Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd Logo
Upload

Welcome to Scribd!

  • 2K views

    Hybridisation

    Uploaded by

    Rajat Goel
    1. The bond identified in the structure is an sp2-sp2 bond between a carbon bearing a double bond (sp2 hybridized) and another carbon (sp2 hybridized). 2. The compound shown has 3 sp2-sp2 sigma bonds. 3. The carbon hybridizations in the given compound from left to right are: sp3, sp2, sp, sp3, sp2, sp2.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd

    Hybridisation

    Uploaded by

    Rajat Goel
    2K views4 pages
    1. The bond identified in the structure is an sp2-sp2 bond between a carbon bearing a double bond (sp2 hybridized) and another carbon (sp2 hybridized). 2. The compound shown has 3 sp2-sp2 sigma bonds. 3. The carbon hybridizations in the given compound from left to right are: sp3, sp2, sp, sp3, sp2, sp2.

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    1. The bond identified in the structure is an sp2-sp2 bond between a carbon bearing a double bond (sp2 hybridized) and another carbon (sp2 hybridized). 2. The compound shown has 3 sp2-sp2 sigma bonds. 3. The carbon hybridizations in the given compound from left to right are: sp3, sp2, sp, sp3, sp2, sp2.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    2K views4 pages

    Hybridisation

    Uploaded by

    Rajat Goel
    1. The bond identified in the structure is an sp2-sp2 bond between a carbon bearing a double bond (sp2 hybridized) and another carbon (sp2 hybridized). 2. The compound shown has 3 sp2-sp2 sigma bonds. 3. The carbon hybridizations in the given compound from left to right are: sp3, sp2, sp, sp3, sp2, sp2.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    HYBRIDISATION

    Q.1 The bond identified (with the arrow) in the structure shown is best
    described as :

    O
    ||
    CH3C - CH = CH2
    A
    (A) sp-sp2 (B) p-p C) sp2-sp3
    (D) sp2-sp2 (E) p-p

    Q.2 The compound shown has ................. sp2 - sp2 (sigma) bonds.

    (A) 1 (B) 3 (C) 4


    (D) 5 (E) 6

    Q.3 Select the response that correctly identifies the number of carbon
    atoms of each hybridization in the compound shown :

    O = CH - CH2 - CH = C = CH2

    sp3 sp2 sp sp3 sp2 sp


    (A) 1 3 1 (B) 1 4 0
    (C) 2 3 0 (D) 2 2 1

    Q.4 The bonds between carbon atom (1) and carbon atom (2) in compound
    1 2 3
    N ≡ C - CH = CH2 involves the hybrid as

    (A) sp2 and sp2 (B) sp3 and sp (C) sp and sp2 (D) sp and sp

    Q.5 Which of the following has all carbon atoms sp-hybridized ?

    (A) CH3 - CH = CH - CH3 (B) CH3 - C ≡ C - CH3


    (C ) HC ≡ C - C ≡ CH (D) All the three above
    Q.6 A straight chain hydrocarbon has the molecular formula C8H10. The
    hybridization of the carbon atoms from one end of the chain to the
    other are respectively sp3, sp2, sp2, sp3, sp2, sp2, sp and sp. The
    structural formula of the hydrocarbon would be :

    (A) CH3C ≡ CCH2 - CH = CHCH = CH2


    (B) CH3CH2 - CH = CHCH = CHC ≡ CH
    (C ) CH3CH = CHCH2 - C ≡ CCH = CH2
    (D) CH3CH = CHCH2 - CH = CHC ≡ CH.

    Q.7 The Change in the state of hybridization of the asterisked carbon in


    the following reaction
    * *
    CH3CN 
    →
    H 2O CH3CONH2 is

    (A) sp3 to sp2 (B) sp3 to sp (C) sp to sp2 (D) sp2 to sp3

    Q.8 The type of hybridizations exhibited by carbons in

    are-

    (A) sp3 and sp (B) sp2 only


    (C) sp3 and sp2 (D) sp3, sp2 and sp.

    Q.9 The structural formula of a compound is CH3 - CH = C = CH2. The


    types of hybridization at the four carbons from left to right are-

    (A) sp2, sp2, sp2, sp3 (B) sp2, sp3, sp2, sp2
    (C ) sp3, sp2, sp, sp2 (D) sp3, sp2, sp2, sp2

    Q.10 The state of hybridization of the central carbon atom in 1, 2-propadiene


    (allene) is-

    (A) sp3 (B) sp2


    (C) sp (D) None of these.
    SOLUTIONS (HYBRIDISATION)

    Ans.1 Carbon bearing double bond is sp2-hybridised single bond is formed


    by σ overlapping.

    Ans.2 For organic molecules use formula


    n = no. of lone pairs + no. of σ bonds on that atom.
    if n = 2 sp
    n=3 sp2
    n=4 sp3

    In case of double bond, one bond is σ which is formed by overlapping


    of sp2-orbital while other bond is π formed by overlapping of pure-p-
    orbital.

    Ans.3 O = CH - CH2 - CH = C = CH2


    ↓ ↓ ↓ ↓ ↓
    Sp 2
    Sp 3
    Sp 2
    Sp Sp2

    Ans.4 Carbon bearing Two double bond [=C=] or Triple bond [C≡C] is sp-
    hybridized while corbon bearing double bond is sp2 hybridized.

    Ans.5 (A) CH3 - CH = CH - CH3


    ↓ ↓ ↓ ↓
    Sp3 Sp2 Sp2 Sp3

    (B) CH3 - C ≡ C - CH3


    ↓ ↓ ↓ ↓
    Sp3 Sp Sp Sp3

    (C ) HC ≡ C - C ≡ CH
    ↓ ↓ ↓ ↓
    Sp Sp Sp Sp
    Ans.6 (A) CH3—C ≡ C—CH2—CH = CH—CH = CH2
    ↓ ↓ ↓ ↓ ↓ ↓ ↓ ↓
    Sp 3
    Sp Sp Sp 3
    Sp 2
    Sp 2
    Sp 2
    Sp2

    (B) CH3—CH2—CH = CH—CH = CH—C ≡ CH


    ↓ ↓ ↓ ↓ ↓ ↓ ↓ ↓
    Sp 3
    Sp 3
    Sp 2
    Sp 2
    Sp 2
    Sp 2
    Sp Sp

    (C) CH3—CH = CH—CH2—C ≡ C—CH = CH2


    ↓ ↓ ↓ ↓ ↓ ↓ ↓ ↓
    Sp3 Sp2 Sp2 Sp3 Sp Sp Sp2 Sp2

    (D) CH3—CH = CH—CH2—CH = CH—C ≡ CH.


    ↓ ↓ ↓ ↓ ↓ ↓ ↓ ↓
    Sp 3
    Sp 2
    Sp 2
    Sp 3
    Sp 2
    Sp 2
    Sp Sp

    (Double bonded Carbon)

    Sp2

    ↑
    Ans.7 CH3 - C ≡ N   → CH3 - C - H2
    H O 2

    ||
    ↓ O
    Sp
    (Triply bonded Carbon)

    Ans.8

    * All circled 'C' are sp2 hybridised


    * Carbon without circled is sp3 hybridised

    Ans.9 CH3 - CH = C = CH2


    ↓ ↓ ↓ ↓
    sp 3
    sp 2
    sp sp2

    Ans.10 CH2 = C = CH2 (1, 2-Propadiene)


    ↓
    sp

    You might also like