Stereochem
Stereochem
Stereochem
H
H
Br
A)
B)
C)
D)
E)
CH3
Br
H
CH3
CH3
CH3
Br
H
H
Br
I
II
I
II
III
It does not have a non-superposable enantiomer.
Both II and III
III
H 3C
C C
HO2C
CH3
H
Cl
II
III
Cl
H
A)
B)
C)
D)
E)
CH2Cl
H
H
CH2CH3
I
II
constitutional isomers.
enantiomers.
non-superposable mirror images.
diastereomers.
not isomeric.
OH
HO
I
II
III
IV
V
CH2CH3
Br
OH
A)
B)
C)
D)
E)
CO2H
OH
H
CO2H
IV
CH3
HO
Br
CH2CH3
Chapter 5
CH3
Cl
Cl
CH3
H3C
CH2CH2CH3
CH2CH2CH3
CH2CH2CH3
II
III
CH2Cl
CH2CH2CH3
H3C
Cl
H
CH2CH2CH3
IV
I, II and III, IV
I, II
III, IV
IV, V
None of the structures
A)
B)
C)
D)
E)
Cl
Cl
Cl
C2H5
CH3
H 3C
C2H5
II
I
I, II, III, IV and V
I, II, III and IV
I and II
III and IV
IV alone
A)
B)
C)
D)
E)
OH
Br
CH3
A)
B)
C)
D)
E)
OH
Br
C2H5
CH3
H
CH3
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
Cl
H 3C
Cl
CH2Cl
H
C2H5
C 2H 5
III
IV
Chapter 5
The
H3CH2C
Cl
and
Cl
CH2CH3
Cl
CH2CH3
A)
B)
C)
D)
E)
are
CH2CH3
enantiomers.
diastereomers.
constitutional isomers.
two conformations of the same molecule.
not isomeric.
H
F
CH3
H
A)
B)
C)
D)
E)
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
A)
B)
C)
D)
E)
constitutional isomers.
enantiomers.
diastereomers.
identical.
stereoisomers.
H
F
F
Cl
Cl
CH3
Cl
Cl
CH3
A)
B)
C)
D)
E)
CH3
enantiomers.
diastereomers.
constitutional isomers.
two different conformations of the same molecule.
not isomeric.
Chapter 5
CH3
OH
OH
H
H
CH3
A)
B)
C)
D)
E)
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
A)
B)
C)
D)
E)
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
H
H
CH3
CH3
CH3
A)
B)
C)
D)
E)
structural isomers.
enantiomers.
diastereomers.
identical.
None of these
Chapter 5
CH3
Cl
Br
A)
B)
C)
D)
E)
Br
CH3
II
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
CH3
H2N
CH3
H3C
A)
B)
C)
D)
E)
NH2
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
A)
B)
C)
D)
E)
CH3
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
CH3
F
Cl
H
A)
B)
C)
D)
E)
H
CH3
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
Chapter 5
H
H
Cl
CH3
CH3
Cl
A)
B)
C)
D)
E)
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
Cl
Cl
Br
Br
Cl
Br
Br
Cl
Cl
Br
Cl
Br
Br
I
II
I
II
III
More than one of these
None of these
A)
B)
C)
D)
E)
III
Br
Br
Br
Cl
Cl
Br
Cl
Br
Br
Cl
Cl
A)
B)
C)
D)
E)
II
I
II
III
More than one of the above
None of the above
III
Chapter 5
A)
B)
C)
D)
E)
II
constitutional isomers.
enantiomers.
diastereomers.
identical.
None of these
CH3
CH3
CH3
H
CH3
represent:
A) a single compound.
B) enantiomers.
C) meso forms.
D) diastereomers.
E) conformational isomers.
25. Which pair of structures represents the same compound?
CH3
OH
H
H
OH
H
OH
CH3
CH3
H
OH
H
HO
OH
H
CH3
CH3
OH
H
H
HO
H
HO
CH3
CH3
H
HO
H
HO
H
OH
CH3
CH3
OH
H
OH
H
HO
H
CH3
II
III
IV
A)
B)
C)
D)
E)
I and II
II and III
III and IV
III and V
IV and V
Chapter 5
Cl
CH3
CH3
Cl
CH3
CH2Cl
CH2CH3
H3C
Cl
H3C
Cl
CH2CH3
CH2CH3
CH2CH3
CH2CH3
II
III
IV
CH3
CH2CH3
A)
B)
C)
D)
E)
I
II
III
IV
V
CH3
H
H3C
OH
OH
HO
CH3
HO
CH2CH3
CH2CH3
CH2CH3
CH3
II
III
IV
III and V
I, III, IV and V
I, IV and V
I and III
I, II, IV and V
CH3
A)
B)
C)
D)
E)
OH
CH2CH3
A)
B)
C)
D)
E)
Cl
Cl
CH3
II
I
II
III
More than one of the above
None of the above
Cl
F
III
Chapter 5
29. How many stereogenic centers are there in Lovastatin ( Mevacor : a cholesterollowering drug) ?
HO
O
O
(Lovastatin)
4
5
6
7
8
A)
B)
C)
D)
E)
OH
CH3
HO
CH3
HO
CH3
HO
CH3
CH3
H
OH
H3C
CH3
OH
OH
II
III
IV
Chapter 5
31
Svar
D
B
D
A
C
D
B
B
B
A
A
B
E
C
E
D
C
A
D
B
A
C
A
A
D
C
C
D
E
B
D
Rtt/Fel
10