TRB Syllabus

SYLLABUS FOR COMPETITIVE EXAMINATION FOR
RECRUITMENT OF
ASSISTANT PROFESSORS IN GOVERNMENT ENGINEERING
COLLEGES
2011

T E A C H E R S R E C R U I T M E NT B O A R D , C H E N N A I 6 0 0
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CIVIL ENGINEERING

Unit 1: Engineering Mathematics

Linear Algebra: Matrix algebra, Systems of linear equations, Eigen values and
eigenvectors.

Calculus: Functions of single variable, Limit, continuity and differentiability, Mean
value theorems, Evaluation of definite and improper integrals, Partial derivatives,
Total derivative, Maxima and minima, Gradient, Divergence and Curl, Vector
Identities, Directional derivatives, Line, Surface and Volume integrals, Stokes, Gauss
and Greens theorems.

Differential equations: First order equations ( linear and nonlinear), Higher order
linear differential equations with constant coefficients, Cauchys and Euler s
equations, Initial and boundary value problems, Laplace transforms, Solutions of one
dimensional heat and wave equations and Laplace equation.

Complex variables: Analytic functions, Cauchys Integral theorem, Taylor and
Laurent series.

Probability and Statistics: Definitions of probability and sampling theorems,
Conditional probability, Mean, median, mode and standard deviation, Random
variables, Poisson, Normal and Binomial distributions.

Numerical Methods: Numerical solutions of linear and non-linear algebraic equations
Integration by trapezoidal and Simpsons rule, single and multi-step methods for
differential equations.

Unit 2: Mechanics

Bending moment and shear force in statically determinate beams. Simple stress and
strain relationship; Stress and strain in two dimensions, principal stresses, stress
transformation, Mohr s circle. Simple bending theory, flexural and shear stresses,
unsymmetrical bending, shear centre. Thin walled pressure vessels, uniform torsion,
buckling of column, combined and direct bending stresses.

Unit 3: Structural Analysis

Analysis of statically determinate trusses, arches, beams, cables and frames,
displacements in statically determinate structures and analysis of statically
indeterminate structures by force/energy methods, analysis by displacement
methods (slope deflection and moment distribution methods), influence lines for
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determinate and indeterminate structures. Basic concepts of matrix methods of
structural analysis.

Unit 4: Concrete Structures

Concrete Technology- properties of concrete, basics of mix design. Concrete
design-basic working stress and limit state design concepts, analysis of ultimate load
capacity and design of members subjected to flexure, shear, compression and
torsion by limit state methods. Basic elements of prestressed concrete, analysis of
beam sections at transfer and service loads.

Unit 5: Steel Structures

Analysis and design of tension and compression members, beams and beam-
columns, column bases. Connections-simple and eccentric, beam-column
connections, plate girders and trusses. Plastic analysis of beams and frames.

Unit 6: Soil Mechanics

Origin of soils, soil classification, three-phase system, fundamental definitions,
relationship and interrelationships, permeability and seepage, effective stress
principle, consolidation, compaction, shear strength.

Unit 7: Foundation Engineering

Sub-surface investigations- scope, drilling bore holes, sampling, penetration tests,
plate load test. Earth pressure theories, effect of water table, layered soils. Stability
of slopes-infinite slopes, finite slopes. Foundation types-foundation design
requirements. Shallow foundations-bearing capacity, effect of shape, water table and
other factors, stress distribution, settlement analysis in sands and clays. Deep
foundations-pile types, dynamic and static formulae, load capacity of piles in sands
and clays, negative skin friction.

Unit 8: Fluid Mechanics and Hydraulics:

Properties of fluids, principle of conservation of mass, momentum, energy and
corresponding equations, potential flow, applications of momentum and Bernoulli s
equation, laminar and turbulent flow, flow in pipes, pipe networks. Concept of
boundary layer and its growth. Uniform flow, critical flow and gradually varied flow in
channels, specific energy concept, hydraulic jump. Forces on immersed bodies, flow
measurements in channels, tanks and pipes. Dimensional analysis and hydraulic
modeling. Kinematics of flow, velocity triangles and specific speed of pumps and
turbines.

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Hydrology: Hydrologic cycle, rainfall, evaporation, infiltration, stage discharge
relationships, unit hydrographs, flood estimation, reservoir capacity, reservoir and
channel routing. Well hydraulics.

Irrigation: Duty, delta, estimation of evapo-transpiration. Crop water requirements.
Design of: lined and unlined canals, waterways, head works, gravity dams and
spillways. Design of weirs on permeable foundation. Types of irrigation system,
irrigation methods. Water logging and drainage, sodic soils.

Unit 9: Water requirements

Quality standards, basic unit processes and operations for water treatment. Drinking
water standards, water requirements, basic unit operations and unit processes for
surface water treatment, distribution of water. Sewage and sewerage treatment,
quantity and characteristics of wastewater. Primary, secondary and tertiary treatment
of wastewater, sludge disposal, effluent discharge standards. Domestic wastewater
treatment, quantity of characteristics of domestic wastewater, primary and secondary
treatment Unit operations and unit processes of domestic wastewater, sludge
disposal.

Air Pollution: Types of pollutants, their sources and impacts, air pollution
meteorology, air pollution control, air quality standards and limits.

Municipal Solid Wastes: Characteristics, generation, collection and transportation of
solid wastes, engineered systems for solid waste management (reuse/recycle,
energy recovery, treatment and disposal).

Noise Pollution: Impacts of noise, permissible limits of noise pollution, measurement
of noise and control of noise pollution.

Unit 10: Highway Planning

Geometric design of highways, testing and specifications of paving materials, design
of flexible and rigid pavements.

Traffic Engineering: Traffic characteristics, theory of traffic flow, intersection design,
traffic signs and signal design, highway capacity.

Importance of surveying, principles and classifications, mapping concepts,
coordinate system, map projections, measurements of distance and directions,
leveling, theodolite traversing, plane table surveying, errors and adjustments, curves.

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MECHANICAL ENGINEERING


eigenvectors.

Total derivative, Maxima and minima, Gradient, Divergence and Curl, Vector
identities, Directional derivatives, Line, Surface and Volume integrals, Stokes, Gauss

Differential equations: First order equations ( linear and nonlinear), Higher order

Complex variables: Analytic functions, Cauchys integral theorem, Taylor and
Laurent series.


Numerical Methods: Numerical solutions of linear and non-linear algebraic equations
Integration by trapezoidal and Simpsons rule, single and multi-step methods for

Unit 2: Applied Mechanics and Design

Engineering Mechanics: Free body diagrams and equilibrium; trusses and frames;
virtual work; kinematics and dynamics of particles and of rigid bodies in plane
motion, including impulse and momentum (linear and angular) and energy
formulations; impact.

Strength of Materials: Stress and strain, stress-strain relationship and elastic
constants, Mohr s circle for plane stress and plane strain, thin cylinders; shear force
and bending moment diagrams; bending and shear stresses; deflection of beams;
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torsion of circular shafts; Eulers theory of columns; strain energy methods; thermal
stresses.

Unit 3: Theory of Machines and Vibrations

Displacement, velocity and acceleration analysis of plane mechanisms; dynamic
analysis of slider-crank mechanism; gear trains; flywheels.

Vibrations: Free and forced vibration of single degree of freedom systems; effect of
damping; vibration isolation; resonance, critical speeds of shafts.

Design: Design for static and dynamic loading; failure theories; fatigue strength and
the S-N diagram; principles of the design of machine elements such as bolted,
riveted and welded joints, shafts, spur gears, rolling and sliding contact bearings,
brakes and clutches.

Unit 4: Fluid Mechanics

Fluid Mechanics: Fluid properties; fluid statics, manometry, buoyancy; control-
volume analysis of mass, momentum and energy; fluid acceleration; differential
equations of continuity and momentum; Bernoulli s equation; viscous flow of
incompressible fluids; boundary layer; elementary turbulent flow; flow through pipes,
head losses in pipes, bends etc.

Unit 5: Heat-Transfer

Modes of heat transfer; one dimensional heat conduction, resistance concept,
electrical analogy, unsteady heat conduction, fins; dimensionless parameters in free
and forced convective heat transfer, various correlations for heat transfer in flow over
flat plates and through pipes; thermal boundary layer; effect of turbulence; radiative
heat transfer, black and grey surfaces, shape factors, network analysis; heat
exchanger performance, LMTD and NTU methods.

Unit 6: Thermodynamics and Applications

Zeroth, First and Second laws of thermodynamics; thermodynamic system and
processes; Carnot cycle, irreversibility and availability; behaviour of ideal and real
gases, properties of pure substances, calculation of work and heat in ideal
processes; analysis of thermodynamic cycles related to energy conversion.

Power Engineering: Steam Tables, Rankine, Brayton cycles with regeneration and
reheat. I.C. Engines: air-standard Otto, Diesel cycles. Refrigeration and air-
conditioning: Vapour refrigeration cycle, heat pumps, gas refrigeration, Reverse
Brayton cycle; moist air; psychrometric chart, basic psychrometric processes.
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Turbomachinery: Pelton-wheel, Francis and Kaplan turbines impulse and reaction
principles, velocity diagrams.

Unit 7: Manufacturing Engineering

Engineering Materials: Structure and properties of engineering materials, heat
treatment, stress-strain diagrams for engineering materials.

Metal Casting: Design of patterns, moulds and cores; solidification and cooling; riser
and gating design, design considerations.

Forming: Plastic deformation and yield criteria; fundamentals of hot and cold working
processes; load estimation for bulk (forging, rolling, extrusion, drawing) and sheet
(shearing, deep drawing, bending) metal forming processes; principles of powder
metallurgy.

J oining: Physics of welding, brazing and soldering; adhesive bonding; design
considerations in welding.

Unit 8: Machining and Machine Tool Operations

Mechanics of machining, single and multi-point cutting tools, tool geometry and
materials, tool life and wear; economics of machining; principles of non-traditional
machining processes; principles of work holding, principles of design of jigs and
fixtures

Metrology and Inspection: Limits, fits and tolerances; linear and angular
measurements; comparators; gauge design; interferometry; form and finish
measurement; alignment and testing methods; tolerance analysis in manufacturing
and assembly.

Computer Integrated Manufacturing: Basic concepts of CAD/CAM and their
integration tools.

Unit 9: Production Planning and Control

Forecasting models, aggregate production planning, scheduling, materials
requirement planning.

Inventory Control: Deterministic and probabilistic models; safety stock inventory
control systems.

Unit 10: Operations Research:

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Linear programming, simplex and duplex method, transportation, assignment,
network flow models, simple queuing models, PERT and CPM.

ELECTRICAL AND ELECTRONICS ENGINEERING


Linear Algebra: Matrix Algebra, Systems of Linear equations, Eigen Values and
eigen vectors.

Calculus: Mean Value Theorems, Theorems of integral Calculus Evaluation of
definite and improper integrals, Partial Derivatives, Maxima and minima, Multiple
integrals, Fourier series. Vector identities, Directional derivatives, Line, Surface and
Volume integrals, Stokes, Gauss and Greens theorems.

Differential equations: First order equation (linear and nonlinear), Higher order linear
differential equations with constant coefficients, Method of variation of parameters,
Cauchys and Euler s equations, initial and boundary value problems, Partial
Differential Equations and variable separable method.

Complex variables: Analytic functions, Cauchys integral theorem and integral
formula, Taylor s and Laurent series, Residue theorem, solution integrals.

Probability and Statistics: Sampling theorems, Conditional probability, Mean,
median, mode and standard deviation, Random variables, Discrete and continuous
distributions, Poisson, Normal and Binomial distribution, Correlation and regression
analysis.

Numerical Methods: Solutions of non-linear algebraic equations, single and multi-
step methods for differential equations.

Transform Theory: Fourier transform, Laplace transform, Z-transform.

Unit 2: Electric Circuits and Fields

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2011

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Network graph, KCL, KVL, node and mesh analysis, transient response of dc and ac
networks; sinusoidal steady-state analysis, resonance, basic filter concepts; ideal
current and voltage sources, Thevenins, Nortons and Superposition and Maximum
Power Transfer theorems, two-port networks, three phase circuits.

Gauss Theorem, electric field and potential due to point, line, plane and spherical
charge distributions; Amperes and Biot-Savarts laws; inductance; dielectrics;
capacitance.

Unit 3: Signals and Systems

Representation of continuous and discrete-time signals; shifting and scaling
operations; linear, time-invariant and casual systems; Fourier series representation
of continuous periodic signals; sampling theorem; Fourier, Laplace and Z transforms.

Unit 4: Electrical Machines

Single Phase transformer equivalent circuit, phasor diagram, tests, regulation and
efficiency; three phase transformers connections, parallel operation; auto-
transformer; energy conversion principles; DC machines types, windings,
generator characteristics, armature reaction and commutation, starting and speed
control of motors; three phase induction motors principles, types, performance
characteristics, starting and speed control; Single phase induction motors;
synchronous machines performance, regulation and parallel operation of
generators, motor starting, characteristics and applications; servo and stepper
motors.

Unit 5: Power Systems

Basic power generation concepts; transmission line models and performance; cable
performance insulation; corona and radio interference; distribution systems; per-unit
quantities; bus impedance and admittance matrices; load flow; voltage control;
power factor correction; economic operation; symmetrical components; fault
analysis.

Unit 6: Protection and switchgear

Principles of over-current, differential and distance protection; solid state relays and
digital protection; circuit breakers; system stability concepts, swing curves and equal
area criterion; HVDC transmission and FACTS concepts.
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Unit 7: Control Systems

Principles of feedback; transfer function; block diagrams; steady state errors;
Routh and Niquist techniques; Bode plots; root loci; lag, lead and lead-leg
compensation; state space model; state transition matrix, controllability and
observability.

Unit 8: Electrical and Electronic Measurements

Bridges and potentiometers; PMMC, moving iron, dynamometer and induction type
instruments; measurement of voltage, current, power, energy and power factor;
instrument transformers; digital voltmeters and multimeters; phase, time and
frequency measurement; Q-meters; Oscilloscopes; potentiometric recorders; error
analysis.

Unit 9: Analog and Digital Electronics

Characteristics of diodes, BJ T, FET; amplifiers biasing, equivalent circuit and
frequency response; oscillators and feedback amplifiers; operational amplifiers
characteristics and applications; simple active filters; VCOs and timers;
combinational and sequential logic circuits; multiplexer; Schmitt trigger; multi-
vibrators; sample and hold circuits; A/D and D/A convertors; 8-bit microprocessor
basics, architecture, programming and interfacing.

Unit 10: Power Electronics and Drives

Semiconductor power diodes, transistors, thyristors, triacs, GTOs, MOSFETs and
IGBTs static characteristics and principles of operation; triggering circuits; phase
control rectifiers; bridge converters fully controlled and half controlled; principles of
choppers and inverters; basis concepts of adjustable speed dc and ac drives.

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2011

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ELECTRONICS AND COMMUNICATION ENGINEERING


Linear Algebra: Matrix Algebra, Systems of linear equations, Eigen values and eigen
vectors.

Calculus: Mean value theorems, Theorems of integral calculus, Evaluation of definite
and improper integrals, Partial Derivatives, Maxima and minima, Multiple integrals,
Fourier series. Vector identities, Directional derivatives, Line, Surface and Volume
integrals, Stokes, Gauss and Greens theorems.

Differential equations: First order equation (linear and nonlinear), Higher order linear
differential equations with constant coefficients, Method of variation of parameters,
Cauchys and Euler s equations, Initial and boundary value problems, Partial
Differential Equations and variable separable method.

Complex variables: Analytic functions, Cauchys integral theorem and integral
formula, Taylor s and Laurent series, Residue theorem, solution integrals.

Probability and Statistics: Sampling theorems, Conditional probability, Mean,
median, mode and standard deviation, Random variables, Discrete and continuous
distributions, Poisson, Normal and Binomial distribution, Correlation and regression
analysis.

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Numerical Methods: Solutions of non-linear algebraic equations, single and muti-step
methods for differential equations.

Transform Theory: Fourier transform, Laplace transform, Z-transform.

Unit 2: Networks

Network graphs: matrices associated with graphs; incidence, fundamental cut set
and fundamental circuit matrices. Solution methods: nodal and mesh analysis.
Network theorems: superposition, Thevenin and Nortons maximum power transfer,
Wye-Delta transformation. Steady state sinusoidal analysis using phasors. Linear
constant coefficient differential equations; time domain analysis of simple RLC
circuits, Solution of network equations using Laplace transform: frequency domain
analysis of RLC circuits. 2-port network parameters: driving point and transfer
functions. State equations for networks.

Unit 3: Electronic Devices

Energy bands in silicon, intrinsic and extrinsic silicon. Carrier transport in silicon:
diffusion current, drift current, mobility and resistivity. Generation and recombination
of carriers. p-n junction diode, Zener diode, tunnel diode, BJ T, J FET, MOS capacitor,
MOSFET, LED, p-l-n and avalanche photo diode, Basics of LASERs. Device
technology: integrated circuits fabrication process, oxidation, diffusion, ion
implantation, photolithography, n-tub, p-tub and twin-tub CMOS process.

Unit 4: Analog Circuits

Small Signal Equivalent circuits of diodes, BJ Ts MOSFETs and analog CMOS.
Simple diode circuits, clipping, clamping, rectifier. Biasing and bias stability of
transistor and FET amplifiers. Amplifiers: single-and multi-stage, differential and
operational, feedback, and power. Frequency response of amplifiers. Simple op-amp
circuits. Filters. Sinusoidal oscillators; criterion for oscillation; single-transistor and
op-amp configurations. Function generators and wave- shaping circuits, 555 Timers.
Power supplies.

Unit 5: Digital Circuits

Boolean algebra, minimization of Boolean functions; logic gates; digital IC families
(DTL, TTL, ECL, MOS, CMOS). Combinatorial circuits: arithmetic circuits, code
converters, multiplexers, decoders, PROMs and PLAs. Sequential circuits: latches
and flip-flops, counters and shift-registers. Sample and hold circuits, ADCs, DACs.
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Semiconductor memories. Microprocessor (8085): architecture, programming,
memory and I/O interfacing.


Definitions and properties of Laplace transform, continuous-time and discrete-time
Fourier series, continuous-time and discrete-time Fourier Transform, DFT and FFT,
z-transform. Sampling theorem. Linear Time-Invariant (LTI) Systems: definitions and
properties; causality, stability, impulse response, convolution, poles and zeros,
parallel and cascade structure, frequency response, group delay, phase delay.
Signal transmission through LTI systems.


Basic control system components; block diagrammatic description, reduction of block
diagrams. Open loop and closed loop (feedback)systems and stability analysis of
these systems. Signal flow graphs and their use in determining transfer functions of
systems; transient and steady state analysis of LTI control systems and frequency
response. Tools and techniques for LTI control system analysis; root loci, Routh-
Hurwitz criterion, Bode and Nyquist plots. Control system compensators: elements of
lead and lag compensation, elements of Proportional-Integral-Derivative (PID)
control. State variable representation and solution of state equation of LTI control
systems.

Unit 8: Analog Communication Systems

Random signals and noise: probability, random variables, probability density
function, autocorrelation, power spectral density. Analog communication systems:
amplitude and angle modulation and demodulation systems, spectral analysis of
these operations, superheterodyne receivers; elements of hardware, realizations of
analog communication systems; signal-to-noise ratio (SNR) calculations for
amplitude modulation (AM) and frequency modulation (FM) for low noise conditions.
Fundamentals of information theory and channel capacity theorem.

Unit 9: Digital Communication Systems

pulse code modulation (PCM), differential pulse code modulation (DPCM), digital
modulation schemes: amplitude, phase and frequency shift keying schemes (ASK,
PSK, FSK), matched filter receivers, bandwidth consideration and probability of error
calculations for these schemes. Basics of TDMA, FDMA and CDMA and GSM.

Unit 10: Electromagnetics

Elements of vector calculus: divergence and curl; Gauss and Stokes theorems,
Maxwell s equations; differential and integral forms. Wave equation, Poynting vector.
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Plane waves: propagation through various media; reflection and refraction; phase
and group velocity; skin depth. Transmission lines; characteristics impedance;
impedance transformation; Smith chart; impedance matching; S parameters, pulse
excitation. Waveguides: modes in rectangular waveguides; boundary conditions; cut-
off frequencies; dispersion relations. Basics of propagation in dielectric waveguide
and optical fibers. Basics of Antennas: Dipole antennas; radiation pattern; antenna
gain.

ELECTRONICS AND INSTRUMENTATION


Linear algebra-Matrix algebra-eigen values and eigen vectors; Calculus-evaluation of
definite integrals, partial derivatives, maxima and minima, multiple integrals;
Differential equations- first order (linear and non-linear), higher order linear
differential equations with constant coefficients, Cauchys and Euler s equations,
initial and boundary value problems; partial differential equations-variable separable
method; Complex variables-analytic functions, Cauchys integral theorem and
integral formula, Taylor s series, residue theorem; Numerical methods-solutions of
non-linear algebraic equations and differential equations.

Unit 2: Electric Circuits

Ohms law, KCL, KVL, node and mesh analysis, ideal current and voltage sources,
Network theorems: superposition, Thevenins, Nortons, maximum power transfer;
sinusoidal steady-state analysis; resonance; transient analysis of dc and ac
networks; two-port networks; three-phase circuits.

Unit 3: Analog and Digital Circuits

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Characteristics of diodes, BJ Ts, J FETs and MOSFETs; Amplifiers-single and
multistage; Frequency response; Operational amplifiers - design, characteristics,
linear and non-linear applications; instrumentation amplifiers; precision rectifiers; I
to-V and V-to I converters; active filters; comparators; signal generators and wave
shaping circuits.

Combinational logic circuits-minimization of Boolean functions; IC families (TTL,
MOS, CMOS); arithmetic circuits, multiplexer and decoders. Sequential circuits-flip-
flops, counters, shift registers, schmitt trigger, timers, multivibrators and S/H circuits.
Analog-to-digital and digital-to-analog converters. 8-bit and 16-bit microprocessors
(architecture, memory and I/O interfacing) and 8-bit microcontroller.


Linear Time-Invariant (LTI) Systems-definitions and properties; causality, stability;
Laplace transform and transfer function; Fourier series-Fourier transforms; Impulse
and frequency responses of first and second order systems; Discrete time systems,
difference equations, impulse and frequency responses; Z-transforms and transfer
functions; convolution and correlation; IIR and FIR filters.

Unit 5: Electrical and Electronic Measurements

Measurement of R, L and C; bridges and potentiometers; measurement of voltage,
current, power, power factor and energy; instrument transformers; Q-meter;
waveform analyzers. Digital volt-meters and multi-meters. Time, phase and
frequency measurements; Oscilloscope; Noise and interference in instrumentation.
Introduction to virtual instrumentation.

Unit 6: Transducers and Smart Instruments

Static and dynamic characteristics of transducers; units and standards; calibration
techniques; classification of errors-error analysis; variable resistance, variable
inductance and variable capacitance transducers; piezo-electric transducers; fibre-
optic transducers; ultrasonic transducers; smart transducers; introduction to micro
electro mechanical systems (MEMS).

Unit 7: Industrial and Analytical instrumentation

Pressure, flow, temperature and level measurements- principle of operation,
installation and maintenance, calibration; measurement of force, torque, velocity,
vibration, humidity, viscosity, and density.

Spectrophotometers (UV and IR); pH meters; conductivity meters; analyzers (O
2,
NO
2,
H
2
S), chromatography (gas and liquid); NMR spectroscopy, X-ray spectroscopy
and mass spectrometer.
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Principles of feedback; transfer function, signal flow graphs; time response analysis;
Bode plots, root-loci, Routh and Nyquist criteria; compensation techniques; State
space analysis.

Unit 9: Process control

Batch and continuous process; modeling-level, flow and thermal processes; servo
and regulator operations; interacting and non-interacting systems; control actions
(on-off, P,I, D, PI and PID) and controller tuning; complex control techniques( feed-
forward, cascade, ratio and split-range); dynamic matrix control; distillation column
control; control of heat exchanger; valve-types, characteristics, sizing, positioners,
cavitation and flashing.

Unit 10: Logic and Distributed control system

PLC-sequential and programmable controllers, programming logic-ladder logic and
function block programming; data acquisition system (DAS); direct digital control
(DDC); supervisory control and data acquisition system (SCADA); distributed control
system (DCS); HART and Field bus, OLE for process control (OPC)

COMPUTER SCIENCE AND ENGINEERING / INFORMATION
TECHNOLOGY


Mathematical Logic: Propositional Logic; First Order Logic.

Probability: Conditional Probability; Mean, Median, Mode and Standard Deviation;
Random variables; Distributions; uniform, normal, exponential, Poisson, Binomial.

Set Theory and Algebra: Sets; Relations; Functions; Groups; Partial Orders; Lattice;
Boolean Algebra.

Combinatorics: Permutations; Combinations; Counting; Summation; generating
functions; recurrence relations; asymptotics.

Graph Theory: Connectivity; spanning trees; cut vertices & edges; covering;
matching; independent sets; Colouring; Planarity; Isomorphism.

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Linear Algebra: Algebra of matrices, determinants, systems of linear equations,
Eigen values and Eigen Vectors.

Numerical Methods: LU decomposition for systems of linear equations; numerical
solutions of non-linear algebraic equations by Secant, Bisection and Newton-
Raphson Methods; Numerical integration by trapezoidal and Simpsons rules.

Calculus: Limit, Continuity & differentiability, Mean Value Theorems, Theorems of
integral calculus, evaluation of definite& improper integrals, Partial derivatives, Total
derivatives, maxima & minima.

Unit 2: Theory of Computation

Regular languages and finite automata, Context free languages and Push-down
automata, Recursively enumerable sets and Turing machines, Undecidability; NP-
completeness.

Unit 3: Digital Logic

Logic Functions, Minimization, Design and synthesis of combinational and sequential
circuits; Number representation and computer arithmetic (fixed and floating point).

Unit 4: Computer Organization and Architecture

Machine instructions and addressing modes, ALU and data-path, CPU control
design, Memory interface, I/O interface (interrupt and DMA mode), Instruction
pipelining, Cache and main memory, Secondary storage.

Unit 5: Programming and Data Structures

Programming in C; Functions, Recursion, Parameter passing, Scope, Binding;
Abstract data types, Arrays, Stacks, Queues, Linked Lists, Trees, Binary search
trees, Binary heaps.

Unit 6: Algorithms

Analysis, Asymptotic notation, Notions of space and time complexity, Worst and
average case analysis; Design: Greedy approach, Dynamic programming, Divide-
and-conquer; Tree and graph traversals, Connected components, Spanning trees,
Shortest paths; Hashing, Sorting, Searching.

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Unit 7: Compiler Design

Lexical analysis, Parsing, Syntax directed translation, Runtime environments,
Intermediate and target code generation, Basics of code optimization.

Unit 8: Operating System

Processes, Threads, Inter-process communication, Concurrency, Synchronization,
Deadlock, CPU scheduling, Memory management and virtual memory, File systems,
I/O systems, Protection and security.

Unit 9: Databases

ER-model, Relational model (relational algebra, tuple calculus), Database design
(integrity constraints, normal forms), Query languages (SQL), File structures
(sequential files, indexing, B and B+trees), Transactions and concurrency control.

Unit 10: Computer Networks

ISO/OSI stack, LAN technologies (Ethernet, Token ring), Flow and error control
techniques, Routing algorithms, Congestion control, TCP/UDP and sockets, IP (v4),
Application layer protocols (icmp, dns, smtp, pop,ftp, http); Basic concepts of hubs,
switches, gateways, and routers.

PRODUCTION ENGINEERING


eigenvectors.

Total derivative, Maxima and Minima, Gradient, Divergence and Curl, Vector
identities, Directional derivatives, Line, Surface and Volume integrals, Stokes, Gauss

Differential equations: First order equations (linear and non-linear), Higher order
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Complex variables: Analytic functions, Cauchys integral theorem, Taylor and
Laurent series.


Numerical Methods: Numerical solutions of linear and non-linear algebraic
equations Integration by rapezoidal and Simpsons rule, single and multi-step
methods for differential equations.

Unit 2: Engineering Materials and Applied Mechanics

Engineering Materials: Structure and properties of engineering materials and their
applications: effect of strain, strain rate and temperature on mechanical properties of
metals and alloys; heat treatment of metals and alloys, its influence on mechanical
properties.

Applied Mechanics: Engineering Mechanics equivalent force systems, free body
concepts, equations of equilibrium; strength of materials stress, strain and their
relationship, Mohrs circle, deflection of beams, bending and shear stress, Euler s
theory of columns.

Unit 3: Theory of Machines and Design

Analysis of planar mechanisms, cams and followers; governers and fly wheels;
design of elements failure theories; design of bolted, riveted and welded joints;
design of shafts, keys, spur gears, belt drives, brakes and clutches.

Unit 4: Thermal Engineering

Fluid Mechanics fluid statics, Bernoulli s equation, flow through pipes, equations of
continuity and momentum; thermodynamics zeroth, first and second law of
thermodynamics, thermodynamic system and processes, calculation of work and
heat for systems and control volumes; air standard cycles; basics of internal
combustion engines and steam turbines; heat transfer fundamentals of conduction,
convection and radiation, heat exchangers.

Unit 5: Metal Casting and Forming

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Casting Processes types and applications; patterns types and materials;
allowances; moulds and cores materials, making, and testing; casting techniques
of cast iron, steels and nonferrous metals and alloys; solidification; design of casting,
gating and risering; casting inspection, defects and remedies.

Metal Forming Stress-strain relations in elastic and plastic deformation; concept of
flow stress, deformation mechanisms; hot and cold working forging, rolling,
extrusion, wire and tube drawing; sheet metal working processes such as blanking,
piercing, blending, deep drawing, coining and embossing; analysis of rolling, forging,
extrusion and wire/rod drawing; metal working defects.

Unit 6: Metal Joining Processes

Welding Processes manual metal arc, MIG, TIG, plasma arc, submerged arc,
electroslag, thermit, resistance, forge, friction, and explosive Welding; other joining
processes soldering, brazing, braze welding; inspection of welded joints, defects
and remedies; introduction to advanced welding processes ultrasonic, electron
beam, laser beam; thermal cutting.

Unit 7: Machining and Machine Tool Operations

Basic Machine tools; machining processes-turning, drilling, boring, milling, shaping,
planning, gear cutting, thread production, broaching, grinding, lapping, honing, super
finishing; mechanics of machining geometry of cutting tools, chip formation, cutting
forces and power requirements, Merchants analysis; selection of machining
parameters; tool materials, tool wear and tool life, economics of machining, thermal
aspects of machining, cutting fluids, machinability; principles and applications of
nontraditional machining processes USM, AJ M, WJ M, EDM and Wire cut EDM,
LBM, EBM, PAM, CHM, ECM.

Tool Engineering: J igs and fixtures principles, applications, and design; press
tools configuration, design of die and punch; principles of forging die design.

Unit 8: Metrology and Inspection

Limits, fits, and tolerances, interchangeability, selective assembly; linear and angular
measurements by mechanical and optical methods, comparators; design of limit
gauges; interferometry; measurement of straightness, flatness, roundness,
squareness and symmetry; surface finish measurement; inspection of screw threads
and gears; alignment testing of machine tools.

Unit 9: Powder Metallurgy

Production of metal powders, compaction and sintering.

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Polymers and composites: Introduction to polymers and composites; plastic
processing injection, compression and blow molding, extrusion, calendaring and
thermoforming; molding of composites.

Unit 10: Manufacturing Analysis

Sources of errors in manufacturing; process capability; tolerance analysis in
manufacturing and assembly; process planning; parameter selection and
comparison of production alternatives; time and cost analysis; manufacturing
technologies strategies and selection.

Computer Integrated Manufacturing: Basic concepts of CAD, CAM, CAPP, cellular
manufacturing, NC, CNC, DNC, Robotics, FMS and CIM.

METALLURGICAL ENGINEERING


Linear Algebra: Matrices and Determinants, Systems of linear equations, Eigen
values and eigen vectors.

Calculus: Limit, continuity and differentiability; Partial Derivatives; Maxima and
Minima; Sequences and series; Test for convergence; Fourier series.

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Vector Calculus: Gradient; Divergence and Curl; Line; Surface and Volume
integrals; Strokes, Gauss and Greens theorems.

Differential Equations: Linear and non-linear first order ODEs; Higher order linear
ODEs with constant coefficients; Cauchys and Euler s equations; Laplace
transforms; PDEs Laplace; heat and wave equations.

Probability and Statistics: Mean, median, mode and standard deviation; Random
variables; Poisson, normal and binomial distributions; Correlation and regression
analysis.

Numerical methods: Solutions of linear and non-linear algebraic equations;
integration of trapezoidal and Simpsons rule; single and multi-step methods for

Unit 2: Thermodynamics and Rate Processes

Laws of thermodynamics, activity, equilibrium constant, applications to metallurgical
systems, solutions, phase equilibria, Ellingham and phase stability diagrams,
thermodynamics of surfaces, interfaces and defects, adsorption and segregation;
basic kinetic laws, order of reactions, rate constants and rate limiting steps.

Unit 3: Electro Chemistry and Mass Transfer

Principles of electro chemistry single electrode potential, electro-chemical cells and
polarizations, aqueous corrosion and protection of metals, oxidation and high
temperature corrosion characterization and control; heat transfer conduction,
convection and heat transfer coefficient relations, radiation, mass transfer diffusion
and Ficks laws, mass transfer coefficients; momentum transfer concepts of
viscosity, shell balances, Bernoulli s equation, friction factors.

Unit 4: Extractive Metallurgy

Minerals of economic importance, comminution techniques, size classification,
Flotation, gravity and other methods of mineral processing; agglomeration, pyro-
hydro- and electro-metallurgical processes; material and energy balances; principles
and processes for the extraction of non-ferrous metals aluminium, copper, zinc,
lead, magnesium, nickel, titanium and other rare metals.

Unit 5: Iron and Steel making

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Principles, role structure and properties of slags, metallurgical coke, blast furnace,
direct reduction processes, primary and secondary steel making, ladle metallurgy
operations including deoxidation, desulphurization, sulphide shape control, inert gas
rinsing and vacuum reactors; secondary refining processes including AOD, VAD,
VOD, VAR and ESR; ingot and continuous casting; stainless steel making, furnaces
and refractories.

Unit 6: Physical Metallurgy

Crystal structure and bonding characteristics of metals, alloys, ceramics and
polymers, structure of surfaces and interfaces, nano-crystalline and amorphous
structures; solid solutions; solidification; phase transformation and binary phase
diagrams; principles of heat treatment of steels, cast iron and aluminium alloys;
surface treatments; recovery, recrystallization and grain growth; industrially important
ferrous and non-ferrous alloys; elements of X-ray and electron diffraction; principles
of scanning and transmission electron microscopy; industrial ceramics, polymers and
composites; electronic basis of thermal, optical, electrical and magnetic properties of
materials; electronic and opto-electronic materials.

Unit 7: Mechanical Metallurgy

Elasticity, yield criteria and plasticity; defects in crystals; elements of dislocation
theory - types of dislocations, slip and twinning, source and multiplication of
dislocations, stress fields around dislocations, partial dislocations, dislocation
interactions and reactions; strengthening mechanisms; tensile, fatigue and creep
behaviour; super-plasticity; fracture Griffith theory, basic concepts of linear elastic
and elasto-plastic fracture mechanics, ductile to brittle transition, fracture toughness;
failure analysis; mechanical testing tension, compression, torsion, hardness,
impact, creep, fatigue, fracture toughness and formability.

Unit 8: Metal casting and Forming

Metal casting Patterns and moulds including mould design involving feeding,
gating and risering, melting, casting practices in sand casting, permanent mould
casting, investment casting and shell moulding, casting defects and repair; hot, warm
and cold working of metals, Metal forming fundamentals of metal forming
processes of rolling, forging, extrusion, wire drawing and sheet metal forming,
defects in forming;

Unit 9: Metal joining

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Soldering, brazing and welding, common welding processes of shielded metal arc
welding, gas metal arc welding, gas tungsten arc welding and submerged arc
welding; welding metallurgy, problems associated with welding of steels and
aluminium alloys, defects in welded joints;

Unit 10: Powder Metallurgy

NDT using dye-penetrant, ultrasonic, radiography, eddy current, acoustic emission
and magnetic particle methods.

INDUSTRIAL BIO-TECHNOLOGY


Differential equation - First order equations (linear and non-linear) Higher order
linear differential equation with constant co-efficients Method of variation of
parameters Initial and boundary value problems Partial differential equations and
variable separation methods.
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Probability and statistics Sampling theorem Mean, Mode, Median and
standard deviation Random variables Poisson, normal and binomial distributions
Correlation and regression analysis Tests of significance (x
2
and t)

Numerical methods Numerical solutions of linear and non-linear equations
Integration by trapezoidal and Simpsons rule Single and multi-step methods for
differential equations

Unit 2: Microbiology and Cell Biology

Types of Microbes Bacteria, fungi, algae and viruses Staining of bacteria
Applications of microscopes

Growth Kinetics Role of substrate Growth phases Monod Kinetics
Sterilization methods

Impact of microbes Human diseases and welfare Applications in agriculture
Bio and geo cycles

Cell and tissue structures Cellular components and functions Cell division /
mitosis and meiosis Cellular locomotion Cytoskeletons

Membranes and transport Cellular membrane structure Transport of Na, K, Ca
ions Proton pump Facilitated transports

Signals and Communications Nervous Systems (signal transmission)
Endocrine systems (ligands, receptors and hormones) Secondary signaling
molecules (G proteins, etc.)

Unit 3: Biochemistry and Instrumental Methods

Biomolecules Carbohydrates Proteins Lipids Coenzymes and Cofactors

Biopolymer synthesis DNA, RNA synthesis Proteins synthesis Lipid
synthesis

Metabolic Pathways Oxidative phosphorylation Calvin cycle Nucleic acid
metabolism

Spectroscopic Methods UV-Vis spectroscopy IR, GC, HPLC Mass Spec,
XRD Atomic Absorption, Fluorescence

Immunochemical methods ELISA, RIA Electrophoresis Western Blot
Histochemical techniques
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Chromatographic techniques TLC, ion-exchange Gel permeation Immuno
chromatography

Unit 4: Molecular Biology and Genetic Engineering

DNA and its modifications DNA extraction, modifying enzymes DNA protein
interaction Polymerase Chain Reaction

Molecular biological techniques In vitro transcription In vitro translation
Immuno precipitation

Recombinant DNA Technology Expression systems Organismic modifications
Fundamentals of Genetics Inheritance, selection Mendelism Genotype
phenotype correlation One gene one enzyme hypothesis Epistasis

Gene mapping Gene cloning Sequencing Complex diseases

Applications of genetics Pharmacogenetics Prenatal diagnosis Hybrid vigour
Gene Therapy

Unit 5: Enzyme and Immuno Technology

Sources and applications of free enzymes Microbial, plant and animal enzymes
Tanning, food and detergent industries Diagnostic applications

Enzyme Immobilization Immobilization methods and supports Properties of free
and immobilized enzymes Applications of immobilized enzymes

Purification and characterization Extraction methods Purification techniques
Enzyme characterization Development of enzyme assays

Principles of immunology Antigen-antibody interaction Cell mediated
immunoresponse Mechanism of antibody response

Immunodiagnostic techniques In vitro methods In vivo methods

Vaccines Immunological preparations Types of vaccines

Unit 6: Bioinformatics and Computational Biology

Introduction Biological database: Genbank, Swissprot Human genome project
DNA, RNA, protein sequences

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Pattern matching and Machine learning Pairwise alignment Multiple sequence
alignment BLAST, FASTA Hidden Markov Models

Phylogeny Irrelevant mutations and controls Mutations as measure of time and
distance, Time intervals and distances between species

Protein architecture Primary structure automated Edman method Super
secondary structure Tertiary structure

Protein folding Scaffold design Backbone loop and turn design Search
algorithms for domain analysis

Drug design Computer aided drug design Combinatorial chemistry Protein,
RNA structure prediction

Unit 7: Mass & Heat Transfer

Mass transfer fundamentals Laws of diffusion Vapour liquid equilibria Liquid
liquid equilibria Adsorption equilibria

Distillation Simple, steam, flash distillation McCabe-Thiele Method HETP,
HTU, NTU concepts

Separation equipment Rotary vacuum drier Absorption tower Staged and
continuous extractor Membrane separator

Heat transfer theory Steady state conduction Forced and natural convection
Combined conduction and convection Extended surfaces

Design of heat transfer equipment Double pipe heat exchanger Shell and tube
heat exchanger Multiple effect evaporators

Operations Cooling towers Flash evaporation Settling and sedimentation
Continuous filtration

Unit 8: Unit Operations & Biochemical Engineering

Stoichiometry and energetics of microbial metabolism Mass and energy
balance Heats of reaction and vaporization Energetics ATP as energy currency
Enzyme catalysis Enzyme catalyzed reactions Inhibition, denaturation and
deactivation Enzyme kinetics Mechalis Menton

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Upstream processing Substrate preparation Innoculum preparation
Sterilization techniques

Bioprocess parameters Oxygen transfer in bioreactors Bioprocess monitoring
and control Facultative and anaerobic fermentations

Downstream processing Precipitation, centrifugation, ultra filtration
Crystallization and electrophoresis Solvent mediated separations

Product recovery Nutsche and rotary vacuum filters Magma crystallizer
Supercritical extractor

Unit 9: Reaction Engineering & Thermodynamics

Chemical Kinetics Rate equations for homogeneous reactions Concentration
and temperature dependence Rate equations for heterogeneous catalytic reactions

Ideal reactors and non-ideal flow Isothermal, batch reactors and flow reactors
Performance equations for single reactors RTD in non-ideal flow Reactor
performance with non-ideal flow

Industrial reactors Trickle bed reactors Slurry reactors Fluidized bed reactors

Solution thermodynamics Concepts of chemical potential and fugacity Ideal
and non-ideal solutions Activity coefficients Gibbs-Duhem equation

Phase equilibrium Criteria for phase equilibrium Vapour-liquid equilibrium
calculations for binary systems

Chemical reaction equilibria Evaluation of equilibrium constant Effect of T & P
on equilibrium constant Equilibrium conversion for single reactions

Unit 10: Applications of Biotechnology

Food Biotechnology Food processing using bacteria, yeast, fungi Single cell
protein
Food preservation, cheese manufacture

Plant Biotechnology Plant tissue culture Vectors for plant modification
Genetically modified crops

Animal Biotechnology Animal tissue culture Products from animal cell culture
Transgenic animals

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Chemical feedstock and acids Ethanol, butanol, acetone, glycerol Citric, lactic,
acetic acids Glutamic, aspartic acids and phenylalanine

Environmental Biotechnology Aerobic and anaerobic treatment of waste water -
Solid waste treatment Air pollution and control

Antibiotics and Enzymes Penicillin, streptomycin, erythromycin Proteases,
amylases, lipases Biopesticides, biofertilizers

ENGLISH

Unit 1: Chaucer to Shakespeare

Geoffrey Chaucer : The Prologue to the Canterbury Tales
Edmund Spenser : Prothalamion
Shakespeare : Sonnets
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(12,18,29,30,33,53,54,60,65,73,90,94,107,116,144)
J ohn Donne : A Valediction : Forbidding Mourning
Andrew Marvell : To His Coy Mistress
Francis Bacon : Of Truth
Of Death
Of Revenge
Of Marriage and Single Life
Of Ambition
Of Nobility
Christopher Marlowe : Dr.Faustus
Thomas Middleton : The Changeling
J ohn Webster : The Duchess of Malfi
William Shakespeare : Twelfth Night
Henry IV Part I
Macbeth
The Tempest
Antony and Cleopatra

Unit 2 : Jacobean to Augustan Age

J ohn Milton : Paradise Lost Book IX
J ohn Dryden : Mac Flecnoe
Alexander Pope : An Epistle to Dr.Arbuthnot
Thomas Gray : Elegy Written in a Country Churchyard
Thompson : Spring
Autumn
Winter
William Collins : Ode to Evening
William Blake : A Poison Tree
The Tiger
The Lamb
J ohn Dryden : Preface to the Fables
J onathan Swift : The Battle of the Books
Daniel Defoe : Robinson Crusoe
Addison and Steele : The Spectator and the Coverly Papers (Essays 1-10
Macmillan Edn.)
Samuel J ohnson : Preface to Shakespeare
William Congreve : The Way of the World
R.B.Sheridan : The Rivals
Goldsmith : She Stoops to Conquer
Henry Fielding : Tom J ones

Unit 3 : Romantic Period

Wordsworth : Intimation Ode
Tintern Abbey
Coleridge : Kubla Khan
The Rime of the Ancient Mariner
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P.B.Shelley : To a Skylark
J ohn Keats : Ode to a Nightingale
Ode on a Grecian Urn
Byron : Vision of J udgement
Charles Lamb : Essays of Elia
1. The South-Sea House
2. Dream Children : A Reverie
3. Christ Hospital Five and Thirty Years Ago
4. Oxford in the Vacation
5. All Fools Day
Wordsworth : Preface to the Lyrical Ballads
Walter Scott : The Heart of Midlothian
J ane Austen : Pride and Prejudice
Emily Bronte : Wuthering Heights

Unit 4 : Romantic Period

Tennyson : Ulysses
The Lotus Eaters
Robert Browning : My Last Duchess
Andrea Del Sarto
Matthew Arnold : The Scholar Gipsy
Dover Beach
D.G.Rossetti : The Blessed Damozel
G.M.Hopkins : The Wreck of the Deutschland
Matthew Arnold :
The Study of Poetry
Oscar Wilde : The Importance of Being Earnest
Charles Dickens : Great Expectations
Thomas Hardy : The Woodlanders

Unit 5 : Modern and Contemporary Periods

W.B.Yeats : Sailing to Byzantium
T.S.Eliot : The Waste Land
W.H.Auden : The Unknown Citizen
Philip Larkin : Church Going
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C.B.Lewis : Fern Hill
T.S.Eliot :
Tradition and the Individual Talent
E.M.Forster : (Selections from E.M.Forster.
Edited by R.Krishnamoorthy & Published by Macmillan).
1. Notes on the English Character
2. My Wood
3. Hymn Before Action
4. Tolerance
5. What I Believe
G.B.Shaw : Arms and the Man
J ohn Osborn : Look Back in Anger
T.S.Eliot : Murder in the Cathedral
D.H.Lawrence : The Rainbow
William Golding : Lord of the Flies
J oseph Conrad : Lord J im

Unit 6 : American Literature

Emerson : Brahma
Poe : The Raven
Whitman : When Lilacs Last in the Dooryard Bloomd
Emily Dickinson : Success is Counted Sweetest
I Tasted a Liquor Never Brewed
Because I Could not Stop for Death
A Narrow Fellow in the Grass
Robert Frost : Mending Wall Stopping By Woods on a Snowy Evening
Wallace Stevens :
The Emperor of Ice-cream
Emerson : The American Scholar
Henry J ames : The Art of Fiction
ONeill : The Hairy Ape
Edward Albe : Whos Afraid of Viginia Woolfe
Hawthorne : The Scarlet Letter
Mark Twain : Huckleberry Finn
Ernest Hemingway : The Old Man and the Sea
Faulkner : The Sound and the Fury
Alice Walker : Color Purple

Unit 7 : Indian and English Literature

Toru Dutt : The Lotus
Our Casuarina Tree
R.Parthasarathy : Under Another Sky
A River Once
Sarojini Naidu : Indian Weavers
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Kamala Dass : Introduction My Grandmothers House
Nissim Ezekiel : Enterprise
Night of the Scorpion
A.K.Ramanujan :
Small Scale Reflections on a Great House
Obituary
Sri Aurobindho : The Renaissance in India
Tagore : Post Office
Girish Kamard : Tughlaq
R.K.Narayan : The Guide
Chaman Nahal : Azadi
Deshpande : The Dark Holds No Terror
Arundathi Roy : God of Small Things

Unit 8 : Language and Linguistics

Family of Indo-European Languages
Foreign Influences
Word Making
Change of Meaning
Spelling Reforms
Standard English
Morphology
Basic Sentence Patterns
IC Analysis
Structural Linguistics
T.G. Grammar
English Language Teaching
Translation
Semantics, Pragmatics and Discourse
Descriptions and classification of Consonants and Vowels
Accent
Intonation
Phonetic Transcription
Writing a research paper: Bibliography, abstract, documentation, etc.,
Mechanics of thesis writing

Unit 9 : Criticism and Literary Theories

Aristotle : Poetics
Dr.J ohnson : Life of Milton
T.S.Eliot : The Function of Criticism
I.A.Richards : Four Types of Meaning
Northrop Frye : The Archetypes of Literature
Lionel Trillin : The Meaning of a Literary Idea
Rolland Barthes : The Death of the Author
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Wayne Booth : Telling and Showing
Edward Wilson : A Historical Interpretation of Literature
Derrida : Structure, Sign ad Play in the Discourse of Human
Sciences
Terry Eagleton : Capitalism, Modernism and Post Modernism
Elaine Showalter : Towards a Feminist Poetics
Gayatri Spivak : Imperialism and Sexual Difference

Unit 10 : Post Colonial Literature and European Literature in Translation

A.G.Smith : Ode on the Death of William Butler Yeats
Like an Old Proud King in a Parable.
Margeret at Wood : J ourney to the Interior
P.K.Page : Adolescence
Wilfered Campbell : The Winter Lakes
George Ryga : The Ecstasy of Rita J oe
Margaret Lawrance :
The Stone Angel
Ondaatje : Running in the Family
Sir Thomas More : Utopia
Moliere : The Misanthropist
Ibsen : A Doll s House
Wole Soyinka : The Lion and the J ewel
Chinua Achebe : Things Fall Apart

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MATHEMATICS

Unit 1: Real Analysis

Finite-countable and uncountable sets,-Bounded and unbounded sets-Archimedean
Property-Ordered field-Completeness of R-Extended real number system-
Sequences and series-limsup and liminf of a sequence-convergence of sequences
and series-uniform convergence-continuity of a function-types of discontinuities-
uniform continuity-differentiability-Roll s theorem-mean value theorem monotone
functions, functions of bounded variations,-Riemann Integral and its properties-
Improper integrals and their convergence and uniform convergence- sequence of
functions and series of functions-point wise convergence and uniform convergence-
Bolzano-Weierstrass Theorem-Compact subsets of R
n
-Heine-Borel Theorem-
Riemann-Stieltjes integral and its properties- partial, directional and total derivatives
in R
n
.

Unit 2: Complex Analysis

Algebra of complex numbers, Riemann Sphere, Stereographic projection, lines,
circles, cross ratio, Mobious transformation, Analytic functions, Cauchy-Riemann
equations, line integrals, Cauchys theorem for convex regions, Moreras theorem,
Liouvilles theorem, Fundamental Theorem of Algebra, Cauchys Integral formula,
power series representation, classification of singularities, Riemann theorem for
removable singularities, Taylor s and Laurents series expansions, maximum
modulus principle. Schwarz lemma, Open mapping theorem, Contour integration,
Conformal mapping, Entire functions, Harmonic functions, Elliptic functions, Analytic
continuation.

3. Algebra

Groups, subgroups, normal subgroups, quotient groups, homomorphisms, cyclic
groups, permutation groups, symmetric groups, alternating groups, simple groups,
Sylows theorem, Finite abelian groups, Rings, ideals, integral domains, polynomial
rings, Euclidean ring, Principal ideal domains, Unique factorisation domains, Finite
fields, Extension fields, Splitting fields, Galois Theorem.

Vector spaces, linear independence, bases, dimension, subspaces, quotient spaces,
algebra of linear transformations, kernel, range, isomorphism, matrix representation
of a linear transformation, change of bases, Dual bases, dual space, projection,
transpose, trace, determinant, Hermitian, Unitary and normal transformations, eigen
values and eigen vectors, Cayley-Hamilton theorem, Invariant subspaces, canonical
forms: triangular form, J ordan form, rational canonical form.

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4. Topology

Topological spaces-Basis for a topology-The product topology The subspace
topology-Closed sets and limit points, Continuous functions-the product topology-
The metric topology. Connected spaces-connected subspaces of the Real line
Components and local connectedness, Compact spaces-compact subspaces of the
Real line Limit Point Compactness Local Compactness. The Countability Axioms
The separation Axioms Normal spaces The Urysohn Lemma The Tietze
extension theorem.

5. Measure Theory and Functional Analysis

Measure Theory: Lebesgue Outer Measure-Measurable sets-Regularity
Measurable Functions-Borel and Lebesgue Measurablility- Integration of Non-
negative functions The General Integral Riemann and Lebesgue Integrals, Field
of sets, sigma-field of sets, finitely additive set function and countably additive set
function, measure, Measurable and measure spaces, Extension of measures, signed
measures, J ordan, Hahn decomposition theorem, Monotone convergence Theorem,
Fatous lemma, Dominated convergence theorem, absolute continuity, L
p
spaces-
Convex functions, J ensens inequality, Holder s and Minkowski s inequalities, Radon-
Nikodym derivative, Fubini s Theorem.

Functional Analysis: Normed Linear space-Continuous Linear Transformations
Banach spaces-The Hahn-Banach Theorem The natural embedding of N in N** -
Open mapping theorem Closed graph Theorem Uniform boundedness theorem
conjugate of an operator Inner product space Orthogonalisation process Hilbert
Space Orthonormal sets-Orthogonal complements conjugate space H* - Adjoint
of an operator Self-adjoint Normal and Unitary Operators Projections.

6. Differential Equations

Ordinary Differential Equations : Second order homogeneous equations-Initial
value problems-Linear dependence and independence-Wronskian and a formula for
Wronskian-Non-homogeneous equation of order two. Homogeneous and non-
homogeneous equation of order n Initial value problems- Annihilator method to
solve non-homogeneous equation- Algebra of constant coefficient operators. Initial
value problems Existence and uniqueness theorems- Solutions to solve a non-
homogeneous equation Wronskian and linear dependence reduction of the order
of a homogeneous equation - homogeneous equation with analytic coefficients The
Legendre equation. Euler equation Second order equations with regular singular
points Exceptional cases Bessel Function. Equation with variable separated
Exact equation- method of successive approximations the Lipschitz condition-
convergence of the successive approximations and the existence theorem.
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Partial Differential Equations: Linear and non-linear first order partial differential
equations Second order equations in two independent variables canonical forms
equations with constant coefficients - general solution. The Cauchy problem
Homogeneous wave equation Initial Boundary value problem -Non- homogeneous
boundary conditions Non- homogeneous wave equation Riemann method
Goursat problem spherical wave equation cylindrical wave equation. Separation
of variable Vibrating string problem Existence and uniqueness of solution of
vibrating string problem. Heat conduction problem Existence and uniqueness of
solution of heat conduction problem Laplace and beam equations. Boundary value
problems Maximum and minimum principles Uniqueness and continuity theorem
Dirichlet Problem for a circle, a circular annulus, a rectangle Dirichelt problem
involving Poisson equation Neumann problem for a circle and a rectangle. The
Delta function Greens function Method of Greens function Dirichlet Problem
for the Laplace and Helmholtz operators.

7. Mechanics and Numerical Methods

Mechanics : Generalised coordinates - Constraints Virtual work- Energy and
Momentum, Derivation of Lagranges equations-Examples Integrals of motion.
Hamiltons Principle Hamiltons Equation Other variational principle. Hamilton
Principle function Hamilton-J acobi Equation- Separability, Differential forms and
generating functions Special Transformations-Lagrange and Poisson brackets.

Numerical Methods: Representation of numbers (binary, octal, decimal,
hexadecimal) Errors Difference Table Difference formula Solution of non-
linear equations: Bisection, secant, regula-falsi, Newton-Raphson, Fixed iteration.
Solution of system of equations: Gauss Elimination, J acobi, Gauss-J ordan, Gauss-
Seidal, LU decomposition. Solution of ordinary differential equations: Taylor Series,
Euler and modified Euler, Runge-Kutta method of order two and four, Milne-
Simpson, Adams-Badsforth method.

8. Probability and Mathematical Statistics

Probability : Random events Probability axioms Combinatorial formulae
conditional probability-Bayes Theorem Independent events Random Variables
Distribution Function J oint Distribution Marginal Distribution Conditional
Distribution Independent random variables Function of random variables.
Expectation Moments The Chebyshev Inequality Absolute moments Cumulant
Generating Function, Moment Generating Function and Probability Generating
function Properties of characteristic functions Characteristic functions and
moments characteristic function of the sum of the independent random variables
Determination of distribution function by the Characteristic function - Probability
generating functions. One point, two point, Binomial Poisson distribution Uniform
(discrete and continuous) normal-gamma distributions. Weak law of large numbers
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Central limit theorem (Lindberg Theorem and Lapunov Theorem) Borel-Cantelli
Lemma Kolmogorov Strong Law of large numbers.

Mathematical Statistics: Sampling: Sample mean, sample variance and their
independence-Moments of sample mean and sample variance, t distribution, F
distribution. Point Estimation : Unbiasedness, consistency, sufficiency, efficient and
asymptotically most efficient-Method of moments: One parameter and two
parameters cases-Maximum likelihood Estimation: One parameter and two
parameter cases unbiasedness, mean square error, CR bound. Interval Estimation:
Derivation of confidence interval:-The pivotal method, confidence limits, sample size,
confidence interval for the normal distribution (mean, variance)-Confidence interval
for Binomial and Poisson-Confidence interval for two sample problems (Two normal
means, two population variances, two population propositions, two Poisson
parameters, paired data). Hypotheses, test statistics, decision and errors:
Hypotheses (Null, alternative, simple and composite), one sided and two sided tests,
test statistics, errors (Type I and II errors), Best Test (smallest type-II error), p
values. Best Tests: Testing the value of a population mean, of population variance,
of population proposition. Of the mean of Poisson. Best Tests: Testing the value of
the difference between two population means, ratio of two population variances,
difference between population propositions, difference between two Poisson means,
paired data. Tests and confidence intervals: chi-square test, goodness of fit,
contingency table for independence. ANOVA: One way and two way classifications.

9. Differential Geometry and Graph Theory

Space curve - Arc length tangent normal and binormal curvature and torsion
contact between curves and surfaces- tangent surface involutes and evolutes-
Intrinsic equations Fundamental Existence Theorem for space curves-Helics.
Surface curves on a surface Surface of revolution Helicoids Metric
Direction coefficients families of curves-Isometric correspondence- Intrinsic
properties. Geodesics Canonical geodesic equations Normal property of
geodesics- Existence Theorems Geodesic parallels Geodesics curvatures
Gauss-Bonnet Theorem Gaussian curvature-surface of constant curvature. The
second fundamental form-Principle curvature Lines of curvature Developable
Developable associated with space curves and with curves on surface Minimal
surfaces Ruled surfaces. Compact surfaces whose points are umblics-Hilberts
lemma Compact surface of constant curvature Complete surface and their
characterization Hilberts Theorem Conjugate points on geodesics.

Graph Theory: Graphs and simple graphs Graphs Isomorphism The Incidence
and Adjacency Matrices Subgraphs Vertex Degrees Paths and Connections
Cycles Trees Cut Edges and Bonds Cut Vertices. Connectivity - Blocks
Euler tours- Hamilton Cycles. Matchings Matchings and Coverings in Bipartite
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Graphs Edge Chromatic Number. Vizings Theorem. Independent sets
Ramseys Theorem Chromatic Number Brooks Theorem Chromatic
Polynomials. Plane and planer Graphs Dual graphs Eulers Formula The Five
Colour Theorem and the Four-Colour Conjecture-Directed graphs.

10. Mathematical Programming and Fluid Dynamics

Convex sets-Hyperplane-Open and closed half spaces-Formulation of Linear
Programming problem Graphical solution Types of solutions Simplex
procedure method of penalty Two phase technique-special cases in simplex
method applications Duality Economic Interpretation of duality- Dual Simplex
method Generalised simplex Tableau in Matrix Form Efficient Computational
algorithm Transportation and Assignment problems as linear programming
problems.

Fluid Dynamics : Real fluids and Ideal fluids- Velocity of a fluid at a point, Stream
lines, path lines, steady and unsteady flows- Velocity potential The vorticity vector
Local and particle rates of changes Equations of continuity- Acceleration of a
fluid Conditions at a rigid boundary. Pressure at a point in a fluid at rest
Pressure at a point in a moving fluid -Conditions at a boundary of two inviscid
immiscible fluids Euler s equation of motion Steady motion under conservative
body forces. Sources, sinks and doublets Images in a rigid infinite plane - Axis
symmetric flows Stokes stream function-Two dimensional flow The stream
function The complex potential for two dimensional, irrotational in compressible
flow- Complex velocity potentials for standard two dimensional flows Two
dimensional Image systems The Milne Thomson circle Theorem. Stress
components in a real fluid. Relations between Cartesian components of stress
Translational motion of fluid elements The rate of strain quadric and principle
stresses Some further properties of the rate of strain quadric - Stress analysis in
fluid motion Relation between stress and rate of strain The coefficient of viscosity
and Laminar flow The Navier Stokes equations of motion of a Viscous fluid.

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PHYSICS

Unit 1 : Mathematical Methods

Vector fields: Orthogonal curvilinear co-ordinate systems Expressions for gradient,
divergence, curl and Laplacian- Linear vector spaces: Linear independence, basis,
dimension, inner product Schwartz inequality Orthonormal basis Gram
Schmidt orthogonalization process Linear operators Representation of vectors
and operators in a basis Matrix theory- Cayley-Hamilton theorem Inverse of a
matrix Diagonalisation of matrices Operational methods: Laplace transforms
Solution of linear differential equations with constant coefficients Fourier integral
Fourier transforms- Convolution theorems Applications Complex variables:
Analytic function Cauchy-Riemann conditions Singular points- Multivalued
function and branch points Cauchys integral theorem and formula Taylor s and
Laurentz s expansions - Residue theorem and its applications.

Unit 2 : Classical Mechanics and Relativity

Lagrangian and Hamiltonian formulations Newtons equations and conservation
laws for a system of particles DAlembert s principle and Lagranges equations of
motion Hamiltonian and Hamiltons equation of motion Application: Two-body
central force problem Scattering by central potential, two particle scattering
Cross section in Lab system-Small oscillations- Transformation to normal
coordinates and frequencies of normal modes- Mechanics of rigid bodies: Angular
momentum and kinetic energy Moment of inertia tensor Euler angels Euler s
equation of motion Torque free motion Symmetric top Wave motion Phase
velocity- Group velocity Dispersion Relativity: Special theory of relativity Lorentz
transformation Addition of velocities Mass- energy equivalence.

Unit 3: Quantum Theory and its Applications

Basic principles: Wave particle duality Heisenbergs uncertainty principle
Postulates of quantum mechanics- Interpretation of wave function Schordinger s
wave equation and its application to particle in a box- Harmonic oscillator- tunneling
through a barrier Motion in central field potential: Hydrogen atom angular
momentum and spherical harmonics Addition of two angular momenta
Approximate methods: Time independent perturbation theory for non-degenerate
case application to anharmonic oscillator time dependent perturbation theory
Fermi s golden rule- Scattering theory: Scattering amplitude cross section Born
approximation Partial wave analysis Identical particles and spin Symmetric and
antisymmetric wave functions Representation theory Coordinate and momentum
representations.

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Unit 4: Electromagnetic Theory

Electrostatics Laplace and Poisson equations Boundary value problems
Magnetostatics Amperes theorem-Biot- Savart law Electromagnetic induction
Maxwell s equations in free space and in linear isotropic media Boundary
conditions on the fields at interfaces-Scalar and vector potentials Gauge invariance
Electromagnetic waves- Reflection, refraction, dispersion, interference, diffraction
and polarization- Electrodynamics of a charged particle in electric and magnetic
fields Radiation from moving charges and from a dipole - Retarded potential.

Unit 5 : Thermodynamics and Statistical Mechanics

Laws of thermodynamics and their consequences Thermodynamic potentials and
Maxwell s relations Chemical potential and phase equilibria Phase space,
microstates and macrostates- Partition function Free energy and its connection
with thermodynamic quantities Classical and quantum statistics- Degenerate
electron gas- Black body radiation and Plancks distribution law Bose Einstein
condensation Einstein and Debye models for lattice specific heat.

Unit 6 : Atomic and Molecular Physics

Quantum states of an electron in an atom Hydrogen atom spectrum Electron spin
Stern-Gerlach experiment Spin - orbit coupling Fine structure Relativistic
correction Spectroscopic terms and selection rules- Hyperfine structure- Exchange
symmetry of wave functions Pauli s exclusion principle - Periodic table Alkali-type
spectra LS and J J coupling Zeeman, Paschen Back and Stark effects X-rays
and Auger transitions- Compton effect Principles of ESR, NMR - Molecular
Physics: Covalent, ionic and Vander Waal s interactions Rotation/vibration spectra
Raman spectra Selection rules- Nuclear spin and intensity alternation Isotopic
effects Electronic states of diatomic molecules Frank Condon principle
Lasers: Spontaneous and stimulated emission Optical pumping Population
inversion- Coherence (temporal and spatial) Simple description of ammonia maser
co
2
and He-Ne lasers.

Unit 7 : Condensed Matter Physics

Crystal classes and systems 2d and 3d lattices Bonding in common crystal
structures Reciprocal lattice Diffraction and structure factor - Elementary ideas
about point defects and dislocations Lattice vibrations Phonons Specific heat of
solids Free electron theory Fermi statistics Heat capacity Electron motion in
periodic potential Energy bands in metals, insulators and semiconductors Tight
binding approximation Impurity level in doped semiconductors Electronic
transport from classical kinetic theory Electrical and thermal conductivities Hall
effect and thermoelectric power transport in semiconductors Dielectrics
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Polarization mechanism Clausius- Mossotti equation Piezo, pyro and
ferroelectricity Dia and paramagnetism Exchange interactions Magnetic
ordering : ferro, antiferro and ferrimagnetism Superconductivity: Basic
phenomenology Meissner effect Type 1 and Type 2 superconductors BCS
pairing mechanism.

Unit 8 : Nuclear and Particle Physics

Basic nuclear properties Size, shape, charge distribution, spin and parity binding
energy empirical mass formula- liquid drop model Nuclear forces- Elements of
two body problem Charge independence and charge symmetry of nuclear forces-
Evidence of nuclear shell structure Single particle shell model Its validity and
limitations Collective model Interactions of charged particles and e.m.rays with
matter Basic principles of particle detectors Ionization chamber Proportional
counter GM counter Scintillation and semiconductor detectors Radioactive
decays: Basic theoretical understanding Nuclear reactions Elementary ideas of
reaction mechanism Compound nucleus and direct reactions Elementary ideas
of fission and fusion Particle Physics: Symmetries and Conservation laws
Classification of fundamental forces and elementary particles Iso-spin
Strangeness- Gell-Mann Nishijima formula Quark model C.P.T.invariance in
different interactions Parity nonconservation in weak interaction.

Unit 9: Electronics

Physics of p-n junction Diode as a circuit element Clipping Clamping
Rectification Zener regulated power supply Transistor as a circuit element -
CC,CB and CE configuration Transistor as a switch, OR, AND, NOT gates
Feedback amplifiers Operational amplifiers and its applications Inverting, non-
inverting amplifier Adder Subtractor Integrator Differentiator Waveform
generator Comparator Schmidt trigger Digital integrated circuits NAND and
NOR gates as building blocks X- OR gate Simple combinational circuits Half
and full adder Flip-flop Shift register Counters Basic principles of A/D and
D/A converters- Simple applications of A/D and D/A converters Microprocessor
8085: Architecture Addressing modes Instruction sets Simple programming.

Unit 10 : Experimental Physics

Measurement of fundamental constants: e, h, c Measurement of high and low
resistances, L and C Detection of X-rays, gamma rays, charged, particles,
neutrons etc lionization chamber proportional counter GM counter
Scintillation detectors Solid state detectors Emission and absorption
spectroscopy Measurement of magnetic field. Hall effect Magnetoresistance
X-ray and neutron diffraction Vacuum techniques Basic idea of conductance
Pumping speed etc - Pumps: Mechanical pump Diffusion pump Gauges:
Thermocouple Penning Pirani Hot cathode Low temperature: cooling a
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sample over a range upto 4 K and measurement of temperature Error analysis and
hypothesis testing Propagation of errors Plotting of graph - Distributions Least
squares fitting - Criteria for goodness of fits Chi square test.
CHEMISTRY

Unit -1

Analytical Chemistry: Classification of analytical Methods classical and
instrumental. Errors and Evaluation: Definition of terms in mean and median Types
of errors, propagation of errors, accuracy and precision, least squares analysis,
average standard deviation.

Analytical Techniques: Principle and applications of adsorption, partition, ion
exchange and solvent extraction chromatographic methods TLC HPLC and GC.
Applications of atomic, molecular and emission spectroscopy in quantitative analysis
Electroanalytical techniques cyclic and stripping voltametry, polarography, TGA,
DTA, and DSC. Light scattering techniques including nepelometry and Raman
spectroscopy.

Unit-2

Structure and Bonding: Atomic orbitals Types of chemical Bonds (weak and
strong) intermolecular forces - Theories of bonding (VB and MO) - Concept of
hybridization shapes of polyatomic molecules VSEPR theory Structure of
simple ionic and covalent compounds lattice energy crystal defects Insulators
and semiconductors, superconductors, Band theory of solids Solid state reactions.

Acids and Bases : Bronsted and Lewis acids and bases, pH and pKa, acid-base
concept in nonaqueous media, HSAB concept, Buffer solution.

Redox Reactions: Oxidation numbers, Redox potential, electrochemical series,
Redox indicators, Chemical principles involved in extractions and purification of Iron,
Copper, Lead, Zinc and Aluminium.

Unit-3

Nuclear Chemistry: Radioactive decay and equilibrium, Nuclear reactions: Q valve,
cross sections, types of reactions, Nuclear transmutations, fission and fusion
Radioactive techniques-tracer technique, neutron activation analysis. G.M, Ionization
and proportional counters. Radiolysis of water G value, dosimeters and Hydrated
electron.

Chemistry of Non-transition elements: General properties and structure of their
halides and oxides. Polymorphism of carbon, phosphorus and sulphur. Synthesis,
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properties and structure of boranes, carboranes and metallo carboranes - Wades
rule - preparation, properties and structure of borazines & phosphazenes.

Sulphur-nitrogen compounds-Oxides and oxyacids of nitrogen, phosphorous, sulphur
and halogens. Interhalogen and noble gas compounds. Isopoly and heteropoly acids
and salts.

Unit-4

Chemistry of Transition elements: Co-ordination Chemistry of transition metal
ions-Werner s theory nomenclature and stereo chemistry of co-ordination
compounds stability constants and their determinations CFT, splitting of d
orbitals, CFSE, J ahn Teller effect, charge transfer spectra- spectrochemical series-
Term states for d
n
ions, Orgel and Tanable- sugano diagram, calculation of D
q

B
and parameters.

Inorganic reaction mechanism: Inert and labile complexes-substitution reactions
trans effect redox and electron transfer reactions. Photochemistry of chromium,
ruthenium and cobalt complexes, Chemistry of lanthanides and actinides. Metal
carbonyls and metal clusters, Organometallic reagents in organic synthesis-
Cayatylic reactions- (hydrogeneation, hydroformylation, isomerization and
polymerization) pi-acid metal complexes.

Bioinorganic Chemistry: Metal ions in Biology, Photosynthesis, PSL, PSH,
Nitrogen fixation, Oxygen transport and storage, Hemeproteins haemoglobin,
cytochrome and ferrodoxins.

Spectroscopy : Applications of nmr,nqr and esr to inorganic compounds.

Unit-5

Chirality. Differentiation of assymmetric and dyssymmetric molecules. Identification
of prochiral carbons enantio and diastereoptropic hydrogens in a molecule.
Stereochemistry of disubstituted four, five, and six membered saturated alicyclic
molecules. Conformational analysis of mono and disubstituted cyclohexanes and
piperidines. E-Z nomenclature for isomeric olefins. Stereochemistry of aliphatic
nucleophilic substitutions in acyclic and bicyclic systems. Stereochemistry (specific
or selective) of dihydroxylations, halogen addition, hydroborations and Diels Alder
reaction of suitably substituted olefinic double bonds. Sterospecific E-2 eliminations
in erythro threo isomers. Reduction of ring substituted cyclohexanones to
cyclohexanols.

Unit-6

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Mechanism of SN-1, reactions in substrates with various types of NGP. Methods of
generation and mechanisms of reactions proceeding via carbenes and nitrenes.
Concreted reactions: Mechanism of electrocyclic and chelotropic reactions and
sigmatropic rearrangements. Photochemical reactions: Mechanisms of Norrish I
and II types, Paterno Buchi and Barton reactions, di--methane rearrangements.
Rearrangments: Mechanisms of rearrangements proceedings via carbonium ions
(Wagner Meerwin pinacol pinacolone and Demjanov type) and electrophilic
heteroatoms (Baeyer Villiger and Curtius type).
Mechanism of nucleophilic substitution in activated aryl halides. Regiochemistry of
aryne generation and subsequent additions of o, m and p-substituted aryl halides.

Unit-7

Organic synthesis: Synthesis and any di and trisubstituted benzene derivatives
from any mono substituted benzene or benzene itself. Synthesis of simple
compounds using C-C bond forming reactions involving Wittig, Wittig Honner,
Gilmann Reagents, organolithiums, Grignards, Robinson annulation, Dickmann
condensation, Knovenagel, Mannisch, Stork enamine, and Vilsmeyer reactions and
Umplolung. (1,3-dithane). Synthetic transformations involving Swern oxidation, Birch
Wolf Kishner and metal hydride reductions, catalytic hydrogenations and reagents
like tributyltin hydride, trimethylsilyl iodide, LDA, n-BuLi, Raney nickel, NBS
Chromium reagents, DCC and Pd. Application of protective group concept
(aldelydes, ketones and carboxylic acids) during multistep synthesis. Spectral
identification of organic intermediates by IR (functional group) PMR and CMR and
mass spectra. (simple molecules only).

Unit-8

Numbering and synthesis of unsubstituded (parent) and alkyl, aryl or acyl (wherever
methods are available) substituted furans, pyrroles, thiophene, quionline, iso
quinoline and indoles. Reactivity of these compounds towards electrophiles or
necleophiles. A study of other non benzenoid aromatics (ferrocences, azulenes,
annulenes and fulvenes).

Unit 9

Quantum Chemistry: Plancks quantum theory, Compton effect, wave particle
duality, uncertainty principle, operators: linear and Hermitian, Schrodinger wave
equation, postulates of quantum mechanics. Application of Schrodinger equation to
particle in a box, harmonic oscillator, rigid rotator and hydrogen atom. Angular
momentum: commutation relation, spin orbit interaction Approximation methods:
variation theorem, application of variation method to harmonic oscillator, hydrogen
and helium atoms. Perturbation theory application to helium atom. Born
Oppenheimer approximations: LCAO MO and VB treatments of H
2
molecule.
Huckel theory: application to ethylene, butadiene and benzene. Calculation of
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electron density and bond order. Semi empirical methods: Slater orbital and HF-SCF
methods.
Macromolecules: Techniques, mechanism and kinetics of polymerisation, Kinetics
of copolymerisation-Molecular weights and their determination. Properties of
polymers: glass transition temp. crystallinity of polymers- polymer processing
techniques.

Unit-10

Chemical Kinetics: Theories of reaction rate, collision theory, ARRT, comparison-
potential energy surfaces- treatment of unimolecular reaction.

Complex reactions: simultaneous, parallel and consecutive reactions. Chain
reactions: H
2-
Cl
2
H
2
Br
2
branching reaction- explosion limit.

Reactions in solution: factors determining reaction rate in solution, dielectric constant
and ionic strength, Kinetic isotopic effect, Linear free energy relations. Hammett and
Taft equations.

Homogenous Catalysis: acid base catalysis, enzyme catalysis Heterogeneous
catalysis: Adsorption, Langmuir and BET adsorption isotherms mechanism of
heterogeneous catalysis.

Thermodynamics: First and second Laws of thermodynamics- relation between c
p

and c
v
in terms of coefficients of expansion and compressibility. Maxwell relations-
partial molar properties- Glibbs Duhem equation- variation of chemical potential with
temperature and pressure-fugacity- Third law and calculation of entropy.

Statistical thermodynamics: Maxwell Boltzmann, Bose-Einstein and Fermi-Dirac
distribution- Partition function, translational, rotational and vibrational partition
function, calculation of thermodynamic functions, equilibrium constant and heat
capacity from partition functions. Einstein and Debye theories of heat capacity of
solids., concept of negative absolute temperature.

Nonequilibrium, thermodynamics: Phenomenological laws- Onsagers reciprocity
relation- application to Diffusion potential, electrokinetic phenomena- entropy
production.

Unit 11

Group theory: Symmetry elements and symmetry operations, point groups,
reducible and irreducible representations Direct product representation.
Orthogonality theorem and its consequences- construction of Character Tale (C
2v

C
3v
and C
2h )
Applications: Selection rules for IR, Raman and electronic spectra,
Determining Symmetries of normal vibrational modes of non linear molecules,
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construction of hybrid orbitals, application to electronic spectra of ethylene and
formaldehyde.

Spectroscopy: Rotational Spectra of rigid and non-rigid diatomic rotors, simple
polyatomic molecules.

Vibrational Spectra: harmonic and anharmonic oscillator, overtones, Fermi
resonane-Raman Spectra. Vibration-rotation Spectra-PQR branches, parallel and
perpendicular vibrations.

Electronic Spectroscopy: Spectra of diatomic molecules- Frank condon principle-
Morse function. Polyatomic molecules, types of transition, solvent effects.

Spin resonance Spectroscopy: NMR: Origin of nmr signal, Chemical Shift, factors
affecting chemical shift and spin spin coupling. NMR Spectra of simple AX and ABX
type molecules.
13
C and
19
F

nmr.

ESR: Origin, g-factor, hyperfine structure- Mc Connel equations, Theory and simple
applications of Mossbauer and Photoelectron Spectroscopy.

Unit-12

Electrochemistry: Ion-solvent interaction- Born treatment- solvation number and its
determination. Ion-ion interaction: activity co-efficient, Debye-Huckel equation for
activity coeff - limitations and extension to concentrated solutions. Ion transport:
Debye Huckel Orsager equation for conductance- experimental validity. Ion
association: its effect on conductance and activity coefficient.

Electrode-electrolyte interface: Structure of double layer- electrode kinetics-
overvoltage. Butler Volmer equation for one electron transfer. Corrosion and
Stability of metals: construction and use of Pourbaix and Evans diagram-Prevention
of corrosion, Primary and Secondary cells- Various fuel cells.

Photochemistry: Photophysical processes- Theory of radiationless transition-
fluorscence, phosphorescence, fluorescence quenching- Stern-Volmer equation,
excimer, exciplexes, Quantum yield measurement, Kinetics of Photochemical reac.

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