 234 236 238

Mass number

3 1 According to the graph above, an element such as uranium-238 decays . A until its nucleus no longer contains any protons
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

According to the diagram above, how would you describe this uranium-235 sample? A The sample has subcritical mass. B C The sample is extremely stable. The sample has critical mass.

B C

until its nucleus becomes stable until its neutron-to-proton ratio is approximately 1:1.5

D The sample is not releasing much energy.

D until it reaches a state of instability 4 The process of nuclear fusion involves the . A splitting up of a nucleus into smaller fragments B C combining of atomic nuclei splitting up of electrons into smaller fragments

Which of these is NOT a type of radiation? A alpha radiation B C beta radiation gamma radiation

D delta radiation

D combining of highly unstable nuclei

Chemistry Standardized Test Practice

Chemistry: Matter and Change

47

CHAPTER 24

Nuclear Chemistry, continued

Name:

Date:

Use the graph below to answer question 5.


Half-Life of Element X Time 0 days 20 days 40 days 60 days 80 days 100 days Amount of sample 200.0 grams 100.0 grams 50.0 grams 25.0 grams ?? ??

In order to radiochemically date a human skeleton, scientists need to compare the ratio of carbon-14 to carbon-12 in the skeleton . with A the amount of uranium decay in the skeleton B C the ratio of carbon-14 to carbon-12 in the atmosphere the amount of nitrogen and oxygen in the atmosphere

D the amount of carbon-14 in the atmosphere

If the trend in the table shown above continues, how much of element X will be left after 100 days of decay? A 5.25 g B C 6.25 g 8.50 g 8 A sample of polonium ( 210 Po) spontaneously 84 decays into lead ( 206 Pb). The neutron-to-proton 82 ratio of the polonium before it began to decay was . A 1:1 B 1.33:1 1.50:1
Copyright Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc.

D 12.50 g

Use the nuclear equation below to answer question 6.


238 92

D 1.75:1

U + 1n 0
239 93

239 92

U
239 94

239 93 0 Pu + -1

0 Np + -1

Np

9 6 The end product of the reaction shown above may be classified as . A a posturanium element B C a nuclear fusion element a transuranium element

Nuclear waste disposal is a major problem for society. The waste is very difficult to properly dispose of because . A it has a very short half-life B C its proton-to-neutron ratio is 1:1 it has a very long half-life

D a chain reaction element

D it explodes when it comes into contact with oxygen

48

Chemistry: Matter and Change

Chemistry Standardized Test Practice

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