AQIS Methyl Bromide Fumigation Standard
AQIS Methyl Bromide Fumigation Standard
AQIS Methyl Bromide Fumigation Standard
www.daff.gov.au
CONTENTS
Fumigant considerations risk assessment, commodity, dosage, temperature ..........5 1.1 Risk assessment.........................................................................................................5 1.2 Commodity (Non perishable)....................................................................................5 1.3 Commodity (Perishable)...........................................................................................5 1.4 Dosage......................................................................................................................6 1.5 Temperature..............................................................................................................7 The fumigation site............................................................................................................8 2.1 Site requirements......................................................................................................8 2.2 Site floor....................................................................................................................8 Consignment suitability for fumigation...........................................................................9 3.1 Fumigant circulation................................................................................................9 3.2 Fumigant penetration.............................................................................................10 The fumigation enclosure................................................................................................11 4.1 Sheet fumigation.....................................................................................................11 4.2 Using gas-tight containers as fumigation enclosures.............................................12 4.3 Pressure testing requirements for un-sheeted containers......................................13 4.4 Chamber fumigation...............................................................................................14 4.5 Safety.......................................................................................................................15 Preparing the fumigation enclosure...............................................................................16 5.1 Monitoring tubes.....................................................................................................16
5.2 Fumigant supply pipes............................................................................................17 5.3 Fans........................................................................................................................18 5.4 Sand and water snake specifications......................................................................18 Calculating the dosage of fumigant required................................................................19 6.1 Calculation of fumigation enclosure volume..........................................................19 6.2 Calculation of fumigant dosage..............................................................................19 Performing the fumigation..............................................................................................20 7.1 Using a vaporiser...................................................................................................20 7.2 Distributing fumigant within the enclosure............................................................21 7.3 Checking for leaks..................................................................................................21 Monitoring and maintaining fumigant concentrations................................................22 8.1 Monitoring frequency.............................................................................................22 8.2 Fumigant levels Start-point and End-point.........................................................23 8.3 Fumigant concentrations........................................................................................24 8.4 Topping-up..............................................................................................................26 Completing the fumigation..............................................................................................27 9.1 Ventilation...............................................................................................................27 9.1 Continued................................................................................................................28 9.2 Certification............................................................................................................28 APPENDIX 1: Fumigation of Perishable Commodities...............................................29 APPENDIX 2: Fumigation of vessels with methyl bromide.........................................33 1. PRIOR TO FUMIGATION........................................................................................33
2. FUMIGATION PROCEDURE..................................................................................34 2. Continued......................................................................................................................35 2. Continued..................................................................................................................36 2. Continued..................................................................................................................37 2. Continued..................................................................................................................38 2. Continued..................................................................................................................39 APPENDIX 3: Commodities for which problems may occur when fumigated with methyl bromide.............................................................................................................40 APPENDIX 4: Example of a record of fumigation.......................................................41 APPENDIX 5: Example of a fumigation certificate.....................................................42 APPENDIX 6: Pressure testing enclosures for gas-tightness......................................46 APPENDIX 7: Monitor tube placement for container fumigation...............................50 APPENDIX 8: Fumigant gas supply pipe systems.......................................................51 APPENDIX 9: Calculating the volume of differently shaped fumigation enclosures. .52 APPENDIX 10: Vaporisers for methyl bromide...........................................................53 APPENDIX 11: Methyl bromide fumigation ready reckoner.......................................55 APPENDIX 12: Examples of Top-up calculations....................................................56 APPENDIX 13: Methyl bromide as a quarantine fumigant.........................................58 APPENDIX 14: Methyl bromide as an ozone depleting gas........................................59 APPENDIX 15: Glossary of terms...............................................................................60
AQIS Requirements
AQIS requirements for this section are designed to be subject to audit during quality control procedures, either by AQIS, by other quarantine authorities or by authorised agents of either. This section is divided into two main columns:
Appendices
These appendices provide information on a range of issues that may be helpful to a fumigator on various aspects of the fumigation procedure.
MANDATORY
This column lists conditions that MUST be achieved and actions which MUST be undertaken in order to conform to the requirements of the AQIS Standard.
INFORMATIVE
This column lists information that may be helpful to a fumigator in achieving the Mandatory Requirement.
MANDATORY
INFORMATIVE
FUMIGANT CONSIDERATIONS RISK ASSESSMENT, COMMODITY, DOSAGE, TEMPERATURE 1.1 Risk assessment
1.1.1 Before commencing any fumigation process a risk assessment must be carried out.
The purpose of risk assessments is to ensure that any fumigation undertaken is carried out in such a way that minimises any Occupational Health and Safety (OH&S) risks, meets local regulations, protects the local population and the environment,and addresses potential adverse effects on the commodity being fumigated. A risk assessment may be written or visual, as appropriate
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MANDATORY
INFORMATIVE
Overdosing (the application of fumigant at rates above those specified by AQIS) to compensate for poor fumigation practice or inadequate equipment or sheeting should not be undertaken. See the ICON database (www.aqis.gov.au/icon)
1.4 Dosage
1.4.1 Dosage must conform to: Permit conditions to import Quarantine Material into Australia; AQIS Import Conditions (ICON) database outside Australia; Quarantine Directions (within Australia). 1.4.2 For the majority of commodities (excluding perishables) AQIS treatment dosages must be based on the anticipated minimum ambient temperature that the commodities inside the fumigation enclosure will experience during the fumigation period.
TABLE 1 : COMMON STANDARD DOSAGE FOR METHYL BROMIDE FUMIGATION REQUIRED PEST/COMMODITY CONCENTRATION 128g/m at 21 C for 24 hours at Giant African Snail Normal Atmospheric Pressure (NAP) 80 g/m for 48 hours with a Khapra Beetle minimum concentration of 24 g/m after 24 hours at NAP 32 g/m at 21 C for 24 hours at Stored Product Pest of Quarantine concern NAP 48 g/m at 21 C for 24 hours at Timber NAP
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MANDATORY
INFORMATIVE
At temperatures below 10 C the fumigant has decreased effectiveness against pests, and more of the gas may be absorbed by the commodity. Excessive fumigant uptake can pose an increased safety risk, as the gas is difficult to remove from the commodity.
1.5 Temperature
1.5.1 Fumigation for quarantine purposes is not permitted if the ambient minimum temperature falls below 10 C. 1.5.2 Dosage must be compensated for temperatures below 21 C.
For each 5C (or part of 5C) the temperature is expected to fall below 21 C, 8g/m must be added to the dosage, unless otherwise specified by AQIS. For example, using the standard dosage of 48g/m for a 24 hour exposure period, the dosage at:
21 C and above is 16 20 C is 11 15 C is 10 C is
The fumigation provider must record the temperature information on the fumigation certificate.
The temperature in the fumigation enclosure must be raised above 10 C during fumigation if the minimum temperature inside the enclosure is expected to fall below 10 C.
Heaters incorporating a fan and thermostat may be used for this purpose. Flash proof heaters should be used if the commodity is flammable. Consideration can also be given to storing and fumigating the commodity in heated warehouses during extended cold periods.
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MANDATORY
INFORMATIVE
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MANDATORY
INFORMATIVE
3.1.2 Timber must be separated by a minimum of 5 mm of air space in one dimension every 200 mm.
The separators must allow for any sagging to ensure that the 5 mm minimum separation is maintained along the entire length of the timber.
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MANDATORY
INFORMATIVE
If suitable declarations cannot be obtained the container should be unpacked for inspection prior to fumigation. The inspection must be conducted either by the fumigator or by another party that subsequently provides the fumigator with a written declaration indicating that it is free from impervious surfaces or wrappings. The AQIS Wrapping and Perforation Standard To meet AQIS perforation requirements for fumigation impervious materials must contain not less than four (4) perforations of 6 mm diameter / 100 cm2 (10 cm x 10 cm square) or five (5) perforations of 5 mm diameter / 100 cm2. Plastic wraps containing numerous pinholes (at least 6 holes / cm2), frequently used for transportation of fruit and vegetables are also acceptable. Methyl bromide will, in general, only penetrate 100 mm from the surface into timber within the fumigation exposure period.
3.2.2 Untreated timber products must have at least one physical dimension which is less than 200 mm thick.
Timber products must be fumigated before any surface coating such as lacquering or paint is applied unless the product has at least one uncoated surface and a maximum thickness of 100 mm from the uncoated surface.
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MANDATORY
INFORMATIVE
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MANDATORY
INFORMATIVE
Thinly coated, woven materials allow too much gas to be lost and are unsuitable as fumigation sheets. Pool liners or annealed polypropylene sheets are also unsuitable as they allow methyl bromide to escape too rapidly.
4.1 Continued
4.1.3 The sheets must: Be free from any defects (for example faulty seams/welds, tears or holes); Have a permeability of less than 0.02 grams per square metre (of fumigation sheet) per 24 hours (multiplied by the dose in g/m). 4.1.4 Sheets must be positioned to create a gas-tight seal with the floor.
Sand or water snakes used to seal the junction of fumigation sheets and the floor must be overlapped and positioned to prevent fumigant leakage. See 5.4 Sand and water snake specifications
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MANDATORY
INFORMATIVE
To perform a pressure test, the pressure inside the closed container should be raised to 250 Pa using high-pressure compressed air supplied from a portable compressor or gas cylinder. As the pressure inside the container reaches 250 Pa, turn off the compressed air supply and: Allow the pressure to decay to 200 Pa; Start measuring the time (in seconds) when it reaches 200 Pa; Stop measuring the time (in seconds) when it reaches 100 Pa; Record the pressure decay time.
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MANDATORY
INFORMATIVE
Chamber fumigation refers to fumigation treatments performed inside specifically designed chambers or permanently situated containers adapted for this purpose. The following actions should occur before performing any chamber fumigation: Check that the chamber is not damaged and that there are no objects between the chamber and the chamber door to impair the seal; Visually inspect the door seals of the chamber and replace where necessary.
4.4.2 Monitoring tubes must be placed within the fumigation chamber. 4.4.3 Fumigant supply pipes must be placed within the fumigation chamber. 4.4.4 Fans must be placed within the fumigation chamber. 4.4.5 Where heating is required, a flashproof heater(s) must be placed within the fumigation enclosure.
NOTE The use of an exhaust fan will aid in the ventilation of the chamber.
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MANDATORY
INFORMATIVE
4.5 Safety
4.5.1 The fumigation enclosure and the surrounding area must be made safe for unprotected personnel.
A risk area must be set up with a minimum of 3 metres clearance around the sheeted fumigation enclosure in the open, or 6 metres clearance in an enclosed area, and warning signs put in place. The area must be cleared of any unprotected personnel, that is, personnel not wearing a respirator, and at no time during the fumigation treatment should unprotected personnel be allowed to enter the risk area. Respirators must be fitted with a correct gas cartridge and specified by the manufacturer as suitable for methyl bromide (AX filter type). Gas filter canisters should be used and replaced in accordance with the manufacturers instructions.
4.5.2 A full-face respirator or selfcontained breathing apparatus must be used when releasing fumigant and while working within the risk area after the fumigant has been released.
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MANDATORY
INFORMATIVE
as close to the centre of the commodity at the front base of the commodity.
TWO containers (in the one enclosure) must have one monitoring tube placed:
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MANDATORY
INFORMATIVE
Monitoring tube inlets should be at least 2 metres from the outlet of fumigant supply pipes.
5.2.2 Multiple containers under the one enclosure must have a fumigant supply pipe in each container.
Where multiple fumigant supply pipe systems are used, the entire system must be balanced in order to achieve even distribution throughout the enclosure. In order to balance the system, each arm of the system must consist of fumigant supply pipes that are equal in total length and diameter.
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MANDATORY
INFORMATIVE
5.3 Fans
5.3.1 Fans must be positioned to ensure that the fumigant is rapidly and effectively distributed throughout the fumigation enclosure. 5.3.2 For methyl bromide fumigation in small enclosures (such as freight containers), at least one fan must be used. For fumigation in larger enclosures, at least two fans must be used. 5.3.3 Where multiple containers are fumigated under the same sheets, fans must be placed in each container.
The fans must be switched on 10-15 minutes Where high velocity and high volume fans are used, they should not run for longer before the gas is introduced and for 30 minutes than 15 minutes after the introduction of the gas, as they may force the fumigant after the introduction of the methyl bromide, or out of the enclosure. until gas monitoring indicates that uniform gas distribution has been achieved. Fans should have a capacity to make at least 20 air changes an hour, taking into consideration the volume of the enclosure
Water snakes must be filled to only 75% - 85% If water snakes are used, the sheets should be weighed down and sealed using a of capacity so that they lie flat on the single, continuous water snake placed flush against the enclosure. Particular fumigation floor. attention should be given to ensure a complete seal where the ends of the water snake meet. Water snake placement should not start or end on a corner.
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MANDATORY
INFORMATIVE
CALCULATING THE DOSAGE OF FUMIGANT REQUIRED 6.1 Calculation of fumigation enclosure volume
6.1.1 The volume of a fumigation enclosure must be calculated from the measured dimensions.
When fumigating sheeted enclosures the measured external dimensions must be used Where an enclosed un-sheeted container or chamber is used for fumigation, the volume of any gas circulation equipment external to the chamber must be included in the calculation of the enclosure volume, together with the known internal volume of the container or chamber See APPENDIX 9: Calculating the volume of differently shaped fumigation enclosures. The volume of most freight containers is commonly found on the outside of the container, but this measurement can only be used if the container is not sheeted and has been satisfactorily pressure tested. See 4.3 Pressure testing requirements for un-sheeted containers.
6.2.2 Compensation must be applied to the dosage for fumigant mixtures containing less than 100% methyl bromide. 6.2.3 Compensation must be applied for temperatures below 21 C.
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MANDATORY
INFORMATIVE
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MANDATORY
INFORMATIVE
If all concentration levels cannot be achieved within 15% of the lowest reading (equilibrium) the fumigant should be redistributed by turning on the fan for a further period of time. Concentrations should then be measured to see if equilibrium has been reached. This process should be continued until either equilibrium is reached or when the levels drop below the standard. The fumigation cannot start if the fumigant levels drop below the standard concentration (A) as displayed in APPENDIX 11: Methyl Bromide Fumigation Ready Reckoner. If the cause can be identified and rectified without removing the sheet or losing excessive fumigant from the enclosure, the enclosure may be re-dosed and the fumigation process continued.
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MANDATORY
INFORMATIVE
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MANDATORY
INFORMATIVE
TABLE 2 : MONITORING TIMES Exposure period Less than 48 hours Start-point monitoring Take the first readings once it is reasonable to expect that equilibrium has been achieved.* Take the first readings once it is reasonable to expect that equilibrium has been achieved.* Mid-point monitoring Not required but may be undertaken 24 hours after start and as required. End-point monitoring End of exposure period
48 hours or more
* Equilibrium can be achieved quicker if: There is good free air space in the enclosure The are sufficient fans and they are positioned to best effect The methyl bromide is applied as a hot gas.
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MANDATORY
INFORMATIVE
The concentrations presented in the ready reckoner are based on the required percentage retention in the following table: TABLE 3: STANDARD CONCENTRATIONS REQUIRED AT SPECIFIC MONITORING TIMES
Monitoring times 0.5 hours 1 hours 2 hours 4 hours 12 hours 24 hours 48 hours
Concentration of original fumigant required 75% or more 70% or more 60% or more 50% or more 35% or more 30% or more 25% or more
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MANDATORY
8.3.2 Fumigant concentrations at all monitoring points must be within 15% of the lowest concentration at the start of the fumigation exposure period.
INFORMATIVE
If readings from the monitoring points are NOT within 15% of the lowest reading at start point, there may be a problem with: Inadequate fumigant distribution throughout the enclosure. Blockages in the monitoring tubes or other monitoring problems. Monitoring equipment (malfunction). Where the problem is identified as inadequate fumigant distribution, the fan(s) should be turned on and run for a further period of 15-30 minutes and the readings retaken. If fumigant levels are below the required standard concentrations at any time during the fumigation exposure period, in addition to the possible causes listed above, there may be a problem with: Fumigation sheets or fumigation floor. Gas-tight seals between sheets and floor. Highly sorptive commodity. Incorrect dosage. If the cause can be identified and rectified without removing the sheet or losing excessive fumigant from the enclosure, the fumigation can continue as normal so long as concentrations are equal to or above the standard concentrations (A) as set out in the Ready Reckoner. See Appendix 11 Methyl Bromide Fumigation Ready Reckoner. Additional fumigant may need to be added to top-up the concentration to a satisfactory level. Where the cause cannot be readily identified (particularly in smaller fumigation enclosures, such as containers) fumigation should be stopped and the fumigant ventilated from the enclosure. Once the area is safe (free of fumigant at levels hazardous to humans) the commodities and the enclosure should be inspected for possible causes.
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MANDATORY
INFORMATIVE
There are two options available for topping-up methyl bromide: Option 1 - Top-up Start-point and End-point monitoring with top-up option at the end. This option allows for topping-up the level of methyl bromide at the end of the fumigation period, but only in certain circumstances and only if fumigant concentration levels have been monitored according to TABLE 3. If the fumigant concentration falls below the standard concentration (A) but not below the minimum concentration (C) indicated in APPENDIX 11: Methyl Bromide Fumigation Ready Reckoner. The fumigant levels may be topped up to not more than the maximum top-up concentration (B). Option 2 - Top-up Continuous monitoring with top-up options. This option should be used when highly sorptive commodities have to be fumigated and the need for a top-up is indicated. Commodities considered to be highly sorptive to methyl bromide include: Fish Meals; Bone Meals; Corn Meals; Nuts; Seeds; Fats; Coffee Beans and commodities packed in polystyrene material. See APPENDIX 12: Examples of Top-up calculations.
8.4 Topping-up
8.4.1 Topping-up must only be undertaken when fumigant concentrations are above the minimum top-up level at all monitoring points. 8.4.2 Topping-up is not an option for fumigations of less than 12 hours.
When topping-up is done after the end point monitoring the exposure period must be extended for a further 4 hours and final monitoring readings must be taken and recorded. The top-up dosage must be applied in accordance with Section 7: Performing the fumigation. Topping-up is not an acceptable action solely to compensate for inadequate operational practices e.g. use of torn or unsuitable fumigation sheets. Topping-up must only be undertaken when fumigant concentrations are above the minimum concentration to allow top-up (B) at all monitoring points. Fumigant levels must not be topped-up above the maximum top-up concentration (C). In addition to the monitoring times in TABLE 2 monitoring must take place at intervals not greater than 6 hours apart throughout the fumigation period if it is suspected that the relevant final concentration will not be achieved. Monitoring at the set times must still be done.
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MANDATORY
INFORMATIVE
Commodities are tightly packed or sorptive; Free airspace around the commodity is less than a total of 350 mm. Before measuring TLV, the fumigator should switch off all fans being used for aeration of the fumigation enclosure. Where containers have been sheeted, the sheet must be fully removed prior to testing for TLV. Where containers have been fumigated, fumigant concentrations should be sampled from one or more representative points from within the fumigation enclosure. After taking the samples the fumigator will close the enclosure and leave the risk area. After 30 minutes of ventilation, the fumigator should reopen the enclosure and check the fumigant concentration inside the enclosure. If the concentration is less than or equal to 5 ppm, the enclosure may be declared safe. If concentrations of fumigant above 5 ppm are detected, the fumigator should leave the risk area, reventilate using fans or naturally ventilate the enclosure for a further period of time and recommence the TLV check procedure. This process should be repeated until all sections of the fumigation enclosure have been proved safe for re-entry. Note Commodities that have not been adequately ventilated threaten the health of people packing and inspecting fumigated commodities. A notice may be placed on the container stating: Due to possible desorption of fumigant from the commodities within this container, further ventilation may be necessary before the container is entered and the commodities removed
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MANDATORY
INFORMATIVE
Where there is no documentation showing that an enclosure or container has been ventilated, handlers should treat it as still under gas until it can be declared safe.
9.1 Continued
9.1.3 At the end of the fumigation exposure period, concentrations of methyl bromide in the fumigation enclosure, the air spaces of the treated commodity and the surrounding area must fall below the TLV.
Before any unprotected personnel are allowed access to a fumigation enclosure and risk area it must be declared free from hazardous levels of fumigant (at or below TLV). Before a fumigated container or commodity is released from the control of the fumigator, it must be declared free from hazardous levels of fumigant (at or below TLV) in air spaces of the commodity or packing material enclosing the commodity. Leak detection equipment must not be used for this purpose.
9.1.4 The equipment used for measuring methyl bromide concentrations in risk areas and post treatment clearance of enclosures must be fit for the purpose and capable of detecting concentrations of between 1 100 ppm v/v.
9.2 Certification
9.2.1 For offshore fumigations, fumigation providers must issue a certificate indicating the fumigation was successful and conformed to the AQIS standard. To support the claims made on the fumigation certificate, a Record of Fumigation sheet must also be completed on site and retained for audit purposes.
See APPENDIX 4: Example of a record of fumigation. See APPENDIX 5: Example of a fumigation certificate.
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FRESH FRUIT AND VEGETABLES, NURSERY STOCK AND FRESH CUT FLOWERS MANDATORY INFORMATIVE
If the plants are to remain in their original boxes or other packages, or are placed in other packages for fumigation, ensure that there is adequate ventilation by cutting holes or making numerous gaps in all sides of the packages.
1. General conditions
1.1 Impervious wrappings or bags without perforations must be removed or opened. 1.2 The consignment must be prepared and stacked to allow effective fumigant circulation. 1.3 Cartons, boxes and other receptacles used to transport fumigated perishable goods must also be fumigated.
See Sections 6.1 and Section 6.2 of the Standard See Section 8.3 of the Standard
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MANDATORY
INFORMATIVE
Some commodities require specific minimum temperatures, e.g. New Zealand strawberries 18 C. Where appropriate, the commodity may be warmed to meet the minimum temperature requirement.
Some perishable commodities (e.g. garlic and onions) release high amounts of carbon dioxide and this affects gas measurements of some instruments. It is particularly important to maintain the carbon dioxide and moisture absorbers fitted to instruments. Where batteries are used, they should be checked for working condition.
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MANDATORY
INFORMATIVE
Chloropicrin is phytotoxic and must not be used. See Section 1.5 of the Standard. Plants may be covered with single sheets of damp newspaper so that the gas is not circulated directly on to them. The fumigation of plants above 30 C should be avoided as plants may become stressed or damaged. Plants should not be wet, but roots should be moist to prevent damage. Low humidity during treatment may damage plants. Relative humidity in the fumigation enclosure should be held above 75% during fumigation. In the absence of water misters within the fumigation chamber, damp newspapers and shallow trays of water may also be placed on the floor of the fumigation chamber to help prevent plant desiccation. See Section 5.3 of the Standard. Excessive air currents during fumigation or the post-treatment aeration period aggravate injury. It is recommend that circulating and ventilating fans or blowers be operated for the minimum length of time required for distributing the fumigant evenly or for removing toxic concentrations after treatment. Alternatively, flowers can be removed from the cartons and placed upright in the fumigation enclosure. Some flowers, for example roses, may be imported with cardboard collars or plastic sleeves to prevent bruising during transport. These may be retracted or removed to allow effective gas circulation.
3.4 Fans must be used to disperse the fumigant throughout the enclosure. 3.5 Where the lids of cardboard boxes are not sufficiently vented, the boxes must be opened and stacked to allow adequate gas circulation.
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MANDATORY
INFORMATIVE
The original packing material may be used as long as it has been fumigated also.
4. Post fumigation
4.1 Fumigated plants must not be packed into plastic boxes or boxes lined with plastic.
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THESE REQUIREMENTS APPLY TO VESSELS UNDER TWENTY FIVE (25) METRES IN LENGTH AND MAY BE APPLIED TO LARGER NON-COMMERCIAL VESSELS THAT CAN BE EFFECTIVELY SEALED. IT IS NOT INTENDED TO BE APPLIED TO THE FUMIGATION OF CARGO VESSELS. MANDATORY INFORMATIVE
1. PRIOR TO FUMIGATION
1.1 An assessment must be made to determine if the vessel can be effectively fumigated. 1.2 Due to the complex nature of vessel
fumigations, a written plan for each fumigation must be submitted to AQIS for approval before fumigation commences. Timber components must not be covered or coated. See Section 3.2 of the Standard.
The fumigator must visit the vessel to assess how it will be prepared and fumigated. The written plan must contain the following information: Location of fumigation site How the vessel will be sealed/sheeted If the vessel is to be sealed, how it will be pressure tested The number and locations of fumigant supply pipes The number and location of fans The number and location of monitoring tubes The calculation of fumigant to be used and enclosure volume. See Section 6.1 of the Standard.
The plan can be presented as a diagram with locations of supply pipes, fans and monitoring tubes clearly indicated. The diagram does not have to be to scale, but needs to be legible and should indicate the fumigant enclosure volume accounting for volume reductions for any added fittings etc. Yacht dimensions are usually provided in the owners manual.
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THESE REQUIREMENTS APPLY TO VESSELS UNDER TWENTY FIVE (25) METRES IN LENGTH AND MAY BE APPLIED TO LARGER NON-COMMERCIAL VESSELS THAT CAN BE EFFECTIVELY SEALED. IT IS NOT INTENDED TO BE APPLIED TO THE FUMIGATION OF CARGO VESSELS.
2. FUMIGATION PROCEDURE
2.1 The fumigation site must be secured and a safety risk assessment must be undertaken.
If the vessel is to be fumigated on water, a risk area must be set up around the fumigation enclosure or moored vessel (3 metres if achievable) with warning signs visible from all sides of the vessel. See Section 5.4 of the Standard. Only authorised personnel are allowed within the risk area. The area must be cleared of any unprotected personnel, that is, personnel not wearing a respirator, and at no time during the fumigation should unprotected personnel be allowed to enter the risk area. Proximity to other vessels should be taken into consideration when fumigating. If the vessel to be fumigated is moored on a public jetty security personnel may be required. Permission to fumigate may be required from the relevant: 1. Harbour master 2. Marina/Jetty 3. Council 4. Waterways For containerised, dry dock, patent slip or flat rack fumigations refer to Section 2.1 and Section 2.2 of the Standard.
2.2 If the vessel is to be fumigated on water, weather conditions, such as sea and wind conditions for the following 24 hours must be taken into account.
If the vessel is to be fumigated on a flat rack, refer to Section 2.1 and Section 2.2 of the Standard. The weather conditions should be determined by checking with the Bureau of Meteorology to obtain the forecast applicable to the area where the fumigation will be performed.
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MANDATORY
INFORMATIVE
2. CONTINUED
2.3 If fumigating on water the sheeting of a vessel must be weighted and extend below the water to ensure an air tight seal (the sheet must be secure enough not to be affected by sea conditions).
It is preferable to sheet the entire vessel/container as per Section 4.1 of the Standard. Multiple vessels/containers may be fumigated under a single gas proof sheet. If the sheet is unable to enclose the mast or superstructure, a seal must be secured to prevent gas leakage Regardless of whether a vessel is sealed, containerized, individually sheeted or part of a multi-vessel fumigation, the fumigant supply pipe, fan and monitoring tube requirements in Section 5.1, Section 5.2 and Section 5.3 of the Standard apply. Water proof does not necessarily mean gas tight.
2.4 If a vessel cannot be entirely sheeted, all windows, doors, hatches, ventilation points, entry/exit points, etc. must be made gas tight.
Prior to every treatment, any items used for sealing the vessel must be visually inspected for tears, holes and abrasions, as these are a major contributing factor to significant gas loss. The entry/exit points for gas supply pipes and monitoring tubes must be made gas tight. The cabin or area to be treated must be sealed with tape. Any bung holes need to be sealed and all foam rubber, beds, etc. must be removed.
2.5 Sealed vessels must be pressure tested. 2.6 The vessels volume must be determined so that the correct amount of fumigant can be applied.
See Appendix 6: Pressure testing enclosures for gas tightness of the Standard.
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MANDATORY
INFORMATIVE
The size and design of a vessel will determine the number of fumigant supply pipes needed for effective fumigation. Single storey vessels: Single storey vessels are those with one accommodation deck with under-floor compartments that have a shared air space and a simple weather deck. Vessels with a distinct separate but simple wheelhouse on the upper deck could be treated as a single storey vessel. Vessels with one accommodation deck, but segregated by waterproof bulkheads broken into distinct spaces, may need to be treated separately.
2. Continued
2.7 Fumigant supply pipes must be positioned to allow fumigant to be introduced and circulated effectively throughout the vessel.
See Section 5.2 of the Standard. Minimum requirements for single storey vessels:
One pipe per vessel less than 15 metres in length. The line should be centrally located (e.g. mid-ship). Two pipes per vessel greater than 15 metres in length. One line should be placed forward and one aft.
2.8 Where multiple fumigant supply pipes are used, the entire system must be balanced in order to achieve even distribution throughout the enclosure.
One pipe per storey for vessels less than 15 metres in length. With due regard for internal lay out, the line should be centrally located (e.g. mid-ship). Two pipes per storey for vessels greater than 15 metres in length. With due regard for internal lay out, one line should be placed forward and one aft.
Multi-storey vessels: Multi-storey vessels are those that have separate floors/levels, including inhabitable levels. Vessels with a single storey that have storage and bilge areas under the floor should be treated as a single-storey vessel. Complex or unusual vessels will often have distinct sealed bulkheads and storage compartments (for example: patrol boats, fishing vessels and pack ice vessels). When fumigating these types of vessels, these requirements should be taken into account to determine fumigant supply pipe numbers and placement. In some cases, there will need to be a fan, a supply pipe and a monitoring tube in each separate compartment.
In order to balance the system, each arm of the system must consist of fumigant supply pipes that are equal in total length and diameter.
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MANDATORY
INFORMATIVE
Fans should run sequentially to assist with the movement of the fumigant from areas where it has been introduced to areas where no fumigant supply pipe is present. All doors and compartments should be opened to allow fans to be effective.
2. Continued
2.9 Fans must always be used in vessel fumigations.
There must be enough fans situated in appropriate locations throughout the vessel, with enough capacity to adequately and evenly distribute the fumigant. Fans are required for at least the first 30 minutes of the fumigation or until equilibrium and initial dose concentrations have been reached. See Section 5.3 and Section 7.2 of the Standard. Minimum requirements are: Single storey vessels: One fan per vessel for small single cabin area vessels (e.g. cabin cruisers). The fan must be located adjacent to an injection line. Two fans per vessel between 15 30 metres in length. One fan must be placed forward and one aft. Three fans per vessel greater than 30 metres in length. One fan must be placed forward, one mid-ship and one aft. Multi-storey vessels: Two fans per storey. One fan must be placed forward and one aft. The size and design of a vessel will determine the number of fans needed.
High velocity and high volume fans should not run for longer than 15 - 20 minutes after the introduction of the fumigant, as they may force the fumigant out of the enclosure.
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MANDATORY
INFORMATIVE
The size and design of a vessel will determine the number of monitoring tubes.
2. Continued
2.10 Vessels must have a minimum of three monitoring tubes per storey/level. 2.11 Inside the vessel, all monitoring tubes must be located at least 2 metres away from any fumigant supply pipes.
For fumigation under sheet, an additional monitoring tube must be placed outside the vessel, between the vessel and the sheet. Minimum requirements are: Single storey vessels: Three tubes per vessel. Each vessel must have one tube placed as follows: Ceiling level forward Mid-ship around 1.5 metres above the floor. At or below floor level aft. For vessels greater than 30 metres in length, four monitoring tubes are required. These are to be situated as above, with the additional placed mid-ship one in a cabin and one in a corridor, both around 1.5 metres above the floor. Multi-storey vessels: Three monitoring tubes per storey. Each storey must have one tube placed as follows: Ceiling level forward Mid-ship around 1.5 metres above the floor Below floor level aft (If it is not possible to place the tube below floor level it must be placed at floor level).
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MANDATORY
INFORMATIVE
2. Continued
2.12 Dosage and Temperature
See Section 1.4 of the Standard. See Section 1.5 of the Standard. See Section 6.2 of the Standard. See Section 8.3 of the Standard. See Section 8.4 of the Standard. See Section 7.3 of the Standard. See Section 8.1 of the Standard. See Section 9.1 of the Standard.
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APPENDIX 3: Commodities for which problems may occur when fumigated with methyl bromide
Commodity 1. Foodstuffs: a. Butter, lard and fats; b. Iodised salt stabilised with sodium hyposulphite; c. Full fat soybean flour, whole wheat flour, other high protein flours and baking powders; d. Nuts with high oil content; e. Certain baking sodas, cattle licks, salt blocks, or other foodstuffs containing reactive sulphur compounds; f. Bone meal. 2. Leather Goods 3. Woollens Notes Never exceed the recommended dosage or exposure periods for food or foodstuff commodities. Foods imported into Australia or manufactured in Australia must comply with the Food Standards Code www.foodstandards.gov.au.
4. 5. 6.
Viscose rayon
Photographic chemicals Paper: a. Silver polishing papers; b. Certain writing and other papers cured by sulphide processes; c. Photographic prints; d. Carbonless carbon paper; e. Blueprint papers. 7. Rubber Goods: a. Sponge rubber; b. Foam rubber, such as rug padding, pillows, cushions, mattresses, and some car seals; c. Rubber stamps and other similar forms of reclaimed rubber. 8. Vinyl 9. Furs Feathers Rug Padding Charcoal, cinder blocks and activated carbon Horsehair articles Oil artworks Sulphur-based paint Cellophane Polystyrene packaging and containers
Particularly kid or other leather goods tanned with sulphur processes. Extreme caution should be used in the fumigation of Angora woollens. Some adverse effects have been noted on woollen socks, sweaters, shawls and yarn. Rayons processed or manufactured with the use of carbon bisulfide. Excluding camera film or X-ray film.
Polystyrene can absorb large quantities of methyl bromide, which may take a long time to desorb.
Declaration The AFAS accredited fumigator (or accredited officer if the certificate is endorsed by the relevant regulatory authority) responsible for ensuring that the treatment is effective and performed according to the requirements of the AQIS Methyl Bromide Fumigation Standard must sign and date the certificate and print their name and accreditation number. They may also wish to stamp the certificate with their company stamp. Additional Information Any additional information that the fumigator wishes to supply may be included in the Additional Declarations field. False declarations may result in AFAS accreditation being revoked.
A purpose made instrument, the CONTESTOR, which combines a pressure sensor with a timer that cuts in when the required pressures have been achieved.
NOTE AQIS considers containers that give a pressure decay time from 200 to 100 Pascals of 10 seconds or more to be gas-tight. Such containers may be fumigated with methyl bromide without enclosing them under gas proof sheets. Where the pressure decay time does not meet the minimum requirements, the container must be enclosed in gas proof sheets.
FIGURE 1 FINGER MANIFOLD FOR DELIVERING HIGH PRESSURE COMPRESSED AIR INTO A CONTAINER AND MEASURING THE PRESSURE INSIDE THE CONTAINER.
The finger manifold is designed to deliver compressed air into a container, pressurise it and allow the pressure decay to be measured. The manifold (illustrated above) has twelve fingers, nine of which deliver compressed air into the container, while three measure the pressure within it. The fingers are made of soft copper tubing that can be bent to shape as necessary. The manifold can be bent to fit either over the front of the sill or between the vertical door seal. In either case sealant is applied between the fingers of the manifold and door seals and removed after the pressure test has been completed.
FIGURE 2. TECHNICAL DRAWING OF THE FINGER MANIFOLD FOR PRESSURE TESTING FREIGHT CONTAINERS.
One container in one enclosure Three gas monitoring points (1) Top back (2) Middle centre (3) Front base
Two containers in one enclosure Three gas monitoring points One top centre of the commodity in each container, one front base of either container
Three or more containers in one enclosure One gas monitoring point at the top centre of the commodity in each container
a
a b
Vaporiser
Vaporiser
Vaporiser
Complex systems All splits must contain pipes of equal length and diameter a+c+c = b+d+d
Gassing pipes of unequal length or diameter Apply equal quantity through each tap in turn
Complex Systems
These examples demonstrate possible methods of creating balanced systems for distribution of fumigant gas. Multiple manifold systems are the most adaptable, allow for quick, safe and effective fumigation and are recommended.
Vaporiser
Vaporiser
Gassing pipes of unequal length or diameter Pipes connected individually and equal quantities of gas dispensed
Gassing pipes of equal length and diameter Pipes connected to manifold and total quantity of gas dispensed
Shape 1 H
Shape 2 H
D D D
The internal volume of a fumigation enclosure can be calculated by adding up the volume of its parts where: L = Length R = Radius (Diameter/2) (Pi) = 3.142 Volumes are: Shape 1 (triangular prism): Shape 2 (rectangular prism): Shape 3 (dome): Shape 4 (cone): Shape 5 (cylinder): 1/2(L x W x H) LxWxH 2/3( x R x R x R) 1/3( x R x R x H) W = Width D = Diameter (Radiusx2) H = Height
(R x R) x H
5 m min
5 m min
5 m min
6 mm ID
9 mm ID
12 mm ID
The lengths of tubing must be carefully joined in a manner that is completely gas-tight. Suitable connectors should be fitted to the inlet and outlet to meet the requirements of the gas inlet and outlet pipes. This instruction shows the use of a manifold with four outlet taps that easily allow for a balanced system to fumigate up to four or more containers at the same time, ensuring that the same amount of gas is introduced to each. The manifold should be constructed from 19 mm to 24 mm tubing, with suitable gas taps and outlets fitted. The tubing should be coiled as tightly as possible to allow for the coil to fit into a suitable water container. The inlet and outlet ends should be positioned above the top segment of the coil so that they are clear of the water bath (see Diagram 2).
Fittings
The choice of fittings for both inlet and outlet will depend on the individual and the equipment used. Support cowling Gas burner However it is strongly recommended that good quality, gas rated fittings are used. Threaded fittings on all gas piping is strongly recommended, rather than relying on hose clamps to hold piping in place on bare copper tubing.
Diagram 2
Chart 1 graphically shows what should happen to methyl bromide levels during a well-sealed, sheeted fumigation, based on the values in Table 3. and an initial dosage of 48g/m3. Also shown are the boundaries around the standard concentration, below which the fumigation will not be acceptable. The middle line (standard concentration represents the theoretical progress of a fumigation treatment in a well-sealed sheeted fumigation enclosure. The middle line is the AQIS STANDARD CONCENTRATION (value A in the Methyl Bromide Fumigation Ready Reckoner). The lower boundary is the Minimum concentration to allow top-up (value B in the Methyl Bromide Fumigation Ready Reckoner). The upper boundary is the Maximum top-up concentration (value C in the Methyl Bromide Fumigation Ready Reckoner). If the methyl bromide concentration falls below the minimum concentration then the fumigation has failed and a TOP-UP MAY NOT BE CARRIED OUT.
Fumigation has been carried out, applying methyl bromide at 48 g/m3. At 24 hours the lowest fumigant concentration at the monitor points is 12 g/m3.
14.4
9.4
12 g/m3 is below the AQIS Standard for 48 g/m3 at 24 hours (14.4 g/m3, as shown, centre figure) but above the Minimum Concentration to allow top-up (9.4 g/m3 as shown, bottom right figure). The AQIS Standard allows for the fumigant concentration to be topped-up to the Maximum Top-Up Concentration (19.4 g/m3 as shown, top left figure).
48 g/m3 @ 24 hours
To determine the amount of fumigant to be added to the enclosure, subtract the lowest concentration from the maximum top up value, as shown below:
Fumigation has been carried out, applying methyl bromide at 48 g/m3. At 12 hours the lowest fumigant concentration on the monitor tubes is 17 g/m3.
16.8
11.8
It is suspected that fumigant levels may drop below standard by the end of the fumigation and a decision to top-up is made. The AQIS Standard allows for the fumigant concentration to be topped-up to the Maximum Top-Up Concentration (21.8 g/m3 as shown, top left figure).
48 g/m @ 12 hours
To determine the amount of fumigant to be added to the enclosure, subtract the lowest concentration from the maximum top up value, as shown below:
NOTE In some situations the chloropicrin may condense and pool, increasing the health and safety hazards associated with the use of methyl bromide.
Any timber components used in construction or fittings of the yacht e.g. railings, non-slip strips on deck.
Empty space between, above or around a commodity to allow the fumigant access to the commodity to eradicate pests. A chemical, which at a particular temperature and pressure can exist in a gaseous state in sufficient concentration and for sufficient time to be lethal to insects and other pests. A relatively large diameter pipe used to supply fumigant to a fumigation enclosure. Application of a fumigant to a fumigation enclosure to eradicate pests. Documentation certifying that a fumigation treatment has been undertaken in compliance with AQIS requirements. A permanent chamber used for fumigation purposes that meets the AQIS pressure test requirements. Any space or area designed to contain fumigant for the purposes of fumigation. Examples include gas-tight containers, gas-proof sheets sealed to an impermeable floor with sand or water snakes, and purpose built structures. Gas impervious material (generally made from vinyl, coated nylon or polyethylene) capable of creating a temporary fumigation enclosure (also known as tarps or tarpaulins). At the start of fumigation, where the gas concentration at each monitoring point is within 15% of the lowest reading. AQIS only accepts that a fumigation exposure has started AFTER it has been demonstrated that equilibrium has been achieved and concentrations at all monitoring points are at or above the standard. Any timber items found inside the yacht e.g. wooden fittings, floors, drawers and panels. A relatively small diameter tube used to withdraw a sample of gas/air mixture from within a fumigation enclosure for measuring fumigant concentration. Standard, natural atmospheric (air) pressure (105 Pa). A platform used to support commodities during shipment generally of standard dimensions to allow for easy stacking. Pallets used in shipping are generally made of timber, plywood, metal, plastic or moulded fibreboard.
Fumigant supply pipe Fumigation Fumigation certificate Fumigation chamber Fumigation enclosure
Fumigation sheets
Gas equilibrium
Term Term Patent slip Perishable commodities Permeability Pest Phytotoxic Quarantine pest
Definition Definition Moveable cradle that is able to slide under the vessels keel in the water, then transport the vessel beyond the high tide mark to a work area. Cut flowers, fresh fruit, vegetables and nursery stock. The rate at which a substance (such as methyl bromide) flows through a material (such as a fumigation sheet). Any animal, plant or other organism that may pose a threat to the community or the natural environment. Poisonous to plants. A pest of potential economic and/or environmental importance to an area where it is not yet present, or is present but not widely distributed and is being officially controlled. Any area in proximity to a fumigation enclosure into which fumigant may escape in hazardous concentrations as determined by local legislation relevant to fumigation practice in the location in which the treatment is performed. May also be referred to as danger area. Sand filled tubes approximately 1 metre long used as weights to hold fumigation sheets in place during fumigation. Yacht or vessel that may be effectively sealed to retain gas pressure as per the AQIS pressure testing requirements (see Section 4.2, 4.3 and Appendix 5). A process of creating a gas-tight enclosure by covering/enclosing the commodities to be fumigated under a gas proof sheet, which is sealed to an impermeable floor (generally using sand or water snakes). Yacht or vessel that has been covered by a fumigation sheet that meets AQIS requirements (see Section 4 and 5, Sheet fumigation). The uptake of a fumigant by any material being treated with a fumigant. This may be reversible (unchanged fumigant may be released on ventilating) or irreversible (leading to residues of fumigant or breakdown of products in the commodity). TLV is the maximum concentration of fumigant that a worker can be repeatedly exposed to in the workplace without harmful effects. This figure is based on an 8 hour day, 40 hour working week and is currently 5ppm in Australia. A term of commerce for wood, either as logs or sawn units. Term used to describe container(s) that do not have documentation that states that the container has been ventilated to TLV (5ppm in Australia). See gas equilibrium. Water filled tubes used as weights to seal fumigation sheets to the floor. These perform the same function as sand snakes. Water snakes are much longer and wider than sand snakes. Non-commercial vessels of any dimension for private use, either powered or under sail.
Risk area
Threshold Limit Value (TLV) Timber (also known as lumber) Under gas Uniform gas distribution Water snakes
Yachts