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Key Quiz Ch14

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CHEM-102 Chapter 14 Quiz Name : __________KEY______________

July 20, 2011

Banner ID : _________________

MULTIPLE CHOICE QUESTIONS (10 points: each question is worth 1 points)


d 1. What is the name of the following structure? a. ethyl isopropyl aldehyde b. ethyl isobutyl aldehyde c. 2-methyl-4-hexanone d. 5-methyl-3-hexanone 2. Which structure represents benzaldehyde?
OH

O
O

a. a

b.

c.

3. Pick the one answer below that shows compounds in order of lowest to highest solubility: a. alkane, aldehyde, alcohol b. aldehyde, alkane, alcohol c. alcohol, aldehyde, alkane 4. What is the product of methyl methyl ketone (aka acetone) with the permanganate ion? a. acetic acid b. methanol c. hemiacetal d. acetal e. no reaction 5. What is the condensed structural formula of acetaldehyde? a. CH3-CHO b. CH3CH2-CHO c. H-CHO d. CH3-COOH 6. What is the condensed structural formula of propanone? a. CH3-CHO b. CH3CH2-CHO c. H-CHO d. CH3-COOH

e. CH3-CO-CH3

e. CH3-CO-CH3

7. Benedicts reagent will oxidize with which of the following compounds? a. any aldehyde b. any ketone c. -hydroxy ketone d. -hydroxy aldehyde

e. c & d

8. During a hydride reduction, which statement below is correct? a. a hydride ion is created by LiAlH4 to attack the carbonyl oxygen first; a proton from H2O attacks carbon next b. a hydride ion is created by H2O to attack the carbonyl carbon first; a proton from LiAlH4 attacks oxygen next c. a hydride from LiAlH4 and a proton from H2O attack the carbonyl group at the same time d. a hydride from LiAlH4 first attacks the carbonyl carbon, then a proton from H2O attacks the oxygen last 9. Both hemiacetals and acetals contain the functional group O-CH3 . This is called what? a. methanol group b. methoxy group c. oxymethane group d. methaldehyde group

f 10. Which of the following compounds will react with permanganate or dichromate ions to change color (i.e., oxidize to a different compound)? a. alkene b. aldehyde c. ketone d. primary alcohol e. b & d f. a,b, & d

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