IIT JEE Advanced Sample Question Paper With Detailed Solutions 2

PAPER 2
Time : 3 Hours Maximum Marks : 240

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consists of four sections.
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darken ONLY the bubble corresponding to the correct answer and zero marks otherwise.
There are no negative marks in this section.
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in which you have darkened ALL the bubble(s) corresponding to the correct answer(s) ONLY
and zero marks otherwise. Thus, each question in this section carries a maximum of 8
marks. There are no negative marks in this section.
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(2) Vidyalankar : IIT JEE 2011 Question Paper & Solution
2
Useful Data
R = 8.314 JK
1
mol
1
or 8.206 10
2
L atm K
1
mol
1
1F = 96500 C mol
1
h = 6.626 10
34
Js
1 eV = 1.602 10
19
J
c = 3.0 10
8
ms
1
N
A
= 6.022 10
23
IIT JEE 2011 Question Paper & Solution (Paper II) (3)
3
PART - I : CHEMI STRY
SECTI ON I (Total Marks : 24)
Single Correct Answer Type
This section contains 8 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
1. Amongst the compounds given, the one that would form a brilliant colored dye on
treatment with NaNO
2
in dil. HCl followed by addition to an alkaline solution of
|naphthol is
(A) (B)
(C) (D)
1. (C)
CH
3
N N
O H
2. The major product of the following reaction is
O
RCH
2
OH
(A) a hemiacetal (B) an acetal (C) an ether (D) an ester
2. (B)
O
2
R CH OH
H anhydrous
O
O CH
2
R
3. The following carbohydrate is
H
(anhydrous)
4
(A) a ketohexose (B) an aldohexose (C) an o furanose (D) an opyranose
3. (B)
Carbohydrates is an aldohexase
4. Oxidation states of the metal in the minerals haematite and magnetite, respectively, are
(A) II, III in haematite and III in magnetite
(B) II, III in haematite and II in magnetite
(C) II in haematite and II, III in magnetite
(D) III in haematite and II, III in magnetite
4. (D)
Fe
2
O
3
2 Fe + 3(0) = 0
(Haematite) 2 Fe + 3(2) = 0
2 Fe = 6
Fe = +3
Fe
3
O
4
FeO + FeO
3
(Magnetite) +2 +3
5. Among the following complexes (K P),
K
3
[Fe(CN)
6
(K) , [Co(NH
3
)
6
]Cl
3
(L) , Na
3
[Co(oxalate)
3
] (M) , [Ni(H
2
O)
6
]Cl
2
(N),
K
2
[Pt(CN)
4
] (O) and [Zn(H
2
O)
6
] (NO
3
)
2
(P)
The diamagnetic complexes are
(A) K, L, M, N (B) K, M, O, P (C) L, M, O, P (D) L, M, N, O
5. (C)
K
3
[Fe (CN)
6
] Fe
+3
Paramagnetic
[Co(NH
3
)
6
]Cl
3
diamagnetic
Na
3
[Co(oxalate)
3
] diamagnetic
[Zn(H
2
O)
6
] (NO
3
)
2
diamagnetic
K
2
[Pt(CN)
4
] diamagnetic
6. Passing H
2
S gas into a mixture of Mn
2+
, Ni
2+
, Cu
2+
and Hg
2+
ions in an acidified aqueous
solution precipitates
(A) CuS and HgS (B) MnS and CuS (C) MnS and NiS (D) NiS and HgS
6. (A)
Group II Hg
2+
and Cu
+2
7. Consider the following cell reaction :
2
(s) 2(g) (aq) (aq) 2 ( )
2Fe O 4H Fe 2H O
+ +
+ + 2 +
/
E = 1.67 V
At [Fe
2+
] = 10
3
M, P(O
2
) = 0.1 atm and pH = 3, the cell potential at 25C is
(A) 1.47 V (B) 1.77 V (C) 1.87 V (D) 1.57 V
OH
H
O
H
OH
H
O H
O H
H
OH
|pyranose
d
2
sp
3
5
7. (D)
E =
2
2 2
10
4
O
0.0591 [Fe ]
1.67 log
4
[H ] (P )
+
+
= 1.67 0.103 1.567 V =

8. The freezing point (in C) of a solution containing 0.1 g of K
3
[Fe(CN)
6
] (Mol. Wt. 329) in
100 g of water (K
f
= 1.86 K kg mol
1
) is
(A) 2.3 10
2
(B) 5.7 10
2
(C) 5.7 10
3
(D) 1.2 10
2
8. (A)
K
3
[Fe (CN)
6
] 3K
+
+ [Fe (CN)
6
]
3
i = 4
AT
f
=
f
0.1 1000
iK m 4 1.86
329 100
| |
=
|
\ .
=
2
4 1.86
0.0226 2.23 10
329

= =
T
f
= 2.23 10
2
SECTI ON I I (Total Marks : 16)
(Multiple Correct Answer(s) Type)
This section contains 4 multiple choice questions. Each question has four choices (A) , (B) ,
(C) and (D) out our which ONE or MORE may be correct.
9. The equilibrium
I O II
2Cu Cu Cu +
In aqueous medium at 25C shifts towards the left in the presence of

(A)
3
NO
(B) Cl
(C) SCN
(D) CN
9. (B), (C), (D)

Cl
, SCN
,CN
forms ppt. with Cu

+
.
10. Reduction of the metal centre in aqueous permanganate ion involves
(A) 3 electrons in neutral medium (B) 5 electrons in neutral medium
(C) 3 electrons in alkaline medium (D) 5 electrons in acidic medium
10. (A), (C), (D)
2
4 2
MnO 8H 5e Mn 4H O
+ +
+ + + (Acidic)
4 2 2
MnO 2H O 3e MnO 4OH

+ + + (Neutral and weak Alkaline)
11. The correct functional group X and the reagent/reaction conditions Y in the following
scheme are
(A) X = COOCH
3
, Y = H
2
/Ni/heat (B) X = CONH
2
, Y = H
2
/Ni/heat
(C) X = CONH
2
, Y = Br
2
/NaOH (D) X = CN , Y = H
2
/Ni/heat
6
11. (C), (D)
(C)
(D)
12. For the first order reaction
2 5(g) 2(g) 2(g)
2N O 4NO O +
(A) The concentration of the reactant decreases exponentially with time.
(B) The halflife of the reaction decreases with increasing temperature.
(C) The halflife of the reaction depends on the initial concentration of the reactant.
(D) The reaction proceeds to 99.6% completion in eight halflife duration.
12. (A), (B), (D)
C = C
0
e
KT
for 1
st
order reaction
t =
10
2.303 100
log
K 0.4
| |
|
\ .
t = 8 t
1/2
SECTI ON I I I (Total Marks : 24)
(I nteger Answer Type)
This section contains 6 questions. The answer to each of the questions is a single-digit
integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to be
darkened in the ORS.
13. The total number of contributing structures showing hyperconjugation (involving CH
bonds) for the following carbocation is
13. [6]
No. of hyperconjugative structure = 6
N H
2
C (CH
2
)
4
C
O
NH
2
O
O H C (CH
2
)
4
C
O
OH
O
(CH
2
)
4
NH
2
N H
2
(CH
2
)
4
N C N
H H O
(CH
2
)
4
C
O
Br
2
/NaOH
(CH
2
)
4
C C N N
H
2
/Ni/A
N H
2
CH
2
(CH
2
)
4
CH
2
NH
2
O H C (CH
2
)
4
C
O
OH
O
(CH
2
)
6
N C N
H H O
(CH
2
)
4
C
O
7
14. Among the following, the number of compounds than can react with PCl
5
to give POCl
3
is
O
2
, CO
2
, SO
2
, H
2
O, H
2
SO
4
, P
4
O
10
14. [4]
5 2 3 2
PCl SO POCl SOCl + +
5 2 3
PCl H O POCl 2HCl + +
5 4 10 3
6PCl P O 10POCl +
15. The volume (in mL) of 0.1 M AgNO
3
required for complete precipitation of chloride ions
present in 30 mL of 0.01 M solution of [Cr(H
2
O)
5
Cl]Cl
2
, as silver chloride is close to
15. [6]
No. of moles of AgNO
3
required =
0.01 30
2
1000
| |
|
\ .
=
0.1 V
1000
0.01 30 2
1000

=
0.1 V
1000
V = 6 mL
16. In 1L saturated solution of AgCl [K
sp
(AgCl) = 1.6 10
10
], 0.1 mol of CuCl
[K
sp
(CuCl) = 1.0 10
6
] is added. The resultant concentration of Ag
+
in the solution is
1.6 10
x
. The value of x is
16. [7]
[Ag ]
+
=
sp
sp sp
K (AgCl)
K (CuCl) K (AgCl) +
=
10 10
7
3
10 6
1.6 10 1.6 10
1.6 10
10
1.6 10 10

= =
+
17. The number of hexagonal faces that are present in a truncated octahedron is
17. [8]
In geometry, the truncated octahedron is an Archimedean
solid. It has 14 faces (8 regular hexagonal and 6 square), 36
edges, and 24 vertices. Since each of its faces has point
symmetry the truncated octahedron is a zonohedron.
If the original truncated octahedron has unit edge length, its
dual tetrakis cube has edge lengths
9
2
8
and
3
2
2
.
18. The maximum number of isomers (including stereoisomers) that are possible on
monochlorination of the following compound, is
8
18. [8]
3 2 2 3
CH CH CH CH CH
-
CH
3
C H
2
CH
2
CH CH
2
CH
3
Cl CH
3
C H
3
CH
Cl
CH
CH
3
CH
2
CH
3
C H
3
CH
2
C
CH
3
Cl
CH
2
CH
3
C H
3
CH
2
CH CH
2
CH
3
CH
2
Cl
+
*
(d & l)
*
(d & l)
+
+
SECTI ON I V (Total Marks: 16)
(Matrix Match Type)
This section contains 2 questions. Each question has four statements (A,B,C and D) given
in Column I and five statements (p, q, r, s and t) in Column I I . Any given statement in
Column I can have correct matching with ONE or MORE statement(s) given in Column
I I . For example, if for a given question, statement B matches with the statements given in
q and r, then for the particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.
19. Match the reactions in Column I with appropriate types of steps/reactive intermediate
involved in these reactions as given in Column I I
Column I Column I I
(A) (p) Nucleophilic substitution
(B) (q) Electrophilic substitution
(C) (r) Dehydration
*
9
19. (A) (r), (s), (t); (B) (p), (s), (t); (C) (r), (s); (D) (q), (r)
(A)
(B)
(C)
(D)
20. Match the transformations in Column I with appropriate options in Column II
Column I Column I I
(A)
2 2
CO (s) CO (g) (p) Phase transition
(B)
3(s) (s) 2(g)
CaCO CaO CO + (q) Allotropic change
(C)
2
2H H (g) - (r) AH is positive
(D) P
(white, solid)
P
(red, solid)
(s) AS is positive
(t) AS is negative
(D) (s) Nucleophilic addition
(t) Carbanion
18
18
18
10
20. (A) (p), (r), (s); (B) (r), (s); (C) (t); (D) (p), (q), (t)
(A) CO
2(s)
CO
2 (g)
There is a phase change (transition) from solid to gas. AH is positive as heat is
required to change from solid to gas.
AS : is also positive as randomness is increasing from solid to gas.
(B) AH is positive as that is required to decompose CaCO
3(s)
to CaO
(s)
and CO
2 (g)
.
AS is positive as randomness is increasing on the right hand side of the reactor.
(C) AS is negative as free radical is converted to H
2(s)
molecule.
(D) Allotropic change is seen from P(white) P(red) and since P(red) is a polymeric
form the entropy of the product is decreasing. Therefore AS is negative.
PART II : PHYSICS
(Single Correct Choice Type)
(A), (B), (C) and (D) out of which ONLY ONE is correct.
21. A ball of mass 0.2 kg rests on a vertical post of height 5 m. A bullet of mass 0.01 kg,
traveling with a velocity V m/s in a horizontal direction, hits the centre of the ball. After
the collision, the ball and bullet travel independently. The ball hits the ground at a
distance of 20 m and the bullet at a distance of 100 m from the foot of the post. The initial
velocity V of the bullet is
(A) 250 m/s (B) 250 2 m/ s (C) 400 m/s (D) 500 m/s
21. (D)
2
2H
V 20
g
=
2
10
V 20
10
=
2
V 20 =
1
2H
V 100
g
=
ball
1 2
11
1
V 100 =
(0.01) V = (0.2) (20) + (0.01) 100
0.01 V = 4 + 1
V = 500 m/s.
22. The density of a solid ball is to be determined in an experiment. The diameter of the ball
is measured with a screw gauge, whose pitch is 0.5 mm and there are 50 divisions on the
circular scale. The reading on the main scale is 2.5 mm and that on the circular scale is 20
divisions. If the measured mass of the ball has a relative error of 2%, the relative
percentage error in the density is
(A) 0.9 % (B) 2.4 % (C) 3.1 % (D) 4.2 %
22. (C)
=
m
V
A % = Am % + AV %
AV % = 3 (Ar) %
A % = Am % + 3 (Ar) %
L.C. =
0.5
(0.01)
50
= min
r = 2.5 + (20) (0.01) = 2.7
Ar % =
(0.01)
100
2.7
=
1 10
0.37
2.7 27
= =
A % = (2 + 3 (0.37)) = 3.1 %.
23.A wooden block performs SHM on a frictionless surface with frequency, v
0
. The block
carries a charge +Q on its surface. If now a uniform electric field E
,
is switchedon as
shown, then the SHM of the block will be
(A) of the same frequency and with shifted mean position.
(B) of the same frequency and with the same mean position.
(C) of changed frequency and with shifted mean position.
(D) of changed frequency and with the same mean position.
23. (A)
Force of E will be constant. So only mean position will shift to
0
QE
x
K
=
e remain same.
12
24. A light traveling in glass medium is incident on glassair interface at an angle of
incidence u. The reflected (R) and transmitted (T) intensities, both as function of u, are
plotted. The correct sketch is
(A) (B)
(C) (D)
24. (C)
At the
c
u
T
i 0 =
r i
i i =
at u < u
c
there will be partial reflection.
(B) cannot be correct as at u = 0
T R i
i i i + > (according to graph) which is not possible.
T R 1
i i i + = at any moment i.e., shown in (C).
25. A satellite is moving with a constant speed V in a circular orbit about the earth. An
object of mass m is ejected from the satellite such that it just escapes from the
gravitational pull of the earth. At the time of its ejection, the kinetic energy of the object is
(A)
2
1
mV
2
(B)
2
mV (C)
2
3
mV
2
(D) 2mV
2
25. (B)
KE +
GMm
r
| |
|
\ .
= 0
KE = +
GMm
r
2
2
mv GMm
r r
=
2
GM
v
r
=
KE = mv
2
.
26. A long insulated copper wire is closely wound as a spiral of N turns. The spiral has inner
radius a and outer radius b. The spiral lies in the XY plane and a steady current I
flows through the wire. The Z-component of the magnetic field at the center of the spiral
is
13
(A)
0
NI b
1n
2(b a) a

| |
|
\ .
(B)
0
N I b a
1n
2(b a) b a
+ | |
|
\ .
(C)
0
NI b
1n
2b a

| |
|
\ .
(D)
0
N I b a
1n
2b b a
+ | |
|
\ .
26. (A)
Current flowing per unit width of the spiral wire :
di N
i
dx b a
=
di =
N
i dx
b a
B at centre
dB =
0
di
2x
dB =
0
Ni dx
2x b a
B =
( )
b
0
a
Ni dx
2 b a x
}
B =
( )
0
Ni b
n
2 b a a
| |
|
\ .
/
27. A point mass is subjected to two simultaneous sinusoidal displacements in x-direction,
x
1
(t) = A sin et and x
2
(t) =
2
Asin t
3
t | |
e +
|
\ .
. Adding a third sinusoidal displacement
x
3
(t) = B sin (et + |) brings the mass to a complete rest. The values of B and | are
(A)
3
2 A,
4
t
(B)
4
A,
3
t
(C)
5
3 A,
6
t
(D) A,
3
t
27. (B)
Net displacement = 0.
1 2 3
x (t) x (t) x (t) 0 + + =
( )
2
Asin t Asin t Bsin t 0
3
t | |
e + e + + e + | =
|
\ .
( )
2
A sin t sin t Bsin t
3
t ( | |
e + e + = e + |
| (
\ .
14
L.H.S.
2 2
t t t t
3 3
2Asin cos
2 2
t t | | | |
e + e + e e
| |
| |
\ . \ .
2Asin t cos
3 3
t t | | | |
e +
| |
\ . \ .
1
2A sin t
2 3
t | | | |
e +
| |
\ . \ .
Asin t
3
t | |
e +
|
\ .
A sin t
3
t | |
e + + t
|
\ .
A sin
4
t
3
t | |
e +
|
\ .
Comparing with R.H.S.
B = A
& | =
3
4t
Alternate solution :
By phasor,

2 2 2
1 2
2
| y y | A A 2A cos
3
t
+ = + +
, ,
= A
& o =
3
t
For
1 2 3
y y y 0 + + =
, , ,
3
| y | A =
,
& direction should be
4
3
t
(In 3
rd
quadrant).
1
y
,
2
y
,
1 2
y y +
, ,
1
y
,
2
y
,
1 2
y y +
, ,
3
y
,
15
28. Which of the field patterns given below is valid for electric field as well as for magnetic
field?
(A) (B)
(C) (D)
28. (C)
The given pattern is valid for magnetic field around a straight wire for which length is
perpendicular to the plane of paper and current is flowing such that it is coming out of the
paper. As well as it represents an induced electric field due to a varying magnetic field.
(A) & (B) are not valid as B
,
should form close loop and in (D) one line terminates at
second point as well as another one emerging from it. That is not possible.
(A), (B), (C) and (D) out of which ONE or MORE may be correct.
29. A series RC circuit is connected to AC voltage source. Consider two cases; (A) when C
is without a dielectric medium and (B) when C is filled with dielectric of constant 4. The
current I
R
through the resistor and voltage V
C
across the capacitor are compared in the
two cases. Which of the following is/are true?
(A)
A B
R R
I I > (B)
A B
R R
I I <
(C)
A B
C C
V V > (D)
A B
C C
V V <
29. (B), (C)
E =
2 2
R C
V V +
=
2 2
C
I (R) X +
E =
2
2 2
1
I R
C
+
e
If C is greater, X
C
will be less and therefore V
C
will be less.
C =
0
KA
d
c
16
B A
C 4C =
B
C is greater than
A
C
hence
A B
C C
V V > [C is correct]
Now,
E =
2
2 2
1
I R
C
+
e
E remains same for both cases.
If C is greater
C
X will be smaller. I will be greater.
B A
C C >
B A
C C
X X <
B A
I I >
30. Two solid spheres A and B of equal volumes but of different
densities d
A
and d
B
are connected by a string. They are fully
immersed in a fluid of density d
F
. They get arranged into an
equilibrium state as shown in the figure with a tension in the
string. The arrangement is possible only if
(A) d
A
< d
F
(B) d
B
> d
F
(C) d
A
> d
F
(D) d
A
+ d
B
= 2 d
F
30. (A), (B), (D)
For B :

B F
Vd g Vd g T 0 = (1)
T +
A f
Vd g Vd g 0 = (2)
B F A F
Vd g Vd g Vd g Vd g = +
B A F
d d 2d + = (D)
Now, A has a tendency to go up
A F
d d < (A)
B has a tendency to go down.
B F
d d > (B)
31. A thin ring of mass 2 kg and radius 0.5 m is rolling without
slipping on a horizontal plane with velocity 1 m/s. A small
ball of mass 0.1 kg, moving with velocity 20 m/s in the
opposite direction, hits the ring at a height of 0.75 m and
goes vertically up with velocity 10 m/s. Immediately after
the collision
(A) the ring has pure rotation about its stationary CM.
(B) the ring comes to a complete stop.
(C) friction between the ring and the ground is to the left.
(D) there is no friction between the ring and the ground.
31. (A), (C)
Horizontal momentum is conserved.
P
i
= 0.1 Kg 20 2 1 = 0
Final horizontal momentum of 0.1 Kg = 0
u
d
B
B
mg
d
A
A
mg
T
T
17
Final horizontal momentum of ring = 0
L
i
= 0.75 0.1 20 = 1.5 (of 0.1 Kg) [Into the plane of figure]
L
i
= Ie = (MR
2
+ MR
2
)
V
2MVR
R
=
= 2 2 1 0.5 = 2 [out of the plane]
L
i
= 0.5 (out of plane)
After collision :
L
1
=
3 1
10
2 2
| |
0.1
|
\ .
(of 0.1 kg) [into the plane]
=
3
4
L
2
= (mR
2
) e = 2 0.25 e = 0.5 e (as it is pure rotation about centre)
By conservation of angular momentum
0.5 =
3
4 2
e
+
3
0.5
2 4
e
= +
e > 0 e is out of the plane.
Thus rotation is anticlockwise.
Thus friction is towards left.
32. Which of the following statement(s) is/are correct?
(A) If the electric field due to a point charge varies as r
2.5
instead of r
2
, then the Gauss
law will still be valid.
(B) The Gauss law can be used to calculate the field distribution around an electric dipole.
(C) If the electric field between two point charges is zero somewhere, then the sign of the
two charges is the same.
(D) The work done by the external force is moving a unit positive charge from point A at
potential V
A
to point B at potential V
B
is (V
B
V
A
).
32. (C), (D)
Gauss law tells
in
0
q
E dA =
c
}
, ,
[i.e., constant w.r.t. distance from a point charge]

Electric flux from a point charge
1
r
[in new condition & that is not constant]
Hence (A) is incorrect.
Gauss law is used to calculate amount of flux but not the field distribution.
Hence (B) is incorrect.
If there are only two charges then (C) is correct.
By definition, (D) is correct.
0.75
18
This section contains 6 questions. The answer to each of the questions is a single-digit
33. A silver sphere of radius 1 cm and work function 4.7 eV is suspended from an insulating
thread in free-space. It is under continuous illumination of 200 nm wavelength light. As
photoelectrons are emitted, the sphere gets charged and acquires a potential. The
maximum number of photoelectrons emitted from the sphere is A 10
Z
(where 1<A< 10).
The value of Z is
33. [7]
The loss of electrons, charges the sphere positive.
The final potential acquired by the sphere is indeed the slopping potential.

s max
hc
eV K = = |
=
1242nm eV
4.7
200nm
= 6.21 4.7
s
eV 1.51 = eV

s
V =1.51 volts.
s
0
1 q
V
4 r
=
tc
where q is the charge acquired by the sphere.
1.51 = 9 10
9
2
q
m
1 10
q =
11
1.51
10
9

The no. of electrons =

11
8
19
q 1.51 10 1.51
10
e 14.4 9 1.6 10
= =

~ 1 10
7
. Z = 7.
34. A train is moving along a straight line with a constant acceleration a. A boy standing in
the train throws a ball forward with a speed of 10 m/s, at an angle of 60 to the horizontal.
The boy has to move forward by 1.15 m inside the train to catch the ball back at the initial
height. The acceleration of the train, in m/s
2
, is
34. [5]
The ball is thrown w.r.t. to the boy at 10 m/s at angle of 60.
Time of flight =
2u sin 2 10sin 60 3
2 3
g g 2
u
= = =
The projectile has an deceleration of a in the frame of the boy.
R = u cos u t
1
2
a t
2
1.15 = 10 cos 60
1
3 a 3
2

1.15 = 5 3 1.5a
1.5a = 5 1.73 1.15
1.5 a = 8.65 1.15
1.5 a = 7.5
a =
7.5
1.5
= 5 m/s
2
.
19
35. A block of mass 0.18 kg is attached to a spring of
force-constant 2 N/m. The coefficient of friction
between the block and the floor is 0.1. Initially the
block is at rest and the spring is un-stretched. An
impulse is given to the block as shown in the
figure. The block slides a distance of 0.06 m and
comes to rest for the first time. The initial velocity
of the block in m/s is V = N/10. Then N is
35. [4]
ext
W K U = A + A
N x = 0
1
2
mv
2
+
1
2
kx
2
0.1 m g x =
1
2
mv
2
+
1
2
kx
2
x = 0.06
= 0.1
m = 0.18
k = 2
0.1 0.18 10 0.06 =
1
2
0.18 v
2
+
1
2
2 (0.06)
2
1.8 6 10
3
= 0.09 v
2
+ 36 10
4
0.09 v
2
= 10
4
(144)
v
2
= 10
2
144
9
v =
1 1
12
10 4 10
3

=
N = 4.
36. Two batteries of different emfs and different internal
resistances are connected as shown. The voltage across
AB in volts is
36. [5]
Total EMF = (6 3) V = 3 V
i =
3V
1A
3
=
O

A B
V V 3V i 2 = + = 3V + 2V = 5V.
37. Water
4
with refractive index
3
| |
=
|
\ .
in a tank is 18
cm deep. Oil of refractive index
7
4
lies on water
making a convex surface of radius of curvature
R = 6 cm as shown. Consider oil to act as a thin
lens. An object S is placed 24 cm above water
surface. The location of its image is at x cm
above the bottom of the tank. Then x is
20
37. [2]
For surface (I)
2 1 2 1
1 1
V u R

= (1)
It will be object for second surface and by applying same formula on surface (II).
3 3 1 2
1
V V
| |
=
|
\ .
(2)
by adding (1) and (2)
3 1 2 1
1
V u R
| |
=
|
\ .
7
1
4 1 4
3V ( 24) 6
| |
|
\ .
=
+
4 1 1 1
3V 8 24 12
= =
V = 16 below surface
2 cm above surface.
38. A series RC combination is connected to an AC voltage of angular frequency e = 500
radian/s. If the impedance of the RC circuit is R 1.25 , the time constant (in
millisecond) of the circuit is
38. [4]
e = 500 rad/s.
C
1
X
C
=
e
2 2 2 2 2 2
C C
Z R X 1.25R R X = + = +
C
1
X 0.5R
C
= =
e
RC =
2 3
1 2 2 2 20
10 10
0.5 500 5 5

= = = =
e e
s
RC = 4 ms.
SECTI ON VI (Total Marks : 16)
(Matrix-Match Type)
This section contains 2 questions. Each question has four statements (A, B, C and D) given
Column I can have correct matching with ONE or MORE statement(s) given in Column II.
For example, if for a given question, statement B matches with the statements given in q and
r, then for the particular question, against statement B, darken the bubbles corresponding to q
and r in the ORS.
~
R
21
39. Column I shows for systems, each of the same length L, for producing standing waves.
The lowest possible natural frequency of a system is called its fundamental frequency,
whose wavelength is denoted as
f
. Match each system with statements given in
Column I I describing the nature and wavelength of the standing waves.
Column I Column I I
(A) Pipe closed at one end (p) Longitudinal waves
(B) Pipe open at both ends (q) Transverse waves
(C) Stretched wire clamped at both ends (r)
f
= L
(D) Stretched wire clamped at both ends and at mid-point (s)
f
= 2L
(t)
f
= 4L
39. (A) (p), (t); (B) (p), (s); (C) (q), (s); (D) (q), (r)
(A) (p), (t)
(B) (p), (s)
f
/4
f
/2
22
(C) (q), (s)
(D) (q), (r)
40. One mole of a monatomic ideal gas is
taken through a cycle ABCDA as
shown in the P-V diagram. Column II
gives the characteristics involved in
the cycle. Match them with each of the
processes given in Column I.
Column I Column I I
(A) Process A B (p) Internal energy decreases.
(B) Process B C (q) Internal energy increases.
(C) Process C D (r) Heat is lost.
(D) Process D A (s) Heat is gained.
(f) Work is done on the gas.
40. (A) (p), (r), (t); (B) (p), (r); (C) (q), (s); (D) (r), (t)
(A) (p), (r), (t)
Process [A B] is a isobaric process in which volume decreases. Hence temperature also
decreases. Hence Internal Energy decreases. Also AT < 0 AU < 0 i.e., Heat is lost.
Also work to be done on gas.
(B) (p), (r)
Process [B C] is isochoric and pressure falls.
Hence temperature falls. Au < 0 and AQ < 0.
(C) (q), (s)
Process [C D] is isobaric and volume increases. Hence temperature also increases.
AQ > 0 & Au > 0.
(D) (r), (t)
Process [D A] volume decreases. Thus work is done on gas.
T
A
=
3P V 9PV
R R
3
=
D
9V P 9PV
T
R R
= =
AT = 0 Au = 0
AQ = W AQ < 0
f
/2
f
23
PART III - MATHEMATICS
(Single Correct Answer Type)
(A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct.
41. Let f : [1, 2] [0, ) be a continuous function such that f(x) = f(1 x) for all
x e [1, 2]. Let R
1
=
2
1
x
}
f(x) dx, and R
2
be the area of the region bounded by y = f(x),
x = 1, x = 2, and the xaxis. Then
(A) R
1
= 2R
2
(B) R
1
= 3R
2
(C) 2R
1
= R
2
(D) 3R
1
= R
2
41. (C)
f(x) = f(1x)
R
1
=
2
1
x f (x)
}
dx (i)
R
1
= ( ) ( )
2
1
1 x f 1 x

}
dx
( ) ( )
2
1
1
R 1 x f x dx
=
}
(ii)
f(1x) = f(x)
adding (i) and (ii)
2R
1
=
2
1
f (x)
}
2R
1
= R
2
42. Let f(x) = x
2
and g(x) = sin x for all x e R. Then the set of all x satisfying
(f g g f) (x) = (g g f) (x), where (f g) (x) = f(g(x)), is
(A) n , t n e {0, 1, 2, } (B) n , t , n e {1, 2, }
(C)
2
t
+ 2nt, n e {, 2, 1, 0, 1, 2, } (D) 2nt, n e {, 2, 1, 0, 1, 2, }
42. (A)
f(x) = x
2
g(x) = sin x
( ) ( ) ( ) ( )
( ) ( ) ( )
f g g f x g g f x = =
( ) ( )
2
sin sin x
( ) ( ) ( )
2
2 2
sin sin x sin sin x =
( )
2
sin sin x 0,1 =
( )
2
sin x can not be
2
t
So, sin x
2
= 0
2
x n = t
x = nt
x = 0, 1, 2,..
24
43. Let (x, y) be any point on the parabola y
2
= 4x. Let p be the point that divides the line
segment from (0, 0) to (x, y) in the ratio 1 : 3. Then the locus of P is
(A) x
2
= y (B) y
2
= 2x (C) y
2
= x (D) x
2
= 2y
43. (C)
By section formula
P(o, |) =
x y
,
4 4
| |
|
\ .
So,
x
4
o= &
y
4
|=
x 4 = o & y 4 = |
As (x, y) lies on y
2
= 4x
( ) ( )
2
4 4 4 | = o
|
2
= o
Hence locus y
2
= x
44. Let P(6, 3) be a point on the hyperbola
2 2
2 2
x y
a b
= 1. If the normal at the point P intersects
the xaxis at (9, 0), then the eccentricity of the hyperbola is
(A)
5
2
(B)
3
2
(C) 2 (D) 3
44. (B)
Slope of tangent at P(x
1,
y
1
) is =
2
1
2
1
x b
y a
Slope of normal at P(x
1,
y
1
) is =
2
1
2
1
y a
x b
So, slope of normal at P(6, 3) =

2
2
a
2b
So, equation of normal y 3 = ( )

2
2
a
x 6
2b

Given it passes through (9, 0)
0 3 = ( )
2
2
a
9 6
2b

2
2
b 1
2
a
=
2
2
b 1 3
e 1 1
2 2
a
= + = + = .
45. A value of b for which the equations x
2
+ bx 1 = 0
x
2
+ x + b = 0
have one root in common is
(A) 2 (B) i 3 (C) i 5 (D) 2
45. Let o be the common root.
o
2
+ bo 1 = 0 ..(i)
o
2
+ o + b = 0 ..(ii)
Q(x,y)
(0,0)
3
P(o, |)
25
(i) (ii)
b 1
b 1
+
o=
Substituting, o in (i) is
b
2
+ 3 = 0
b = i 3
46. Let e = 1 be a cube root of unity and S be the set of all nonsingular matrices of the form
2
1 a b
1 c
1
(
(
e
(
(
e e

where each of a, b and c is either e or e
2
. Then the number of distinct
matrices in the set S is
(A) 2 (B) 6 (C) 4 (D) 8
46. (A)
A = 1 (1 ce a (e e
2
c) + b (0))
A = 1 ce ae + e
2
ac
A = 1 e (c + a) + e
2
ac
c = e a = e
2
singular
c = e
2
a = e singular
c = e a = e non singular
c = e
2
a = e
2
singular
for every pair (a, c) there are two possible values of b hence 2 matrices.
47. The circle passing through the point (1, 0) and touching the yaxis at (0, 2) also passes
through the point
(A)
3
, 0
2
| |
|
\ .
(B)
5
, 2
2
| |
|
\ .
(C)
3 5
,
2 2
| |
|
\ .
(D) (4, 0)
47. (D)
(x o)
2
+ (y 2)
2
= o
2
x
2
2xo + o
2
+ y
2
4y + 4 = o
2
x
2
+ y
2
2xo 4y + 4 = 0
The circle passes through (1, 0)
1 + 0 + 2o + 4 = 0
o =
5
2
The equation of circle
x
2
+ y
2
+ 5x 4y + 4 = 0
Now, the point (4, 0) satisfy the above equation.
Hence the point (4, 0) lies on the circle.
48. If
( )
1
2
x
x 0
lim 1 xIn 1 b
(
+ +

= 2b sin
2
u, b > 0 and u e (t, t], then the value of u is
(A)
4
t
(B)
3
t
(C)
6
t
(D)
2
t
(0, 2)
(o, 2)
26
48. (D)
( )
1
2
x
x 0
lim 1 x n 1 b
(
+ +

l
=
( )
2
n 1 b
e
+ l
= (1 + b
2
)
Hence, 1 + b
2
= 2 b sin
2
u
sin
2
u =
2
1 b
2b
+
(1)
Now,
2
1 b
2b
+
> 1
Hence (1) is true only when
sin
2
u = 1
u =
2
t
This section contains 4 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE or MORE may be correct.
49. Let E and F be two independent events. The probability that exactly one of them occurs is
11
25
and the probability of none of them occurring is
2
25
. If P(T) denotes the probability
of occurrence of the even T, then
(A) P(E) =
4
5
, P(F) =
3
5
(B) P(E) =
1
5
, P(F) =
2
5
(C) P(E) =
2
5
, P(F) =
1
5
(D) P(E) =
3
5
, P(F) =
4
5
49. (A), (D)
( ) ( )
11
P EF P FE
25
+ = . (i)
( )
2
P EF
25
= .. (ii)
Using (i)
11
P(E) P(F) P(F) P(E)
25
+ =
P(E) (1 P (F)) + P(F) (1 P (E)) =
11
25
P(E) + P(F) 2 P (E) P (F) =
11
25
(iii)
(1 P (E)) (1 P(F)) =
2
25
.. (iv)
(A) and (D) are satisfying (iii) and (iv)
27
50. If
x , x
2 2
cos x, x 0
f (x)
2
x 1, 0 x 1
In x, x 1,
t t
s
< s
=

< s
>
then
(A) f(x) is continuous at x =
2
t
(B) f(x) is not differentiable at x = 0
(C) f(x) is differentiable at x = 1 (D) f(x) is differentiable at x =
3
2
50. (A), (B), (C), (D)
f(x) is continuous everywhere, not differentiable at x = 0, hence (A), (B), (C), (D) are
correct.
51. Let f : (0, 1) R be defined by f(x) =
b x
1 bx
, where b is a constant such that 0 < b < 1.

Then
(A) f is not invertible on (0, 1) (B) f = f
1
on (0, 1) and f'(b) =
1
f '(0)
(C) f = f
1
on (0, 1) and f'(b) =
1
f '(0)
(D) f
1
is differentiable on (0, 1)
51. (C), (D)
f (x) =
b x
1 bx

( )
f x ' =
( )( ) ( )( )
( )
2
1 bx 1 b x b
1 bx

=
( )
2
2
1 bx b bx
1 bx
+ +
=
( )
2
2
b 1
1 bx
(1)
( )
f x ' < 0 b < 1
f is decreasing strictly b
2
< 1
f
1
exists
1
1
0
28
y =
b x
1 bx
y ybx = b x
y b = ybx x
y b = x (yb 1)
y b
yb 1
= x
x =
y b
yb 1
( )
1
f x
=
x b
xb 1
( )
1
f x
=
b x
1 bx
f =
1
f

on (0, 1)

( )
f b ' =
2
1
b 1
( )
f 0 ' = b
2
1
( )
f b ' =
( )
1
f 0 '
52. Let L be a normal to the parabola y
2
= 4x. If L passes through the point (9, 6), then L is
given by
(A) y x + 3 = 0 (B) y + 3x 33 = 0
(C) y + x 15 = 0 (D) y 2x + 12 = 0
52. (A), (B), (D)
t x + y = 2t + t
3
Since normal passes through (9, 6)
9t + 6 = 2t + t
3
t
3
7t 6 = 0
(t 3) (t + 1) (t +2) = 0
For t = 3, 1, 2 normals are
y + 3x 33 = 0, y x + 3 = 0 and y 2x + 12 = 0 respectively.
This section contains 6 questions. The answer to each of the questions is a singledigit
53. The straight line 2x 3y = 1 divides the circular region x
2
+ y
2
s 6 into two parts. If
S =
3 5 3 1 1 1 1
2, , , , , , ,
4 2 4 4 4 8 4
| | | | | | | |
`
| | | |
\ . \ . \ . \ . )
, then the number of point(s) in S lying inside the
smaller part is
53. (2)
If (x, y) belongs to smaller part then it satisfies
x
2
+ y
2
s 6 and 2x 3y 1 > 0
29
a)
3
2,
4
| |
|
\ .
satisfies x
2
+ y
2
s 6
and also 2x 3y 1
= 2 (2) 3
3
4
| |
|
\ .
1
= 4
9
4
1 > 0
(2, 3) e smaller required region.
b)
5 3
,
2 4
| |
|
\ .
does not satisfy x
2
+ y
2
s 6
c)
1 1
,
4 4
| |
|
\ .
satisfies both x
2
+ y
2
s 6 and 2x 3y 1 > 0
d)
1 1
,
8 4
| |
|
\ .
does not satisfy 2x 3y 1 > 0
54. Let e = e
it/3
, and a, b, c, x, y, z be nonzero complex numbers such that
a + b + c = x
a + be + ce
2
= y
a + be
2
+ ce = z
Then the value of
2 2 2
2 2 2
| x | | y | | z |
| a | | b | | c |
+ +
+ +
is
54. [solution will depends on the value of a, b & c]
e =
i /3
e
t
Let a = b = c = 1. a, b, c e I and nonzero.
We have, x = 3
y = 1 + e + e
2
= z
Let us see the value of
2 2
2
2 2 2
2 2 2 2 2 2
3 1 3i 1 3i
| x | | y | | z |
| a | | b | | c | | a | | b | | c |
+ + + +
+ +
=
+ + + +
=
9 4 4 17
3 3
+ +
= eZ
So for a = b = c = 1, the final solution is nonintegral.
Value of
2 2 2
2 2 2
| x | | y | | z |
| a | | b | | c |
+ +
+ +
depends on values taken by a, b, c.
And hence the problem is ambiguous.
55. The number of distinct real roots of x
4
4x
3
+ 12x
2
+ x 1 = 0 is
55. [2]
f(x) = x
4
4x
3
+ 12x
2
+ x 1
f (x) ' = 4x
3
12x
2
+ 24x + 1
30
f (x) '' = 12x
2
24x + 24 = 12(x
2
2x + 2) > 0 x R
f (x) ' is always increasing and hence f(x) = 0 will have only one root.
f (x) ' = 0 has only one real root and f(x) is taking both positive and negative values,
f(x) = 0 has exactly two real roots.
56. Let y'(x) + y(x) g'(x) = g(x) g'(x), y(0) = 0, x e R, where f'(x) denotes
df (x)
dx
and g(x) is
a given nonconstant differentiable function on R with g(0) = g(2) = 0. Then the value of
y(2) is
56. [0]
( )
dy
g x y
dx
' + = g (x).
( )
g x '
Integrating factor =
( )
g x dx
e
'
}
= e
g(x)
Solution is y.e
g(x)
=
( )
g x
e
}
.g(x).
( )
g x ' dx
y e
g(x)
= e
g(x)
g(x) e
g(x)
+ C
y e
g(0)
= e
g(0)
g(0) e
g(0)
+ C
0 = 0 e+ C
C = 1
for x = 2,
y e
g(2)
= e
g(2)
.g(2) e
g(2)
+ 1
y 1 = 0 1 + 1
y = 0
57. Let M be a 3 3 matrix satisfying
0 1
M 1 2
0 3
( (
( (
=
( (
( (

,
1 1
M 1 1
0 1
( (
( (
=
( (
( (

and M
1 0
1 0
1 12
( (
( (
=
( (
( (

.
Then the sum of the diagonal entries of M is
57. [9]
Let M =
1 2 3
1 2 3
1 2 3
a a a
b b b
c c c
(
(
(
(

1 2 3
1 2 3
1 2 3
a a a 0
b b b . 1
c c c 0
( (
( (
( (
( (

=
1
2
3
(
(
(
(

a
2
= 1, b
2
= 2, c
2
= 3
Also,
1 2 3
1 2 3
1 2 3
a a a 1
b b b 1
c c c 0
( (
( (
( (
( (

=
1
1
1
(
(
(
(

a
1
a
2
= 1
a
1
= 0, b
1
= 3, c
1
= 2
1 2 3
1 2 3
1 2 3
a a a 1
b b b . 1
c c c 1
( (
( (
( (
( (

=
0
0
12
(
(
(
(

c
1
+ c
2
+ c
3
= 12
c
3
= 12 5 = 7
Sum of diagonal elements = a
1
+ b
2
+ c
3
= 0 + 2 + 7 = 9
31
58. Let
` `
a i k, b i j and c i 2j 3k = = + = + +
, , ,
` ` ` ` `
be three given vectors. If r
,
is a vector such
that r b c b and r a 0 = =
, , , , , ,
, then the value of r b
, ,
is
58. [9]
r b c b =
, , , ,
( )
r c b 0 =
, , ,
r c b =
, , ,
r c b = +
, , ,
r .a c.a b.a = +
, , , , , ,
0 = c.a b.a +
, , , ,
c a
b.a
+
=
, ,
, ,
( ) 4
1
=+
r c 4b = +
, , ,
r .b c. b 4b. b = +
, , , , , ,
= 1 + 4 2
r. b 9 =
, ,
SECTI ON I V (Total Marks : 16)
(Matrix-Match Type)
This section contains 2 questions. Each question has four statements (A, B, C and D) given
Column I can have correct matching with ONE or MORE statement(s) given in Column I I .
For example, if for a given question, statement B matches with the statements given in q and
r, then for that particular question against statement B, darken the bubbles corresponding to q
and r in the ORS.
59. Match the statements given in Column I with the intervals/union of intervals given in
Column I I
Column I Column I I
(A) The set
2
2iz
Re : z is a complex number,| z | 1, z 1
1 z
| |
= =
`
|
\ . )
is
(p) (, 1) (1, )
(B)
The domain of the function f(x) = sin
1
x 2
2(x 1)
8(3)
1 3
| |
|
|
\ .
is
(q) (, 0) (0, )
(C)
If f(u) =
1 tan 1
tan 1 tan
1 tan 1
u
u u
u
, then the set
f ( ) : 0
2
t
u s u <
`
)
is
(r) [2, )
(D) If f(x) = x
3/2
(3x 10), x > 0, then f(x) is increasing in (s) (, 1] [1, )
(t) (, 0] [2, )
32
59.
(A) (S)
| z | = 1 z = e
iu
( )
i
2 2i
2i cos i sin 2iz 2ie
1 cos 2 i sin 2
1 z 1 e
u
u
u+ u
= =
u u

=
( )
2
2i cos i sin
2sin i2sin cos
u+ u
u u u
=
( )
( )
2i cos i sin
2i sin cos i sin
u+ u
u u+ u
=
1
sin
u
= cosecu
So, A ( , 1] [1, )
(B) (t)
f(x) =
( )
x 2
1
2 x 1
8.3
sin
1 3
| |
|
|
\ .
domain, 1
x 2
2x 2
8.3
1
1 3
1
x
2x
8.3
1
9 3
s
taking, t = 3
x
1
2
8t
1
9 t
s
Case 1
0
2
8t
1
9 t
s
2
8t
1 0
9 t
s
2
2
t 8t 9
0
t 9
+
>
( ) ( )
( )( )
t 9 t 1
0
t 3 t 3
+
>
+
t 1
0
t 3
>
t e (, 1] (3, )
3
x
e (0, 1] (3, )
x e (, 0] (1, ) ..(i)
Case 2
1
2
8t
9 t
2
8t
1 0
9 t
+ >
33
2
2
t 8t 9
0
t 9

>
( )( )
( ) ( )
t 9 t 1
0
t 3 t 3
+
>
+
t 9
0
t 3
>
te ( , 3) [9, )
3
x
e (0, 3) [9, )
xe (, 1) [2, ) .(ii)
Intersection of (i) & (ii) is
xe (, 0)] [2, )
(C) (r)
f(u) =
1 tan 1
tan 1 tan
1 tan 1
u
u u
u
= sec
2
u + sec
2
u
= 2 sec
2
u
(D) (r)
f(x) = ( )
3
2
x 3x 10
f
1
(x) = ( ) ( )
3 1
2 2
3
x 3x 10 x . 3
2
+
= ( )
3 x
3x 10 2x
2
+ (

= | |
3 x
5x 10
2

Given increasing function f'(x) 0 x 2
60. Match the statements given in Column I with the values given in Column I I .
Column I Column I I
(A)
If
` ` `
a j 3k, b j 3k and c 2 3k = + = + =
, , ,
` `
form a
triangle, then the internal angle of the triangle
between a
,
and b
,
is
(p)
6
t
(B)
If
b
a
(f (x) 3x)dx
}
= a
2
b
2
, then the value of f
6
t | |
|
\ .
is
(q) 2
3
t
(C)
The value of
5
2 6
7
6
sec( x) dx
In3
t
t
}
is
(r)
3
t
(D)
The maximum value of
1
Arg
1 z
| |
|
\ .
for |z| = 1, z = 1 is
given by
(s)
t
(t)
2
t
34
60. (A) (q)
`
a j 3k = +
,
`
`
b j 3k = +
,
`
`
c 2 3k =
,
a b | a || b | cos = u
, ,
1 + 3 = 4 cos u
4 cos u = 2
cos u =
1
2
u =
3
t
Hence the angle is
2
3 3
t t | |
t =
|
\ .
(B) (p)
b
2 2
a
(f (x) 3x).dx a b =
}
let b = x, a = 0
x
2
0
(f (t) 3t).dt x =
}
f(x) 3x = 2x
f(x) = x
f
6 6
t t | |
=
|
\ .
(C) (s)
5/6
2
7/6
sec( x)dx
In3
t
t
}
=
5/6
2
7/6
1 x
In tan
In3 4 2
t t t | |
+
|
t
\ .
=
5 7
In tan In
In3 4 12 4 12
( t t t t t | | | |
+ +
( | |
\ . \ .

=
8
tan
12
In
10
In3
tan
12
t
t
t
=
2
tan
3
In
5
In3
tan
6
t
t
t
=
3
In
1
In3
3
t
= ln3
In3
t
t
(D) (s)
Let z = cos u + i sin u
1
Arg
1 (cos i sin )
| |
|
u+ u
\ .
a
,
b
,
c
,
u
35
1 1
Arg
2sin sin i cos
2 2 2
| |
|
u u u | |
|
| |
\ . \ .
1 1
Arg
i 2sin cos i sin
2 2 2
| |
|
u u u | |
| +
| |
\ . \ .
( )
i /2
i
Arg e
2sin
2
u
| |
|
u
|
\ .
i( /2 /2)
1
Arg e
2sin
2
t u
| |
|
u
|
\ .
2 2
t u
t < u s t
0 s
2 2
t u
< t
Maximum value = t

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PAPER 2

Time : 3 Hours Maximum Marks : 240

= 1.67 0.103 1.567 V =

In aqueous medium at 25C shifts towards the left in the presence of

9. (B), (C), (D)

forms ppt. with Cu

[i.e., constant w.r.t. distance from a point charge]

The no. of electrons =

So, slope of normal at P(6, 3) =

So, equation of normal y 3 = ( )

, where b is a constant such that 0 < b < 1.

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