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    Amine Value

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    iqbalpec8721
    This document provides a procedure for determining the epoxide equivalent of epoxy resins and the amine value of polyamide resins. It involves titrating samples of the resins with a standardized hydrobromic acid (HBr) solution. The epoxide equivalent is calculated based on the weight of the epoxy sample and the volume and normality of HBr used. The amine value is calculated based on the weight of the polyamide sample and the volume and normality of HBr used. The endpoint colors for titrating epoxy and polyamide samples differ. Archived versions of the procedure are also available.

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    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd

    Amine Value

    Uploaded by

    iqbalpec8721
    4K views3 pages
    This document provides a procedure for determining the epoxide equivalent of epoxy resins and the amine value of polyamide resins. It involves titrating samples of the resins with a standardized hydrobromic acid (HBr) solution. The epoxide equivalent is calculated based on the weight of the epoxy sample and the volume and normality of HBr used. The amine value is calculated based on the weight of the polyamide sample and the volume and normality of HBr used. The endpoint colors for titrating epoxy and polyamide samples differ. Archived versions of the procedure are also available.

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    © Attribution Non-Commercial (BY-NC)

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    This document provides a procedure for determining the epoxide equivalent of epoxy resins and the amine value of polyamide resins. It involves titrating samples of the resins with a standardized hydrobromic acid (HBr) solution. The epoxide equivalent is calculated based on the weight of the epoxy sample and the volume and normality of HBr used. The amine value is calculated based on the weight of the polyamide sample and the volume and normality of HBr used. The endpoint colors for titrating epoxy and polyamide samples differ. Archived versions of the procedure are also available.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    4K views3 pages

    Amine Value

    Uploaded by

    iqbalpec8721
    This document provides a procedure for determining the epoxide equivalent of epoxy resins and the amine value of polyamide resins. It involves titrating samples of the resins with a standardized hydrobromic acid (HBr) solution. The epoxide equivalent is calculated based on the weight of the epoxy sample and the volume and normality of HBr used. The amine value is calculated based on the weight of the polyamide sample and the volume and normality of HBr used. The endpoint colors for titrating epoxy and polyamide samples differ. Archived versions of the procedure are also available.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    DETERMINING EPOXIDE EQUIVALENT AND AMINE VALUE OF RESINS

    TXDOT DESIGNATION: TEX-815-B

    Test Procedure for

    DETERMINING EPOXIDE EQUIVALENT AND AMINE VALUE OF RESINS


    TxDOT Designation: Tex-815-B
    Effective Date: May 2000

    Texas Department of Transportation

    1.
    1.1 1.2 1.3

    SCOPE
    Use this method to determine the epoxide equivalent for epoxy resins and the amine value for polyamide resins. Reference ASTM D 1652 and D 2074 (modified by D-9-J). The values given in parentheses (if provided) are not standard and may not be exact mathematical conversions. Use each system of units separately. Combining values from the two systems may result in nonconformance with the standard.

    2.
    2.1 2.2

    APPARATUS
    Buret, 25 ml (0.85 fl. oz.), for titration. Erlenmeyer flasks, 50 ml (1.7 fl. oz.), with stoppers. two for duplicate titration used in standardization of HBr solution two for duplicate titration used for each sample of epoxy or polyamide resin.

    3.
    3.1 3.2 3.3 3.4 3.5

    MATERIALS
    Hydrobromic Acid (HBr), 47-49%, reagent grade. Acetic acid, glacial, reagent grade Potassium acid phthalate (Pht), reagent grade. Methyl violet indicator, 0.1 g in 100 ml (3.4 fl. oz.) glacial acetic acid. Methyl isobutylketone (MIBK), reagent grade. Note 1The presence of water at any time in this procedure will invalidate the results. Cloudiness in the sample or test solutions indicates the presence of water.

    CONSTRUCTION DIVISION

    13

    EFFECTIVE DATE: MAY 2000

    DETERMINING EPOXIDE EQUIVALENT AND AMINE VALUE OF RESINS

    TXDOT DESIGNATION: TEX-815-B

    4.
    4.1 4.1.1 4.1.2 4.1.3 4.1.4 4.1.4.1 4.1.4.2 4.2 4.2.1

    PROCEDURES
    Standardizing Titrant: Prepare the 0.1 N HBr in glacial acetic acid by adding 8 g of hydrobromic acid to 500 ml (16.9 fl. oz.) of acetic acid. Analytically weigh 0.4 0.005 g of potassium acid phthalate into a 50 ml (1.7 fl. oz.) Erlenmeyer flask. Weigh a duplicate. Add 10 ml (0.33 fl. oz.) of glacial acetic acid to each sample and heat gently to dissolve the phthalate. Titrate the sample, using approximately 12.5 ml (0.42 fl. oz.) of the 0.1 N HBr solution, to a green color using two to three drops of methyl violet indicator (See Section 5). Use the same amount of indicator for each sample because of the small amount of solvent. The solution will change from purple to dark, then light blue until obtaining the green color. The final color change is obvious. Determining Epoxy Equivalent or Amine Value: Analytically weigh 1.0 0.001 g of the 75% solids epoxy, 0.4 0.001 g 100% solids epoxy, or 0.4 0.001 g of the 70% solids polyamide sample into a 100 ml (3.4 fl. oz.) beaker (0.75 or 0.35 g for a 100% solids sample). Use a quantity of sample that will yield 0.001 to 0.002 g equivalents of epoxy groups (See Section 5). Also run a duplicate sample. Dissolve the samples in 10 ml (0.35 fl. oz.) of MIBK acid. Just prior to titration, add 10 ml (0.35 fl. oz.) glacial acetic acid to the sample, and titrate with the standardized HBr to the same color as the standards. The endpoint for the amine value is not the same as for the epoxide procedure. The amine value solution turns milky, then green.

    4.2.1.1 4.2.1.2 4.2.2

    5.
    5.1

    CALCULATIONS
    Calculate the normality of the HBr solution:

    Normality of HBr Solution =

    Weight of Pht 1000 204.2 mL of HBr

    CONSTRUCTION DIVISION

    23

    EFFECTIVE DATE: MAY 2000

    DETERMINING EPOXIDE EQUIVALENT AND AMINE VALUE OF RESINS

    TXDOT DESIGNATION: TEX-815-B

    5.2

    Calculate the epoxy equivalent of epoxy resins:

    Epoxy Equivalent = 1000


    5.3

    Weight of Sample % NVM (fraction) Normality of Hbr mL of Hbr

    Calculate the amine value of polyamide resins:

    Amine Value =

    mL of HBr Normality of HBr 56.1 Weight of Polyamide % NVM (fraction)

    6.
    6.1

    ARCHIVED VERSIONS
    Archived versions are available.

    CONSTRUCTION DIVISION

    33

    EFFECTIVE DATE: MAY 2000

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