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    7 Silicate Formation

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    Anonymous T02GVGzB
    The document contains thermodynamic data for various reactions involving quartz, soda ash, limestone, and carbon dioxide. It lists standard enthalpies, entropies, and Gibbs free energies at 298K for the reactions. It also provides heat capacity data and calculated thermodynamic values over a range of temperatures.

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    Attribution Non-Commercial (BY-NC)
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    7 Silicate Formation

    Uploaded by

    Anonymous T02GVGzB
    9 views15 pages
    The document contains thermodynamic data for various reactions involving quartz, soda ash, limestone, and carbon dioxide. It lists standard enthalpies, entropies, and Gibbs free energies at 298K for the reactions. It also provides heat capacity data and calculated thermodynamic values over a range of temperatures.

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    © Attribution Non-Commercial (BY-NC)

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    The document contains thermodynamic data for various reactions involving quartz, soda ash, limestone, and carbon dioxide. It lists standard enthalpies, entropies, and Gibbs free energies at 298K for the reactions. It also provides heat capacity data and calculated thermodynamic values over a range of temperatures.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLS, PDF, TXT or read online from Scribd
    Download as xls, pdf, or txt
    9 views15 pages

    7 Silicate Formation

    Uploaded by

    Anonymous T02GVGzB
    The document contains thermodynamic data for various reactions involving quartz, soda ash, limestone, and carbon dioxide. It lists standard enthalpies, entropies, and Gibbs free energies at 298K for the reactions. It also provides heat capacity data and calculated thermodynamic values over a range of temperatures.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLS, PDF, TXT or read online from Scribd
    Download as xls, pdf, or txt
    of 15

    T in C

    25
    SiO2
    quartz
    Na2CO3 soda ash
    CaCO3
    limestone
    CO2(g)
    Na2OSiO2
    Na2O2SiO2
    2Na2OCaO3SiO2
    reaction
    Na2CO3 + SiO2
    Na2CO3 + 2SiO2
    2Na2CO3 + CaCO3 + 3SiO2

    T in K

    -H(T)
    kJ/mol

    S(T)
    J/(molK)

    -G(T)
    kJ/mol

    298
    298
    298
    298
    298
    298
    298

    910.9
    1129.7
    1206.9
    393.5
    1563.1
    2473.6
    4763.0

    41.5
    135.0
    92.7
    213.7
    113.8
    164.4
    309.6

    923.3
    1170.0
    1234.5
    457.2
    1597.0
    2522.6
    4855.3

    <===>
    <===>
    <===>

    Na2OSiO2 + CO2
    Na2O2SiO2 + CO2
    2Na2OCaO3SiO2 +3CO2

    dG Teq in C
    39.0
    25
    36.7
    25
    117.3
    25

    cP(T)

    44.6
    111.3
    81.9
    37.2
    111.8
    156.5
    319.5

    cP1(T)

    cP2(T)

    cP3(T)

    cP4(T)

    cP5(T)

    H1(T)

    H2(T)

    H3(T)

    H4(T)

    44.606
    111.302
    81.874
    37.228
    111.814
    156.504
    319.539

    61.903
    88.565
    81.874
    37.228
    179.080
    292.880
    501.076

    61.903
    189.540
    81.874
    37.228
    179.080
    261.080
    501.076

    61.903
    189.540
    81.874
    37.228
    179.080
    261.080
    501.076

    61.903
    189.540
    81.874
    37.228
    179.080
    261.080
    501.076

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    911.480
    1115.839
    1206.900
    393.500
    1534.328
    2523.994
    4611.262

    911.480
    1125.475
    1206.900
    393.500
    1534.328
    2461.401
    4611.262

    911.480
    1125.475
    1206.900
    393.500
    1534.328
    2461.401
    4611.262

    H5(T)

    S1(T)

    S2(T)

    S3(T)

    S4(T)

    S5(T)

    G1(T)

    G2(T)

    G3(T)

    911.480
    1125.475
    1206.900
    393.500
    1534.328
    2461.401
    4611.262

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

    37.712
    161.623
    92.700
    213.700
    106.345
    64.575
    316.045

    37.712
    109.469
    92.700
    213.700
    106.345
    138.457
    316.045

    37.712
    109.469
    92.700
    213.700
    106.345
    138.457
    316.045

    37.712
    109.469
    92.700
    213.700
    106.345
    138.457
    316.045

    923.273
    1169.950
    1234.539
    457.215
    1597.029
    2522.616
    4855.336

    922.724
    1164.027
    1234.539
    457.215
    1566.035
    2543.247
    4705.491

    922.724
    1158.113
    1234.539
    457.215
    1566.035
    2502.682
    4705.491

    G4(T)

    G5(T)

    -H(298)

    S(298)

    T2

    T3

    T4

    T5

    Hm2

    922.724
    1158.113
    1234.539
    457.215
    1566.035
    2502.682
    4705.491

    922.724
    1158.113
    1234.539
    457.215
    1566.035
    2502.682
    4705.491

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

    847
    723
    3000
    3000
    1361
    983
    1483

    3000
    1130
    3000
    3000
    3000
    1147
    1483

    3000
    3000
    3000
    3000
    3000
    3000
    1483

    3000
    3000
    3000
    3000
    3000
    3000
    1483

    0.700
    0.700
    0.000
    0.000
    52.300
    2.500
    252.104

    Hm3

    Hm4

    Hm5

    A1

    A2

    A3

    A4

    A5

    B1

    0.000
    29.700
    0.000
    0.000
    0.000
    35.600
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    43.930
    11.000
    104.520
    44.140
    130.290
    185.690
    370.117

    58.910
    50.080
    104.520
    44.140
    179.080
    292.880
    501.076

    58.910
    189.540
    104.520
    44.140
    179.080
    261.080
    501.076

    58.910
    189.540
    104.520
    44.140
    179.080
    261.080
    501.076

    58.910
    189.540
    104.520
    44.140
    179.080
    261.080
    501.076

    38.830
    244.050
    21.920
    9.040
    40.170
    70.540
    67.948

    B2

    B3

    B4

    B5

    C1

    C2

    C3

    C4

    C5

    10.040
    129.080
    21.920
    9.040
    0.000
    0.000
    0.000

    10.040
    0.000
    21.920
    9.040
    0.000
    0.000
    0.000

    10.040
    0.000
    21.920
    9.040
    0.000
    0.000
    0.000

    10.040
    0.000
    21.920
    9.040
    0.000
    0.000
    0.000

    -9.690
    24.480
    -25.940
    -8.540
    -27.070
    -44.640
    -62.969

    0.000
    0.000
    -25.940
    -8.540
    0.000
    0.000
    0.000

    0.000
    0.000
    -25.940
    -8.540
    0.000
    0.000
    0.000

    0.000
    0.000
    -25.940
    -8.540
    0.000
    0.000
    0.000

    0.000
    0.000
    -25.940
    -8.540
    0.000
    0.000
    0.000

    D1

    D2

    D3

    D4

    D5

    E1

    E2

    E3

    E4

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    E5 hx hx hx

    0.000
    0.000
    0.000
    0.000
    0.000
    0.000
    0.000

    876.692
    1067.263
    834.673
    236.542
    1396.293
    2325.916
    4269.666

    hx hx hx

    hx hx hx

    hx hx hx

    hx hx hx

    hx hx hx

    hx hx hx

    hx hx hx

    874.712 707.581 707.581 707.581 707.581 707.581 707.581


    1079.724 997.506 928.471 613.367 613.367 613.367 613.367
    834.673 834.673 834.673 834.673 834.673 834.673 834.673
    236.542 236.542 236.542 236.542 236.542 236.542 236.542
    1320.465 1050.481 1050.481 1050.481 1050.481 1050.481 1050.481
    2270.521 2275.383 2266.777 1756.002 1756.002 1756.002 1756.002
    3917.220 4017.562 4017.562 4017.562 4017.562 4017.562 4017.562

    sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx sx dh dh dh

    103.904 109.345 200.848 200.848 200.848 200.848 200.848 200.848


    259.856 235.169 335.724 440.445 547.073 547.073 547.073 547.073
    378.791 378.791 378.791 378.791 378.791 378.791 378.791 378.791
    335.278 335.278 335.278 335.278 335.278 335.278 335.278 335.278
    339.829 424.139 519.800 519.800 519.800 519.800 519.800 519.800
    411.441 516.353 459.174 447.367 741.230 741.230 741.230 741.230
    949.888 1283.451 1119.884 1119.884 1119.884 1119.884 1119.884 1119.884

    876.692
    1067.263
    834.673
    236.542
    1396.293
    2325.916
    4269.666

    dh dh dh

    875.412
    1080.424
    834.673
    236.542
    1372.765
    2273.021
    4169.324

    dh dh dh

    dh dh dh

    dh dh dh

    dh dh dh

    dh dh dh

    dh dh dh

    707.000 707.000 707.000 707.000 707.000 707.000


    1011.367 972.031 617.591 617.591 617.591 617.591
    834.673 834.673 834.673 834.673 834.673 834.673
    236.542 236.542 236.542 236.542 236.542 236.542
    1079.253 1079.253 1079.253 1079.253 1079.253 1079.253
    2224.989 2251.982 1768.201 1768.201 1768.201 1768.201
    4169.324 4169.324 4169.324 4169.324 4169.324 4169.324

    ds ds ds

    ds ds ds

    103.904 108.519
    259.856 234.201
    378.791 378.791
    335.278 335.278
    339.829 385.711
    411.441 513.809
    949.888 1113.455

    ds ds ds

    ds ds ds

    ds ds ds

    ds ds ds

    ds ds ds

    ds ds ds

    204.636 204.636 204.636 204.636 204.636 204.636


    309.101 387.539 572.604 572.604 572.604 572.604
    378.791 378.791 378.791 378.791 378.791 378.791
    335.278 335.278 335.278 335.278 335.278 335.278
    527.255 527.255 527.255 527.255 527.255 527.255
    559.000 516.155 767.174 767.174 767.174 767.174
    1113.455 1113.455 1113.455 1113.455 1113.455 1113.455

    -H1

    -H2

    -H3

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    -H4

    -H5

    S1

    S2

    S3

    S4

    S5

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    910.900
    1129.700
    1206.900
    393.500
    1563.100
    2473.600
    4763.024

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

    41.500
    135.000
    92.700
    213.700
    113.800
    164.400
    309.616

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