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    Tempo M Edio de Resid Encia: FGF 2012 (IST)

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    Filipe Gama Freire
    The document describes modeling a non-ideal continuously stirred tank reactor (CSTR) based on experimental residence time data. The model consists of three parameters: a bypass that diverts 30% of the feed, a plug flow reactor (PFR) with a residence time of 5 minutes, and a CSTR with a residence time of 8 minutes. The volumes of the PFR and CSTR were calculated to be 0.35 L and 0.56 L, respectively, with the remaining volume of 0.59 L attributed to a holdup tank.

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    Tempo M Edio de Resid Encia: FGF 2012 (IST)

    Uploaded by

    Filipe Gama Freire
    16 views19 pages
    The document describes modeling a non-ideal continuously stirred tank reactor (CSTR) based on experimental residence time data. The model consists of three parameters: a bypass that diverts 30% of the feed, a plug flow reactor (PFR) with a residence time of 5 minutes, and a CSTR with a residence time of 8 minutes. The volumes of the PFR and CSTR were calculated to be 0.35 L and 0.56 L, respectively, with the remaining volume of 0.59 L attributed to a holdup tank.

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    The document describes modeling a non-ideal continuously stirred tank reactor (CSTR) based on experimental residence time data. The model consists of three parameters: a bypass that diverts 30% of the feed, a plug flow reactor (PFR) with a residence time of 5 minutes, and a CSTR with a residence time of 8 minutes. The volumes of the PFR and CSTR were calculated to be 0.35 L and 0.56 L, respectively, with the remaining volume of 0.59 L attributed to a holdup tank.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    16 views19 pages

    Tempo M Edio de Resid Encia: FGF 2012 (IST)

    Uploaded by

    Filipe Gama Freire
    The document describes modeling a non-ideal continuously stirred tank reactor (CSTR) based on experimental residence time data. The model consists of three parameters: a bypass that diverts 30% of the feed, a plug flow reactor (PFR) with a residence time of 5 minutes, and a CSTR with a residence time of 8 minutes. The volumes of the PFR and CSTR were calculated to be 0.35 L and 0.56 L, respectively, with the remaining volume of 0.59 L attributed to a holdup tank.

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    © All Rights Reserved
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    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal

    Tempo medio de residencia


    A resposta de um reactor a uma experiencia com um tracador introduzido
    como um pulso no reactor e dado na gura. Qual e o tempo medio de
    residencia para este reactor nao-ideal?
    t(min)
    C(t)
    mol /m
    3
    5 15
    0,5
    10
    FGF 2012 (IST) Problemas de DTR November 30, 2012 1 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Denic oes necessarias
    E(t) =
    c(t)

    0
    c(t) dt


    0
    E(t) dt = 1

    t =


    0
    t E(t) dt
    FGF 2012 (IST) Problemas de DTR November 30, 2012 2 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Normalizacao da resposta em concentracao


    0
    c(t) dt = (0, 5)(15 5)
    1
    2
    = 2, 5
    mol
    m
    3
    min
    t(min)
    C(t)
    mol /m
    3
    5 15
    0,5
    10
    FGF 2012 (IST) Problemas de DTR November 30, 2012 3 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    DTR - E(t)
    t(min)
    E(t)
    min
    1
    5 15
    0,2
    10
    declive=
    00,2
    155
    = 0, 02
    E(t) = 0 t < 5 t > 15
    E(t) = 0, 02 t + b
    t = 15 E(t) = 0 0 = 0, 02(15) + b b = 0, 3
    E(t) = 0, 02 t + 0, 3
    FGF 2012 (IST) Problemas de DTR November 30, 2012 4 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal

    t =


    0
    t E(t) dt =

    15
    5
    t(0.03 0, 02 t) dt =
    0, 3t
    2
    2

    15
    5

    0, 02t
    3
    3

    5
    5

    t = 0, 15(15
    2
    5
    2
    ) 0, 00667(15
    3
    5
    3
    ) = 8, 2 min
    FGF 2012 (IST) Problemas de DTR November 30, 2012 5 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    DTR - Modelacao
    Um reactor contnuo agitado nao ideal tem a seguinte resposta
    normalizada para um tracador introduzido em degrau.
    t(min)
    1
    min
    1
    0,3
    5
    0,3
    0, 3 + 0, 7[1 e
    (t5)/8
    ]
    10
    FGF 2012 (IST) Problemas de DTR November 30, 2012 6 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Como compreender a resposta?
    1
    Desenvolva um modelo com 3 parametros deste reactor nao ideal.
    O modelo pode consistir em reactores ideais, recrculos, bypass e
    volumes mortos.
    2
    Determine o valor desses parametros para esse modelo.
    O volume total do reactor e de 1,5 L e o caudal de entrada de 0,10
    L/min.
    FGF 2012 (IST) Problemas de DTR November 30, 2012 7 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Bypass
    Pela analise da curva, existe um bypass, pois se a entrada em degrau
    normalizada e
    t(min)
    1
    min
    1
    0,0
    t=0
    FGF 2012 (IST) Problemas de DTR November 30, 2012 8 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Bypass
    e se vemos imediatamente tra cador, implica que 30% da alimentacao nao
    vai ao reactor.
    t(min)
    1
    min
    1
    0,3
    5
    0,3
    0, 3 + 0, 7[1 e
    (t5)/8
    ]
    10
    FGF 2012 (IST) Problemas de DTR November 30, 2012 9 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Bypass
    O nosso modelo e, ate agora:
    0,1 L/min 0,07 L/min
    0,03 L/min
    sada
    detector
    FGF 2012 (IST) Problemas de DTR November 30, 2012 10 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    PFR
    Como a resposta esta atrasada de 5 min, corresponde a ter-se um PFR de
    = 5min:
    0,1 L/min
    PFR
    = 5min
    0,03 L/min
    sada
    detector
    0,07 L/min
    Isto e:
    PFR
    =5 min=
    V
    PFR
    Q
    V
    PFR
    = 0, 35 L
    FGF 2012 (IST) Problemas de DTR November 30, 2012 11 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    PFR
    O nosso modelo e, ate agora:
    0,1 L/min
    PFR
    = 5min
    0,03 L/min
    sada
    detector
    0,07 L/min
    FGF 2012 (IST) Problemas de DTR November 30, 2012 12 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    CSTR
    t(min)
    1
    min
    1
    0,3
    5
    0,3
    0, 3 + 0, 7[1 e
    (t5)/8
    ]
    10
    A aproxima cao para estado estacionario indica ser um CSTR,
    FGF 2012 (IST) Problemas de DTR November 30, 2012 13 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    CSTR
    O nosso modelo e, ate agora:
    0,1 L/min
    PFR
    = 5min
    0,03 L/min
    sada
    detector
    0,07 L/min
    CSTR
    FGF 2012 (IST) Problemas de DTR November 30, 2012 14 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    CSTR
    Tra cador para t> 5 min
    0, 7[1 e
    (t5)/8
    ]
    com:
    0,7 o caudal.
    5 - o atraso gerado pelo PFR
    e o 8 e o tempo de permanencia no CSTR
    teremos entao
    CSTR
    = 8 min =
    V
    CSTR
    Q
    =
    V
    CSTR
    0,7 L/min
    V
    CSTR
    = 0, 56 L
    FGF 2012 (IST) Problemas de DTR November 30, 2012 15 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Volume Morto
    Como o volume total do reactor e de 1,5 L e o
    V
    CSTR
    + V
    PFR
    = 0, 56 + 0, 35 = 0, 91 L
    Quer dizer que ha um volume morto de V
    holdup
    = 1, 5 0, 91 = 0, 59 L
    FGF 2012 (IST) Problemas de DTR November 30, 2012 16 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    VOLUME MORTO
    e o esquema do nosso modelo vem:
    holdup
    0,1 L/min
    PFR
    = 5min
    0,03 L/min
    sada
    detector
    0,07 L/min
    CSTR
    FGF 2012 (IST) Problemas de DTR November 30, 2012 17 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Qual seria a resposta deste sistema a um tra cador
    introduzido em pulso?
    FGF 2012 (IST) Problemas de DTR November 30, 2012 18 / 19
    Tempo Medio de Residencia Modelo de um reactor CSTR nao ideal
    Qual seria a resposta deste sistema a um tra cador
    introduzido em pulso?
    0
    t(min)
    Con.
    5 min
    exp.
    FGF 2012 (IST) Problemas de DTR November 30, 2012 19 / 19

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